Brochure Matting Agents E

DEUTERON
Matting Agents
Polymethyl urea for

matting surfaces
DEUTERON
Duroplastic organic
Matting Agents
Based on polymethyl urea
Introduction
Properties
Matting
Mechanical properties
Haptic properties
Viscosity
Optical properties
Weathering
Metallic coatings & effect coatings
Softfeel coatings
Coatings for glass
Overview of products
Overview of properties
Technical product sheets
Samples and product range
Standard formulations
DEUTERON GmbH
www.deuteron.com contact@deuteron.com
P.O.Box 1645 D-28822 Achim HRB Walsrode 120187
++49 (0)421 / 48 32 27 Fax: ++49 (0) 421 / 48 36 02
DEUTERON
Introduction
The main matting agents used in coatings are silicas. Various
DEUTERON and PERGOPAK matting agents are organic,
types of waxes are also used to provide special properties
duroplastic, urea-methanal polymers.
such as slip effects and anti-blocking effects. In general, min-
Organic matting agents based on polymethyl urea are not a
eral fillers only play a subsidiary role as matting agents. Ther-
replacement for silicas. However, in some cases their use al-
moplastic polymer powders are mostly used to provide func-
lows surface properties and benefits to be realised which either
tional effects in special areas such as coil coatings and power
cannot be achieved solely with standard matting agents, or
coatings.
which can only be partly achieved or which can only be
The diffuse reflection properties of the surface are decisive for
achieved using combinations of standard matting agents.
the intensity of the matting effect. This is influenced by the
Due to their chemical nature and structure, organic matting
type, quantity and alignment of the matting agents. The most
agents are suitable for use as either the sole matting agent or
important parameter is the physical macrostructure of the
as a supplementary matting agent in a variety of coating mate-
matting agent. For DEUTERON matting agents the respective
rials.
reflectometer value is directly dependent on the relevant parti-
Ground and classified DEUTERON and PERGOPAK matting
cle size distribution and this can be measured at the surface
agents provide very effective matting, good surface texture,
via the roughness profile. The requirements with regard to film
good mechanical resistance and a pleasant feel.
thickness, binder solid content, etc. can be fulfilled with these

products for any specific application.
As the DEUTERON and PERGOPAK matting agents are duroplastic polymers, this opens up useful properties for users. For
example, their high hardness and non-melting have advantages for the overall resistance of the coatings.
DEUTERON and Pergopak matting agents can be used in
water-based, solvent-based and UV curing systems. Reactive
and non-reactive systems. Due to the interparticular moisture,
these organic matting agents cannot be employed in moisturecuring systems.
DEUTERON
Introduction
DEUTERON matting agents have many advantages which allow special properties to be realised.
- Narrow particle size distribution

- Large pore volume
- Thermal stability to over 200C
- Baking temperatures of over 300C possible for short periods
- High transparency in the film
- High scratch resistance
- Resistance to metal marking
- Resistance to shear
- No adverse effect on the recoatability, printability and writability

of the film
- Little effect on the viscosity / rheology
- No effect on the elasticity
- Can be cleaned and decontaminated
- Good gloss retention in all weather
- High resistance to polishing
- No melting point
- Reduces the susceptibility to metal marking
- Resistance to chemicals
- No swelling in solvents typically used in coatings
- High surface smoothness

- "Pleasant" haptic properties - soft-feel effects
- Positive effect on the blocking resistance
- No adverse effect on catalysts

- Beneficial reactions of methylol groups
- Little effect on the "Anfeuerung"
DEUTERON
Introduction
Comparison of electron microscope images
DEUTERON MK
silica; precipitated / wax-treated
10m
10m
1m
1m
200nm
The primary particles of the PMU matting agent are

essentially spherical and the agglomerates are also
approximately spherical. This results in relatively easy
incorporation of the product into the coating and favourable rheological properties.
The matting effect is primarily achieved via the particle
structure, typical of these products, which gives a
relatively high specific surface area.
The images show the typical particle structures of the
two polymethyl urea matting agents (DEUTERON MK
and DEUTERON PMH-C). These are the primary
particles, which agglomerate to become larger units.
Even the input of very high energy does not cause the
agglomerates to disperse into primary particles,
meaning that "over-grinding" does not cause loss of
the matting effect.
The magnified images clearly show the difference
between the amorphous structure of the silicas and
the particle shape of the organic matting agents.
200nm
DEUTERON
Introduction
Comparison of electron microscope images
Pyrogenic silica
DEUTERON PMH-C
10m
10m
1m
200nm
1m
200nm
In addition to the wax additives and compounds, DEUTERON

GmbH offers two base types of polymethyl urea matting
agents.
The DEUTERON MK and PERGOPAK product lines are
manufactured in a continuous process. In contrast, DEUTERON PMH-C and the related DEUTERON OG are produced in batch processes.
The products differ due to the differing management of the
condensation-polymerisation process. The reaction can be
controlled in such a way that different specific surface areas
can be achieved. There are other differences in the precipitation process and in post-treatments procedures such as grinding, drying and classifying. The resulting particles are chemically identical but have different particle sizes and different
surface microstructures and hence have different effects on
the surfaces of coatings.
DEUTERON
Matting
The particle size and particle size distribution of the matting

agent determines the matting effect in the dried coating film.
Factors such as the orientation on the surface also play a role
100 m
in determining the matting effect.

Due to the physical structure of the particles on the surface,
the incident light is diffusely reflected and no longer direction-
Electron microscope image of a coating surface matted with

DEUTERON MK.
ally reflected or parallel reflected. Besides the particle morphology and the binders, other factors which play an important
role are film shrinkage, volume concentration of the matting
agent to the total binder and the shrinkage time (= open time).
Further factors which influence the development of surface
structures that alter the directional reflection of light and generate an optically matt appearance are the other components
of the formulation such as the solvent, wetting agents and
dispersing agents, flow control agents and other additives.
The application conditions also partly determine the degree of
the matting effect.
100
Gloss [RE] at 60
90
80
70
60
50
40
30
20
10
0
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Amount added [% solid]

Comparison of the matting effect of different additives in a
universal, solvent-based 2-C acrylic coating (solid content of
the binder plus hardener ca. 30%).
DEUTERON OG 8654
DEUTERON OG 8650
TF-wax
PP-wax
Amidw wax
DEUTERON PMH-C
DEUTERON MK
Modified silica
Pyrogenic silica
DEUTERON
Matting
For matting agents, the respective reflectometer value / degree of gloss depends on the size of the particles on the surface and the matt effect. For a specific type of matting agent it
is directly proportional to the roughness on the surface. The
graph shows the Rz values = the maximum roughness proflie
height.
100
90
Gloss [RE] at 60
Roughness Rz [m]
18
16
80
14
70
12
60
10
50
40
30
20
10
0
0%
2%
4%
6%
8%
10%
Comparison of four DEUTERON MK matting agents in a solvent-based 2-C universal acrylic coating; matting effect as a
function of the roughness profile Rz.
100
Gloss [RE] at 85
90
80
70
60
50
40
30
20
10
In coating systems in which the presence of organic matting
agents does not result in the desired reduction of gloss, it may
be sensible to also use small amounts of inorganic matting
agents and/or waxes. Possible partial loss of the benefits of
the organic matting agent should in that case be taken into
account. In some cases, synergistic effects can also be
achieved.
For special applications DEUTERON GmbH offers a selection
of its own compounds.
0
0%
2%
4%
6%
8%
10%
DEUTERON
Matting
Comparison of the roughness profiles of various DEUTERON

matting agents and surface additives in a coil coating. Wet film
thickness ca. 25 m.
The differing particle size distributions directly manifest themselves on the surface and hence in the respective matting
effect.
16
Average depth of rougness [m]

14
12
10
Amount added
6.0 %
0
Pergopak M3 DEUTERON MK
DEUTERON
PMH-C
DEUTERON
MK-F
DEUTERON DEUTERON OG DEUTERON OG DEUTERON OG

MK-F6
8650
8652
8654
3.0 %
1.5 %
Graphical comparison of several DEUTERON PMU matting

agents with regards to the frequency of the respective particle
sizes (full lines) and particle size distributions (dotted lines).
The d50 and d90 values are specified. These mean that 50%
and 90% of the particles are smaller than or equal to the indicated values. The d-values can be directly read off the graph
(dotted lines).
100
90
80
70
60
50
40
30
Pergopak M3
20
DEUTERON MK
10
DEUTERON MK-F
DEUTERON MK-F6
DEUTERON PMH-C
0.1
Measurement method:
DEUTE RON hou se method e A PM-3 1
Par ticle size d istrib ution u sing a
Fritsch P artikel Size r An alysette 22
10
100
D-Value curves
DEUTERON
Matting
For solvents which evaporate at different rates there are also

other physical factors which determine the alignment and
orientation of the matting agents on the surface of the coating.
The slower the solvent evaporates, the less intense the convective currents and the less the evaporation cooling. This can
have a direct influence on gloss development.
When the gloss development is compared (see graph below),
organic matting agents show lower overall deviation than
silicas. The percentage difference is even higher.
The same behaviour is found for different drying temperatures
or application conditions. Organic matting agents can therefore be used to compensate or suppress surface differences
induced by the physical conditions.
Experience has shown that organic PMU matting agents can
be used to create surfaces which are significantly less sensitive to different application and formulation conditions.
These effects depend on the respective overall system and
are influenced by many factors. Experiments in our laboratory
have demonstrated that fluctuations in the degree of gloss are
less when organic matting agents are used.
25
Gloss 60 [GU]
20
15
10
2-C acrylate coating with about 35% mixed solids. The solvents
have differing volatility (evaporation rate), make up 22% of each

coating system and cause significant
differences in the change in the degree of gloss:
DEUTERON MK
ca. 3.0 RE 85 = ca. 16.4%
Wax-mod. SILICA
ca. 5.5 RE 85 = ca. 40.4%
Deuteron MK
Analogously, the roughness measurements show lower values

with increasing degree of gloss:
DEUTERON MK
ca. 4%
Wax-mod. SILICA
ca.12% lower Rz.
Acetone
Butyl acetate
Methoxypropyl acetate
Wax-modiefied silica
DEUTERON
The organic DEUTERON matting agents are very hard and

even in agglomerate form have a near-spherical shape. Their
presence on the surfaces of coatings leads to higher mechanical resistance than is possible with conventional matting
agents. On exposure to mechanical stress, the resistance of
the PMU particles on the surface first has to be overcome
before the actual coating matrix can be damaged. Naturally,
the behaviour depends on the performance of the total system. There are certainly differences between the mechanical
properties of hard/brittle and elastic/tough coating films which
have to be taken into account. In general the organic matting
agents are very effectively integrated in the coating matrix.
Detachment and subsequent acting as a "polishing agent"
only seldom occurs. Any mechanical load first has to mechanically abrade the particles of the matting agent. The mechanical resistance is also aided by the near-spherical shape of the
particles, which is also responsible for the favourable haptic
and slip properties. The use of more-protective PMU matting
Prototype of the scrubbing and scratch tester.
agents either alone or in combination with other agents enables the amount of more sensitive surface additives to be
reduced and in some cases eliminated altogether.
This can be tested for example using a modified scrub test.
Instead of using a hammer to which a scrubbing pad is
bonded, an automatic oscillating device is employed. This
eliminates the subjective factor and makes reproducible results possible. The nature and intensity of the stress can be
varied by the test weight, the scrubbing-sanding-polishing pad
and the number of strokes.
The evaluation using a reflectometer is achieved by measuring the change in the degree of gloss and by an image re-
Different scrubbing pads and weights.
cording system which records the changing surface via the

changing composition of the grey portions of the images and
their BW (black-white) histograms. Optionally, the surface
roughness can be measured with the profilometer method.
Measurement method:
DEUTE RON house method e A PM-45
Optical e valuatio n of p olish ing &
scr atch ing in the scru b te st
Macroscope with image database.
DEUTERON
Optical evaluation of the change in greyscale histograms allows more detailed statements to be made about the nature
and degree of stress or damage to a surface than is possible
merely from changes in gloss. The surfaces are evaluated as
greyscale images, with representation in 256 steps from 0 =
black to 255 = white. When a curve shifts to the right in the
histogram, namely into the whiter region, that is interpreted as
due to scratching. A shift of the grey values into the black
region is interpreted as the polishing of the surface and an
increase in the saturation.
When selecting the optical parameters, the exposure, white
balance, light angle to the surface and light intensity can be
precisely adapted for the surface under test in order to get
The following example shows the differing direction and mag-
optimum comparative results. On comparing the curves with
nitude of the change of a surface matted with silica and with
each other, information about their position and knowledge of
DEUTERON MK as well as the change arising from polishing
the load level allow statements to be made about precisely
or sanding tests.
when a surface is no longer polished but rather scratched.
200000
DEUTERON MK with no scrubbing
The resulting classification is a good approximation for evalu-
DEUTERON MK with polishing fleece
ating the surface. To do this otherwise, several individual
DEUTERON MK with abrasive fleece
Number of pixels
(Polishing)
parameters had to be used, including many subjective comparisons. The values show up differences in regions in which
150000
visual discernment is no longer possible.

