Unit o Theameclynamic pelohens. Shhecdeuction > | d t can he axfuuserbed ‘Este epeutic came mic penhes — Predkuste eat 2 yale Cleppetoers ir internal Lntagy u, ealkalpy 4, onteepy ce Anclkes too thexmectynqete his ewhroh Bee onside tf exmed Tee et chefeal reactions axe Le Helohelt pesiekton” f+ U-bhs Catbbs frodter cy. 2 eur abeve “fe prepohis prsture, volume vi te masued are ly 4 eagerly Pemaint o pestis et be ved thes £ Oreitcar Ae te Shaah The ni measuioalle ww divelty | * | thes “frre Prope tm bew ee ee proprhis can he | Thise Pewnetyramts | met ei ditvamiasd with The a extatn re | gulakeenes (woth rhe he } eee Spavil | dextraltias). tucda entritals Fastal devtvatiies | Censeles thee” Yortall X,y apne | “thedr rochteral welotfership is taprezerd 4 | Blt, Yee albovn Scan Be cyad ee o | Se. ee | Xef wey prog ls) 22h ne) =O | ck Affe venkele:- © Cie Noe , Thy the Vaviohis 2 Van Eo es ss oa Ze 5 C44)a acl Can he wraiths as ,; d y be Condit © by i Gy * etpesiarle cheap lo byt canstanh Fi se Ar dz 2 Midx +N 4 Gre MadN az tobi | etext evoltres, thie Secor) Powk a a 2 | Da es) aay me es = being Continous procties y Ze dy ~@ Suck ea ee ase. talhd Sack aia when de aie aos zZ fe 2?) capa i Bia. ot ‘x when chong dx te x alone, Zz wert” ae ae ‘wo o y (22) 2 not Fd . Equalter @ con fr wxtlth a v. AUDUs Bet jose al dexhobtte can fe a WO 5, “agfucens te bab for React ~| © = e feb x25 ( yz) ach pod (x, x) ren he = <.. Coty “GS ) ae 7° 4 (By as ya 7 ro ach en © ae ie dk 2 [d« ei > joo hie (Beye ey ae ef -B5) Bey) = +] yy) Same changes X ard z axe toh tnt Le ei can he ansgad ay valus %H eqn '@- Lt dz 20 when dyleo . on ae) |e te @ ua Fore. | EB ipey lee ae . | 1-09) ) - ee | “(Be ), ele a . Px @. Sh the aber en @ @® advco, wh azo co ep © veh te | De Gee cae | BE Cty = - Ey But fro op ® By owe ® Ge), =), 4ee pe eater a ie Kb ep Ovo © | x \ . (2 | Gy, - eS =) a OS i a) Gy (Gy - 7° et bove egp s rat a Te ~ wplabron hems eee ree eqn (BP can be moet tA as. Ge -Ge) =! Se E v Mexuaell Rel Relate. st Ee Thevmadyng mee ac aylicd EUV eins fe oy Oeics ae Lait T° J ay = du- yp de a® > pdy ry teen of Lord low = a ee | dys + de a@ 2 | ib

. oe oh fees 4y leu cae te pha chan hts cay falpe in calculating ht chops 4 ave in’ twe gehen Clanstn< c Ge | dvered — etlhce oe & BD See 4 TRewmecypans st wilh The Morulllt Flatter. a ofeepy C2) is a fe Ferop (1) and volume a * a | Yorn (‘2 gilertin @ OS. y) Bie? og? Peis aif, trp oly : ope pei f ioe tan ota ae, be Bp - #3" Corstctcs the ie Oo fa oe ol te a tee ay ks ee ae ‘tall pes | fh ete ty aap ore op» volume © a& My a Tht= = 4-y ‘4 (37) = Gti eR ac Y 44 Aub eqn © acd @hm eO ore Ty decay assaté on froo tapped Shs 3 pe ey rhe ean it a SS teu teat oda duwing rages hy oe ab aattesation fr oS aug SP =e? ; equ ation © &% aoe clausiis - se ba ars) - he aa eaip he a Chars phase hasty alta Diy be (©) cual oa oa % a abere” cane AP fis The lope tages Curve. ap Clausen plone to opprestak ¥ vais = kothexmel rae heres ap @ be ces