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Sample Paper 5
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PART A: CHEMISTRY
1.
An aqueous solution containing 5.0 gm of horse haemoglobin in 1 litre of water shows an osmotic
pressure of 1.80 103 atm at 298 K. What is the molecular weight of horse haemoglobin ?
(a) 6800
2.
(b) 34000
(a) 9.26
4.
C6H5NH2 + H+
(b) 9.73
(c) 4.27
(d) 4.74
3
O2(g)
O3(g)
2
what will be the standard entropy change in the formation of ozone at 298 K ?
(Given S0(O3 ) = 56.8 cal/mole-deg and S0(O2 ) = 49 cal/mole-deg)
For the following reaction,
K2Cr2O7 is preferred to Na2Cr2O7 for the use in volumetric analysis (titrations) because
(a) K2Cr2O7 is hygroscopic
+
(d) 3400
100 ml of 0.1 M C6H5NH2 solution is mixed with 75 ml of 0.1 N HCl solution, what will be the
pH of resulting solution (mixture) ?
Given that pKa is 4.74 for C6H5 N H3
3.
(c) 68000
6.
Regarding the energy of the 3d-electron in the sodium atom and 3d-electron in a hydrogen atom,
which statement is correct ?
(a) In case of sodium atom it is much high than that of hydrogen atom.
(b) In case of sodium atom it is much less than that of hydrogen atom
(c) Nearly the same
(d) In case of hydrogen atom, electron cannot excited.
7.
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8.
At 55C, ethanol has a vapour pressure of 168 mm, and the vapour pressure of methyl
cyclohexane is 280 mm. A solution of the two, in which the mole fraction of ethanol is
approximately double as that of methyl cyclohexane, has a total vapour pressure of 376 mm at
550C. This solution formed from its components
(a) with the evolution of heat
(b) with the absorption of heat
(c) may be with the evolution of heat or absorption of heat
(d) H = 0
9.
10.
An ion Mn+ (molar mass = 30) discharged at cathode according to the following reaction
CO2 + M
Mn+ + C2 O 24
10 ml of 0.1 M solution of M is converted into Mn+ by 20 ml of 0.03 M solution of KMnO4 in
acidic medium. What weight of M can be produced when 3 ampere current is passed through
the solution for 9.65 hours.
(a) 1.08 g
(b) 10.8 g
(c) 108 g
(d) 32.4 g
11.
For the complex ion [Cr(H2O)6]3+, the hybridization and magnetic nature are respectively.
(b) d2sp3, paramagnetic
(a) sp3d2, paramagnetic
(d) d2sp3, diamagnetic
(c) sp3d2, diamagnetic
12.
Nitramide, O2NNH2, decomposes slowly in aqueous solution according to the following reaction
O2NNH2
N2O + H2O
The experimental rate law is
d [ N 2O ]
[O NNH ]
=k 2 + 2
[H ]
dt
Which of the following step is not appropriate for the mechanism of above reaction ?
(a) O2NNH2
k1
kb
O2NNH + H+ (fast)
k1
(b) O2NNH
N2O + OH
(c) H+ + O2NNH2
kf
kb
O2NNH3+ (fast)
k2
(d) H+ + OH
H2O
(slow)
(fast)
Page2
AglaSem Admission
13.
In which case the solubility of the solute decreases as the temperature increases?
(b) KNO3 in H2O
(a) Na2SO4 in H2O
(d) KCl in H2O
(c) NaCl in H2O
14.
N2O4 + H2O
A + B
B
C + NO + H2O
C + H2O
A + B
Identify B and C (respectively)
(a) HNO3, N2O
(c) HNO2, NO2
15.
16.
In Bessemer and Thomas processes of extraction of iron, lining of the convertor may damages due
to presence of
(a) Phosphorus
(b) C
(c) CO
(d) Mn
17.
18.
The values of Ksp of following sparingly soluble salts Ni(OH)2, Ce(OH)4, AgCN and Al2(SO4)3
are respectively 2 1015, 4 1035, 6 1017 and 3.2 1034.
Which salt is most soluble?
(a) Ni(OH)2
(b) Ce(OH)4
(c) Al2(SO4)3
(d) AgCN
19.
A tetrahedral site in a closest packed lattice can be generated by placing four spheres of radius R
at alternate corners of the cube. What is the length of the body diagonal of this cube ?
(a)
20.
6R
(c) 2 2R
(b) 2R
Page3
(d) 3R
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21.
22.
24.
(b) NO +2
(c) Na+
(d) R+
H(A)
(B)H
R
CH
C
O
CH2
OH
Slow
Which is correct ?