100000
50000
Grey values
(Section from 0-255)
-> scratching / greying
0
10
20
30
40
50
60
70
80
Modifizied silica with no scrubbing

Silica with polishing fleece
200000
Silica with abrasive fleece
Number of pixels
(Polishing)
150000
DEUTERON MK
Wax-modified silica
Scrub test results after 256 strokes with 3M fleece no. 7498
100000
and with a 600 g weight of 5 cm diameter. Both coatings (2-C

solvent-based acrylic coating) are set to ca. 15 RE at an 85
50000
Grey values
(Section from 0-255)
-> scratching / greying
0
10
20
30
40
50
60
70
80
angle.
DEUTERON
Susceptibility to polishing
With regards to their sensitivity to polishing and sanding loads,
PMU matting agents generally perform better than silicas and
waxes.
The degree of gloss of the surface is a key parameter. Calculation of the polishing coefficients also gives one a tool which
indicates the intensity and direction of the change.
The polishing coefficient is the change given as the gradient
of the respective gloss curve to the base curve. Positive values indicate polishing, negative values indicate scratching.
The values are proportional to the change.
Gloss units 60
20
Polishing coefficient
19
15
10
Blocking resistance
The various matting additives have a certain mechanical influ-
19
18
0
18
-5
17
ence on the coating even during the drying process. In some

cases, systems matted with an organic agent also have considerable advantages with regards to blocking resistance and
early mechanical strength. Here the type and particle size of
the matting agent hardly pays a role.
-10
17
Number of strokes with Scotch fleece 7448
-15
16
0
16
32
48
64
80
96
112
128
With DEUTERON products there is normally a considerable

reduction of the blocking tendency. With mixed matting agent
systems there are sometimes synergistic effects, for example
earlier attainment of the final hardness and blocking resis-
Degree of gloss and calculated polishing coefficients (dotted

lines) using the example of a 2-C acrylic coating.
tance.
120
Pendulum damping according to Knig

[Oscillations]
The changes with DEUTERON MK are less.

100
DEUTERON MK
80
Modified silica
Pyrogenic silica
60
Dotted = Polishing coefficients

40
20
Drying time [Days]

0
0
10
12
Unmatted clear laquer

DEUTERON MK
Measurement methode:
DE UTERO N Informa ti on shee t
Theo retical pr incipl es o f
polish ing coe fficien ts
Pyrogenic silica
PP-Wax
Mix 1/3 of each additive
DEUTERON
Haptic properties & friction
The static friction is the force which has to be applied to over-
DEUTERON matting agents have a favourable effect on the
come the adhesion. The dynamic friction is the force required
haptic properties of the surfaces. The feel becomes signifi-
to maintain motion and is generally less than the static friction.
cantly softer, similar to surfaces modified with waxes. In con-
Differences in friction measurements for different additives

(amount added ca. 2.5%) at similar degrees of gloss (16-22
trast to the situation with most waxes, the ability of the surface
to be recoated is not adversely affected.
The polymethyl urea particles in the DEUTERON matting
RE):
agents are near-spherical or round in shape. The agglomer-
0.9
Friction Value []
0.8
ates also have this structure. That is the reason for the velvety
0.7
soft feel and the increase in surface smoothness. Friction on
0.6
the surface is reduced to a sort of "roll-off" effect.
0.5
In some cases the DEUTERON matting agents markedly

decrease the values for the static and dynamic friction. With
0.4
these matting agents the surfaces are considerably smoother
0.3
than when silicas are used, especially when higher amounts
0.2
of additive are employed.

0.1
With the DEUTERON OG types, friction values below those of
Measurement time [sec]

0
0
10
20
30
40
50
60
waxes and close to those of PTFE modified coatings can be

achieved, without disadvantages such as adverse effects on
Example of the changes in the static and dynamic friction for
recoatability and on intermediate layer adhesion. The surface
a nitrocellulose coating with different amounts of additive:
smoothness remains close to that of surfaces without addi-
0.9
Friction value []
tives.
Static friction
0.8
In contrast, the DEUTERON ST series of texturing agents give
0.7
a roughness effect which initially gives increased friction val-
0.6
ues. Only when the amount added in the relevant system is
0.5
high enough and the particles lie close to each other is there a
0.4
"roll-off" effect. Surfaces with customised anti-slip properties
0.3
or slip properties can be prepared, in particular by using com-
0.2
binations of additives.
0.1
Amount added [%]
0.0
0
0.8
Friction value []
Dynamic friction
0.7
0.6
0.5
DEUTERON MK
0.4
DEUTERON PMH-C
0.3
Pyrogenic silica
0.2
Synthetic silica
0.1
Amount added [%]
0.0
0
DEUTERON Wax TF
DEUTERON OG 863
Baseline with no additives
Measurement methode:
DEUTE RON hou se method e A PM-2 8
Smoo th ness measu remen t
DEUTERON
Viskosity and rheology
In many systems, the somewhat lower matting effect of the

PMU matting agents compared to classical silicas can be
compensated by increasing the amount added, without adversely affecting the viscosity. In general the viscosity does
not increase to same extent as it does with silicas. In addition,
the use of organic matting agents does not cause loss of
pseudoplasticity. Although smaller quantities of inorganic
matting agents are often required to gave the corresponding
degree of gloss, the viscosity at an equivalent degree of gloss
is considerably higher.
With DEUTERON matting products the rheological properties
have not been predetermined! Precise control of the viscosity
and flow behaviour rests with the formulator, who hence has a
greater number of options.
3000
Viskosity [mPas]
2500
2000
1500
1000
Pyrogenic silica
500
Synthetic silica
Wax-modified silica
Amount added [%]

0
DEUTERON MK
10
DEUTERON PMH-C
Viscosity as a function of the amount of additive in an high

solid alkyd coating for DIY use.
1400
Viskosity [mPas]
1200
1000
800
600
400
Pyrogenic silica
200
Synthetic silica
Degree of gloss [GU]

0
DEUTERON MK
DEUTERON MK-F
100
80
60
40
20
Viscosity as a function of gloss in a 2-C acrylic / nitrocellulose

universal coating.
DEUTERON PMH-C
DEUTERON
Viskosity and rheology

The flow behaviour of a coating system is dependent on many
factors. Normally thixotropic behaviour is desired in coatings.
High shear during application means low viscosity and good
flow. After application the system should build up its viscosity
again relatively quickly so that there is no running of the coating.
The lower effect of organic matting agents on the viscosity
and rheological properties allows more precise formulation of
the coating with special additives and raw materials. Destruction of the rheological properties due to mechanical influences, for example too high shear forces on silicas, does not
occur when using organic matting agents.
Comparison of the flow curves (viscosity plotted against
350
Viskosity [mPas]
speed) for the geometric program with increasing and then

decreasing speed. The steepness of the curves and viscosity
loss with increasing speed and redevelopment of the starting
viscosity provides a detailed description of the pseudoplastic
behaviour of a coating. Pseudoplasticity is the property of a
non-Newtonian* fluid to show a lower viscosity under high
shearing forces and this is a required base property of many
300
250
200
150
100
coating systems.
DEUTERON MK
Coating without matting agent
Mea su reme nt me th od:

DEUTERON house method APM-46
Viskosity det ermination with Brookfield
LV-DVIII Ultra rotary viskosimet er
Pyrogenes Silica
DEUTERON PMH-C
50
Speed [rpm]
0
0
10
20
30
40
50
60
70
80
90 100 110 120 130 140 150
Example of high viscosity and thixotropy:

A 1-C Aqua Parquet Lacquer with 10% matting agent
(for illustrative purposes)
DEUTERON MK
Synthetic silica
*= Newtonian fluid: shear stresss is proportional to the shear rate.
DEUTERON
Optical properties
Transparency
Although DEUTERON matting agents in the wet, unprocessed
coating system can cause considerable clouding, there is the
reverse effect in the dried coating.
Due to the high transparency of the actual particles, it is possible, despite the high degree of matting, to produce coatings
with relatively low film turbidity. This is important where there
are strict requirements on there being little change of colour
shade. Even when the amount of added matting agent is very
high in the dull range, where the matt surface alone has a
cloudy appearance, there is still a positive effect on the brilliance of the base surface. The wetting properties of the coating are not adversely affected.
Without matting
agent
Polypropylene
Wax
Pyrogenic silica
Anfeuerung (Warm-look)
Compared to conventional solid surface agents, DEUTERON
matting agents have little effect on the optical properties, for
Wax-treated silica
DEUTERON
PMH-C
DEUTERON MK
example the "warm-look" of the base surface. A more neutral

base surface appearance is possible using PMU matting
agents. That is still so in situations where somewhat higher
amounts of organic matting agents are required to achieve the
same degree of gloss as surfaces matted with silicas.
4% DEUTERON MK-F
Untreated wood
3,5% Silica
Unvarnished beechwood compared to two matted 2-C acrylic

varnishes. Degree of gloss ca. 15 RE 60.
DEUTERON
Weathering
DEUTERON matting agents are UV-resistant when used in

coating applications.
Our experience is that systems matted with our products do
not fundamentally differ from conventionally matted systems
when exposed to climatic conditions. This also naturally depends on the properties and effectiveness of the coating system. In some systems the resistance to moisture and UVresistance can however still be further improved. In other
systems there may be turbidity due to hydrophilic interactions,
which normally do not affect the resistance of the coating film
or its degree of gloss, etc. The use of hydrophobicising additives, the use of some silica and in particular the selection of
suitable binders can be advantageous here.
6
Evaluation category
Example changes in the degree of gloss for different concentrations of matting agent determined via the 2000 hour QUV
test
5
4
20
Change in the degree of gloss 60 [%]

10
0
0
-10
500
1000
1500
2000
Amount added [%]
-20
-30
QUV test duration [hours]
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
-40
-50
-60
-70
1% Matting agent
2000 hours QUV Test,

Alkyd coating, 200 m spiral-draw-down
Each cycle 4 hours UV exposure at 360 nm, 4 hours 60 condensation Classification on scale from 0 to 6.
0 corresponds to: No visible change.
6 corresponds to: Surface highly damaged / destroyed.
150
Change in the degree of gloss 60 [%]
DEUTERON matting agents and texturing agents are inert to

the film and pot preservatives typically used in coatings. Our
100
agents have long been employed in relevant products, for

example wood glazes, without negative effects on the pre-
50
servatives.
0
0
500
1000
1500
2000
DEUTERON MK
DEUTERON MK-F6
-50
DEUTERON PMH-C
QUV test duration [hours]

