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Sardina
[45]
[54]
3,690,839
3,691,020
Dec. 9, 1986
[57]
ABSTRACT
References Cited
585/440; 585/914
[58]
[56]
Date of Patent:
[75] Inventor:
4,628,136
3,515,764
11/1968
Ward
. . .. .. . . . . . .... . . .
. . . ..
from water.
585/402
OVERifAD
CONDENSB?
TO VENT
GAS RECOVERY
lNHlBlTOR
104
FUEL
STEAM
SUPERHEATER
DEHYDROGENATION
SYSTEM
E5 9
LIGHTER
HEAT RECOVERY
8 MDENSATION
REACTOR!
EFFLLENT
EXCHANGER
SPUI'E"
STYRENE
,_-_--
('06
CONDENSATE
Puw
HEAVER
comm
STRIPPtNG
109
EB PUMP
ETHYLBENZENE
4,628,136
tion in the presence of steam. Early patents on the sub~ 25 nated and that much of the diluent steam needed as
ject have concerned themselves essentially with the
sensible heat for the dehydrogenation reaction can be
ation. Its novelty consists of vaporizing water with a 60 The present dehydrogenation process for the produc
tion of styrene comprises dehydrogenation of ethylben
reaction mixture that has been cooled to 90-120 degrees
zene, preferably in a multi-bed, preferably two-bed,
C. and is at a pressure of 0.4-1.2 atm., and compressing
radial flow reactor, using a conventional catalyst for
the resultant steam to 1.4-2.5 atm. and using it to pre
this purpose, such as one based on iron oxide, and con
pare the ethylbenzene, water, and steam feed mixture.
US. Pat. No. 3,515,767 embodies the same inventive 65 ventional operating conditions.
It is understood that certain equipment such as
concept as this Offenlegungsschrift. It teaches the gen
eration of subatmospheric steam from the heat of
valves, piping, indicators and controls, and the like have
been omitted from the drawings to facilitate the descrip
quenched reaction zone effluent, and compresses the
4,628,136
reaction temperature.
Feed ethylbenzene is vaporized in an EB vaporizer 2,
4,628,136
20
Adiabatic
Isothermal
Steam/EB Ratio, wt
1.0-2.2
0.5-1.5
EB Conversion, %
50-90
50-90
530-650
530-720
0.3-1.5
0.3-1.5
Dehydrogenation Temperature,
deg. C.
Dehydrogenation Pressure,
kg/cmzA
25
Steam import, kg
Fuel import, kcal
Cooling water (10 deg. C.
Loss to polymer, kg
Scheme A
Scheme B
1.729
726
113
0.995
614
65
0.00]
0.0025
min.) kg
4,628,136
0.3-1.5 kg/cmzA.
0.3-1.5 kg/cmZA.
being vaporized during said indirect heat exchange into 25 sisting of a gaseous phase comprising hydrocarbons, an
a gaseous mixture; and said gaseous mixture being
passed into said dehydrogenation zone.
2. A process for the production of styrene according
to claim 1, wherein the net weight ratio of water to
ethylbenzene in said gaseous mixture is from about 0.3 30
to about 0.6.
55
65