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Definitions
Anion:
Atomic
Radius
Avogadros
number
Cation
Divalent
Ductile
Electron
Affinity
Electronegati
vity
Ion
Ionisation
Energy
Isotope
Malleable
Oxidation
Valence
shell/electro
ns
Guide
Words in this colour have their definitions in the table of definitions above.
Atoms
The
The
The
The
The Electrons
Electrons are negatively charged particles which orbit around the nucleus of an atom.
They determine how the atom behaves and most of its properties.
The Bohr Model:
Proposed by the scientist Niels Bohr.
The Bohr Model states that electrons have set distances in
which they orbit a nucleus.
Each set distance is a shell and can be referred to as n.
Each set distance has a fixed amount of energy with each
electrons in that orbit having that amount of energy.
The further distance away you get from the nucleus, the
more energy is contained in the orbits.
Orbitals (sub-shells):
Within each shell of an electron are orbitals.
An orbital is a probability cloud and is defined as an area in space where there is a high
probability of finding electrons.
Each orbital can only hold a maximum of two electrons.
There are s, p, d and f orbitals and each orbital has its own unique shape.
Electrons fill shells from the lowest energy level to the highest.
The periods in the periodic table represent which shell the electrons will go into.
s-orbital:
Found in the first shell of the atom.
It can hold a maximum of two electrons.
Is a spherical shape.
This is why the first period in our period table only has two elements.
p-orbital:
Found in the second shell of the atom.
The second shell is larger and can include more than just the s-orbital.
It can hold a maximum of six electrons.
It consists of three configurations along the 3D x-y-z axis with each one holding two
electrons.
d-orbital:
Found in the third shell of the atom.
It can hold a maximum of ten electrons.
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f-orbital:
Found in the fourth shell of the atom.
It can hold a maximum of fourteen electrons.
It consists of seven configurations each one holding two electrons.
Electron Configuration:
Electron configurations are a way of writing down where each electron is located within
an atom.
It involves three main parts written down to form an equation.
In order to write the electron configuration of an atom, we write:
1. The number of the shell.
2. The letter of the orbital.
3. The number of electrons in that orbital.
Electrons fill orbitals in a certain order, from the lowest energy to the highest. A trick
we can use to write this is to memorise the following diagram and draw diagonal lines
to determine the order in which orbitals will be filled in.
From this diagram, we know that electrons will fill in the following order:
1s2 2s2 2p6 3s2 3p6 4s2 3d10 and so on.
Just by looking at the above equation, we know:
This atom has a total of 30 electrons. (Total number of electrons in each orbital.
We can determine that this is an atom of Zinc. (Assuming it isnt an ion)
Write the
electron
configuration
for Chromium.
Ionization Energy:
Ionization energy is the amount of energy required to remove an electron from an atom
to create a positively charged Ion.
When an electron is removed from an atom, it forms a positively charged ion called a
cation. This is because before the electron was removed there were an equal number
of protons and electrons and hence the overall charge was neutral. Now that the
electron is removed, there are more protons than electrons and hence the overall
charge is positive.
The outer most electrons have the most energy and hence require the least energy to
be removed so they are the first to be removed.
The closer an electron is to its nucleus, the more energy required to remove the
electron.
When all of the electrons in the outer most shell are removed, there is a jump in energy
required to start removing electrons in the next outer most shell.
This makes sense as electrons are being attracted towards the protons in the nucleus
and the closer they are, the stronger the
force of attraction and hence the more
energy required to remove the electron.
Energy is also required when adding
electrons to form negatively charged ions
called anions. This energy is called the
electron affinity.
The orbitals are also on periodic table as
shown below with the number of
elements for each row of the orbitals
corresponding to the number of electrons the orbital can hold, for example all the sorbitals in green have only two elements in each row.
Stoichiometry
Stoichiometry is the science of measuring chemicals that go into and out of reactions.
It allows us to count atoms and molecules by weighing them.
Atomic Mass:
The atomic mass of an element is the average number of all the isotopes of that
element and their abundance on earth.
Atomic mass is measured in atomic mass units (amu).
We can calculate atomic mass by adding the number of protons and neutrons in an
element.
We can also calculate it if given the isotopes and their abundances by using the
following steps.