-100
Pyrogenic silica
Modified silica
PP-Wax
8% Matting agent
Baseline without additive
Measurement method:
DEUTERO N h ouse meth od APM- 49
QUV Alter nating cli mate te st in
accorda nce with DIN EN ISO 115 07
DEUTERON
Metallic- & effect-coatings
Aluminium pigments are effect-pigments and have a special

metallic appearance. The so-called flip-flop effect occurs with
metallic pigments and other effect-pigments, whereby differing
brightness is observed depending on the viewing angle or
angle of incidence of the light. This effect depends on the
nature, shape, size, texture of the edges and the orientation of
the pigments in the film. Due to the platelet-like structure of
these effect-pigments, they orientate themselves in the medium parallel to the substrate and the combination of many
small individual "mirrors" causes a metallic effect. The thinner
a pigment platelet, the easier it orientates itself in the coating
film and the more intense the flip-flop effect.
Due to their relatively narrow particle size distribution and

their compact and almost spherical shape, DEUTERON matting agents are able to markedly influence the flip-flop effect of
most metallic, glimmer and mica pigments. The additive particles are incorporated into the coating matrix between the
pigment platelets and so define the distance between the
pigment particles. Unlike the situation with conventional wax
Incident Light
Directional reflection
Diffuse reflection
Aluminium pigment
additives, the flip-flop effect is consequently not stabilised or

strengthened, but rather attenuated. The brightness remains
constant over a larger angle range and generates a more
Coating matrix
uniform brightness effect. This is desirable in applications
Base surface
where no marked flip-flop effect is wanted.
"Ideally" orientated pigment platelets provide greater directional

reflection due to the lower area of the edge surface relative to the
horizontal surface.
In unorientated pigments there is mainly diffuse reflection.
With additives having a relatively narrow particle size distribution,

the distances between the effect-pigment particles can be fixed
and orientated.
Additives of differing particle size allow the effect to be optimised

by selecting the optimum particle size for the relevant pigment.
By adding different amounts of the additive, the flip-flop effect

can also be influenced and adjusted.
DEUTERON
Metallic- & effect-coatings
Not in all applications is a strong flip-flop effect desired for

metallic surfaces. When viewed from low angles, an intensive
flip-flop effect leads to very little reflection and hence a dark
appearance. In order to overcome this, fine solid particles can
be employed as an additive to reduce the flip-flop effect and
generate greater diffuse reflection on the surface over a large
viewing angle. This allows totally different optical effects to be
achieved, without suppressing the metallic effect and brilliance. The parallel alignment of the pigments is promoted by
The DEUTERON matting and surface agents
the finely ground polymethyl urea resins which act as
can be used to adapt and adjust metallic coat-
"spacers" between the individual metallic pigment particles.
ings and effect-coatings to each other.
The particles form a network structure which prevents tilting of
In order to influence the metallic pigments, a
the small metal platelets as soon as the desired orientation in
dose of only ca. 0.1% to 1.0% in the total sys-
the film has been achieved. Uniform brilliance with less differ-
tem or ca. 2% to 20% based on the pigment is
ence in brightness is achieved, even at different viewing an-
recommended.
gles.
The organic polymethyl urea particles do not act as rheologyadditives or as antisettling agents! If necessary, other additives can be used in conjunction with the PMU particles.
The DEUTERON products are fully compatible with commonly
used wax additives and rheology-additives.
EVA-wax-additive
Light 45 to the surface

Observer 90 to the surface
(45 to the light source)
Light 45 to the surface

Observer 45 to the surface
(90 to the light source)
Additives:
No additive
DEUTERON MK-F
DEUTERON
Metallic- & effect- coatings
A narrow particle size distribution allows largely similar pig-
If classical wax additives are used to stabilise or strengthen
ment platelets to be aligned next to each other and hence
the flip-flop effect in the same coatings, the effects may cancel
produces a uniform effect. The broader the particle size distri-
each other out. However, it is also possible that the combina-
bution, the less uniform the orientation of the pigment particles
tions produce the desired results. In order to test the scope of
to each other. The larger the distance between the pigment
all these influences, it is necessary to carry out laboratory
particles, the more uniform the surface appearance, namely
tests for each specific application. The mutual dependence
the flip-flop effect is attenuated and the surface has a more
and selection of the raw materials is too complex for us to be
even brightness over a larger viewing angle. DEUTERON MK
able to give you detailed recommendations here.
products are very suitable for this application. In order to retain the fine brilliance, the finer products or wet-ground DEUTERON OG can be used.
% difference compared to a mirror
Reflected fraction [%]
Angle of the observer to the light source []

Without additive
EVA-wax dispersion additive
Reflection curves for different additives at constant illumination 45 to the surface. For comparative purposes, a mirror
Pergopak M3
DEUTERON MK-F6
DEUTERON PMH-C
and aluminium plate were also tested. The mirror measure-
DEUTERON OG 8654
ment at 90 to the light source was defined as the standard =
Mirror
100% value.
Aluminiumplate
Measurement method:
DEUTERO N h ouse meth od APM- 48
Compariso n of the b rigth- dark-e ffect
of effect coatings
DEUTERON
Soft-feel coatings
Solvent-based
Water-based
UV-curing
Dashboards / car interiors
Entertainment electronics
Furniture
Leather & upholstery
Communication electronics
Special coatings known as soft-feel coatings are used to coat

objects to give a special surface feel. The most important
components in soft-feel coatings are suitable binders. In addition, special requirements are also put on these surfaces with
regard to the abrasion resistance and scratch resistance at
high degrees of matting. Soft-feel coatings usually have very
low gloss and the micronised organic matting agents in the
DEUTERON MK and PERGOPAK series are ideally suited for
this application.
The narrow particle size distribution and the particle shape
intensifies and promotes the soft-feel of these coatings. The
use of the mentioned matting agents produces highly scratchresistant and abrasion-resistant coatings, whose elastic properties are not adversely affected. This is also so when high
amounts of additives are employed. The products are easy to
incorporate into the coating formulations. The use of wetting
and dispersing agents is generally not required.
In some cases it may be either necessary or desirable to employ silicas, along with the organic matting agents, in order to
adjust the degree of matting. The optimum ratio of organic to
inorganic matting agents must be carefully determined by the
coating manufacturer in laboratory tests. The presence of
you
end re
m
u
m
roch
reco
We o our b oatings
rt
lc
refe oft - fee
s
on
SiO2 may adversely affect the surface properties, for example

the scratch resistance. The use of waxes can influence the
defined softening temperature, for example the resistance to
polishing.
DEUTERON
Coatings for glass
A special application field for DEUTERON matting and texturing agents is the coating of glass and transparent plastics.
These products are particularly suitable for matting and effectcreation.
Due to their unique property profile, surfaces can be created
ranging from wax-like, velvety-soft, silky-gloss and dull
through to special effects such as frosted and structured surfaces. A further plus is the high mechanical resistance of this
product line. The transparency of the
base surface is not impaired here
because the particles themselves are
colourless
and
transparent.
The
clouding effect due to the matt surface

cannot be prevented because this is
due to diffuse reflection at the surface.
glass
d
e
t
t
Ma
Examples of glass coatings in accordance with our standard formulation
e
Etch
s
ffect
no. 93 with DEUTERON MK /

Pergopak M3 and DEUTERON ST-L.
Du
ll
Ma
tt &
St
ru
ctu
re d
t ef
Fros
fects
ptics
o
x
Wa
DEUTERON
At a glance
Duroplastic organic surface additives offer a variety of formulation options and can often be used
to improve coating systems and printing inks.
No fundamental comparison can be made with silicas and
waxes. These products cannot be used in straight exchange or
as alternatives. PMU matting agents cannot be considered to
be a replacement for inorganic matting agents or waxes.
The amount of organic matting agent required in a coating
cannot be easily calculated in percentage terms.
Organic matting agents have different property profiles than
inorganic matting agents and waxes.
Whether or if an organic matting agent, either alone or in combination with other matting agents, can or should be used or
can improve the required coating properties must always be
tested in suitable experiments. No generally applicable recommendations can be given here which cover all systems.
For some properties, organic matting agents offer significant advantages and this can be utilised in specific applications. The following table summarises the influence of the various types of matting agents:
Organic
Onorganic
Waxes
Resistance to polishing
Rheology neutrality
+
+
Viskosity constancy
Resistance to chemicals
Mechanical resistance
Recoating properties
Transparency
Elasticity of the film
= Very good
= Good
= Moderate
* = highly dependent on the amount added
DEUTERON
Product overview
Overview of organic matting agents

Overview of ground polyurea pastes
Product data sheets:
DEUTERON MK, MK-F, MK-F6
DEUTERON PMH-C
PERGOPAK M3
DEUTERON ST-L, ST, ST-S, ST-G
Overview of the DEUTERON product range
Ordering samples
Please find the product data sheets and safety data sheets
from our complete product range on our internet sides.
DEUTERON GmbH
++49 (0)421 / 48 32 27 Fax: ++49 (0) 421 / 48 36 02
DEUTERON
Typical Values of Organic Matting Agents
n
tio
ity
e
p
r
ns
o
e
alu
s
d
v
b
0
a
lk
pH
d5
oil
bu
Product
0
d9
notes
DEUTERON MK
325
150
8,6
6,3
13,8
Heat-resistant up to 200 C, light fast and

weather-resisting.
DEUTERON MK-F
278
150
8,7
4,6
10,6
Low particle size. Use primarily in thin filmsystems.
DEUTERON MK-F6
251
120
7,5
3,4
6,7
Low particle size. Use primarily in thin filmsystems.
DEUTERON MM 659
238
100
7,6
7,4
17,1
For UV-curing systems.
DEUTERON MM 669
183
150
7,4
6,3
14,5
For UV-curing systems.
DEUTERON MM 680
230
100
7,5
6,7
13,9
2-component PU-systems
DEUTERON MM 682
182
145
8,5
6,0
12,8
coil coating systems
DEUTERON MM 684
206
120
7,8
6,0
13,3
do it yourself systems
DEUTERON MM 823
288
150
9,0
6,3
17,3
PTFE modified, excellent heat resistance.
DEUTERON PMH C
167
220
10,0
5,5
12,1
Very low influence on viscosity.
PERGOPAK M3
333
140
8,7
7,0
16,0

weather-resisting.
PERGOPAK M4
325
150
8,6
6,4
14,2

weather-resisting.
Typical Values of Micronised Waxes

n
int
tio
ity
o
p
s
p
r
n
o
g
de
bs
tin
0
k
a
l
l
l
e
d5
oi
bu
m
Product
0
d9
notes
DEUTERON WAX A
53
300
141
6,0
14,4
Polyamide Wax
DEUTERON WAX MPO
51
280
105
5,2
10,7
Polyolefin Wax
DEUTERON WAX PP
43
300
139
6,6
14,4
Polypropylene Wax
DEUTERON WAX TF
50
300
106
4,9
10,6
PTFE-modified Polyolefin WAX
All values are based on average analysis and are therefore only approximate values.
These values are not always a component of the respective specifications.
Notes:
Oil absorption value:
Bulk density:
pH - Value:
Particle size analysis:
Melting point
Method APM - 30 (house method), Palatinol N, dimension: g/100g

Method APM - 13 (house method), dimension: kg/m3
Method APM - 10 (house method)
Methods MWM 29; APM - 31 (house method), dimension: m
Methode APM - 12 (housemethod), Dimension: C
DEUTERON GmbH
TD-0001.2 - Typical Values MM
www.deuteron.com / contact@deuteron.com
P.O.Box 1645*D-28822 Achim*HRB Walsrode 120187*Phone ++49(0)421 / 483227*Fax ++49(0)421 / 483602
DEUTERON
Overview of Finest Grinded Polymethylurea-Pastes
r)
ne
t
n
n
i
e
nt
Th
lv
nte
o
So tive
C
ac
lid
d50
(Re
So
Product
9
d9
Remarks
DEUTERON OG 861
Shellsol A 150 ND
ca. 32%
3,5
12,0
solvent based systems
DEUTERON OG 8612
Shellsol A 150 ND
ca. 32%
2,3
7,0
DEUTERON OG 8614
Shellsol A 150 ND
ca. 32%
< 1,5
< 3,5
DEUTERON OG 863
2-Propanol
ca. 32%
3,5
12,5
waterborne systems
DEUTERON OG 8632
2-Propanol
ca. 32%
2,3
7,0
waterborne systems
DEUTERON OG 8634
2-Propanol
ca. 32%
< 1,5
< 3,5
waterborne systems
DEUTERON OG 8650
Butyl acetate
ca. 30%
3,5
12,5
DEUTERON OG 8652
Butyl acetate
ca. 30%
2,3
7,0
DEUTERON OG 8654
Butyl acetate
ca. 30%
< 1,5
< 3,5
DEUTERON OG 8670
Water
ca. 22%
3,5
12,5
waterborne systems
DEUTERON OG 8672
Water
ca. 22%
2,8
8,0
waterborne systems
DEUTERON OG 8674
Water
ca. 22%
< 2,0
< 5,0
waterborne systems
DEUTERON OG 8803
DPGDA
ca. 30%
3,5
12,0
radic. UV-Systems
DEUTERON OG 8805
DPGDA
ca. 30%
2,8
8,0
radic. UV-Systems
DEUTERON OG 8807
DPGDA
ca. 30%
< 2,5
< 7,0
radic. UV-Systems
DEUTERON OG 8810
GPTA
ca. 30%
3,5
12,0
radic. UV-Systems
DEUTERON OG 8812
GPTA
ca. 30%
2,8
8,0
radic. UV-Systems
DEUTERON OG 8814
GPTA
ca. 30%
< 2,5
< 7,0
radic. UV-Systems
DEUTERON OG 8820
TMPEOTA
ca. 30%
3,5
12,0
radic. UV-Systems
DEUTERON OG 8822
TMPEOTA
ca. 30%
2,8
8,0
radic. UV-Systems
DEUTERON OG 8824
TMPEOTA
ca. 30%
< 2,5
< 7,0
radic. UV-Systems
All values are based on average analysis and are therefore only approximate values.
These values are not always a component of the respective specifications.
Note:
Particle size analysis:
Methods MWM 29; APM - 31 (house method), dimension: m

