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Acid-Base Theories
1.1.1.
Arrhenius Acids and Bases
In 1887, according to Swedish chemist Svante
Arrhenius, acids are compounds containing hydrogen
that ionize to produce hydrogen ions (H+) in aqueous
solution. On the other hand, bases are compounds that
ionize to produce hydroxide ions (OH-) in aqueous
solution.
1.1.2.
Brnsted-Lowry Acids and Bases
In 1923, Danish chemist Johannes Brnsted (18791947), and English chemist Thomas Lowry (1874-1936)
independently proposed a new theory. Brnsted-Lowry
acid is defined as a hydrogen-ion donor, and a
Brnsted-Lowry base is defined as a hydrogen-ion
acceptor.
1.1.3.
Lewis Acids and Bases
The third theory was proposed by Gilbert Lewis
(1875-1946). He focused on the donation or acceptance
of a pair of electrons during a reaction. A Lewis acid
is a substance that can accept a pair of electrons to
form covalent bond. A Lewis base is a substance that
can donate a pair of electrons to form covalent bond.
Type
Arrhenius
Brnsted-Lowry
Lewis
2. Arrhenius
Arrhenius acids are compounds that contain hydrogen that
ionize to yield hydrogen (H+) ions in aqueous solution.
Monoprotic acid is an acid that contains one ionizable
hydrogen. Nitric acid (HNO3) is an example. Sulfuric acid
(H2SO4) or any acid that contains two ionizable protons is
called diprotic acid. A tripotic acid is an acid that
contains three ionizable protons like in phosphoric acid
(H3PO4).
However, not all compounds containing hydrogen are acids
or hydrogens in an acid are released as hydrogen ions. Only
hydrogens in very polar bonds are ionizable.
I
II
H-C-C-O-H
I
H
Common Acids
Formula
HCl
HNO3
H2SO4
H3PO4
CH3COOH
H2Co3
3. Brnsted-Lowry
A Bronsted-Lowry acid is defined as a hydrogen-ion donor,
while a Bronsted-Lowry base is a hydrogen-ion acceptor.
Lets have ammonia as an example. When ammonia dissolves
in water it acts as a base because it accepts a hydrogen
ion from water.
NH3 (aq) + H2O (l) NH4+ (aq) + OH- (aq)
In this reaction, ammonia is the Bronsted-Lowry base.
Water, on the other hand, is the Bronsted-Lowry acid.
Hydrogen ions are transferred from water to ammonia.
Heating an aqueous solution of ammonia drives off
ammonia gas. As the ammonia gas moves out of solution,
the equilibrium in the ammonia dissolution equation moves
to the left. The ammonium ion (NH4+) reacts with OH- to
form NH3 and H2O. When the reaction goes from right to
left, NH4+ gives up a hydrogen ion; it acts as a BronstedLowry acid. The hydroxide ion accepts a H+; it acts as a
Bronsted-Lowry base. Then we have two acids and two
bases.
NH3 (aq) + H2O (l) NH4+ (aq) + OH- (aq)
Base
acid
conjugate
conjugate
acid
base
Formula
Locations
HC2H3O2 Vinegar
(aqueous solution)
HC9H7O4 Aspirin
ion.
acid
Ascorbic acid
Citric acid
Hydrochloric acid
Sulfuric acid
Bases
Ammonia
H2C6H6O6 Vitamin C
H3C6H5O7 Lemon juice, citrus fruits
HCl
Gastric juices
(digestive fluid in stomach)
H2SO4
Batteries
NH3
Household cleaners
(aqueous solution)
Calcium hydroxide
Ca(OH)2 Slaked lime
(used in mortar for construction)
Magnesium hydroxide Mg(OH)2 Milk of magnesia
(antacid and laxative)
Potassium hydroxide KOH
Soft soap
(also called
caustic potash)
Sodium hydroxide
NaOH
Drain and oven cleaners
5. Strength of Acids and Base
Acids are classified as strong or weak depending on the
degree to which they ionize in water.
Strong acids are completely ionized in aqueous solutions
Examples are hydrochloric acid and sulfuric acid. Weak
acids ionize only slightly in aqueous solution.
An acid-base equilibrium always lies in the direction
of the weaker acid.
Acid
Base
Kc = [H+][OH-]
[H20]
The value of Kc at room temperature is 1.8 x 10 -16. In
water, its concentration remains 56 M at 25 C. Replacing
[H2O] by Kc, then the ionic product [H+] [OH-] equals a
constant:
[H2O]K = [H+][OH-], and the value of the constant is
called the ion-product constant for water (Kw). At 25 C, the
value of Kw is 1.00 x 10-14.
Acidic solution: [H+] > 1.00 x 10-7 M
Neutral solution: [H+] = 1.00 x 10-7 M
Basic solution: [H+] < 1.00 x 10-7 M
7. pH (acid) and pOH (base) concepts
In 1909, Danish scientist Soren Sorensen (1868-1939)
proposed the pH scale. On the pH scale, neutral solutions
have a pH of 7.0. A pH is strongly acidic. The pH of a
solution is the negative logarithm of the hydrogen-ion
concentration.
pH = -log[H+]
In a neutral solution [H+] = 1.0 x 10-7 mol/L. The pH of a
neutral is 7.
pH = -log (1.0 x 10-7 mol/L)
pH = -(log 1 + log 10-7)
pH = -[0.0 + (-7)] = 7.0
Meanwhile, the pOH of a solution equals the negative
logarithm of the hydroxide-ion concentration.
pOH = -log[OH-]
A neutral solution has a pOH of 7.0. A solution with a
pOH less than 7.0 is basic, and higher than 7.0 is acidic.
pH + pOH = 14
pH = 14 pOH
pOH = 14- pH
Neutral solution: pH = 7.0; [H+] = 1 x 10-7 m/L
Acidicl solution: pH < 7.0; [H+] > 1 x 10-7 m/L
Basic solution: pH > 7.0; [H+] < 1 x 10-7 m/L
8. Indicators
An indicator (In) is a weak acid or base that undergoes
dissociation in a known pH range. In this range, the acid
or base is a different color from its conjugate bases or
acid.