Convert the abundance of each isotope of the element from a percentage
to decimal.
Multiply the abundance of each isotope by its mass.
Add the final results of each isotope together.
Relative Atomic Mass:
The ratio of the average mass of an atom to 1/12 th of the mass of an atom of carbon-12.
1 amu = 1/12th the mass of a carbon-12 (12C) atom which is 1.99264648 x 10-23.
1.
2.
3.
4.
5.
6.
Moles:
A mole is one of the most important units in chemistry.
It allows us to express a chemicals atomic mass in terms of grams.
A mole is equivalent of the amount of atoms in 12 grams of Carbon-12 which is 6.022 x
1023.
This number is known as Avogadros number.
A mole of anything means 6.022 x 1023 of that object, so a mole of rice would mean
6.022 x 1023 grains of rice.
For example, a mole of oxygen would mean 6.022 x 1023 atoms of oxygen which in
total comes to 16 grams. If you look at the period table, the relative atomic mass of
oxygen is 16 amu.
This is known as the elements Molar Mass.
To calculate the molar mass of a compound, you must add the molar mass of all the
individual elements.
Calculate the
Molar Mass of
Sucrose C12H22O11.
Reactions:
A reaction takes place when atoms of the same
or different elements react together to form a
new substance.
A reaction involves the reactants which are the elements that are being rearranged
and the products which are the new substances that are formed due to the reaction.
The total number of atoms of each element remains the same before and
after the reaction. (Conservation of mass)
Balancing Equations:
A balanced equation is an equation that has an equal number of each element on both
sides of the equation.
This involves the law of conservation of mass.
This equation is used to tell you how much of each element goes into and comes out of
the reaction.
In order to balance an equation we use the following steps:
Start with the most complicated molecule.
Now since the goal is to have an equal number of each atom on each side
of the equation, we start multiplying atoms by certain amounts on each
side of the equation until we end up with a balanced equation.
We demonstrate this by placing a number beside the element to show how
many of that element is required.
Balance the
following
equation of
sucrose:
C12H22O11 + O2 = CO2 +
H2O
Molar Ratios:
Molar ratios are used to calculate the amount of a compound for a certain amount of
another.
By some simple mathematics, you can calculate your answer.
How much
Oxygen would
you need to
inhale in order to
burn 5 grams of:
C12H22O11 + O2 = CO2
+ H2O
Polarity:
Polarity refers to having one side slightly
positive in charge and the other side
slightly negative.
For a molecule to be polar, it cannot be
made of the same elements as the
electronegativity of both elements is
the same and one side will not be more
negatively charged than the other.
For a molecule to be polar, the difference
between their electronegativys must be
greater than 0.5.
When the difference is greater than 0.5,
the valence electrons of the atoms spend most of their time around the more
electronegative atom.
This result in one side of the molecule being slightly negative and the other side being
slightly positive.
This is called a Dipole Moment and is required for a molecule to be polar.
A dipole moment is when there is one part of a molecule which is negatively charged
and the other part positively charged.
When one of the atoms in the molecule is more
electronegative, it will pull not only its own but also its
neighbouring electrons closer towards itself.
This will lead the electron cloud of negativity to be greater
on
one side than the other and hence a polar molecule. This is
seen in the picture to the right.
Although if the atom is symmetrical, the distribution of
charges may cancel each other out making the molecule
non-polar.
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This can be seen in the following pictures with these opposite charges cancelling each
other out:
This leads to all the molecules of water or other polar solutions being arranged in a way
that achieves the lowest surface area.
When a non-polar liquid is added to a polar solution such as oil being added to water,
this mixture of non-charged oil molecules and charged water molecules will not want to
mix.
Water will continue to do everything it can to minimise its surface area much like when
there is air in a solution it tends to rice, the same will occur with the molecules of the
non-polar solution as they will be pushed up as the molecules of water attempt to
reorganise themselves back into their lowest energy state and surface area.
Dissolving:
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This is due to the particle having a larger surface area, which means more molecules
of the solute are exposed to the molecules of the solvent which.
Temperature:
The higher the temperature is, the more the solvent will dissolve.