TD-0004 - bersicht OG Pasten(e)
DEUTERON GMBH
P.O. Box 1645*D-28822 Achim*HRB Walsrode 120187
Phone ++49(0)421 / 483227*Fax ++49(0)421 / 483602
Sc
ra
tc
h
re
Sl
si
ip
st
pr
op anc
R
er
e
es
tie
is
s
ta
n
W
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ea
to
th
so
er
Ab
lv
in
en
g
ra
an
ts
si
d
on
U
Ea
V
se resi
re
st
si
of
an
st
in
St
an
ce
co
ab
ce
rp
le
o
t
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o
at
Li
t
io
ttl
em
e
pe n
ef
fe
ra
R
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t
ec
ur
to
e
oa
n
an
vi
t
sc
d
An abi
s
lit
o
tis
y
ity hea
bl
oc
r
R
k
in
ea
g
ct
iv
it
R
es y-n
eu
is
ta
tr
Ea nce al
se
to
of
po
cl
N
lis
e
eu
hi
ng
tra ani
ng
l
in
M
fra
et
al
-m red
si
ar
An
g
ki
ting nat
sl
ur
ip
e
Fl
(c
ex
am
ib
ilit
ou
y
N
fla
re
eu
ge
te
tra
)
l e ntio
n
ffe
ct
on
ca
ta
ly
st
s
+ = very suitable
O=
suitable
= not suitable
Matting agents
Pergopak M3
7.2
17.5
Powder
DEUTERON MK
6.3
13.8
Powder
DEUTERON MK-F
4.6
10.6
Powder
DEUTERON MK-F6
3.5
6.5
Powder
DEUTERON PMH-C
5.5
12.1
Powder
DEUTERON MM 680
6.7
13.9
Powder - Compound
DEUTERON MM 682
6.0
12.8
Powder - Compound
DEUTERON MM 659
7.4
17.1
Powder - Compound
DEUTERON MM 684
6.0
13.3
Powder - Compound
DEUTERON MM 823
6.3
17.3
Powder - Compound
DEUTERON MM 669
6.3
14.5
Powder - Compound
DEUTERON MM 677
Dispersion
Water
+
+
+
+
+
o
o
o
o
+
o
+
+
+
+
+
+
o
o
o
o
+
o
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
o
o
o
o
+
o
+
+
+
+
+
+
+
+
+
+
o
+
+
+
+
+
+
+
o
o
o
o
o
o
+
+
+
+
+
+
o
o
o
o
+
o
+
+
+
+
+
+
o
o
o
o
o
o
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
o
o
o
o
+
o
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
o
o
o
o
o
o
o
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
o
o
o
o
+
o
+
+
+
+
+
+
o
o
o
o
+
o
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
o
+
o
+
o
o
o
o
o
+
o
+
o
+
+
o
+
+
o
+
o
o
o
o
+
+
+
+
o
+
o
o
+
+
+
+
+
+
+
+
+
+
-
+
+
+
+
o
o
o
o
+
o
+
o
+
+
+
+
+
+
+
+
Polypropylene wax, general
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
+
o
o
o
o
o
o
o
o
+
+
+
+
+
+
+
+
+
+
+
+
Texturing agent, general
General
General
General
General
General
Solvent-based PU, AC, EP systems
Baked coatings, can & coil coatings
UV coatings
PMU in combination with silicas
PTFE wax modification of PMU polymer
UV coatings
Water-based systems
Fine-matting
DEUTERON OG 861X
1.5-3.5
3.5-12
Dispersion
Shellsol A 150
DEUTERON OG 863X
1.5-3.5
3.5-12
Dispersion
Isopropanol
DEUTERON OG 865X
1.5-3.5
3.5-12
Dispersion
Butyl acetate
DEUTERON OG 867X
2-3.5
5-12.5
Dispersion
Water
DEUTERON OG 880X
2.5-3.5
7-12
Dispersion
DPGDA
DEUTERON OG 881X
2.5-3.5
7-12
Dispersion
GPTA
DEUTERON OG 882X
2.5-3.5
7-12
Dispersion
TMPEOTA
Thin film systems, printing inks & printing lacquers

UV, printing inks & printing lacquers
Waxes
DEUTERON Wax PP
ca. 5 m
Powder
DEUTERON Wax A
ca. 7 m
Powder
DEUTERON Wax TF
ca. 5 m
Powder
ca. 5 m
Powder
DEUTERON Wax MPO
Polyolefin wax, general

PTFE modifified polyolefin wax, general
Polyamide wax, general
Coarse-matting
DEUTERON ST-G
20
30
Powder
DEUTERON ST-S
26
38
Powder
DEUTERON ST
31
43
Powder
DEUTERON ST-L
40
57
Powder


Micronized mattingplastic
Chemical Description
Application
Polycondensate plastics
DEUTERON MK-matting agents are suitable as exclusive

matting agents for water-borne, solvent-containing and solvent-free systems, air-drying as well as stoving. They can also
be used in printing inks, wood lacquers, UV-curing coating,
coil-coatings, lacquers on foils, aqueous wood- and furniture
varnishes.
Physical Data
DEUTERON
MK
MK-F
MK-F6
approx.
150
150
120
Specific weight approx.
1,4
1,4
1,4
Particle size d50 approx.
6,3
4,6
13,8
Oil absorption* approx.
325
Bulk density
Flash point
g/l
The finer types are suitable where particularly low dry film
thickness is applied or where very smooth surfaces have to be
realized.
3,5
10,6
6,5
The combination with inorganic matting agents is possible and

leads to improved mechanical resistances. Scratch resistance
and resistance against polishing will be increased.
278
251
Does not apply
Appearance
Fine white powder
* ( g/100g Palatinol N / DIN ISO 787/5 )
Dosage
The quantity depends first of all on the requested gloss and
the used binder. Additions of 1,0 - 15,0 % calculated on total
formulation are common. The exact dosage should be determined by own trials.
Processing
Properties
DEUTERON MK matting agents are micro-ground resp. micronized powders. The fineness allows for the use of DEUTERON MK-products in a wide field of applications for producing satin-flat and satin-gloss coatings. The small binder demand of DEUTERON MK only leads to a nonessential viscosity influence, which is significant for UV-curing lacquers. DEUTERON MK is resistant against solvents and chemicals which
are customary in the paint industry. These products can also
be used in exterior applications. Adjustments to specific requirements can easily be made due to the available particle
sizes.
DEUTERON MK-types show a heat resistance of more than
200 C, temporarily up to 300 C. Weather resistance and
light stability are most favorable. They are suitable for the use
in UV and water-based coatings to decrease the blocking
without worsening of the recoatability.
Because of their excellent dispersing properties DEUTERON MK-products can be stirred into the liquid phase with
a simple stirrer. This is applicable for water-based and solvent
-based systems. It is also possible to grind them with the mill
base to obtain an optimum of dispersion in paints containing
pigments.
Storage conditions
DEUTERON MK-types can be stored for at least 24 months at
room temperature and dry conditions.
Package Sizes
Paper bag (10 kg net)
DEUTERON MK, MK-F, MK-F6 are insolvable in standard

solvents used in the industry.
Safety Regulations
In some cases the surface properties can be increased by

using a combination of DEUTERON MK with a suitable wax,
e.g. DEUTERON WAX PP or DEUTERON WAX TF.
DEUTERON MK matting agents are not classified as hazardous substances or preparations according to EU Directive
67/548/EWG or its amendments.
Due to the fine fractions of the matting agents, measures for
dust protection must be heeded and the build up of electrostatic charge must be avoided.
This leaflet intends to give technical advice without warranty and does not claim to be complete.
DEUTERON GmbH
P.O. Box 1645 D-28822 Achim HRB Walsrode 120187
Phone ++49 (0)421 / 48 32 27 Fax ++49 (0)421 / 48 36 02
V01.274008
Page 1 of 1
DEUTERON PMH-C
Organic matting agent / micronized thermoset
Chemical Description
Dosage
Polymethylurea
The optimum in dosage depends on the required degree of

gloss and the character of the used binder. The addition can
be 1.0 7.0 %. The optimum in dosage should be determined
by own trials.
Physical Data
Appearance
Oil Absorption*
fine, white powder

approx. 167 g
Processing
* g/100g Palatinol N (DIN ISO 787/5)
Bulk density
Specific Weight
Water Absorption
Particle size d50
Particle size d90
Flash Point
approx. 220 kg/m

approx. 1,4 g/cm
approx. 215 g/100 g
approx. 5,5 micron
approx. 12,1 micron
does not apply
Properties
Due to its excellent dispersing properties DEUTERON PMH-C

can be easily incorporated with a mechanical stirrer or dissolver. Attention has to be paid on a sufficient rate of shear. This
also applies for aqueous lacquers systems. The use of a wetting agent is generally not necessary. Due to its good temperature resistance DEUTERON PMH-C can be also added to
the mill base.
Storage conditions
DEUTERON PMH-C (compact) is a micronized, pure thermoset with compact particle structure. Due to its excellent fineness the product can be used in a wide application for matting
of varnishes and coatings or as an additive.
DEUTERON PMH-C can be stored for at least 24 months at

room temperature and dry conditions.
Even in higher dosages, the products specific oil absorption

value gives favorable results regarding viscosity increase.
Flexibility of the coating will be spoiled only insignificantly by
the use of DEUTERON PMH-C as matting agent.
Package Sizes
As a thermoset, DEUTERON PMH-C in many cases increases the blocking stability of coatings, whenever the character of the used binder shows tendency to thermoplasticity.
Safety Regulations
DEUTERON PMH-C is resistant to most customary solvents

in use in the coatings industry. The product also offers good
chemical resistance.
DEUTERON PMH-C is resistant to temperatures above
200 C. Color fastness and weather resistance are excellent.
The use in exterior applications is possible practically without
limitation. The coatings are recoatable. DEUTERON PMH-C is
free of waxes.
Paper bag (15 kg net)
DEUTERON PMH-C is not classified as a hazardous substance or preparation according to EU Directive 67/548/EWG
or its amendments.
Due to the fine fractions of the product, measures for dust
protection must be heeded and the build up of electrostatic
charge must be avoided.
In certain fields of application the products effectiveness in

matting can be increased by combining it with small amounts
of Si02.
Application
DEUTERON PMH-C can be used as a matting agent in aqueous and solvent based coating systems. A suitable matting
agent combination can be created for solvent free, radiation
curing varnishes with the additional use of SiO2 .
With its favorable oil absorption value the product is predestinated for coatings with high flexibility, for instance coil coatings and leather finishes.
In powder coatings the presence of DEUTERON PMH-C can
improve fluidity and spraying property of the powder coating.
DEUTERON GmbH
Phone ++49 (0)421 / 48 32 27 Fax ++49 (0)421 / 48 36 02
V01.274008
Page 1 of 1
PERGOPAK M 3
Einsatzbeispiele /
Applications
PERGOPAK wird als Lackhilfsmittel mit mattierenden Eigenschaften in der

