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n
.
a
Time : 3 Hours
t
e
SECTION - A
Max. Marks: 60
h
b
i
(ii) Answer ALL the questions at one place in the same order.
at
r
p
10 2 = 20
1.
2.
3.
4.
5.
6.
7.
u
d
a
n
e
e
.
w
w
t
e
n
.
a
h
8.
Write the names and structures of the monomers of the following polymers
(a) Dacron and
(b) Teflon.
9.
10.
b
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t
a
r
p
SECTION - B
u
d
a
n
e
e
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ww
12.
13.
6 4 = 24
Calcualte (a) Molality (b) Molarity and (c) Mole fraction of KI, if the
density of 20% (mass/ mass) aqueous KI is 1.202 g mL-1.
(molar mass of KI = 166).
Explain the terms (a) Tyndall effect (b) Brownian movement (c) Kraft
temperature and (d) gold number.
Explain briefly the extraction of aluminium from bauxite?
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14.
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e
15.
16.
17.
18.
n
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a
h
b
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t
a
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p
u
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SECTION - C
a
n
e
e
.
w
w
2 8 = 16
t
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n
.
a
h
b
i
t
d) Aldol condensation.
21.
a
r
p
du
b) Na2S2O3 and
a
n
c) Iron.
e
e
.
ww
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ANSWERS
SECTION - A
1.
t
e
n
.
a
Ans: The stoichiometric, point defect that arises when cation occupies interstitial site
instead of lattice sites in crystalline solids.
h
b
i
t
a
r
Ans: Misch metal is an alloy of 95% Lanthanoid metal and 5% Iron and traces of S,
Ca, C and Al. It is used to make bullets.
3.
p
u
d
Ans: At a given temperature, the partial pressure of a gas (p) (in vapour phase) is
a
n
directly proportional to the mole fraction of the gas (x) in the solution.
px
p = KH . x
e
e
.
w
w
t
e
n
.
a
h
63
Ans: c = current = 1.5 amperes, E =
2
b
i
t
E
63
1
e = = , t = time = 10 60 = 600 sec
96,500
2
96,500
a
r
p
5.
u
d
a
n
e
e
.
ww
1.5 63 600
=
2 96,500
= 0.2938 grams.
Ans: The molten liquid obtained in reverberatory furnace contains mainly Cu2S and
little FeS is called "matte". The solidified Cu obtained in Bessemer
6.
Ans: The anion vacancies are occupied by the electrons in metal excess defect. These
electrons are responsible for colour and paramagnetic nature.
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7.
t
e
kind of monomers.
n
.
a
e.g.: n C2H4 C C n
h
b
i
t
a
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p
u
d
a
n
e
e
.
w
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t
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n
COOH
.
a
h
(b) TEFLON:
b
i
t
F
Monomer: Tetrafluoro ethene:
C=C
ra
F
9.
p
u
d
a
Ans: Antibiotic is the substance produced by chemical synthesis, which inhibits the
n
e
e
.
ww
Ans: The drug that prevents the interaction of histamine with the receptors of
stomach wall are called "antihistamines".
e.g.: Seldane, Dimetane.
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t
e
SECTION - B
11.
Calculate (a) Molality (b) Molarity and (c) Mole fraction of KI, if the
density of 20% (mass/ mass) aqueous KI is 1.202 gm lit-1
(molar mass of KI = 166).
n
.
a
h
b
i
mass
100
Ans: Volume of the solution = = = 83.2 ml
density 1.202
t
a
r
Mass of solute
1000
a) Molality (m) =
Gram molar mass of solute
Mass of solvent
p
u
d
20
1000
= = 1.51 mol/ kg.
166
80
a
n
e
t
e
n
Mass of solute
1000
b) Molarity (M) =
gram molar mass of solute Volume of solution
e
.
w
w
20 1000
= = 1.45 mol/ lit.
166 83.2
WH O
2
.
a
h
b
80
c) no. of moles of water = nH O = = = 4.44
2
18
MH O
i
t
a
WKI
20
no. of moles of KI = nKI = = = 0.12
166
MKI
r
p
u
d
a
n
nKI
0.12
Mole fraction of KI = = = 0.026.
nKI + nH O 0.12 + 4.44
12.
e
e
.
w
w
Brownian
movement
(b) Brownian
movement: The
continous rapid zig-zag movement by colloidal
particles in the dispersion medium is known as
"Brownian movement".
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(c) Kraft temperature: The temperature above which micelles are formed.
(d) Gold number: The minimum number of milligrams of lyophilic colloid
t
e
n
.
a
h
b
i
Ans: Al is extracted either from red bauxite (consists iron oxide impurities) or from
white bauxite (consists SiO2). Powdered ore is concentrated by leachal agent
NaOH at 35 - 36 bar pressure and 473 - 523 K temperature to get sodium
t
a
r
aluminate.
p
u
d
a
n
e
e
.
w
w
t
e
n
1470 K
.
a
h
Purified Al2O3 is added with CaF2 (Fluorspar) to lower the fusion temperature
and Na3AlF6 (Cryolite) is added to increase conductivity. This mixture is taken
b
i
t
in steel vessel coated with carbon lining acts as cathode and graphite acts as
anode and electrolysed.
