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CHE 301 Problem set #8

1. Anexperimental arrangementformeasuringthethermal conductivity ofsolidmaterials


involves the use of two long rods that are equivalent in every respect, except that one is
fabricated from a standard material of known thermal conductivity kA while the other is
fabricatedfromthematerialwhosethermalconductivitykBisdesired.Bothrodsareattachedat
oneendtoaheatsourceoffixedtemperatureTb,areexposedtoafluidoftemperatureT,andare
instrumentedwiththermocouplestomeasurethetemperatureatafixeddistancex1fromtheheat
source.Ifthestandardmaterialisaluminum,with kA =200W/mK,andmeasurementsreveal
valuesof TA =75oCand TB =60oCat x1 for Tb =100oCand T =25oC,whatisthethermal
conductivitykBofthetestmaterial?

2.Policearriveatthesceneofamurderandfindabodyandaleakingbarrelofwine.Thebarrel
hastwo6mmbulletholes20cmabovethefloorlevel.Wineisstillleaking,andthewinelevel
atthetimeofarrivalofthepoliceisnotedtobe36cmabovethelevelofthebulletholes.The
totalheightofthewinebarrelis1.2m,anditsdiameteris0.6m.Assumingthatthebarrelwas
fullatthetimeoftheshooting,howmuchtimehaselapsedbetweentheshootingandthearrival
ofthepolice?
3.Hexamethylenetetraamnie,N4(CH2)6,istobeproducedinawellstirredsemibatchreactorby
adding aqueous ammonia solution at a constant rate of 10liters/min toan initial charge of
formalinsolution:
6HCHO+4NH3>N4(CH2)6+6H2O
The reaction is instantaneous, irreversible, and exothermic. The initial charge of formalin
solution is 2000 liters with a formaldehyde (A) concentration, CAi, of 15.0 gmol/liter. The
concentrationofammonia(B)inthesolutionisC B =15.0gmol/liter.Heatcapacityofboth
ammonia and formalin solution is 1000 cal/liter oC. Heat of reaction is 74.6 kcal/gmol of
N4(CH2)6.Thetemperatureofammoniasolutionis0oC.
a.Calculatethetimerequiredforcompleteconsumptionofformaldehyde.
b.Iftheinitialtemperatureofformalinsolutionisat60 oC,estimatetheheattobeaddedor
removedifthereactionmixtureistobemaintainedat60oC.
c.Iftheinitialtemperatureofformalinsolutionisat0 oC,determinethetimerequiredfor
thereactortoreach60oCforadiabaticoperation.
4.Wehaveanumberofsmalljetsthatwillbeusedinattitudecontrolinspace.Thesejetswillbe
poweredbylowpressurenitrogengasheatedbyanarcatthejetnozzle.Yourproblemdeals
withthenitrogenstoragesystem.

Thenitrogenisstoredinalargewellinsulated,14.5ft 3sphereat1atmpressure.Attakeoff
thetemperatureis40oF.ThemassrateoffloworN2willbeconstantandbeequalto0.01lb/s.
Sincethepressureinsidethespheremustalwaysbekeptat1atm,aheaterwillbeusedinsidethe
sphere.
Under these conditions, what will be the temperature of the N 2 in the sphere, the
instantaneousrateofheatflowtotheheater,andthetotalheatrequiredafter10secofoperation?
YoucanassumenitrogenasanidealgaswithCp=7.0Btu/lbmol.oR.
5.Alongcylindricalfinisinaconvectionenvironmentwithaheattransfercoefficienthandan
ambienttemperatureT.Determinethetemperatureatx=10cmandtheheatdissipatedbythe
finifthebasetemperatureofthefinisTo.
T

T (x )
T

L
x

dx

Data:k=230W/moK,h=50W/m2oK,findiameter=1cm,To=100oC,andT=25oC
6.
Q

h
Q

Theabovefigureshowsatankintowhichanincompressibleliquidispumpedatavolumetric
flowrateQo(ft3/s).Theheightofliquidintheverticaltankish(ft).Theflowrateoutofthetank
isQ(ft3/s).ThelengthoftheexitlineisL(ft)anditsinsidediameterisDp (ft).Thecylindrical
tankhasaninsidediameterDt(ft).Plottheliquidlevelhandthevelocityinsidethepipeasa
functionoftimegivenaninitialheighthoandinitialvelocityVooftheliquidinthepipe.Usethe
datagiveninTable1andplottheresultsfromt=0tot=600s.
Table1Gravityflowtankdata
_______________________________________________________________________
Pipe:
ID=3ft
Area=7.06ft2
Length=2000ft

Tank:
Initialvalues
Parameters

ID=12ft
h=4.0ft

Area=113ft2
Height=7ft
V=7.0ft/s
density=62.4lb/ft3 Kf=0.0281lbfs2/ft3

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