Lackindustrie eingesetzt.
Die Hauptvorteile sind: intensive Mattierungswirkung geringe Rheologiebeeinflussung Verbesserung der Kratzfestigkeit Elastizitt, Adhsion,
Witterungs-, Temperatur- und Glanzstabilitt.
PERGOPAK is used as a matting and effects agent for the paint and varnish
industry.
Its main advantages are: high matting efficiency low impact on rheology
improved scratch and abrasion resistance improvement of adhesion and
elasticity excellent weather resistance and gloss retention
Durchschnittsanalyse /
Typical analysis
Chemische Konstitution /
Chemical composition
Polymethylharnstoffharz mit ca. 0,6 %

freien Methylolgruppen
Polymethyl urea resin with approx. 0.6 %
reactive methylol groups
Dichte / Density
[g/cm3]
Schttdichte / Bulk density
[kg/m3]
ca. 80
Spez. Verpackungsgewicht (gepresst)

Packed bulk density (compressed)
[kg/m3]
ca. 200
[ m]
[ m]
[ m]
6 8.5
15 19
36
Spezifische Oberflche (BET) /

Specific surface (BET)
[m2/g]
14 22
laufnahme / Oil absorption
[cm3/100g]
Teilchengre (Laser Beugung) /

Particle Size (laser diffraction)
d50
d90
d100
Brechungsindex / Refractive index
Stand / Issue:
12.02 D
1.47
ca. 310
1.607
Feststoff-Gehalt / Solid content
[%]
83
Zersetzungstemperatur /
Decomposition temperature
[C]
> 220
Lagerstabilitt / Storage stability
Jahre / years
Die oben genannten Werte sind nur als Richtwerte zu verstehen und nicht etwa als zugesicherte Eigenschaften.
The above mentioned values should be taken only as indications and not as guaranteed properties.
>1
Shipping Information
Transportation classification: not regulated for transportation

Harmonized tariff number: 39091000
Packaging and minimum order quantity information is available from sales
or customer service.
Safety and Handling

Information
For specific safety, toxicity and handling information, please refer to the
material safety data sheet on this product.
Chemical Registration
Numbers
CAS No. :
ALBEMARLE and the Albemarle signet are registered

trademarks of Albemarle Corporation.
The information presented herein is believed to be
accurate and reliable, but is presented without guarantee
or responsibility on the part of Albemarle Corporation.
It is the responsibility of the user to comply with all

applicable laws and regulations and to provide for a safe
workplace. The user should consider any information
contained herein, including information about any
health or safety hazards, only as a guide, and should
take those precautions that are necessary or prudent
to instruct employees and to develop work practice
procedures in order to promote a safe work environment.
Further, nothing contained herein shall be taken as
an inducement or recommendation to manufacture or
use any of the herein described materials or processes
in violation of existing or future patents.
Issue: October 2007
2007 Albemarle Corporation
9011-05-6
EC-/EINECS No.: Polymer Exempt

ENCS:
7-576
ECL
KE-35175
AMERICAS
ASIA PACIFIC
Albemarle Corporation
451 Florida Street
Baton Rouge,Louisiana 70801
Phone:+1-225-388 -7402
Fax:+1-225 -388 -7848
Albemarle Asia Pacific Company

480 Lorong 6 Toa Payoh
#16-01 HDB Hub East Wing
Singapore 310480
Phone: +65-6424-8400
Fax: +65-6424-8401
Albemarle China Corporation

China World Tower, Room 1317
No.1 Jian Guo Men Wai Avenue
Beijing 100004, China
Phone: +86-10-6505-4153 and -54
Fax: +86-10-6505-4150
Albemarle Overseas Development

Corporation
16th Floor, Fukoku Seimei Building
2-2, Uchisaiwaicho, 2-Chome
Chiyoda-ku, Tokyo 100-0011, Japan
Phone: +81-3-5251-2541
Fax: +81-3-3500-2547
Albemarle Korea Corporation

602 Trade Tower
World Trade Center
159-1 Samsung-dong, Kangnam-gu,
135-729 Seoul, Korea
Phone: +82-2-555-3005
Fax: +82-2-555-3002
EUROPE, MIDDLE EAST,
AFRICA
Albemarle Europe SPRL
Parc Scientifique de LLN
Rue du Bosquet 9
B-1348 Louvain-la-Neuve Sud,Belgium
Phone:+32-10-48-1711
Fax:+32-10-48-1717
Martinswerk GmbH
Klner Strae 110
D-50127 Bergheim
Phone:+49-2271-902-424
Fax:+49-2271-902-557
Albemarle Chemicals China

Corporation
Room 2208, Shui On Plaza
No. 333 Huaihai Zhong Road,
Shanghai 200021, China
Phone: +86-21-5306-1360
Fax: +86-21-5306-2420
INTERNET
www.albemarle.com
www.martinswerk.de

Duroplastic texturing agents for coating systems
Chemical Characteristic
Dosage
Crosslinked methyl urea resin
The amount added to coatings depends on the desired surface texture. This in turn depends on the thickness of the
applied coating. Even the addition of 1% results in textured
surfaces. If desired, 15% or more can be used, due to the low
binder requirement. The optimum amount required to realize a
desired effect must always be determined by own trials.
Physical Data
DEUTERON
ST-L
ST ST-S ST-G
Bulk density approx.
500
500
500
500
Specific weight approx.
1.4
1.4
1.4
1.4
40
31
26
20
57
43
38
30
Appearance
g/l
Fine white powder
Processing
The texturing agents can be mixed into the coating using a
speed-stirrer or dissolver. Concomitant use of wetting agents
is not required, even when used in water-based systems. The
products are very stable to shear but dispersion processes,
that can be caused by grinding, must be avoided. In pigmentcontaining systems, texturing agents must therefore, where
required, be added after grinding the pigment.
Storage Conditions
Properties
DEUTERON ST texturing agents are powders. They give
coatings a surface texture. The nature and degree of texturing
depends on the film thickness that is applied and the ratio of
texturing agent to binder.
The texturing agents have different particle size distributions.
The coarser grade induces more intense texturing with good
maintenance of gloss. The finer grade gives finer texturing.
Depending on the specific formulation this can lead to a reduction in the degree of gloss. The coarser fractions are responsible for the texturing, whilst the finer particles can lead to
matting.
Depending on the duration of exposure to heat, the texturing
agents are thermally stable to well over 200 C. The products
do not melt and this therefore distinguishes them from wax
and amide-based products. The texturing agents are resistant
to the solvents typically used in coatings.
DEUTERON ST texturing agents can be stored for at least 24

months at room temperature under dry conditions
Package Sizes
Plastic sacks (20 kg net)
Safety regulations
DEUTERON ST texturing agents are not classified as hazardous substances or preparations according to EU Directive
67/548/EWG or its amendments.
Due to the fine fractions of the texturing agents, measures for
dust protection must be heeded and the build up of electrostatic charge must be avoided.
Depending on the composition of the coating, the texturing

agents may tend to sediment during storage of the coating. In
such cases it is therefore necessary to employ an anti-settling
agent.
Application
DEUTERON ST texturing agents can be used in both solventbased and water-based coating systems. Potential applications include coil-coating systems and coatings for plastic
surfaces. They can be used to customize the haptic and optical surface properties and can be used as functional additives
to reduce the coefficient of sliding friction.
DEUTERON GmbH
Phone ++49 (0)421 / 48 32 27 Fax ++49 (0)421 / 48 36 02
V01.274008
Page 1 of 2

Duroplastic texturing agents for coating systems
The images below give an overview of the particle sizes. DEUTERON ST-L, ST and ST-S are manufactured via fractionation using
sifting machines. DEUTERON ST-G is prepared by grinding.
DEUTERON GmbH
Phone ++49 (0)421 / 48 32 27 Fax ++49 (0)421 / 48 36 02
V01.274008
Page 2 of 2
The product range

of DEUTERON GmbH
1 - Matting Agents
based on urea condensation polymers
2 - Mar and Slip Agents
based on urea condensation resins, silicone resins or waxes / paraffins
3 - Surface additives
based on urea condensation resins, silicone resins or waxes / paraffins
4 - Conductivity Agents
based on quaternary ammonium compounds
5 - UV-Initiators
for cationic curing (no benzene, low odour, high curing speed)
based on bis-(dodecylphenyl) iodonium hexafluoroantimonate

or bis-(4-methyl-phenyl) iodonium hexafluorophosphate
suitable in native raw materials
6 - Thickening- and Thixotropy Agents
based on Xanthan Gums
7 - Wetting- and Dispersing Agents
based on amin oleates, Sodiumpolyaldehydcarboxylates
8 - Air Release Agents and Defoamers
based on fatty acids / N-heterocyclus-derivatives
9 - Specialities
among other things...Structure Agents
based on duroplastic (thermosetting) polymers

no melting point
temperature resistant depending on the time more than 200C
This leaflet intends to give technical advice,
but without warranty and does not claim to be complete
The staff of DEUTERON GmbH is at your disposal!
DEUTERON GmbH
P.O.Box 16 45 * D-28822 Achim * HRB Walsrode 120187
Phone ++49 (0)421/48 32 27 * Fax ++49 (0)421/48 36 02
DEUTERON
Starting formulations
RR 44 - Water-based 2-C Epoxy Primer

RR 56 - Aqua 1-C Parquet Lacquer
RR 62 - 2-C Soft-Feel Coating
RR 64 - 2-C Soft-Feel Coating, black
RR 77 - Aqua 1-C PUR Baked Coating
RR 78 - Aqua Topcoat
RR 82 - Aqua Clear Lacquer for Wood
RR 87 - 1-C Baked Soft-Feel Coating
RR 90 - UV Powder Coating, Colourless
RR 91 - Coil Coat with Structuring Effect
RR 92 - Baked Texturing Coating
RR 93 - 2-C Structured Coating for Glass
RR 94 - Baked Texturing Coating
RR 95 - 2-C Soft-Feel Clear Lacquer
RR 96 - 2-C Texturing Coating
RR 97 - Metallic Effect-Coating with reduced Flip Flop
RR 98 - Aqua UV Floor Coating
RR 99 - Aqua 1-C Wood Varnish
RR 101 - Aqua 1-C Furniture Lacquer
RR 102 & 103- Aqua 2-C PUR Floor Coating
RR 104 - Water-based Decorating and Building Paint
DEUTERON GmbH
++49 (0)421 / 48 32 27 Fax: ++49 (0) 421 / 48 36 02
Starting formulation 44
Aquaeous
2-component epoxi under coating and primer
__________________________________________________________________________________
Part A:
1
2
3
4
5
6
7
8
9
29,00
1,00
2,00
8,00
0,50
18,00
12,00
4,00
25,50
Epilink DP 660
Surfynol 420
Foamex 815 N
Titandioxid
Anorganic black pigment
Blanc fix Micro
Talc 10 M 2
DEUTERON MK
Wasser, demineralized
(1)
(1)
(2)
(6)
(6)
(3)
(4)
(5)
(3)
Epires ER 8
(1)
100,00
Part B: Hardener
10
30,0
Technical Data
Mixing ratio*:
Solid content laquer:
Solid content hardener:
Mixing solid content:
10:3
app. 71,5%
100%
78,8%
After mixing Part A and B, water (approx. 10%) should be added for brush and roller applications.
The formulation can be used as primer or topcoat on floorings. The system can be processed by roller coating application,
application by brush or spraying. DEUTERON MK as matting agent imparts the coating a uniform flat effect with good abrasion
resistance.
Manufacturers / Suppliers
(1)
(2)
(3)
(4)
(5)
(6)
Air Products and Chemicals Ltd., NL

Tego Chemie GmbH, D
Sachtleben Chemie GmbH, D
Luzenac S.A.
DEUTERON GmbH
Various manufacturers
This informations are given as guideline without warranty and this also where proprietary rights of third parties are involved. Our technical advice in any form does not
release you from the obligation to test our products to their suitability for the intended processes and uses. The use and application of our products in products manufactured by you are outside our control and, therefore, entirely your own responsibility. Our products are sold with our General Terms and Conditions of Sale and Delivery.
DEUTERON GmbH
P.O.Box 16 45 D-28822 Achim HRB Walsrode 120187
Telefon ++49 (0)421 / 48 32 27 Telefax ++49 (0)421 / 48 36 02
e-Mail: contact@deuteron.com Internet: http://www.deuteron.com
V01.181008
Page 1 of 1
Starting formulation RR 56
Aqua 1-C Parquet varnish for brushing procedure
__________________________________________________________________________________
Formulation
1
2
3
11,00
2,50
2,00
4
5
6
7
8
9
1,00
0,50
40,00
40,00
0,50
2,50
Butylglykol / water (1:1)