2 Al2O3 + 3 C 4 Al + 3 CO2
Reaction at Cathode: Al +3 + 3 e Al
a
r
p
u
d
a
n
e
e
.
ww
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(b) XeO3
..
Xe = 5s2 5px1 5py1 5pz1 5d1 5d1 5d1 (3rd excited state)
hybridization
bonds
Xe
Xe has one lone pair and six bond pairs. 3 bond pairs
O
form 3 pi bonds. Xe undergoes sp3 hybridization. The O
O
shape of XeO3 is pyramidal. Bond angle is 103.
15. What is Lanthanoid contraction? What are consequences of Lanthanoid
contraction?
Ans: The gradual decreage in atomic radii & ionic radii of 14 Lanthanoid elements
(with increasing atomic number) due to poor shielding of valence electrons
and diffused shape of f orbitals is called "Lathanoid contraction".
Consequences:
t
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a
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b
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a
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p
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a
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.
w
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The formation of n - Hexane with HI & red P indicates straight chain for
glucose.
.
a
h
HI
OHC - (CHOH)4 - CH2OH CH3 - CH2 - CH2 - CH2 - CH2 - CH3
b
i
t
The formation of Oxime with NH2OH & the formation of cyanohydrin with
HCN indicates presence of
C = O group.
a
r
p
u
d
a
n
e
e
.
ww
CH2OH
CH2OH
The formation of saccharic acid with HNO3 indicates presence of one primary
-OH group.
CHO
(CHOH)4
CH2OH
HNO3
COOH
(CHOH)4
COOH
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The formation of pentaacetate with acetic anhydrate indicates presence of
t
e
CHO
CHO
Acetic anhydride
(CHOH)4 (CH COOCH3)4
n
.
a
CH2 COOCH3
CH2OH
h
b
i
CHO
HO H
p
u
d
H OH
H OH
a
n
CH2OH
17.
t
a
r
OH
e
e
.
w
w
t
e
n
Ans: Reaction of CH3Cl with OH- ion is the best example of SN2 mechanism. It is
.
a
h
b
i
t
a
r
p
C Cl HO..... C ..... Cl HO C H + Cl
u
d
a
n
e
e
.
ww
both CH3Cl & OH-) and bi molecular (as 2 molecules are taking part in the
rate determining step).
Order of reactivity: 1- alkyl halide > 2- alkyl halide > 3- alkyl halide.
Effect of leaving group: RI > RBr > RCl > RF.
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18.
t
e
N2Cl
n
.
a
Cl
h
b
i
Cu
HCl
..
(b) H - N - H
+ N2 + CuCl
H
..
t
a
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p
u
d
H -C N-H
H
a
n
e
e
.
w
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19.
SECTION - C
t
e
n
.
a
h
b
i
t
Ans: This theory was proposed by Arrhenius and developed by Max Trautz &
William Lewis to explain the rates of gaseous reactions.
a
r
p
u
d
a
n
e
e
.
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In addition to the normal molecules, the molecules must acquire some extra
amount of energy, called " activation energy (Ea)".
Ea = ET - ER.
ER
t
e
n
.
a
ET
Ea
P.E.
P.E.
ET
EP
h
b
i
t
a
r
p
u
d
EP
ER
Reaction coordinate
Reaction coordinate
(Exothermic reaction)
(Endothermic reaction)
The molecules possesing threshold energy are called "activated molecules".
a
n
e
e
.
w
w
t
e
n
.
a
h
b
i
t
The number of collisions per second per unit volume of the reaction
mixture is known as collision frequeny (Z). Activation energy also affects
the rate of a reaction.
a
r
p
u
d
a
n
e
e
.
ww
Drawbacks:
It considers atoms or molecules as hard spheres.
It ignores structural aspect of molecules.
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20.
Explain
a) Reimer - Tiemann reaction b) Williamson's ether synthesis
c) Hell - Volhard - Zelinsky reaction and d) Aldol condensation.
t
e
h
b
i
OH
t
a
r
65C
+ CH Cl3 + 3 Na OH
n
.
a
CHO
+ 3 NaCl + 2 H2O
p
u
d
a
n
e
e
.
w
w
t
e
n
.
a
h
b
i
t
a
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p
21.
u
d
a
n
e
e
.
ww
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S + O2 SO2
4 FeS2 + 11 O2 2 Fe2O3 + 8 SO2
t
e
n
.
a
V2O5
2 SO2 + O2 2 SO3; H = - 19.6 KJ/mol.
h
b
i
t
a
r
p
u
d
a
n
e
e
.
w
w
.
a
h
b
i
t
t
e
n
a
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p
u
d
a
n
e
e
.
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