ecibilly . ot [2 xBey } Cota ne BY S ea) = otLolo | ep 1G) re Oe Be 7 Gy eee | ~ (DS | - Fy 2 > GE) cy | ceed Ln je Mele Shloral Eang, | ul = Tde— pdvi aO C Fre yy, huh 6 is a fe 4 Temp (1) aed 9 volume Wo, ge -tlny) | de (Ze) ar + or 3® Rik ag @ 4 O du = TT Ge ES) aw | -p- dy =+® Coe ee eet dre neuntl Be 3 - (2 "Oi ay Bub the oboe toc eqn '& eqn ©. du [ror x 7 @) dv] —pedv du = ¢,a% + 1 (By dv apdv =® Jeon en D ve can dthrmine rhe Merl eat: te Terms measurable — prepcthius all 0s PvadT Bde,| Entecpy ul Tulations s Cds Be patten)'- | a obey i «fon of Temp ot Pe Bul qq Bad © 9D | ( | =| Ceabeory a pecne Subsante. Can Be Eqousced | lec a eG tmp ad B | £-5l7P = me ; a-B yr Gyre | ** Bier, | ZS Ge), = a =a © hen Mecwwll Eqn. | ts pe > a | eee | | eo a ee das + y z (Baya Ghee beeen eo Le ee - (2) - “herr renal : z) = (3) »® |) fib a Beil O.% <9rO dene aa dt +> (BE yi dv zeliy ete asRome: Shon fa a Bealpy lh = orck 4 vp eo enleepy Tulabtors- = ae [> de = cp ee a) Tds= - ape fer mee gee ee | db = pt ar(e= yrs vl Toon abere gn “the. cathalpy by terme y measure ble ftepeskes Buch 02 PY, 7 ard cp | | can be tabcalatd . claustus cla pe: gp echirate rh enthalpy V3 tye oa at te cahusatioy herp. Take prog data. Tg = 2208 5 vp = 0+ 082 OM ieg Ay ap conaoig, | (F D5 8 ig/x. a | Bae elation ue fay iT Tt Oye %) Mey hone ly (Bey243) Cortes ~ &-con') byg = TAbR lay. “fom SF af Ty = 220 hig - sea a fky2 | Caleulatr the sp. heed Be Censlank pe. ab be bres See PT asa fh. Cato avottable fab. 3, Pe aohas; EF Yeo = EIDE | aon ser Po robax bp 2 aeoke Sie BPSYS ‘alka | ie | stoke 't . omen = Scot = F233 | e AS Shegue | e Cp ot Cendant pr. 2 TelSe) tee eee eee (ts -t,) itadee —ie \ Better vist owe Petter vy, will be“ ohtated bey user AT 26 Local ae possible. ie? Teuls Thaoéen eecenk (HM) e- pplicchier Tele Thence Conpiebont | aleaty wrath “hang SS ier Ste a Habe ~ ee bi nee ee eo ts pa. Orop Paso ae 2 lena proce | calted eo ard a Such peccesr athalpg Torn ncdedh aa deoedy scm ooh Srp Thownally treuloteel ¢| | pee ere ak toncanh (R/T) fy lock Piped Linder, © 2 ee (Be pacer noes oo Hismally a tebe ard rhe fw a: on dow neks2or0 His ples ee a cb > pbeowattr ze tarcteol, 7 # Femp Ts Hoied deeonubrear side & mossrerdl, A Sexiis expoccinesie ape corcbnctid ee 2 | pk Prep. pratt 2 neu ge a %yT; oo oh ti Pen, OF dounckcessn téde “fabs Fhe Lewd fh cobs of B&B, Roo ek ard “teep- aw pordizdly Ter Ma eh + peed Cosees, Anke 7 owe ng } sO a ge hre Bh 5 Malye ee ee o The value plotted oy : Me Contant otal es alee toed Bo, on uptheerm Sede. va eae the Mae, ph ty tach cme & calbal Four — poroh> Ard ihe loco of FAs tnvaxxton pl 1 Called Feweraion cows | Toul - Themen Couppresinl Hoot ary A & cipred oe he clepe of Yecathalpre tafe. ak br pant Cr-p) Plane, Ss Mey Wee Gr) —~ © At fnvexeton pt MM o=e The value Gok femicay taekipemeh Th Poa crete th Pwacdim Gv. and Hw aa easel: «FAR Rcd meen, “tere,Digte a pe the Prvewetey Cooure. ele | rae 4 7 Shee pss chop tm a. Herattti | Prowse 