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Keltan ACETM
2
Peroxide decomposition
governs kinetics of peroxide
(PO) curing.
VNB
MH - ML (Nm)
6
5
None
4
VNB
DCPD
DCPD
ENB
ENB
2
1
0
0
10
can be achieved.
Direct savings on peroxide cost
Limited or no bloom from peroxide decomposition products
Reduced smell of peroxide decomposition products
Reduced fogging
Reduced shrinkage
Less residual peroxide after curing improved high temperature set properties
Less residual peroxide after curing improved ageing characteristics
Improved electrical properties
Improved Mooney scorch characteristics (one step mixing, extrusion output)
Less stickiness after peroxide curing
Hyper-branched structures
A small fraction of hyper-branched polymer chains contributes to:
Enhanced shear-thinning behaviour
Excellent bale integrity
Improved compound integrity
Peroxide reduction
> cost reduction
> no blooming
> odor/taste improvement
> reduced fogging
> reduced shrinkage
> improved electrical properties
> less down shearing (TPV)
Increased crosslink density
> reduced (oil) swell
> increased filler loading
> improved chloramine resistance
Reduced residual peroxide
> improved high T ageing performance
> improved high T compression set
Unique branch structures
> enhanced Mooney scorch times
> high collapse resistance
> excellent high-shear properties
Low residual unsaturation
> improved ageing performance
> improved high T compression set
VNB cure site
> enhanced hydrosilylation curing
> enhanced ene grafting/curing
> absence of black scorch
TPV
roller covers
O-rings
conveyor belts
window gaskets
cable insulation
wipers
anode caps
airco hoses
brake parts
V belts
coolant hoses
Properties
Units
Mooney Viscosity
ML (1+4) 125C
MU
80 5
Volatile
wt%
0.5
Ethylene Content
wt%
50.0 2.1
VNB Content
wt%
3.0 0.5
Medium
Molecular Weight
Distribution*
10
11
Peroxide Reduction
Cost reduction
10-15%
15-20%
30-40%
40-50%
50-60%
60-70%
12
Peroxide Reduction
No blooming
Perkadox 14/40 most
popular cross-linking
peroxide
Bis(hydroxy-isopropyl)benzene blooms from cured
products, forming needlelike crystals.
Blooming can be prevented
if less than 4.5 phr is added
to a typical EPDM
formulation
Decomposition products of
Perkadox 14/40
13
Peroxide Reduction
Low odor, taste, fogging, shrinkage, conductivity
Odour and taste characteristics of VNB similar to ENB (isomeric
compounds).
Low third monomer content low residual diene.
Less volatiles and extractables from peroxide decomposition
products.
Polar peroxide decomposition products reduce dielectric strength.
Post-curing processes aimed for reducing peroxide decomposition
products from cured products can be made more cost-effective.
14
300
250
K8340A
High ENB
Standard ENB
K720Z
Standard DCPD
DE6002
DE8270C
200
K4802
150
100
50
0
0
10
15
Elongation
50
Resilience
Oil tolerance
CS @ low T
Tear
Modulus
NEN
HEN
VNB
CS @ high T
90
80
70
60
K8340A
Standard ENB
50
K720Z
Standard DCPD
DE8270C
DE6002
40
30
20
10
0
135
140
145
150
155
160
165
100
95
90
85
80
75
70
....
65
60
55
50
HiPO
MePO
LoPO
K8340A
K8340A ENB
K8340A
Standard
HiPO
MePO
LoPO
K720Z
K720ZDCPD
K720Z
Standard
HiPO
MePO
LoPO
DE6002 DE8270C
DE6002 DE6002
18
Inc M100@150
19
1000@150
Keltan DE8270C can combine high crosslink density with low residual
unsaturation.
20
80
70
60
High-VNB
50
K8340A
40
K720Z
30
Log. (High-VNB)
20
Log. (K720Z)
10
0
0
MH-M L (Nm)
21
systematically changed
Responses:
Extrudate exit temperature (IR)
Head pressure
Power consumption
INGREDIENT
PHR
Polymer
Stearic acid
PEG
CaO-80
N550 carbon black
Whiting
Tudalen B-8014
100
0.5
2
6
130
60
70
Perkadox 14-40
Die swell
Extruder output
Collapse resistance
22
Standard ENB
DE8270C
23
DE8270C
Keltan DE8270C has unique performance benefits in terms of:
Extremely efficient peroxide curing
Improved balance of aged and unaged material properties
Improved processability
24
Contact us
Herman Dikland
DSM Elastomers
Keltan ACE Business Manager
PO Box 43
6130 AA Sittard
+31 46 4773565
+31 6 53321308
herman.dikland@dsm.com
Or your local Keltan sales representative
25