Fluowet SB 1 % in H2O
DEUTERON MK oder
Pergopak M3
Byk 025
Byk 346
Luhydran N 850 S
Ercrothane 75
Tego Phobe 1401
Schwego PUR 8020
(1)
(2)
(2)
(3)
(4)
(5)
(6)
100,00
Add. position 1-5 in a row vorlegen, stirring and dispersing. Add position 6-9 while stirring.
Technical data:
Flow time
Solid content
Application amount
Dustdry at room temperature
Tackdry at room temperature
app. 40 Sek. 4mm DIN cup

app. 42%
app. 80-120g/m
app. 30 min
app. 2 Stunden
Manufacturer / Supplier
(1)
(2)
(3)
(4)
(5)
(6)
Clariant, D
BYK-Chemie, D
BASF, D
Ercros, D
Evonik-Degussa-Tego, D
Schwegmann, D
DEUTERON GmbH
Telefon ++49 (0)421 / 48 32 27 Telefax ++49 (0)421 / 48 36 02
V01.181008
Page 1 of 1
2 K-Softfeel-Lacquer, solvent borne, pigmented
_________________________________________________________________________________
Formulation
1
2
3
4
5
6
7
8
9
14,7
14,7
10,6
2,8
4,9
1,7
2,8
1,4
39,1
Desmophen 1652
Desmophen C 200
Inorganic Oxyd-Pigment
Sillitin Z 86
DEUTERON MK
Acematt OK 412
Bentone 38, 10 %-Paste*
Dabco T12-N, 1 %ig in Butyl acetate
Butyl acetate / Xylol 1 : 1
(1)
(1)
(8)
(2)
(3)
(4)
(5)
(6)
(8)
Desmodur N 75
(1)
100,0
Hardener
10
10,0
Recommendation for production and processing

Predisperse with mechanical stirrer and after that grind on a laboratory equipment (Red Devil). After the hardener has been
added the mixture is adjusted to app. 30 sec efflue time (DIN 53211), 4 mm nozzle) and sprayed conventionally.
* (Antisettling agent with thixotropic effect)
10 % attack
weight units
Bentone 38
Toluene
Antiterra U (Byk Chemie)
10,00
85,00
5,00
Stirr under dissolver at 15 m/sec. till gel is formed (10 min.)
(1)
(2)
(3)
(4)
(5)
(6)
(7)
(8)
Bayer AG, D
HOFFMANN MINERAL GmbH & Co. KG, D
DEUTERON GmbH, D
EVONIK, Degussa, D
RHEOX, Inc., USA
Air Products, NL
BYK-Chemie, D
Varius manufacturers
DEUTERON GmbH
Telefon ++49 (0)421 / 48 32 27 Telefax ++49 (0)421 / 48 36 02
V01.182008
Page 1 of 1
2 K-Softfeel-Finishing lacquer, black, flat, solvent borne
__________________________________________________________________________________
Formulation
1
2
3
4
5
6
6,00
0,20
0,20
1,00
0,60
6,00
Synthalat A-HD 5667

Byk P 104
Aerosil R 972
Black-Pigment
Lancowax PE 1544
Butyl acetate
(1)
(2)
(3)
(X)
(4)
30 Min. Perlmhle o.., Kornfeinheit < -- 15 Micron

7
8
9
10
11
12
13
14
15
16
17
4,00
2,00
36,00
12,40
0,80
0,80
4,00
4,00
8,00
2,00
12,00
Synthalat A-HD 5667

Butylacetat
Synthoester 1179
Butyl acetate
Byk P 104
Aerosil 200
Syloid ED 30
PERGOPAK M3
Shellsol A
DBTL 5 %ig in Xylol
Butyl acetate
(1)
(1)
(2)
(3)
(5)
100,00
Hardener
Desmodur N 3390
Mix ratio 7:1
Technical data:
Viskosity Flow time:
Thinner:
Drying:
app. 45 sec 4mm DIN cup

app. 10 % Butyl acetate to app. 30 sec DIN 4
At toomemperatur over night or forced at higher temperatures in oven.
(1)
(2)
(3)
(4)
(5)
(X)
Synthopol Chemie, D
Byk Chemie, D
EVONIK-Degussa, D
Lubrizol, D
Grace Davison, USA
Various manufacturers
DEUTERON GmbH
Telefon ++49 (0)421 / 48 32 27 Telefax ++49 (0)421 / 48 36 02
V01.183008
Page 1 of 1
Aqueous 1K-PUR baking enamel, flat, for application on glass
RR 77 is corresponding to formulation "BBB 2637-1" from Bayer AG, Leverkusen
__________________________________________________________________________________
Formulation
1
2
3
21,67
60,95
17,38
Bayhydrol VP LS 2239, ( 35% in Water/NMP 60:5 )

Bayhydur VP LS 2240, ( 35% in Water/MPA/X 56:4,5:4,5 )
DEUTERON MK Paste ( 87,9% Bayhydrol VP LS 2239
12,1% DEUTERON MK )
Disperse paste for 20 min under dissolver at app 3500 rpm.
(1)
(1)
Dipropylene glykol
Silquest A 189
Dynasylan AMEO
(2)
(3)
(4)
100,00
Adhesion promoter
4
5
6
Mix ratio:
1,6
0,2
0,2
Laquer : Adhesion promoter = 100 : 2 ( Erst vor Verarbeitung zugeben ! )
Due to insufficient stability in the varnish silane solution (part 2) should be added shortly before application.
Characteristics
NCO/OH-proportion
Addition of silane (calculated on solid resin)
Spraying/dipping viscosity, DIN-cup 4/23 C
Solids content at application
Content of cosolvents at applicationapp. 9 %
pH-value
Drying conditions
1:1
1,2 %
20 25 s
app. 34 %
app. 8
30 min 170 C
Bayhydrol VP LS 2239 and Bayhydur VP LS 2240 are experimental products those development is not yet finished.
Varnishes based on this formulation are only designed for industrial application. The use in do-it-yourself-field has to
be excluded !
Manufcturers / Suppliers:
(1)
(2)
(3)
(4)
Bayer AG, D
Various producers
Momentive, USA
EVONIK-Degussa, D
DEUTERON GmbH
Telefon ++49 (0)421 / 48 32 27 Telefax ++49 (0)421 / 48 36 02
V01.183008
Page 1 of 1
Water borne Top Coating, grey, silk mat
This formulation is corresponding to RR 1.05.001 from CTP Chemicals GmbH
__________________________________________________________________________________
Formulation / Component A
1
2
3
4
5
6
7
20,40
28,80
1,00
0,30
8,60
37,20
3,70
CeTePox 2320 H, as supplied

Water, deionized
CeTePox 1613 H
Nopco 8034
Pigment, RAL 7032
Omyacarb 10
DEUTERON WAX MPO or
DEUTERON MK
(1)
(1)
(2)
(3)
(4)
100,00
Start with position 1. Add in portions and stir homogenious with high speed mixer. Mix in and thereafter stir in in order and
disperse fine
Hardener / Component B
CeTePox 464 R, supplied form
Mix ratio: 5:1
Important technical data

Mixing rate:
Density (DIN 51 757, T 3, 23C)
Pot life:
Dust-dry:
5 : 1 parts by weight
app. 1,4 g/cm3
app. 60 min at 23 C
after app. 3 hours at 23 C
The mixture can be diluted down with water.
(1)
(2)
(3)
(4)
CTP Chemicals, D
Mnzing GmbH, D
Clariant GmbH, D
Omya GmbH, D
DEUTERON GmbH
Telefon ++49 (0)421 / 48 32 27 Telefax ++49 (0)421 / 48 36 02
V01.183008
Page 1 of 1
Matt clear coat on wood for interior use
__________________________________________________________________________________
Formulation
1
2
4
5
6
7
8
9
10
11
12
74,50
8,00
0,20
1,00
0,20
0,50
1,00
0,20
0,30
2,50
2,00
13
8,60
Mowilith LDM 7460 app. 46 %

Water
Mergal K 10 N
1,2 Propandiol
Wetting agent AMP 90
Byk 348
Texanol
Agitan 295
Tafigel PUR 40
Methoxy butanol
DEUTERON MK or
DEUTERON MK-F
Water (to adjust the viskosity)
(1)
(2)
(3)
(4)
(5)
100,00
Add all single components in a row while stirring
(1)
(2)
(3)
(4)
(5)
CELANESE, USA
TROY, USA
DOW-Angus Chemie, D
Byk-Chemie, D
Mnzing Chemie GmbH, D
DEUTERON GmbH
Telefon ++49 (0)421 / 48 32 27 Telefax ++49 (0)421 / 48 36 02
V01.183008
Page 1 of 1
Solvent-borne 1C polyurethane-stoving soft-feel coating, grey, matt
RR 87 is corresponding to RR 6837 from Bayer AG
__________________________________________________________________________________
Formulation
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
15
31,00
9,00
0,50
0,10
0,10
2,50
6,20
1,20
2,50
15,00
11,00
1,20
2,00
3,80
1,30
12,60
Desmophen 1652, 100 %

