Академический Документы
Профессиональный Документы
Культура Документы
Chemistry II Laboratory
Introduction: Thermodynamics is the study of energy changes that occur in chemical and
physical processes. The enthalpy and entropy changes of a system undergoing such processes
are interrelated by the change in free energy, G, according to the equation,
G = H - TS
(1)
(2)
G will be calculated from the H and S values obtained electrochemically. The validity of
the Equation (1) will be tested by comparing the value of H obtained electrochemically with the
value of H obtained calorimetrically for the same reaction.
The Electrochemical Method:
The electrochemical method offers simple and accurate means for the determination of
thermodynamic quantities. A simple electrochemical cell can be assembled with use of small
beakers and a convenient and easily constructed salt bridge. The galvanic cell is described
Cu(s)/CuSO4(aq) || Zn(s)/ZnSO4(aq)
(3)
(4)
(5)
(6)
E = S (T) - H
nF
nF
(7)
or
(8)
Y- intercept = - H_
nF
(9)
and
G can now be calculated by means of Equation (1). We can verify its value by using Equation
(5). Please note that in both cases, G must be calculated for the same temperature. If the
calculations are done for 298 K (25 C), we can also verify the experimental value of E for this
temperature by employing the Nernst equation (7)
E = E RT ln [products]
nF
[reactants]
(10)
where E is the standard potential measured at 25 C and is 1.100 V for the cell under
consideration. When concentrations of the ZnSO4 and CuSO4 solutions are equal, the log term
of the Nernst equation becomes zero. Under these conditions, the standard voltage, E , of the
cell is equal to the measured voltage, E.
Safety Precautions: Safety goggles must be worn in the lab at all times. Any skin contact by
chemicals should be washed immediately.
1. Once the MicroLab window opens then select Sensor so that it is highlighted blue
(shown below).
From the drop down menu, select thermistor. Then click on the CAT-5 A input so that it is
highlighted red as shown above. Make sure your actual Thermistor is plugged into the same
CAT-5 jack on the front panel of the MicroLab interface panel. In the Label window, type in
Temperature. Click next to calibrate.
4. Once the calibration is complete then next task is continued construction of your
program. Follow similar steps to record voltage vs. temperature, so that the voltage
measurement is on the y-axis and the temperature is on the x-axis. There is no need to
calibrate the voltage sensor.
5. Once both sensors are added, you can click and drag each sensor to the graph,
spreadsheet and digital window. The temperature sensor should be on the x-axis and
voltage on the y-axis of the graph. By doing this you can see the change in voltage with
temperature in real time on the graph and digital window, as well the data will be
recorded to a spreadsheet for later analysis. (See image below.)
6. Once the sensors are in place and the program is complete, click on File on the top
toolbar, then click save experiment. Give your experiment program a name, such as
DeltaG.
7. It is important that the program is saved on the computer hard drive and that you
remember the program name and location in order to complete the experiment.
Part II Electrochemistry
Materials:
Zinc and Copper metal strips
0.5 M Copper sulfate
0.5 M Zinc Sulfate
0.1 M Potassium Nitrate
Petri Dish
Set of 3 10 mL beakers
Forceps
Microlab Voltage Alligator Clips
DeltaG.exp Microlab Program
Waste Container
Procedure:
1. Create an ice/water bath with the pan provided. Take care to not add too much ice or
water to the bath as to upset or over flow into the electrochemical cells.
2. Place the ice bath with electrochemical cell on a hot plate do not turn the heat on yet!!
Let the set-up stand for 15 minutes until the temperature stabilizes.
3. Pour about 5 mL of 0.1 M potassium nitrate (KNO3) into the center well of the
electrochemical cell. Pour about 5 mL of 0.5 M zinc sulfate (ZnSO4) into one of the
outer wells and add about 5 mL of 0.5 M copper sulfate (CuSO4) into a second outer
well. Do not let any of the solutions mix, they should be separate uncontaminated
solutions.
4. With clean forceps, take a strip of filter paper and dip one end into the center beaker
containing the KNO3 and then place the other end of the filter paper into the well
containing the ZnSO4. Repeat this procedure for a second piece of filter paper with the
KNO3 and CuSO4. This creates a salt bridge for the galvanic cell.
5. With clean forceps, take a strip of zinc metal and sand it to clean the surface of an oxide
layers. Bend the zinc strip so that one end of the zinc metal is in the well of ZnSO4
solution and the remaining portion is bent over the edge of the electrochemical cell.
Repeat this step for a strip of copper metal with one end immersed in the cell containing
CuSO4 solution.
6. Fasten the thermistor temperature probe to the ring stand with a clamp and adjust the
temperature probe so that the tip is immersed in the center well containing the KNO3. It
is assumed that the temperature of all three wells will be very close throughout the
experiment. Let the entire system come to equilibrium.
7. Make sure the DeltaG.exp Microlab program is open and record the temperature.
Record the initial temperature in your lab notebook.
8. Attach the alligator clips to the metal strips and record the voltage reading. If a negative
value appears on the screen, then reverse the alligator clips. Disconnect the alligator clips
once you have recorded a positive voltage in your lab notebook.
9. This step should be done as quickly as possible. Reattach the alligator clips, turn on
the hot plate to high, click on Start to engage DeltaG.exp Microlab program to begin
recording values. {Prolonged connection of the wires will cause electric current to flow
through the cell. This discharge will result in changes in concentrations of the solutions.
Since the measured voltage depends on these concentrations, there will be an error in the
voltage readings.}
10. Stop recording data when the temperature reaches 40 C. Turn off the hot plate!!
Disconnect the alligator clips and carefully remove the electrochemical cell from the
water bath and hot plate.
11. Retain and clean the zinc and copper strips. Collect all other waste into the waste jar
provided.
Microlab Software manipulations:
If you are working on this data after lab, open Microlab and choose Simulate/Open File/Hand
Enter to look at your data. Once the program opens you must then open each individual file to
use the data collected.
Post Laboratory Report: You will need the enthalpy value found from Experiment 1.
Electrochemistry:
1. The Microlab Spreadsheet displays the voltage values of the cell in volts and is the y-axis
values of the plot. The temperature readings in degrees Celsius must be converted to
Kelvin. The temperature in Kelvin and is the x-axis values. Export the data as a
Comma-Separated- Value text file or .csv file and import to Excel. Using Excel,
construct a plot of voltage vs. temperature in Kelvin and then apply a linear curve fit
through the data. Report the equation for the linear fit. Include a copy of the plot.
2. Using the linear curve fit equation, calculate S from the slope (S/nF ) and H from
the Y-intercept = - (H/nF ).