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BOARD OF INTERMEDIATE EDUCATION

Sr. INTER CHEMISTRY MODEL PAPER
(English Medium)

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(w.e.f. 2013 - 14)

Time: 3 Hours

Max. Marks: 60

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SECTION A

Note: I. Very Short answer type questions.

II. Answer ALL THE QUESTIONS at one place in the same order.
III. Each question carries 2 MARKS
10 2 = 20
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.

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What are 'Schottky defects' in crystalline solids?

Calculate the 'spin only' magnetic moment of Fe+2(aq.) ion.
Calculate the mole fraction of sodium hydroxide in 10% W/W NaOH solution.
How is change in Gibbs energy (G) related to the emf (E) of a galvanic cell?
What is the role of Cryolite in the extraction of aluminium?
How do you distinguish between crystal lattice and unit cell?
What is PHBV? How is it useful to man?
Write the names and structures of the monomers of the following polymers.
(a) Bakelite and (b) Nylon 6, 6
Write the possible chain isomers of the compound having molecular
formula C4H9Br.
How is ethane converted to bromoethane?

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SECTION B

Note: I. Short answer type questions.

II. Answers any SIX questions.
III. Each question carries 4 MARKS
6 4 = 24
11. State Raoult's law. Calculate the vapour pressure of a solution containing 9 g of
glucose in 162 g of water at 293 K. The vapour pressure or water at 293 K is
17.535 mm Hg.
12. What is Catalysis? What are the types of catalysis? Give one example for each
type.
13. Differentiate roasting and calcination with examples?
14. Explain the structures of a) XeF4 and b) XeOF4.
15. Explain Werner's theory of coordination compounds with suitable examples.

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16.

17.
18.

Give the sources of the following vitamins and name the diseases caused by this
deficiency.
a) A
b) D
c) E and d) K
Write short notes on
a) Analgesics
b) food preservatives
Explain Sand Meyer reaction and Carbyl Amine reaction

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SECTION C

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Note: I. Long answer type questions.

II. Answer any TWO questions.
III. Each question carries 8 MARKS.
2 8 = 16
19. a) State and explain Kohlrausch's law of independent migration of ions.
b) What is order of a reaction? How is it different from the molecularity of a
reaction? Give one example each for first order and second order reactions.
20. a) How is Ozone prepared? How does Ozone reacts with
i) PbS ii) Moist KI iii) Hg and iv) Ag ? Give equations.
b) Write the balanced equations for the following.
i) NaCl is heated with conc. H2SO4 in the presence of MnO2.
ii) Chlorine is passed into a solution of NaI in water.
21. a) Explain i) Cannizzaro reaction
ii) Decarboxylation
b) Explain the acidic nature of phenols and compare it with that of alcohols.

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ANSWERS
SECTION - A
1.

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What are "Schottky defects" in crystalline solids?

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Ans: A stoichiometric point defects that occurs due to missing of equal number of
cations and anions from their original lattice points, present in crystalline solids

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are called schottky defects. e.g.: NaCl, CsCl.

2.

Calculate the "spin only" magnetic moment of Fe+2 (aq.) ion?

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Ans: Fe = 26 = [Ar] 3d6 4s2

Fe+2 = [Ar]3d6

Magnetic moment () = n(n + 2). Where n = number of unpaired e = 4

= 4(4 + 2)

= 24 = 4.89 B.M.

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3.

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Calculate the mole fraction of sodium hydroxide in 10% W/W NaOH

solution.

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Ans: n1 = number of moles of water = = 5
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10
n2 = number of moles of NaOH = = 0.25
40

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n2
0.25
0.25
1
X2 = mole fraction of NaOH = = = = = 0.0476
n1 + n2 5 + 0.25
5.25 21
4.

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G) related to the emf (E) of a galvanic cell?

How is change in Gibbs energy (

Ans: G = n F Ecell

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where G = change in Gibbs energy

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n = number of electrons

F = Faraday = 96487 C mol1

Ecell = emf of the cell.
5.

What is the role of cryolite in the extraction of aluminium?

Ans: To dissolve alumina.