(a) A is more reactive than B
(c) both are of same reactivity
25.
(d) 4
23.
(c) 0
H 2 SO4
(a) CO2
(c) CH4
(d) C H 3
26.
27.
28.
In the extraction process of aluminium from bauxite ore, aluminium hydroxide is precipitated
from the strongly alkaline aluminate solution, by bubbling in some CO2. The function of CO2
(a) to increases the pH
(b) to decrease the pH
(c) to remove waste material like ironoxide
(d) CO2 has no effect in above process
Which of the following is not aromatic ?
(a)
(b)
(c)
(d)
..
N
H
N
..
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29.
30.
PART B: PHYSICS
31.
The acceleration a (in ms2) of a body, starting from rest varies with time t (in s) according to the
relation a = 3t + 4
The velocity of the body at time t = 2s will be
(a) 10 ms1
32.
(c) 14 ms1
(d) 16 ms1
Light of wavelength 4500Ao in air is incident on a plane boundary between air and another
medium at an angle 30o with the plane of boundary. As it enters from air into the other medium it
deviates by 15o towards normal. Find the wavelength of given light in the medium
(a) 3700Ao
33.
(b) 12 ms1
(b) 3800Ao
(c) 3674Ao
(d) 3895Ao
F = 200 N
M = 10kg
30
= 0.5
34.
v = 50 m/sec
50 m
(c) 1 rad/sec
(d) None
35.
A particle is projected with 40 m/sec making angle 60 from horizontal radius of curvature when
it will make angle 30 from horizontal
(a)
36.
32
3 3
(b)
32
3
(c)
32 3
3
(d) None
A magnet makes 30 oscillations per minute at a place where H = 0.15 104 T. At another place,
it takes 1.5 second to complete one vibration. What is the value of earths horizontal field at that
place ?
(b) 0.26 105T
(c) 0.26 106 T
(d) 0.26 107 T
(a) 0.26 104 T
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AglaSem Admission
37.
An satellite of mass m, is orbiting around the earth at a distance r from centre of earth, if it
stopped suddenly the loss in total energy will be
(a)
38.
GMm
2r
(b)
GMm
r
(c)
GMm
2r
(d) None
F
F
3
2F
(c)
3
(a)
(b) zero
(d) None
39.
Two identical capacitors, have the same capacitance C. One of them is charged to potential V1
and the other to V2. The negative ends of the capacitors are connected together. When the positive
ends are also connected, the decrease in energy of the combined system is
1
1
1
1
(b) C(V12 + V22 )
(c) C(V1 V2 ) 2
(d) C(V1 + V2 ) 2
(a) C(V12 V22 )
4
4
4
4
40.
20
(a)
9
11
(c)
5
41.
9
(b)
2
3
B
(d) None
10V
B
1A
3
20V
5A
C
42.
1F
1
1
(b) 6 sec
(c) 3 sec
(d) 1 sec
S
E
43.
2atm
(b) 100 J
(d) 100 J
P
1atm
(1 10 -3 )
V
Page6
(2 10 -3 )m3
AglaSem Admission
44.
45.
46.
C=2.5mF
(c) 0.15 KJ
(d) 0.10 KJ
(c) 1.4
E1 = 10 0V
S
R2 = 20
a b
R1 = 10
E2 = 20 0V
47.
The work function of a substance is 4.0 eV. The longest wavelength of light that can cause
photoelectron emission from this substance is approximately
(b) 400 nm
(a) 540 nm
(d) 220 nm
(c) 310 nm
48.
49.
(b) 0.02
(d) 0.04
If radius of earth were to shrink by one percent, its mass remaining same, the acceleration due to
gravity on the earths surface would
(a) Decrease
(b) Remain unchanged
(c) Increase
(d) Be zero
Page7
AglaSem Admission
50.
Spring man system is placed on smooth horizontal surface. Initially system is equilibrium man m2
is given v1 = 10 m/sec and m1 is given 5 m/sec velocity of centre of man will be
m1= 10kg
m2= 5kg
5m/sec
(a)
51.
10
m/sec
3
v1= 10m/sec
(b) 5 m/sec
(c) zero
(d) None
3
Box-1
(a) 5A
5A
(b) 3A
(c) 4A
I2
(d) None
Box-2
~
V,fHz
52.
53.
54.
P
A symmetrical square lamina of mass M has uniform semi-circular
plates attached to it on its four sides as shown in the figure. Each
A
B
plate has the same mass M, and the side of a square is equal to a.
