Академический Документы
Профессиональный Документы
Культура Документы
This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
131.155.81.2 On: Fri, 21 Nov 2014 18:12:13
JANUARY, 1961
SWETS,
R. W.
LEE, AND
R. C.
FRANK
exp (558056RT
and in the high-temperature range they are expressed by
cal/g atom) cm2/sec.
D = 740X 10-' exp (_ 661340RT
The solubility was also determined by dividing the permeability by the diffusion coefficients. This was expressed by
cal/g atom) a t oms/ cm 3
S = 1.99X 1017 exp (_ -68060RT
in the temperature range of 24 to 300C and by
g atom)
17
S =128XI0
exp ( _ -1174120cal/
RT
atoms / cm 3
in the range 300 to 1034C.
INTRODUCTION
EXPERIMENTAL PROCEDURE
To Mass spectrometer
17
This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
131.155.81.2 On: Fri, 21 Nov 2014 18:12:13
18
Diffvdon CoeFficient
I = Woll Thicknesl
L = Effective Time lag
= Evolution Time Constant
'0
the
Fused Qvar'-
--1---
ll
---1
He I'IUfTI E
va ulion
FRANK
where h is the mass spectrometer reading, p is the pressure outside the specimen, and K is a constant of
prop?rtionality, x was found to be slightly less than 1,
varymg from about 0.93 to 0.97. The error of the method
was such that this value could not be established more
accurately without performing a large number of tests.
(1)
n=1
(2)
(3)
n=O
This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
131.155.81.2 On: Fri, 21 Nov 2014 18:12:13
19
DEGREES CENTIGRADE
750
2
]
....1
r-.r-,
I x 10
(5)
1kJ- (2hJ2/12D) =0
r.~
(6)
'"
....
sri
6
f\,~.:::
I
S
10
12
14
16
18
20
1/T
22
24
26
2S
30
32
34
36
x 10
(8)
D=Doe-E1RT,
where Do is the frequency factor, (a measure of the
frequency of vibration of the impurity in the interstitial
site); E is the activation energy; R is the gas constant;
and, T is the absolute temperature.
In the high-temperature range (300 0 -1034C) the
least-mean-square line through the points is represented by
(9)
In the lower temperature range the least-meansquare line through the points is represented by
RESULTS
~.f\,
.......
_1
11
".'.
P=DS.
r.. ..
1 x 10~
P= DCo= Permeability,
r..r-,
since
24
100
200
'/>.~
-5
X{1-exp[-(rn 2/P)DtJ}.
400
D=3.04XI0-4 exp( -
This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
131.155.81.2 On: Fri, 21 Nov 2014 18:12:13
20
750
200
==
...01-< 1-:1-
==
=
--
--
100
-- - --
I'
10
13
,=
1=
1-
~t::::
-"-1
==
E
0
').
E
----i
12
.2-
~~
~-
1 x 10
-~
~=
ill
1-
!=
JONES
o WILLIAMS AND FERGUSON
~ ~%
-U-
I~
1=
1-
=
-
24
H-
'.
~t::::
==
~
~~
"
f-
~~-,
'~
F
f:
"
f-f--
1 x lO"
-'-=
'-
I:::F
I=~
I-tI-fI-f-
,,~
~--.
~r..,
,...~
o TSAI
AN D H f r n
NORTON
JONES
8
10 12
14
16
18
1/T
20
22
4
x 10
24
26
28
~~
30
I:::~
"'<ii~
32
I=f=
I-fI-t--
~ ~,
34
36
X exp( -
-1174120caljgatom)
RT
/3
atoms cm .
S= 1.99X 1017
X exp( -
RT
atoms cm.
This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
131.155.81.2 On: Fri, 21 Nov 2014 18:12:13
D IFF U S ION
C 0 E F F I C lEN T S 0 F
DISCUSSION
QUA R T Z
21
This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
131.155.81.2 On: Fri, 21 Nov 2014 18:12:13
22
814
857
854
605
608
1038
1034
1028
1032
Diffusion
coefficients
(10-7 (cm2/sec)
355.
387.
380.
158.
159.
613.
861
861
712
712
717
717
490
489
284
610.
584.
580.
401.
416.
408.
244.
237.
250.
248.
90.2
89.4
19.5
492
380
378
378
700
705
704
191
78
24
112
148
94.5
48.1
43.9
47.7
241.
245.
238.
7.28
1.06
.239
2.15
3.73
860
1034
861
717
490
284
492
380
705
191
78
24
112
148
118.
86.1
62.8
22.2
6.92
27.3
15.3
55.8
3.00
.532
.151
.995
1. 76
227
261
281
334
334
708
430
430
607
606
Diffusion
coefficients
(10-7 cm2/sec)
11.6
17.0
20.6
32.9
33.1
240.
64.0
68.0
177 .
170.
This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
131.155.81.2 On: Fri, 21 Nov 2014 18:12:13