This makes sense because a higher temperature means more kinetic energy, so
the particles are moving a lot faster, which means there will be more collisions with the
solute breaking it down at a quicker rate.
Increasing the temperature also increases the maximum amount of the solvent that
can be dissolved in the solution, not only the speed at which it is absorbed.
Agitation:
Agitation includes physics actions such as stirring or shaking the solvent and the
solution together.
This also works by increasing the Kinetic energy of the particles and causing more
collisions.
Chemical nature of solute:
A polar substance WILL dissolve in another polar substance. Two substances that can
dissolve each other are called Miscible.
A polar substance WILL NOT dissolve a non-polar substance. Two substances that
cannot mix or dissolve each other are called Immiscible.
This leads to a commonly used phrase like absorbs like.
Electrolytes:
An Electrolyte is the name given to an ion that has been dissolved into a solution.
This is due to the ion now being able to float freely in the solution while carrying its
electrical charge around.
Water for example is a poor conductor of electricity, but when you dissolve salt into
water, it becomes a better conductor of electricity due to the now dissolved ions of the
salt becoming electrolytes and able to carry and conduct electricity.
Due to this concept, we know that a solutions electrical conductivity can be related to
the amount of ions dissolved in the solution.
The higher amount of electrolytes in a solution, the higher its electro conductivity.
This can also be reversed to measure how concentrated a solution is by measuring its
electrical conductivity.
Not all electrolytes can conduct electricity equally well; due to this we have strong
electrolytes and weak electrolytes.
If a substance doesnt dissolve to form ions in the solution, the electrical conductivity
will remain the same.
Strong Electrolytes:
Strong electrolytes conduct electricity very well.
They are made up of Ions that dissolve very well solutions.
Salts are able to form strong electrolytes as Na+Cl- dissolving completely to form
Na+ and Cl-.
Strong bases or strong acids like H+Cl- are also another example of strong
electrolytes as they break down completely to form H+ and Cl-.
Strong Electrolytes:
Weak electrolytes do not conduct electricity very well.
They are made up of Ions that dissolve partially in solutions.
NH4+OH dissolve partially into NH4+ and OH which results in weak electrolytes as
only the NH4+ is an ion and the NH4+ is just a molecule.
An acid is a molecule or ion that, when placed in water, will give up a hydrogen ion (H+) to
a base, or accept an unshared pair of electrons from a base.
Water is the best solutions on earth as it is capable of absorbing more than anything else.
Acids and Bases:
H+ ions are also referred to as protons.
An Acid is a molecule or ion that, when placed in water, will give up a hydrogen ion H+
to a base, or accept an unshared pair of electrons from a base.
An acid is a solution that has more free H+ atoms than OH-.
A Base is a substance which dissociates (separates) in aqueous solution to yield
hydroxyl ions OH- or negatively charged hydroxide ions which react with an acid to
form a salt.
A base is a solution that has more free OH- atoms than H+.
Acids and Bases react with each other in a Neutralization Reaction to form a salt.
An easy way to think of it is an acid has the H+ ion and a base has the OH- ion.
When an acid is place in water, it will give up its H+ ion.
Neutralisation Reactions:
When an acid is added to water, it donates
a
+
H to the water.
This leaves us with a positively charged
hydroxide ion H3O+ (which is a H2O
molecule that has gained a H+ ion) and a
salt.
This can be seen in the picture to the right
which shows three different acids donating a
H+ ion to water to form a H3O+ ion and a
negative ion or a salt.
In these reactions, water can react as either a base or an acid. If it gains a H+ ion then
it is a base or if it loses a H+ ion then it is an
acid.
The products of the reaction are called the
conjugate acid and the conjugate base.
If it is a conjugate acid, then it has lost a H+
ion but, if it is a conjugate base then it has
gained a H+ ion.
This can be seen in the picture on the right
of hydrochloric acid HCL acid reacting with
water.
For every acid there is a conjugate base and for every base there is a conjugate acid.
A strong acid is an acid that really likes to get rid of its H+ ion and one once it does it
is very hesitant in taking it back so its conjugate base is a weak base and vice versa.
Precipitation Reactions:
This is when a solid is formed when reacting two aqueous solutions.
Bonds
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Atoms can form different type of bonds including the main three: Ionic, covalent and
hydrogen bonds.