The moment of inertia of the system about an axis passing through
O
S
Q
the centre O, perpendicular to the plane of the lamina is
13
25
Ma 2
Ma 2
(b)
(a)
D
C
6
12
25
Ma 2
(d) none of these
(c)
R
6
A metal ball immersed in alcohol weighs W1 at 0C and W2 at 70C. The coefficient of cubical
expansion of the metal is less than that of alcohol. Assuming that the density of the metal is large
compared to that of alcohol, it can be shown that
(b) W1 = W2
(c) W1 < W2
(d) W1 = (W2 / 2)
(a) W1 > W2
A hydrogen atom in ground state absorbs 10.2 eV of energy. The orbital angular momentum of
electrons is increased by
55.
A convex lens of focal length f is placed between an object and screen. Distance between object
and screen is 15 cm. If magnification produced by lens is 3, then the focal length f is
(a)
45
cm
16
(b)
45
cm
4
(c) 80 cm
Page8
(d) 20 cm
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56.
An electron in a hydrogen atom makes a transition from n1 to n2. The time period of the electron
in the initial state is eight times that in the final state. The possible value of n1 and n2 are
(a) n1 = 6, n2 = 4
(c) n1 = 8, n2 = 1
57.
Cp
undergoes a reversible adiabatic compression. If U , p,V .T represent the internal energy, pressure,
volume and temperature respectively of the ideal gas, then
(a) UV = const.
(b) Up = const.
An
ideal
(c) VU
58.
59.
60.
(b) n1 = 8, n2 = 2
(d) n1 = 6, n2 = 3
1
1
gas
(d) TU 1 = const.
= const.
N
Denser
medium
Rarer
D
r
Medium
90
The wavelength of characteristic X-ray K line emitted by hydrogen like atom is 0.32 . The
wavelength of K line emitted by the same element is
(a) 0.18
(b) 0.48
(c) 0.27
(d) 0.38
When two moles of monoatomic gas expands the ratio of the heat supplied that increases the
internal energy of the gas and that used in the expansion is
(a)
(b) 0
(c) 3/2
(d) 2/3
PART C: MATHEMATICS
61.
If the function f, g, h are defined from the sets of real numbers R to R such that f(x) = x2 1,
0 if x 0
g(x) = x 2 + 1 , h(x) =
, then the composite function hofog(x) = ?
x if x 0
0, x = 0
(a) x 2 , x > 0
2
x , x < 0
62.
0, x 0
(c) 2
x , x 0
(c) | z + z |= 2
0, x = 0
(b) 2
x , x 0
(b) z + z = 22
Page9
AglaSem Admission
63.
Let
R = {(x, y) : x, y R, x2 + y2 25}
4
64.
65.
1 1
1
, and . The probability that the problem will be solved at least by one is
2 3
4
1
1
23
3
(b)
(c)
(d)
(a)
4
24
34
4
66.
67.
68.
If A, B and C are three square matrices of the same size such that B = CAC1, then CA3C1 is
equal to
(a) B
(b) B2
(d) B9
(c) B3
69.
For all x R, if mx2 9mx + (5m + 1) > 0, then m lies in the interval.
70.
4
4 61
4
61
(b) 0,
(a) ,0
(c) ,
(d) ,0
61
61
61 4
4
2
2
If minimum value of f(x) = (x + 2bx + 2c ) is greater than the maximum value of
g(x) = x2 2cx + b2, then (x R)
|b|
|c|
(b)
>| b |
(a) | c |>
3
2
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AglaSem Admission
71.
72.
73.
74.
(x 2 1)dx
(x 2 + x + 1)(x 2 + x + 1)
is equal to
x 2 + x + 1 + x 2 + x + 1
+c
(a) log
x
x 2 + x + 1 x 2 + x + 1
+c
(b) 2log
x
(c) log x 2 + x + 1 x 2 + x + 1 + c
If is the angle subtended by the circle S = x2 + y2 + 2gx + 2fy + c = 0 at a point (x1, y1) outside
the circle and S1 = x12 + y12 + 2gx1 + 2fy1 + c, then cos = ?
(a)
S1 + c g 2 f 2
S1 c + g 2 + f 2
(b)
S1 + c + g 2 f 2
S1 c + g 2 f 2
(c)
S1 c + g 2 + f 2
S1 + c g 2 + f 2
(d)
S1 c + g 2 + f 2
S1 + c + g 2 f 2
(d) 99
a, b, c are in A.P.
p, q, r are in H.P.
p r
ap, bq, cr are in G.P. then + is equal to
r p
a c
a c
b q
(b)
(c) +
(a) +
c a
c a
q b
and
75.