To increase electrical conductivity.
To decrease the melting point of alumina.

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6.

How do you distinguish between crystal lattice and unit cell?

Ans: Crystal lattice: Regular three dimentional arrangement of points in space.

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Unit Cell: The smallest basic three dimentional repeating unit from which

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crystal lattice is built.

7.

What is PHBV? How is it useful to man?

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Ans: PHBV is poly - Hydroxy butyrate Co - Hydroxy valerate. It is a copolymer,

formed due to condensation of 3 - hydroxy butanoic acid and 3 - hydroxy

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pentanoic acid. This biodegradable polymer is used for making capsules and
orthopaedic devices.
8.

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Write the names and structures of the monomers of the following polymers
a) Bakelite b) Nylon 6, 6

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Ans: a) Bakelite:

OH

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Phenol:

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H C H

& Formaldehyde :

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b) Nylon 6, 6:

Adipic acid: HOOC (CH2)4 COOH

Hexa methylene diamine: H2N (CH2)6 NH2
9.

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Write the possible isomers of the compound having molecular formula

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C4H9Br.

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Ans: n-butyl bromide: CH3CH2CH2CH2Br

Secondary butyl Bromide: CH3 CH2 CH CH3

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Br

Tertiary butyl bromide: (CH3)3C Br

10.

How is ethane converted to bromoethane?

Ans: When ethane is heated with bromine, bromoethane is formed due to free
radical bromination.
Heat
C2H5 H + Br Br C2H5Br + HBr

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SECTION - B
11.

State Raoult's law. Calculate the vapour pressure of a solution containing

9 g of glucose in 162 g. of water at 293 K. The vapour pressure of water at
293 K is 17.535 mm Hg.

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Ans: The relative lowering of vapour pressure of a dilute solution of a non volatile

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solute is equal to the mole fraction of the solute (X2).

p p
= X2
p
p = V.P. of pure solvent = 17.535 mm Hg.
p = V.P. of solution = ?
M1 = Molar mass of water (solvent) = 18 g
M2 = Molar mass of glucose = 180 g
w1 = Mass of solvent (water) = 126 g
w2 = Mass of sloute (glucose) = 9 g
M1
p p
w2
=

p
M2
w1

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17.535 p
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18
=
17.535
180
162

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9 18 17.535
p = V.P. of solution = 17.535
180 162
= 17.535 0.0974
= 17.438 mm Hg
12. What is catalysis? What are the types of catalysis? Give one example for
each type.
Ans: Small quantity of substances, which can alter the rate of a chemical reaction and
themselves remain chemically, quantitatively unchanged at the end of reaction
are called catalysts and the phenomenon is called 'Catalysis'.
Homogeneous Catalysis: The catalysis in which the reactants and catalyst are
in the same phase.
NO (g)
2 SO2 (g) + O2 (g) 2 SO3

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HCl(l)
CH3COOC2H5 (l) + H2O (l) CH3COOH + C2H5OH
Heterogeneous Catalysis: The catalysis in which the reactants and catalyst are in
different phases.

Pt (s)
2 SO2 (g) + O2 (g) 2 SO3(g)

Fe (s)
N2(g) + 3 H2(g) 2 NH3(g)

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13. Differentiate roasting and calcination with examples.
Ans: Roasting: The process of heating the ore strongly below its M.P. in presence of
air is called Roasting.
Types of roasting:
a) Oxidising roasting: The type of roasting in which sulphide ore changes into
oxide.
2 ZnS + 3 O2 2 ZnO + 2 SO2
b) Sulphatizing roasting : The type of roasting in which sulphide ore changes
into sulphate.
650C
ZnS + 2 O2 ZnSO4
c) Chloridizing roasting: The type of roasting in which sulphide ore changes
into chloride.
Calcination: The process of heating carbonate or bicorbonate ores below their
melting points in absence of air to give oxides (to remove volatile impurities).

