Академический Документы
Профессиональный Документы
Культура Документы
Carrier Properties: II
Pierret, Semiconductor Device Fundamentals (SDF)
pp. 32-49
Professor Mark Lundstrom
Electrical and Computer Engineering
Purdue University, West Lafayette, IN USA
lundstro@purdue.edu
1/23/15
Lundstrom
ECE 305 S15
announcements
1. Exam 1: Friday, Jan. 30 in class
see the class homepage for info
https://nanohub.org/groups/ece305lundstrom
2. Do the homework!
3. Review the quizzes.
4. Ask questions on Piazza
Lundstrom ECE 305 S15
vocabulary
1. Miller indices
2. Diamond and Zinc blende lattices
3. Energy bands
4. Conduction band, valence band, band gap
5. Energy band diagrams
6. Intrinsic carriers, intrinsic carrier concentration
7. Effective mass and band structure
8. Doping
9. Intrinsic semiconductor
10. Extrinsic semiconductor
11. Density of States
12. Fermi function, Fermi level
13. Non-degenerate semiconductor
intrinsic
extrinsic
4
Fig. 2.22 from R.F. Pierret, Semiconductor
Device Fundamentals
outline
1. Density of States
2. Fermi function
3. Carrier distributions
4. Carrier concentrations
-given Fermi level
-given doping densities
Lundstrom ECE 305 S15
DOS
4Na states / band
conduction band
Na = 5 x 1022 /cm3
valence band
g ( E ) dE
density-of-states
Number of states in an
energy range, dE, per m3.
DOS
E
ECtop
ECtop
g ( E )dE = 4N
gC ( E ) dE
EC
EC
EV
gV ( E ) dE
EV
g ( E )dE = 4N
V
EVbot
EVbot
g(E)
gC ( E ) =
mn* 2mn* ( E EC )
2!3
EC
EV
gV ( E ) =
m *p 2m *p ( EV E )
2!3
bot
V
D(E)
outline
1. Density of States
2. Fermi function
3. Carrier distributions
4. Carrier concentrations
-given Fermi level
-given doping densities
Lundstrom ECE 305 S15
Occupation of states
Si atom (At. no. 14)
4S0
energy
3P2
3S2
States below this
energy have a high
probability of being
occupied.
2P6
2S2
1S2
10
Fermi level
E
ECtop
E = EF
(electrochemical potential)
EC
f (E) =
EV
( E EF )
1+ e
kB T
(Fermi function)
bot
V
D(E)
11
f (E) =
( E EF )
1+ e
kB T
f ( EF ) =
EF
Fermi function
small probability
of being empty.
0.5
f (E)
1
2
Fermi function
Fermi level
f (E)
kBT = 0.026 eV
12
f (E) =
( E EF )
1+ e
kB T
0
EF
13
effect of temperature
f (E)
kBT0
T1 > T0
f (E) =
( E EF )
1+ e
kB T
0
EF
14
T2 < T0
EG = 1.1 eV
EV
15
conduction band
non-degenerate
semiconductor
f (E)
E >> EF
f ( E ) e( EF E ) kBT
small probability
of being full
f (E) =
( E EF )
1+ e
kB T
0
EF
16
EC
valence band
f (E)
fh ( E ) = 1 f ( E ) =
small probability
of being empty
E << EF
f (E) =
( EF E )
1+ e
kB T
fh ( E ) e( EEF ) kBT
non-degenerate
semiconductor
( E EF )
1+ e
kB T
0
EF
17
Non-degenerate semiconductors
f ( EC ) =
1
1+ e( EC EF ) kBT
f ( EC ) ( EF EC ) kBT
EC
EG = 1.1 eV
3k BT
EV
f ( EV ) =
( EV EF )
1+ e
kBT
1 f ( EV ) e( EV EF ) kBT
18
EC
n = ni
E F = Ei
EG = 1.1 eV
EV
f (E) =
( E EF )
1+ e
kB T
p = ni
19
n = ni (T )
T1 > T2
EF
EG = 1.1 eV
T2
EV
p = ni (T )
small probability
of being empty.
20
12
f (E)
21
21
Fig. 2.22 from R.F. Pierret, Semiconductor
Device Fundamentals
n = N C e( EF EC ) kBT
n >> ni
EF
EG = 1.1 eV
f (E) =
EV
22
( E EF )
1+ e
kB T
extrinsic
23
23
Fig. 2.22 from R.F. Pierret, Semiconductor
Device Fundamentals
EC
EG = 1.1 eV
EF
EV
p >> ni
f (E) =
( E EF )
1+ e
Expect:
p e( EV EF ) kBT
24
p = NV e( EV EF ) kBT
kB T
outline
1. Density of States
2. Fermi function
3. Carrier distributions
4. Carrier concentrations
-given Fermi level
-given doping densities
Lundstrom ECE 305 S15
25
gC ( E )
( E EC )
n ( E ) dE = gC ( E ) dE f ( E )
EC
EF
p ( E ) dE = gV ( E ) dE (1 f ( E ))
EV
EVbot
gV ( E )
g(E)
( EV E )
26
carrier distribution
question
1) At T = 0 K, what is the density of holes in the valence
band of a pure semiconductor?
a) the atomic density of the material.
b) Avogadros number.
c) The density of dopants.
d) The packing fraction of the material.
e) Zero
29
another question
2) At T = 0 K, where is the Fermi level located in a pure
semiconductor?
a) Deep inside the conduction band
b) Near EC.
c) Near the middle of the bandgap.
d) Near EV.
e) Deep inside the valence band.
30
gC ( E ) dE
EC
EF
EG = 1.1 eV
n ( E ) dE = f ( E ) gC ( E ) dE
EC
EC
n ( E ) dE = f ( E ) g ( E ) dE
C
EV
31
n = NC e
kB T
EC EF > 3kBT
mn* k BT
NC = 2
2
2 !
For Si at T = 300K:
3/2
EC
EF
N C = 3.23 1019 cm -3
EV
32
p = NV e
m *p kBT
NV = 2
2
2 !
kB T
EF EV > 3kBT
m = 0.81
3/2
For Si at T = 300K:
*
n
EC
NV = 1.83 1019 cm -3
EF
EV
33
summary
n = N C e( EF EC ) kB T
p = NV e( EV EF ) kB T
mn* k BT
NC = 2
2
2 !
m *p kBT
NV = 2
2
2 !
EC
EF
3/2
EV
3/2
summary
1) Semiconductor devices are made by controllably putting a
few electrons in the conduction band and a few holes in
the valence band.
2) In equilibrium, the Fermi function gives the probability
that a state at energy, E, is occupied by an electron.
3) The two parameters in the Fermi function are the Fermi
level and the temperature.
4) The density of states, g(E), tells how the states are
distributed in energy.
5) From the DOS and the Fermi function, we can relate the
electron and hole densities to the location of the Fermi
35
level.