76.
77.
x 2 dx
If 2
then the value of
=
2
2
2
2
2
2(a + b)(b + c)(c + a)
0 (x + a )(x + b )(x + c )
(a)
b a
q p
The function f(x) = p[x + 1] + q[x 1], where [x] is the greatest integer function is continuous at x
= 1, if
(a) p q = 0
(b) p + q = 0
(c) p = 0
(d) q = 0
2
If f (x) = g(x) (x a) , where g(1) 0 and g(x) is continuous at x = a, then
(a) f is increasing in the nbd of a if g(1) > 0 and f is decreasing in the nbd of a if g(1) < 0
(b) f is increasing in the nbd of a if g(1) < 0
(c) f is decreasing in the nbd of a if g(1) > 0
(d) f is increasing in the nbd of a if g(1) < 0 and f is decreasing in the nbd of a if g(1) > 0
4
Rolles Theorem holds for the function f(x) = x3 + bx2 + cx, 1 x 2 at the point , the value of
3
b and c are
(c) b = 5, c = 8
(a) b = 8, c = 5
(b) b = 5, c = 8
(d) b = 5, c = 8
78.
(d)
60
(b)
20
40
(c)
Page11
dx
(x 2 + 4)(x 2 + 9)
0
(d)
80
is
AglaSem Admission
79.
x
x
y
x
, then is
+ , the general solution is y =
log | cx |
x
y
y
given by
(a)
80.
81.
x2
y2
(b)
y2
x2
x2
y2
(c)
(d)
y2
x2
The line joining origin and point of curves ax2 + 2hxy + by2 + 2gx = 0 and
a1x2 + 2h1xy + b1y2 + 2g1x = 0 will be mutually perpendicular if
(a) g(a1 + b1) = g1(a + b)
(b) g(a + b) = g1(a1 + b1)
(d) ag + a1g1 = bg + b1g1
(c) a + b = gg1(a1 + b1)
x 2 y2
The locus of the middle points of the portion of the tangents of the ellipse 2 + 2 = 1, included
a
b
between the axis is the curve
x 2 y2
(a) 2 + 2 = 4
a
b
82.
a 2 b2
(b) 2 + 2 = 4
x
y
5 3
2
2
,
of the curves x y = 8 and
2
2
83.
84.
85.
(b)
(c)
(d)
The area of the region lying inside x2 + (y 1)2 = 1 and outside c2x2 + y2 = c2, where c = ( 2 1)
is
1
1
(a) (4 2) +
(b) (4 + 2)
4
4
2
2
1
(d) None of these
(c) (4 + 2) +
4
2
The equation of the parabola whose focus is the point (0, 0) and the tangent at the vertex is
x y + 1 = 0, is
(b) x2 + y2 2xy + 4x 4y 4 = 0
(a) x2 + y2 2xy 4x + 4y 4 = 0
(c) x2 + y2 + 2xy 4x + 4y 4 = 0
(d) x2 + y2 + 2xy 4x 4y + 4 = 0
If PQ is a double ordinate of the hyperbola
x 2 y2
O being the centre of the hyperbola. Then the eccentricity e of the hyperbola satisfies
(a) 1 < e <
2
3
(b) e =
2
3
(c) e =
Page12
3
2
(d) e >
2
3
AglaSem Admission
86.
87.
r
r
r
If the vector a and b are perpendicular to each other, then a vector V in terms of a and b
rr
rr
r rr
satisfying the equations V.a = 0, V.b = 1 and [V a b] = 1, is
r
r
r r
r r
b
(a b)
b
(a b)
(a) r 2 + r r 2
(b) r + r r 2
|b| |ab|
|b| |ab|
r r 2
b/ | b |
(d) None of these
(c) r r r r
(a b)/ | a b |
Suppose values taken by a variable X are such that a xi b, where xi denotes the value of X in
the ith case for i = 1,2 . n, then
(a) a Var(X) b
(b) a2 Var(X) b2
a2
Var(X)
(d) (b a)2 Var (X)
4
12
3
3
If sin = , 0 < < and cos = , < < , then sin( + ) will be
13
2
5
2
(c)
88.
(a)
89.
56
61
1
65
(c)
(d)
56
60
(b) = 2n
2
(d) = n
4 2
If two towers of heights h1 and h2 subtend angles 60 and 30 respectively at the mid-point of the
line joining their feet, then h1 : h2 =
(a) 1 : 2
(b) 1 : 3
(c) 2 : 1
(d) 3 : 1
(c) =
56
65
90.
(b)
n + (1) n
2
Page13