1 4 Cap” ie Fp) Aine Re temp, alee 7? | beeps becaute posh ve . “a Bgten eubsnte Hx Favetiin, exon venprseale ie co es oso naga & Noelle preese re : | uw she li ipa ie ee 1 5 foam me eo cals Be Ayer ah of Sp col oo, re apeton ie ts Prom ney Pha eect fe rom Secand Gyihbetan eqn. | dh = vdp +ads =o Yeo Saeed Te bath ta » | 1 Sede | i | Velen A < Volumen = Volume ee (A+B) | af POLE ek me Mm +E By Tali’ low *f nae Pe = a Above. *grk- con res eel “ex any ‘no. a Nen - veo che we pa ene ae Compesihton | Ateqecphasie o8e } me re (oleculer| chemecal LApprociinad valws b Risen eee | eee [Aepmeaek tale De cont yecbal, | Vetet one | Cra rather | | | Nitbsegte, Beats |S he a ee, pefesea, L_p¥ 1°994_ Bee ee ete _Acgon 24GB Ae OAs 128 Carsten Diotds| Uyeo | Co | O02 | Avex melted make = 2895+ Cire torstont R= 28t Ne ligns,ot 16 tentaind & a 0: 4s alco asl ue + E at Se. Als hog 22-2, Rot rh ie ON ne ee oes 4 TEA oN, paskal peo 4 aa colldcluact asd soe Peon the. vase) . ' Molaw wnsset Ff tO, Ny are 28,22 ard 28 ‘Phe wal: CrP veo: ; mee = OUSMD 3) Masy a tity, V2 eat Fa tSe +245 eo 2EBK. Me ee OS ae es = 222d. and Ny = H-3/° np Ot we Fy Ho =e, My, = 25 Np liegero'.. ae It ae Moy = 06228 oy aivexea) Cha wacke vie hte ie Cocstast ed Pye eres ee Mole color ase M4 Ro = Rae te Ro, = | ea : ton, C 50 Ouse 29b-4x 288 | 5.2. Nfak- (00 bie Fae ee wv i, = a7, Rg te PROM SARE Sa ipeaeesenis an &® s 1:63.4 boreTotal Pe. io vesatl Re te ta, al 2 (Ope Sd) + Cutcaa- 4) + (16.996-6) | of Sear 64-8 wl (Od ot Be = Chowiaebete Araby 4, ar ICendikeak | Pencent | melecrlor fesse ye ea tet | ee N 4s-6> " Aagen | ar! 40. fee RE al [Cae opi] a Fred 7) CRarcete-sidh'e ee Ceasloot wD Melecalay ut iit) Poxkal p- a eo Shania ie belek pre HT | S23- ree Hh, -oe et 25a» Shige 22 — = en pe p ee > MEG 2 Ser leap : OM ee a ee = PL Bye = 260 Th Mn Se + SE Meee Rigg = SES oo Ie 1) Charackewahe rr torsdand fpr Doe Be eR TMP + eae tts Maas» Fy Ep Th,tee ie ae ee oe a eee ae = (epeecn). € ysedse 29-4) Coren | 209-86) + (0-008 x 188.04) DIBIS AO-FSS2 Zoicrs -o00ey — = SEBEL. 5 8B o alban ! a ji) 1, . air Me PP = BIR - 93.768) ii) elector wi 4 ape 2B} = “Te, TH) Pastel Pd cach tonethutel- Tdal Pes ern Be No- ire, es a maeeees eae Moy a Mo Me 8 Se oe hha | a 2643 | Sapa ae br Sis oats “px a aeons ea a Moa he | So: = Np, i on Ne ey te OPA 4 2-b99) 40-22 4o-0004 > B:bead. Pa = = AP = O84 x polg = S2Inbay | ‘ne 24539 \ Soe 2 oO No oe po 20997 xo = | ea 2 S39 | or > Ten pe POS xnats = pets te ae BUS37 a Tee et ep ee ae BYouy Zoe“ ts a ike wd mv. rho! CF Canis 2 pee a canker ee eS b aie acd hoes Abe pF lect Gi) eqptvadecd enile eedoor Raa +f dalank fol ithe lon Le RES Cpanedet ps 4 ) De eh p. acd parkral veleme . a Rig, Mee, = 6 tg. Pe aoe pe, TH rO'e la! — i) Mol. frackon aL 1 Sy ne = Mp Ne + Oe My Fee Bie ~ See = BD 4&o 2 5. 