An atom is most
Atomic Mass:
The atomic mass of an element is the average number of all the isotopes of that
element and their abundance on earth.
Atomic mass is measured in atomic
Ionic Bonds:
Ionic bonds form when a metal and a non-metal share electrons and bond together
forming a molecule (For Example: NaCl).
This type of bond occurs in three main simplified steps:
1. An atom donates electrons and another atom receives the electron.
2. This causes an imbalance in charges in each atom with the atom gaining the
electron now being negatively charged and the atom donating the electron
having a positive charge.
3. The two atoms attract to each other due to the opposite charges and an ionic
bond is formed.
Ionic bonds are formed due to atoms wanting to have a full valence shell. In the Na+Clexample, by forming an ionic bond, both elements now have a full valence shell.
All atoms in their normal form have a neutral charge due to the balance of protons and
electrons. By gaining and losing electrons, this creates an Imbalance in the charges
resulting in a positively or negatively charged atom.
Due to the change of electrons in the Na and the Cl, they are no longer atoms but are
now called Ions.
The positively charged Ion (Na+) is called a Cation and the negatively charged Ion (Cl-)
is called an Anion.
Once the ionic bond between both ions is formed, the overall charge of the molecule
formed is neutral as the charges of both ions cancel each other out (This means the
molecule formed is NaCl not Na+Cl-). We have now created Sodium Chloride.
Now say we have many Na and Cl atoms all forming ionic bonds with each other, due to
the positive and negative charges of the ions formed, they will all combine together to
form what is called a Lattice Structure.
This forms when the negative side of multiple Na+Cl- bonds combines with the positive
side of other Na+Cl- bonds and vice versa eventually forming the Lattice structure
shown below.
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Electronegativity
Electronegativity is a measure of how desperately an atom wants to gain electrons.
The more electronegative an atom is, the more it wants to gain electrons.
Na with an electronegativity of 0.9 is not very electronegative compared to Cl with
an electronegativity of 3.0.
This is why Na loses an electron while Cl gains one.
Generally, metals are not very electronegative compared to non-metals which are
usually very electronegative.
Ionic Charges
Atoms can form ions of different charges depending on which column or group they
reside in the periodic table.
It is more beneficial to know what charge each Ion gets by understanding the
concept behind the charges.
Keep in mind that each atoms goal is a full valence (outer) shell and all the atoms
originally have an equal number of protons and electrons which maintains their neutral
charge.
In Group 1, all the atoms have 1 valence electron which they would prefer
to donate in order to achieve a full valence shell. Once donated, these
atoms now have 1 less electron than protons. This leaves them with an
overall positive charge of +1.
In Group 2, all the atoms have 2 valence electrons which they would also
prefer to donate. Once donated, they now have two less electrons than
they do in protons and now have an overall charge of +2.
In Group 3, the concept is still the same as they have 3 valence electrons
and lose them to achieve a charge of +3.
Now Group 5 has elements which prefer to gain electrons rather than
donate them. They have 5 valence electrons and would prefer to gain
another 3 to achieve a full valence shell. Once they gain those electrons,
their overall ionic charge becomes -3 as they have 3 more electrons then
protons.
In Group 6 and 7, they gain 2 and 1 electrons respectively and will have
a charge of -2 and -1 respectively.
Finally, Group 8 will not gain or lose any electrons as they already have a
full valence shell and thus do not form ions.
Balancing Charges
In the example of NaCl, the Na is in group 1 and has an ionic charge of +1 while the
Cl is in group 7 and has an ionic charge of -1. These two charges are the same and do
not need balancing but this is not always the case.
An example of this is Lithium Oxide (Li2O) where Lithium sits in group one having a
+1 charge and Oxygen sits in group 6 having a -2 charge. These two charges do not
balance out and thus we need to balance them ourselves.
We can do this by adding more of either atom until the total charges are balanced.
In this example, we can add two Lithiums for every Oxygen. This means that the
charge for the two Lithiums is now +2 which the same as the charge for one Oxygen.
Now we have balanced out Lithium Oxide.
This means for every Oxygen atom, were going to have two Lithium atoms.
This can now be written as Li2O.
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Covalent Bonds:
Ionic
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