Kronos 2160
Heucodur-Gelb 5R
Heucodur-Blau 4G
Black pigment
Silitin Z 86
CAB 531-1, 10% in Solvesso 200 S/Butyl diglykol (2:1)
Acronal 4 F, 50 % in Solvesso 200 S
Bentone 38, 10% (85:5 in Solvesso 200 S/Anti Terra U (8)) (2)
Solvesso 200 S
Desmodur BL 3175, 75 % in Solvent naphtha
Dibutylzinndilaurat, 10% in Xylene
Lanco-Wax TF 1778
DEUTERON MK
Acematt OK 412
Solvesso 200 S
(1)
(2)
(3)
(3)
(4)
(5)
(6)
(7)
(1)
(9)
(10)
(11)
(4)
100,00
Position 1 -10 dispersing and grindig <= 15m. Add position 11 - 15 in arow while stirring then dispersing.
Technical data
Solids content (% by weight)
Flow time, DIN EN ISO 2431 with 4 mm Dse/23oC
Stoving cycle
Gloss Gardner 60 o
app. 59
app. 100 s
PMT 230 oC
app. 4 %
Application amount:
Ablftzeit:
80-120g/m
30min at room temperature
Remarks
The PMT must be increased significantly if DBTL is not added as a catalyst.
The combination of CAB 531-1 and Acronal 4 F ensures good aeration and flow properties
Manufacturers / Suppliers:
( 1)
( 2)
( 3)
( 4)
( 5)
( 6)
( 7)
( 8)
( 9)
(10)
Bayer AG, D
Kronos International INC, D
Heubach, D
Evonik-Degussa, D
Hoffmann Mineral GmbH, D
Krahn Chemie, D
BASF AG, D
Byk-Chemie GmbH, D
Air Products, NL
Lubrizol, D
DEUTERON GmbH
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Page 1 of 1
Solvent-borne 1C polyurethane-stoving soft-feel coating, grey, matt
RR 87 is corresponding to RR 6837 from Bayer AG
__________________________________________________________________________________
Formulation
1
2
3
4
5
6
68,94
14,06
1,00
1,00
7,50
7,50
Uracross P 3125
Uracross P 3307
Irgacure 2959
Resiflow PV 5
DEUTERON MK
Ceraflour 950
(1)
(1)
(2)
(3)
(4)
100,00
Curing conditions
Melt time (s)
Melt temperature (0C)
UV-lamp
UV-lamp power
UV-dose (mJ/cm2)*
UV-dose: sum of UV-A/B/C/V
120
130
H-bulb
120W/cm
1.500
Coating properties
Substrate: MDF
Adhesion (GT)
Gloss 20o
Gloss 60o
Pendulum hardness (s)
Acetone double rubs
Powder stability 1 wk. 30 oC
0
15
65
160
>100
8
Manufacturer / Supplier
( 1)
( 2)
( 3)
( 4)
DSM Resins, NL
Ciba, CH
Worlee-Chemie, D
BYK-Chemie GmbH, D
DEUTERON GmbH
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V01.183008
Page 1 of 1
1C PU Coil-coating-top coat, pigmented, matt, structured
RR 91 is corresponding to starting formulation "BBB 2172" from Bayer AG
__________________________________________________________________________________
Formulation
1
5,64Desmophen T 1775 SN
2
1,25
3
1,10
4
8,50
5
0,43
6
5,16
7
1,40
8
0,17
9
10
11
12
13
14
15
16
17
18
19
25,07
18,73
0,90
1,61
8,05
3,26
1,04
1,28
3,88
1,04
11,49
(1)
Titandioxide
organic yellow pigment
inorganic red pigment
Black-pigment
Solvesso 200 S
Butyl diglycol acetate
Byk P 104 S
(2)
(2)
(2)
(2)
(2)
(2)
(3)
Desmophen T 1775 SN
Desmodur BL 4265, 65 % in Solvent naphta 100
Dabco T12N, 10% in Solvesso 200 S
Acronal 4 F, 50 % in Solvesso 200 S
CAB 531-1, 10 % in Solvesso 200 S / Butyl diglicol (2:1)
Tinuvin 292, 10 % in Solvent naphtha 100
Disparlon 1970, 50 % in Solvesso 200 S
DEUTERON MK
DEUTERON ST
Lanco Wax TF 1778
Solvesso 200 S
(1)
(1)
(4)
(5)
(6)
(7)
(8)
(9)
(2)
100,00
Position 1 -8 dispersing and grindig <= 15m. Add position 9 - 19 in a row while stirring, then dispersing.
Technical data
Solids content (% by wt.)
Application viscosity,
DIN EN ISO 2431 cup with 5 mm jet / 23 C
Stoving cycle
PMT> 232 C
Gloss Gardner 60
approx. 55
approx. 100 sec.
approx. 14 %
Without the use of DBTL as catalyst a significantly higher PMT must be employed.
(1)
(2)
(3)
(4)
(5)
(6)
(7)
(8)
(9)
Bayer AG, D
Various producers
BYK-Chemie, D
Air Products, NL
BASF AG, D
Eastman, USA
Ciba, CH
Kusomoto, JP
Lubrizol, D
DEUTERON GmbH
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Page 1 of 1
Baking Texturing Coating, black
__________________________________________________________________________________
Formulation
1
2
3
4
5
6
7
8,00
1,30
3,00
1,30
1,80
18,00
5,00
Synthalat CC 42
Disperbyk 103
Bentone 34 (10% in Solvesso 150)
Black Pigment Flammru 101
Satintone 5
Bayferrox 306
Butyl glykol
(1)
(2)
(3)
(4)
(5)
(6)
8
9
10
11
12
13
42,00
5,00
2,80
3,50
0,30
8,00
Synthalat CC 42
Maprenal MF 900w/95
Butyl glykol
Solvesso 150
p-Toluen sulfon acid ( 2% in butyl glykol)
DEUTERON ST-L
or
DEUTERON ST
or
DEUTERON ST-S
or
DEUTERON ST-G
(1)
(7)
100,00
Positionen 1 - 7 grinding <= 20m. Let down with position 8 - 13.
Technical data
Solid content
59,4 %
Texturing / structuring agent DEUTERON ST ... 8,0 %
Spaying viscosity (4 mm DIN Cup)
24s
Stoving condition
3 min
Thinner (spraying)
Butyl acetate
Xylene
Ethyl glykol acetate
13,5 % from solid content

(DIN EN ISO 2431)
app. 220 C
40
37
23
100,00
( 1 ) Synthopol Chemie, D
( 2 ) BYK-Chemie, D
( 3 ) Elementis Specialties, B
( 4 ) Evonik-Degussa, D
( 5 ) Solvadis, D
( 6 ) Bayer AG, D
( 7 ) INEOS Melamines, D
DEUTERON GmbH
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2 Component Glass coating, solvent borne
For matt-, dull-, etched- or frost- effects
__________________________________________________________________________________
Formulation
1
2
3
4
20,0
36,0
11,0
7,0
5
6
7
8
9
10
11
12
2,0
0,5
1,0
1,0
4,6
9,2
3,0
4,7
Butyl acetate
Synthalat A 1633 50% in Butyl acetate
Worleecryl A 2445 60% in Xylene/Butyl acetate
DEUTERON ST-G
or
DEUTERON ST-S
or
DEUTERON ST
or
DEUTERON ST-L
DEUTERON MK
Aerosil R972
Baysilone OL17 10% in Xylene
Dabco T-12N 10% in Xylene
Methoxy propyl acetate
Ethyl acetate
Byk 410 ( 4% in 76% Xylene / 20% Butanol )
Aceton
(1)
(2)
(3)
(4)
(4)
(5)
(6)
(7)
(1)
(1)
(8)
(1)
100,00
Adhesion promoter
13
14
15
To make seperately
Use shortly before processing
3,2
0,4
0,4
Butyl glykol / Isopropanol

Dynasilan AMEO
Dynasilan MTMO
(1)
(5)
(5)
In individual case it is possible to use only Pos. 15 directly into the formulation instead the semi finished produkt Pos 13-15.
As alternative to the mentioned products above it is able to use an epoxyfunctional Silane.
Hardener
Desmodur N 75
Mix ratio:
Laquer : Hardener : Adhesionpromoter = 100 : 10 : 4
(9)
Technical data
Viskosity
Spray thinner:
Spray viscosity
Drying:
approx. 40 sec DIN EN ISO 2431 cup with 4 mm jet

34%
ca. 10-30% Butyl acetate
20-25sec DIN EN ISO 2431 cup with 4 mm jet
At room temperatur over night or forced drying conditions with increased temperature.
( 1 ) Various producers
( 2 ) Synthopol Chemie, D
( 3 ) Worlee Chemie, D
( 4 ) DEUTERON GmbH, D
( 5 ) Degussa-Hls AG, D
( 6 ) Borchers GmbH, D
( 7 ) Air Products, NL
( 8 ) Byk-Chemie, D
( 9 ) Bayer AG, D
DEUTERON GmbH
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Page 1 of 1
Solvent-borne 1C-Baking-Texturing-Coating, pigmented, matted
RR 94 is corresponding to guide formulations CZ 74 ST, ST-S, ST-L, ST-G from DEGUSSA GmbH
__________________________________________________________________________________
Formulation
1
2
3
4
5
6
7
8
14
62,5
0,3
9,4
2,4
1,0
0,7
0,6
1,0
8,0
15
16
9,7
4,4
Vesticoat UB 1173-03 / 60% in Solvent naphta

Aerosil 200
Inorganic Pigment Black
Inorganic Pigment Yellow
Catalyst C31
Disparlon L 1984 / 50% in Hydrosol A 230
DEUTERON ST-G
or
DEUTERON ST
or
DEUTERON ST-S
or
DEUTERON ST-L
Di-Basic-Ester
Solvesso 150 ND (Hydrosol A 200)
(1)
(1)
(2)
(2)
(2)
(2)
(1)
(3)
(2)
(2)
100,00
Position 1 - 6 grinding until particle sizes <15m. Add. position 7 - 16 in succession while stirring.
Technical data
Stoving contitions:
Stoving temperature
Stoving time
app.. 59,3
310C (PMT 230oC)
30 sec
(1) EVONIK-Degussa, D
(2) Various producers
(3) Kusomoto Chemicals Ltd., JP
DEUTERON GmbH
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2C-Softtouch-Clearcoat, solvent borne
RR 95 is corresponding to "Startingformulation S 1/11" from Synthopol Chemie
__________________________________________________________________________________
Formulation
1
5667
(1)
2
3
4
5
6
7
8
9
10
11
10,00
Synthalat A-HD
36,00
0,20
7,00
0,20
0,80
Synthoester 1179
Disperbyk 163
PERGOPAK M3
Aerosil R 972
Aerosil 200
(1)
(2)
12,00
8,00
1,00
1,00
23,80
Butyl acetate
Shellsol A
DBTL 10 % in Xylene
Byk 333 10% in Butyl acetate
Butyl acetate
(4)
(4)
(5)
(2)
(4)
(3)
(3)
100,00
Position 1 - 6 in succession stirring / Dispersing.Completing with position 7 - 11
Hardener
Mix ratio:
7 : 1 with Desmodur N 3390
(7)
Technical data
Binder solid
Resulting mixed solid content
42,5 %
48,4 %
Processing
Thinner/Diluent
Drying:
Potlife:
10-15% b.w. with Butyl acetate to app. 30 sec DIN 4

at roomtemperature app. 20C over night or
4 hours air at roomtemperature, then forced drying at
30-50C with air circulating oven.
app. 4h
(1)
(2)
(3)
(4)
(5)
(6)
Synthopol Chemie, D
BYK Chemie, D
EVONIK-Degussa, D
Various producers
Air Products, NL
Bayer AG, D
DEUTERON GmbH
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2C Struktured / textured effect coating, solventborne, clearcoat
Based on hydroxy acrylate- polyurethane, with quick physical drying
__________________________________________________________________________________
Formulation
1
2
3
4
5
6
7
8
9
10
17,00
10,00
2,00
1,50
5,00
7,00
20,00
8,00
0,30
6,00
11
12
13
14
15
16
17
10,00
0,10
0,20
1,00
1,00
1,00
9,90
Butyl acetate
Ethyl acetate
Isopropanol
Ethoxy propyl acetate
Xylene
Celluloseacetbutyrate: CAB 381-0,5
Desmophen A450 50% in Butyl acetate
Worleecryl A 2445 60% in Xylene / Butyl acetate
Disperbyk 103
DEUTERON ST-G
or
DEUTERON ST-S
or
DEUTERON ST
or
DEUTERON ST-L
Ethyl acetate
Aluminium pigment: Stapa Metallux R214
Byk 410
Byk 333 (10% in Butyl acetate)
Dabco T-12N (10% in Xylene)
Aerosil R972
Aceton
(1)
(1)
(1)
(1)
(1)
(2)
(3)
(4)
(5)
(1)
(6)
(5)
(5)
(7)
(8)
(1)
100,00
Load pos.1-5, pos. 6 add slowly while stirring. Pos. 7 - 10 add and mix. Pos. 11 16 stirr in.
Adjust viscosity with pos. 17
Hardener:
50% Desmodur N75 in Butyl acetate, Mix ratio: 10:1
Technical data:
Viskosity
Solid content
Mixed solid content
app. 40 sec. cup 4/20 oC

app. 29,3%
app. 30%
Thinner:
Spray viskosity
Drying conditions:
app. 10-30% Butyl acetate

20-25 sec 4mm DIN cup
at roomtemperature or forced drying
Remarks
The kind and intensity of effects could modiefied with changing the type and amount of strukture/texturing agent and/or the type
of metallic or other effect pigments.
It is possible to use a clear coat as finishing but not required.
Manufacturer / Supplier:
(1) Various producers
(2) Eastman, USA
(3) Bayer AG, D
(4) Worlee Chemie, D
(5) BYK-Chemiel, D
(6) Eckardt, D
(7) Air Products, NL
(8) Evonik-Degussa, D
DEUTERON GmbH
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2C Metallic effect coating with less flip-flop
Solventborne, based on hydroxyacrylates
__________________________________________________________________________________
Formulation
1
2
3
4
5
20,00
10,00
5,00
5,00
6,00
Butyl acetate
Ethyl acetate
Xylene
Methoxy propyl acetate
CAB 381-0,5
(1)
(1)
(1)
(1)
(2)
6
7
8,00
0,50
(3)
(1,50)
Synthalat A1633 50% in Butyl acetate

or
DEUTERON PMH-C
or
DEUTERON OG 8650, OG 8652, OG 8654
8
9
10
10
11
10,00
7,00
3,00
0,30
5,00
Ethyl acetate
Solvesso 150
White spirit 150-200
Disperbyk 103 or 163
Aluminium pigment paste
(1)
(1)
(1)
(4)
(5)
12
13
14
15
1,00
1,00
1,00
8,00
Byk 333 (10% in Butyl acetate)

Dabco T-12N catalyst (10% in Xylene)
Aerosil R972
Ethyl acetate
(4)
(6)
(7)
(1)
17
9,20
(8,2)
Aceton
(1)
(4)
100,00
Pre-mix position 1-4, add. position 5 slowly and stirr until clear solution. Add. position 8-11 separately in a row and let it soak
over night. Add. position 6 & 7 in CAB-solution and dispersing. Add the metallic-slurry in position. 1-7. Finally complete with
position 12 15. Adjust the viscosity with Aceton.
Hardener
60% Desmodur N75 (8) in Butyl acetate