38 Gq fetus pa eee mh, ae. tea eee ie ee MMe Meg ing Gy soos ges. ag i) puiialtet molecular wt of, mite eS ey Muy Fe Mt ws) Equi Paleat ne Condact @ i (0-485 x28) + (o-sis vu) Beh 7 /} Cg. Rom By + TR aa fa 4 ey,(=x 5214) 7 | 0 SET) = oem sige B45 1) Pasttal Pe and Reabtal volome, | Ry =P = Bs Gao ade eS. Shp a Py = ener eee oe % 7 2x GBIY £293 2 P eS sea te0 V, C = T | to = es Ree 2 5x BBY samy. omen | ee oe ee ae ae | 200 Ai A me of & h ard 21 of ge 4? an inadtatid pod, Lx Oxrdingletnt a leo Pa. ook. The Pik av Nempereee det fr lie ( apral vVolual + Molecadbw wt of, oygin is o> a pe a yo. Rete op. irate ot” & 124 on “& at ad Petal ey o ancl Pr- i= seed A oe %, = 2k, pes 2-FF P, > sBeloo KPO, =F, = 200K | Yea Me, Moy 2 8 Mee = WO, > 139, %G, = 106% Setins - mase fa hh Xo, = Pow ee Fa * Ee _ =o Mert Mp, es a Moe ee Bee Re, FS| | | | | | | ans sie ee Sf a, . a ie bs Mp "te Se 4 he ee Mem + me “a ee Moy. ee 4 “From eq ection ¥ saa Py emery My hy ohog = ox BU x 225 P Be seh sh = ee Yee = Per T pe BLU xa0 Pac P 4 Tr gel Myo = 2-800? Volume A mix, Pare Comp eeeid VUE Vg bee = 2-484 2-8 = S54 m* Veloum a tompeuee Avs = Min ecg cs ae = 2st Ratio 4 gp. keab Bh ie ¥ 2 mn % + 5. ye 4 > (o-55 « 24} 4 Couuy x 469) at cies Srbilatd aes aurergble adiabatte — frrotus. Pvt = me Z Yo =] ™ fe i ros = ies (2) oe GS AL.pater de TET nla. ga, Be NTE TA pce ee a 9 al] eo Siac! Tx 5 (2asy SPSS 200 Te 1 oe See, wb = RY -R 5 loors.by - 285-4 x 2-Bo> bone 7 = 100-23 te Cove fe SA ete he pishn) <1 od vigeel Containe 2 mole of nN, ard KMoli fo, oF ber | ard se0K' eel. OB Mg th de ett Rid pe tontond ym ah TE asthaxe (1) poodral pe of each ee Hct vals of Na = 28 17 leg mal, « + 8 G = Se Kaley ds % flor Gio: ay, = 2, Mg ay , Patbm, T= door ‘ masr. po Ba Wnty = eRe =p MO,> 42% 38 = RBkg Fela) was om = Rye Seen 1849 iD Averog, meleculor rose M ard re ear Total nb. of, vlc mK nay, dry = 2th = molte wreleculas max jt -/My xm a ee ni) + (oy me) | = es) «ee aGas censtant fp Me B= pe eS | a AEE ser. a) | | == | ay ently ob wide. | P= fer (ao ene oars Seg iv) Pawtial pe f each fe Re £-%-P fe es p 2 241 20-23% ber .s mnie. b | Fe, = fe Ff Sy fees co. 6b9 fa | arate = ae S| ae Che! ee mi Consishiy apes ard AKG ab a temp % Deb 27 Celta pies OH volume oe oo sin a es Th. sp. totenal Ee . go ate . Agéisme thot m5 av Priok gases. yaks Rex alr S oDat ‘Shp ge Soe & O294 gf en ane OMe ae i Ode Nplege) ae | Alms. ~ 3 Poop hes 1 | — eas v sate = Ble | | ae | 2c by gt] Ban | | Ax 298-52 912-Jo | 220 | G@rpi- Pte rare 7 298i ve im, Re ogp-spenc = 298- rte ly v = 212-40 Kyle, Se PAS Ker /iepre Yoo m | s Tkp, 7 = 298K, Ve teh Ra 2945 [kepe, b= 209. hg pv cde glee, S2 & (6 & liege.Sp. volume ee a G. veums of N, = ‘ee at = eerie 2 Pe. aos Ta > a Fat = Seo Vv Fa ABS SEU Ky = ux Ry Total mass cf Gi, = Meee eles Sp. vole.me ‘ead Vee Me ae = ollie to) {2 Ape di pre Pe Mi 4%, = 26e5 thr = Bab: OF KN] ro 3 gp eta a, ate bee maha +, be ae ra =(24298.52) + CX 2164) See tie eT t Bob: Be Reg ~ Siteral en 3) aux. be 1 HE ye, Ma Yo t ny ne oo = Gcon-de) 4 (4% 22-0) eee Seem 5 ) earteamy 4 tire aT Ly f= MaSa ty, Su, ee : Gdcarys Cte) to S- = ou ask '5- feo 3