ZnCO3 ZnO + CO2

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2 NaHCO3 Na2CO3 + CO2 + H2O

14. Explain the structures of (a) XeF4 and (b) XeOF4. F
Ans: a) XeF4:

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Xe
Xe = 5s25px25py15pz15d15d15d1 (2nd excited state)
Xe undergoes sp3d2 hybridization. Due to presence of
2 lone pairs 4 bond pairs, in Xe, the shape of XeF4 F
O
is square planar.
F
XeOF4:
Xe = 5s25px15py15pz15d15d' 5d1 (3rd excited state)
Xe
Hybridization
bond
Xe undergoes sp3d2 hybridization. Due to presence
F
of one lone pair and 6 bond pairs
(1 b.p. forms bond), the shape of XeOF4 is square pyramidal.

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b)

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15. Explain Werner's theory of coordination compounds with suitable examples.

Ans: Alfred Werner gave satisfactory explanation to the mechanism of formation of
complex. Some of the important postulates are:
Every complex compound has central metal atom or ion.
Central metal ion shows 2 types of valencies.

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Primary Valence:
It is equal to oxidation state of central metal atom.
It is ionisable valence.
It is non directional and represented by .... line.
It is satisfied by -ve ions only.
Secondary Valence:
It is equal to coordination number of central metal ion.
It is satisfied by ligands.
It is non ionisable valence.
It is directional and represented by line.
It is satisfied by -ve ions as well as neutral molecules.

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Cl

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NH3

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NH3

H3N

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Co+3

H3N

Cl

NH3

H3N

Cl

NH3

Co+3

Cl

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H3N

NH3

NH3

Cl

[Co(NH3)6] Cl3
16.

Cl

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NH3
[Co(NH3)5] Cl2

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Give the sources of the following vitamins and name the diseases caused by
their deficiency.
a) A
b) D
c) E
d) K

Ans: S.No.

Sources

Deficiency diseases

Vitamin-A

Carrot,
Fish oil

Night Blindness,
Xerophthalmia

Vitamin-D

Egg Yolk,
Sun Light

Rickets in Children,
Osteo- malacia in adults

Vitamin-E

Sun Flower oil,

Wheat germ oil

Sterility,
Muscular weakness

Vitamin-K

Green leafy
Vegetables,
Cabbage

Haemorrhage,
delay of blood clotting.

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Name of the
Vitamin

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17.

Write short notes on

a) Analgesics and b) Food preservatives

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Ans: a) Analgesics: The drugs which are used to reduce or relieve pain without

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disturbing nervous system. There are 2 types of analgesies:

i) Narcotic analgesies: Analgesies having addictive property, that cause

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depression of central nervous system and relieves strong pains like cardiac
pain and post operative pains. e.g: Heroin, Morphine.

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ii) Non-Narcotic Analgesics: Analgesics having no addictive property and

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relieves mild aches like head ache, back ache etc. e.g.: Aspirin, Ibuprofen.
b) Food Preservatives: Chemicals which are added to preserve food by

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preventing spoilage of food due to microorganisms, to enhance appeal and to

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increase the nutritive value.

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e.g.: Common Salt, Sugar, Sodium Benzoate.

18.

Explain (a) Sand Meyer reaction and (b) Carbyl amine reaction.

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Ans: (a) Sand Meyer reaction: The reaction in which diazonium group of diazonium
salt is replaced by the nucleophiles like Cl or Br or CN in presence of

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Cu+ ion.
e.g.:

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N2Cl

Cl

HCl

Cu2Cl2

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+ N2

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(b) Carbyl amine reaction: A dirty smelling compound Carbyl amine

(Isocyanide) is formed when aliphatic or aromatic primary amine is heated
with Chloroform and ethanolic KOH.

NC

NH2

e.g.:

Heat
+ CHCl3 + 3 KOH

+ 3 KCl + 3 H2O

(Alcoholic)

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SECTION - C
19.

(a) State and explain Kohlrausch's law of independent migration of ions.

(b) What is order of a reaction? How is it different from the molecularity
of a reaction? Give one example each for first order and second order
reactions.
Ans: (a) Kohlrausch's law: The limiting molar conductivity of an electrolyte (m) is
the sum of the limiting molar conductivities of cation (+) and anion ().
m = v+ + + V
Where V+ and V are the no. of cations and anions present in the electrolyte.