Mix ratio: 20:1
Technical data
Viskosity app.:
Solid content:
Spray thinner:
Spray viscosity:
Drying conditions:
25 sec. flow time (4mm Cup DIN EN ISO 2431)

app. 14,5%
app. 10-30% Butyl acetate
18-22 sec flow time (4mm Cup DIN EN ISO 2431)
At room temperature or with higher temperature.
Remarks:
( 1 ) Various producers
( 2 ) Eastman Chemicals, D
( 3 ) Synthopol GmbH, D
( 4 ) Byk-Chemie GmbH, D
( 5 ) Eckardt, D Silberline, GB Schlenk, D
( 6 ) Air Products, NL
( 7 ) EVONIK-Degussa, D
( 8 ) Bayer AG, D
The basecoat should be sprayed dry which means much air and
less laquer. The surface should be just so wet that a leveling is
possible
The appearance of effects can be affected by the type and amount
of the matting / surface additives.
Combination with wax additives for stabilisation is possible but may
disturb the less-flip-flop-effect.
DEUTERON GmbH
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Aqueous UV curing clearcot for flooring, matt
RR 98 is corresponding to formulation "RR PCO-0045BBB" from Bayer AG
__________________________________________________________________________________
Formulation
1
2
3
4
5
6
7
91,30
0,50
1,00
4,00
2,00
1,00
0,20
Bayhydrol UV XP 2453
Dehydran 1293
Hydropalat 3275
DEUTERON MK
Darocur 1173
BYK 348
Borchigel LW 44
(1)
(2)
(2)
(3)
(4)
(5)
100,00
Processing
First position 1, add. position 2 - 4 in a row and dispersing. Then add position 5-7 and stirr in
Technical data
Viskosity (sec 4mm flow cup DIN 53211)
Wet layer thickness
Air drying at roomtemperature
Flash off at 50C
Drying at 80W/cm Hg-lamp
app. 30
app. 50 g/m
app. 2 min
app. 1 min
app. 5m/min
( 1)
( 2)
( 3)
( 4)
( 5)
Bayer AG, D
Cognis, D
CIBA, CH
BYK-Chemie, D
Borchers GmbH, D
DEUTERON GmbH
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Aqueous 1C-Wood-Parquett coating, flat
RR 99 is corresponding to formulation "RR 6694" from Bayer AG
__________________________________________________________________________________
Formulation
1
2
3
4
5
6
7
8
87,70
8,00
1,00
0,20
0,40
0,80
1,20
0,70
Bayhydrol XP 2557
Water / Butyl glycol (1:1)
BYK 028
BYK 346
BYK 341
DEUTERON MK
DEUTERON MK-F
Acrysol RM 895 / Water (1:1)
(1)
(2)
(2)
(2)
(3)
100,00
Technical data
Solid content
Layer thickness
Dustdry at room temperature
Complete dry at room temperature
app. 34 %
app. 120g/m
app. 30 min
app. 1,5 hours
Processing
Roller coating, Spraying, Airmix, Airless, courtain coater, or brushing. As thinner app. 5-15% water if necessary.
(1) Bayer AG, D
(2) BYK-Chemie, D
(3) Rohm & Haas, D
DEUTERON GmbH
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Aqueous 1K-Furniture- / Parquett laquer
RR 101 is corresponding to the formulations "F3641-7 & -8" from ERCROS GmbH
__________________________________________________________________________________
Formulierung
1
2
3
4
5
6
7
11,20
6,00
0,20
0,30
1,50
1,50
4,50
8
9
10
11
12
13
14
70,00
0,50
0,30
0,10
0,30
3,40
0,60
Water
Butyl glycol
Acticid MBN
Byk 28
Disperbyk 191
DEUTERON Wax PP
DEUTERON MK
DEUTERON MK-F
DEUTERON PMH-C
Ercros RA 646 H
Acematt TS 100
Byk 346
Byk 333
Byk 28
Water
Acrysol RM 825
(1)
(2)
(2)
or
or
(3)
(4)
(2)
(2)
(2)
(5)
100,00
Position 1- 5 at first. Stirr in positions 6 and 7 and dispersing. Add. positionen 7 - 12 while stirring.
Add separately mixed positionen 13 and 14.
Technical data
Viscosity
Solid content
Degree of gloss at 85
app. 500-1000 mPas

app. 31%
app. 8-15 RE dependig from used matting agent
Remarks
The coating can crosslinked with the isocyanate hardener Bayhydrol 3100 or Rhodacoat XWT 2104.
In this case it is necessary to calculate the formulation regarding the solid content, degree of crosslinking and potlife.
(1)
(2)
(3)
(4)
(5)
Thor Chemie, D
BYK-Chemie, D
Ercros GmbH, D
Evonik-Degussa, D
Rohm und Haas, D
DEUTERON GmbH
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Aqueous 2C-Floor coating, clearcoat, matt for roller application
RR 102 is corresponding to RR1.16 from OMG Borchers GmbH
__________________________________________________________________________________
Formulierung
1
2
3
4
5
6
7
8
9
10
20,00
1,00
0,5
60,00
0,30
4,50
4,75
1,00
2,00
5,95
Water
Defoamer T
Diethylen glycol
Bayhydrol XP 2457
Baysilone Laquer additiv 3739
DEUTERON MK
Ultralube D-865
BorchiGel L 75 N
BorchiGel 0013
Water
(1)
(2)
(1)
(3)
(1)
(1)
100,00
Add position 1 - 7 in a row while stirring.
Mix position 8 - 10 separately and adjust the viscosity.
Hardener
Bayhydur XP 2451
Mix ratio:
10:1
(2)
Technical data:
Application:
Potlife:
Drying:
Roller with app. 100-120m wet layer thickness

app. 4 hours
app. 35 min
( 1) Borchers GmbH, D
( 2) Bayer AG, D
( 3) Keim Additec, D
DEUTERON GmbH
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V01.184008
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Aqueous 2C-Floor coating, white pigmented, matt, for roller application
RR 103 is corresponding to RR1.16 from OMG Borchers GmbH
__________________________________________________________________________________
Formulation:
1
2
3
4
5
6
7
8
9
10
11
12
5,00
1,00
12,9
1,00
7,10
61,50
0,30
3,00
5,00
0,30
0,70
2,20
Water
Borchi Gen SN 95
Titandioxide white-pigment, rutil-type
Defoamer T
Glimmer C3000
Bayhydrol XP 2457
Baysilone Laquer additiv 3739
DEUTERON MK
Ultralube D-865
BorchiGel L 75 N
BorchiGel 0013
Water
(1)
(2)
(1)
(3)
(4)
(1)
(5)
(1)
(1)
Add position 1 - 5 in a row while stirring, dispersing app. 30min until particle sizes <20m. Add position 6 9 in a row.
Mix position 10 - 12 separately and adjust the viscosity.
Hardener
Bayhydur XP 2451
Mix ratio:
10:1
(2)
Technical data:
Application:
Potlife:
Drying:
Roller with app. 100-120m wet layer thickness

app. 4 hours
app. 35 min
(1)
(2)
(3)
(4)
(5)
Borchers GmbH, D
Diverse Hersteller
Omya AG, CH
Bayer AG, D
Keim Additec, D
DEUTERON GmbH
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V01.184008
Page 1 of 1

Aqueous painter- & house laquer, clearcoat, matt
RR 104 is corresponding to formulation "RR 6.16" from Borchers GmbH
__________________________________________________________________________________
Formulation
1
2
3
4
5
6
94,7
0,50
0,50
3,00
0,50
0,80
WorleePur E 927 W
Borchers AF 0676
Borchi Gol LA 2
PERGOPAK M4 / DEUTERON MK
Borchers Dry 0347 aqua
BorchiGel 0434
(1)
(2)
(2)
(2)
(2)
100,00
Add position 1 - 6 in a row while stirring.
Technical data
Application:
Solid content:
VOC-amount:
Viskosity Brookfield:
Drying time:
Painting or roller
app. 42 %
app. 7,8 g/l
app. 7900 mPas
app. 6 hours
(1) Worlee, D
(2) Borchers GmbH, D
DEUTERON GmbH
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V01.184008
Page 1 of 1
DEUTERON
Abbreviations used:
1-C
2-C
DIY
EVA
PMU
PE
PTFE
PP
RE
SEM
Rz
Rt
BW
One-component (coating)
Two-component (coating)
Do it yourself
Ethylene-Vinyl Acetate - Copolymer
Polymethyl urea / organic polymethyl urea matting agent
Polyethylene
Polytetrafluoroethylene (Teflon)
Polypropylene
Units of reflection for gloss measurement
Scanning Electron Microscope
Maximum roughness profile height from the profilometer method (DIN EN ISO 4287)
and mean roughness value in accordance with DIN 4768
Total roughness (DIN EN ISO 4287)
Black-White
Companies:
Hommel Etamic GmbH
www.hommel-etamic.de
Dhs Dieterman & Heuser Solution GmbH
www.dhssolution.de
Fritsch GmbH
www.fritsch.de
BYK-Gardner GmbH
www.byk.com/instruments
Brookfield GmbH
www.brookfield-gmbh.de
DEUTERON is a registered trademark of the DEUTERON GmbH

PERGOPAK is a registered trademark of the ALBEMARLE martinswerk Corporation
2008 DEUTERON GmbH
V01.016018

Brochure Matting Agents E

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DEUTERON

Polymethyl urea for

The main matting agents used in coatings are silicas. Various

DEUTERON and PERGOPAK matting agents are organic,

types of waxes are also used to provide special properties

duroplastic, urea-methanal polymers.

such as slip effects and anti-blocking effects. In general, min-

Organic matting agents based on polymethyl urea are not a

eral fillers only play a subsidiary role as matting agents. Ther-

replacement for silicas. However, in some cases their use al-

moplastic polymer powders are mostly used to provide func-

lows surface properties and benefits to be realised which either

tional effects in special areas such as coil coatings and power

cannot be achieved solely with standard matting agents, or

which can only be partly achieved or which can only be

The diffuse reflection properties of the surface are decisive for

achieved using combinations of standard matting agents.

the intensity of the matting effect. This is influenced by the

Due to their chemical nature and structure, organic matting

type, quantity and alignment of the matting agents. The most

important parameter is the physical macrostructure of the

as a supplementary matting agent in a variety of coating mate-

matting agent. For DEUTERON matting agents the respective

reflectometer value is directly dependent on the relevant parti-

Ground and classified DEUTERON and PERGOPAK matting

cle size distribution and this can be measured at the surface

agents provide very effective matting, good surface texture,

via the roughness profile. The requirements with regard to film

good mechanical resistance and a pleasant feel.

thickness, binder solid content, etc. can be fulfilled with these

- Narrow particle size distribution

- No adverse effect on the recoatability, printability and writability

- High surface smoothness

- No adverse effect on catalysts

- Little effect on the "Anfeuerung"

silica; precipitated / wax-treated

The primary particles of the PMU matting agent are

In addition to the wax additives and compounds, DEUTERON

The particle size and particle size distribution of the matting

in determining the matting effect.

Electron microscope image of a coating surface matted with

Amount added [% solid]

Comparison of the roughness profiles of various DEUTERON

Average depth of rougness [m]

DEUTERON DEUTERON OG DEUTERON OG DEUTERON OG

Graphical comparison of several DEUTERON PMU matting

For solvents which evaporate at different rates there are also

have differing volatility (evaporation rate), make up 22% of each

ca. 3.0 RE 85 = ca. 16.4%

ca. 5.5 RE 85 = ca. 40.4%

Analogously, the roughness measurements show lower values

ca.12% lower Rz.

The organic DEUTERON matting agents are very hard and

Prototype of the scrubbing and scratch tester.

Different scrubbing pads and weights.

cording system which records the changing surface via the

Macroscope with image database.

optimum comparative results. On comparing the curves with

nitude of the change of a surface matted with silica and with

each other, information about their position and knowledge of

DEUTERON MK as well as the change arising from polishing

the load level allow statements to be made about precisely

when a surface is no longer polished but rather scratched.

DEUTERON MK with no scrubbing