Acid
Base
neutral
[H+]
(mol/L)
100
10-1
10-2
10-3
10-4
10-5
10-6
10-7
10-8
10-9
10-10
10-11
10-12
10-13
10-14
pH
10
11
12
13
14
Universal
indicator
red
red
green
darkgreen
blue
blue
blue
blue
blue
cyanidin
(red
cabbage
water)
red
red
red
cerise
purple
blue
blue
blue
lime
lime
blue litmus
indicator
red
red
red
red
red
red
red
blue
blue
blue
blue
blue
blue
blue
blue
5.0 8.0
red litmus
indicator
red
red
red
red
red
red
red
red
blue
blue
blue
blue
blue
blue
blue
5.0 8.0
pink
pink
pink
pink
pink
pink
pink
8.3 10.0
pH
range
phenolphthalein
indicator
colour colour
-less -less
colour
-less
colour colour
-less
-less
colour
-less
thymol
blue
indicator
yellow yellow
blue
blue
blue
blue
blue
blue
8.0 9.6
phenol red
yellow yellow yellow
indicator
yellow yellow
red
red
red
red
red
red
red
6.8 8.4
yellow yellow
yellow yellow
blue
blue
blue
blue
blue
blue
blue
6.2 7.6
bromothymol
blue
indicator
methyl red
indicator
bromocresol
green
indicator
methyl
orange
indicator
bromophenol
blue
pink
pink
pink
red
red
red
cresol red
red
red
red
pH
pink
pink
yellow yellow
red
yellow
yellow
blue
yellow yellow
colour colour
-less
-less
blue
yellow
4.4 6.0
bluegreen
bluegreen
bluegreen
3.8 5.4
yellow
3.1 4.4
pink
pale
bluegreen
blue
blue
bluegreen
blue
blue
blue
yellow
blue
blue
blue
blue
blue
10
11
12
9. Buffers
Buffer is a solution characterized by the ability to
withstand changes in pH when limited amounts of acid or
base are added to it.
13
14
3.0 4.6
0.2 1.8
pH
Chlorides
AgCl -- 1.6 x 10-10
Hg2Cl2 -- 1 x 10-18
PbCl2 -- 1.7 x 10-5
Chromates
Ag2CrO4 -- 2 x 10-12
BaCrO4 -- 2 x 10-10
PbCrO4 -- 1 x 10-16
SrCrO4 -- 4 x 10-5
Fluorides
BaF2 -- 2 x 10-6
CaF2 -- 2 x 10-10
PbF2 -- 4 x 10-8
Hydroxides
Al(OH)3 -Cr(OH)3 -Fe(OH)2 -Fe(OH)3 -Mg(OH)2 -Zn(OH)2 --
5
4
1
5
1
5
x
x
x
x
x
x
10-33
10-38
10-15
10-38
10-11
10-17
Iodides
AgI -- 1 x 10-16
PbI2 -- 1 x 10-8
Sulfates
BaSO4 -- 1.4 x 10-9
CaSO4 -- 3 x 10-5
PbSO4 -- 1 x 10-8
Sulfides
Ag2S -- 1 x 10-49
CdS -- 1 x 10-26
CoS -- 1 x 10-20
CuS -- 1 x 10-35
FeS -- 1 x 10-17
HgS -- 1 x 10-52
MnS -- 1 x 10-15
NiS -- 1 x 10-19
PbS -- 1 x 10-27
ZnS -- 1 x 10-20
1.1.6.
Common Ion Effect
In
a
saturated
solution
of
equilibrium is established between
chloride and its ions.
silver
chloride
the solid silver
Barium sulfate
BaSo4
Calcium chloride
CaCl2
Calcium sulfate
dihydrate (gypsum)
Copper sulfate
pentahydrate (blue
vitriol)
Calcium sulfate
sesquihydrate
Potassium chloride
CaSO42H2O
Gastrointestinal
studies; white
pigment
Deicing roadways
and sidewalks
Plasterboard
CuSO45H2O
Dyeing, fungicide
CaSO41/2H2O
Plaster casts
KCl
Potassium
permanganate
Silver nitrate
Silver bromide
KMnO4
Sodium hydrogen
carbonate (baking
soda)
Sodium carbonate
decahydrate
(washing soda)
Sodium chloride
(table salt)
NaHCO3
Sodium-free salt
substitute
Disinfectant and
fungicide
Cauterizing agent
Photographic
emulsions
Antacid
Sodium thiosulfate
(hypo)
Na2S2O3
AgNO3
AgBr
Na2CO310H2O
Glass manufacture;
water softener
NaCl
Body electrolyte;
chlorine
manufacture
Fixing agent in
photographic
process