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e.g.: (1) m (NaCl) = Na+ + Cl

(2) m (BaCl2) = Ba+2 + 2 Cl

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(b) Order : The sum of the powers of the concentration terms of the reactants
present in rate determining step at a given temperature.

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S.No.
1.

ORDER

MOLECULARITY

The sum of the powers

of the concentration terms
in rate equation.

No. of species participating

in rate determining step.

2.

It is determined
experimentally.

It is determined theoritically
from reaction mechanism.

3.

This can have values zero,

+ve, -ve or fractional.

This can not have values

zero, -ve or fractional.

4.

It is applicable to entire
reaction.

It is applicable to a part of the

reaction.

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Heat
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1st order reaction: e.g.: N2O5 2 NO2 + O2
2
2nd order reaction: e.g.: CH3COOC2H5 + NaOH CH3COONa + C2H5OH
20.

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(a) How is ozone prepared? How does ozone reacts with

(i) PbS

(ii) Moist KI

(iii) Hg and

(iv) Ag.

Give equations.

(b) Write the balanced equations for the following.

i) NaCl is heated with conc. H2SO4 in presence of MnO2.
ii) Cl2 is passed into a solution of NaI in water.

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Ans: (a) By passing silent electric discharge through pure, dry, cold oxygen 10%
ozone is formed. Pure O3 can be condensed in a vessel surrounded by liquid
oxygen.
silent
3 O2 2 O3; H = +142 K.J./mol
electric discharge
i) O3 oxidizes black PbS to white PbSO4.

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PbS + 4 O3 PbSO4 + 4 O2

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ii) O3 oxidizes moist KI to I2.

2 KI + H2O + O3 I2 + O2 + 2 KOH
iii) Hg loses lustre and meniscus and sticks to glass surface when reacts with
O3. This is called "tailing of mercury".
2 Hg + O3 Hg2O + O2
iv) O3 oxidizes Ag to Ag2O.
2 Ag + O3 Ag2O + O2

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(b) (i) By heating NaCl with conc. H2SO4 & MnO2, chlorine gas is liberated.
4 NaCl + MnO2 + 4 H2SO4 MnCl2 + 4 NaHSO4 + 2 H2O + Cl2
ii) Cl2 oxidizes NaI to I2.

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Cl2 + 2 Na I 2 NaCl + I2

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(a) Explain i) Cannizzaro reaction and ii) Decarboxylation.

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(b) Explain the acidic nature of phenols and compare it with that of
alcohols.

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Ans: (a) i) Cannizzaro reaction: Aldehydes do not have alpha Hydrogens undergo
disproportionation on heating with strong alkali. Here aldehyde is oxidised

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to salt of carboxylic acid & reduced to alcohol.

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C= O+

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H

C = O + Conc.KOH

CH3OH + HCOOK

ii) Decarboxylation: The phenomenon of lose of CO2 from the sodium salt of

carboxylic acid when it is heated with soda lime (3 parts NaOH + 1part CaO)
to form alkane.

CaO
eg: CH3 COONa + NaO H CH4 + Na2CO3

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(b) Acidic Nature of Phenols: Proton (H+) donor is acid -OH is electron with
drawing group and is attached to sp2 carbon of benzene ring. As
electronegativity of sp2 carbon of phenol, electron density decreases on
oxygen. This will increase the polarity of O H bond and results increase
in ionisation of phenols than that of alcohols. In alkoxide ion (RO ), the
negative charge is localised only on oxygen, where as in phenol, negative
charge is deloclaised. Due to resonance, stable phenoxide ion is formed by
losing H+ ion easily.

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..
RO
..
OH

R O + H+

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..
.. O ..

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..
.. O ..

+ H+

.. O ..

.. O ..

.. O ..

..
.. O ..

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phenoxide ion is more stable than that of alkoxide ion. Acidity of phenols
is more than that of alcohols. When electron withdrawing groups like -NO2
are attached to benzene in ortho, para positions in phenol, acidic nature will
increases further. From pka data we will understand that phenol is million
times more acidic than that of ethanol.

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- A.N.S. SANKARA RAO, Senior Lecturer.

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