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SOLUTION OF JEE MAIN. 2015

PART - C [CHEMISTRY] (CODE C)
Q.61 The vapour pressure of acetone at 20oC is 185 torr. When1.2 g of a non-volatile substance was
dissolved in 100 g of acetone at 20oC, its vapour pressure was 183 torr. The molar mass (g mol1)
of the substance is :
(1) 488
Sol.

(2) 32

(3) 64

(4) 128

o
(3) PS Pacetone
Xacetone

100

58

M0 64 g / mol
183 185
100 1.2
58 M
0

Q.62 3 g of activated charcoal was added to 50 mL of acetic acid solution (0.06N) in a flask. After an hour
it was filtered and the strength of the filtrate was found to be adsorbed (per gram of charcoal) is :
(1) 54 mg
Sol.

(2) 18 mg

(3) 36 mg

(4) 42 mg

(2) 50 0.06 50 0.042 meq of CH3COOH absorbed.

3 2.1 meq 0.9meq 0.9 60 mg 54mg

Hence, 3g Charcoal 54 mg CH3COOH
1g ----------------- 18 mg CH3COOH

18 mg CH3COOH / gm charcoal.
Q.63 Which of the following is the energy of a possible excited state of hydrogen ?
(1) + 6.8 eV

(2) 13.6 eV

(3) 6.8 eV

(4) 3.4 eV

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Sol.

(4) En 13.6eV

12
n 2, E2 3.4eV
n2

Q.64 Which among the following is the most reactive ?

Sol.

(1) ICI

(2) CI2

(3) Br2

(1) Most reactive ICI

I CI due to polarity..

(4) I2

Q.65 Which polymer is used in the manufacture of paints and lacquers ?

Sol.

(1) Poly vinyl chloride

(2) Bakelite

(3) Glyptal

(3) Glyptal

NCERT- Pg. 436 Table 15.1

(4) Polypropene

Q.66 The molecular formula of a commercial resin used for exchanging ions in water softening is
C8H7SO3Na (Mol. wt. 206). What would be the maximum uptake of Ca2+ ions byh the resin when
expressed in mole per gram resin ?
(1) 1/412
Sol.

(2) 1/103

(3) 1/206

(4) 2/309

C8H7SO3 2 Ca
(1) 2 C8H7SO3Na Ca2
2 mole resin 1 mole Ca2+

1
1
2
mole re sin
mole Ca / gm re sin
206
412

1
2
412 mole Ca / gm re sin

Q.67 In Carius method of estimation of halogens, 250 mg of an organic compound gave 141 mg of
AgBr. The percentage of bromine in the compoind is :
(at mass Ag = 108 ; Br = 108)
Sol.

(1) 60

(2) 24

(2) Ag Br

188 g AgBr

80 g Br

141 mg

80

188 141 mg Br

108 + 80 = 188

(3) 36

(4) 48

80

188 141
100% 24%
% Br
250
Q.68 Assertion : Nitrogen and Oxygen are the main components in the atmosphere but these do not
react to form oxides of nitrogen.
Reason : The reaction between nitrogen and oxygen of nitrogen and oxygen requires high
temperature.
(1) Both the assertion and reason are incorrect
(2) Both assertion and reason are correct, and the reason are correct explanation for the assertion.
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(3) Both assertion and reason are correct, but the reason is not the correct explanation
for the assertion.
(4) The assertion is incorrect, but the reason is correct.
Sol.

(1) Assertion and Reason are both correct and Reason is the correct explanation of assertion.
N2 and O2 react at higher temp.

Q.69 The following reaction is performed at 298 K.

2NO g O2 g
2NO2 g
The standard free energy of formation of NO(g) is 86.6kJ/mol at 298 K. What is the standard free
12
energy of formation of NO2(g) at 298 K? K p 1.6 10

Sol.

(1) 0.5[2 86600 R(298) l n(1.6 1012 )]

(2) R(298) l n(1.6 1012 ) 86600

(3) 86600 R(298) l n(1.6 1012 )

(4) 86600

l n(1.6 1012 )
R(298)

(1) 2NO g O2 g
2NO2 g
GoRe action 2 Gof NO2 g 2 Gof NO g
RT ln K P 2 Gof NO2 g 2 86600

Gof NO2 g 0.5 2 86600 R 298 ln 1.6 1012

Q.70 Which one of the following alkaline earth metal sulphate has its hydration entalpy greater than its
lattice enthalpy ?
(1) SrSO4
Sol.

(2) CaSO4

(3) BeSO4

(4) BaSO4

(3) BeSO4 (most soluble)

Q.71 The number of geometrical isomers that can exist for square planar [Pt (CI) (py) (NH3) (NH2OH)]+
is (py = pyridine) :
(1) 6

(2) 2

CI

Sol.

(3) 3

Pt

(3)
NH3

Py

CI

NH2OH

(4) 4
CI

Pt
Py

NH3

NH2OH
Pt

NH2OH

Py

NH3

[M(abcd)]
Q.72 The synthesis of alkyl fluorides is best accomplished by :

Sol.

(1) Swarts reaction

(2) Free radical fluorination

(3) Sandmeyers reaction

(4) Finkelstein reaction

(1) Swart reaction

Q.73 The intermolecular interaction that is dependent on the inverse cube of distance between the
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molecules is :
(1) hydrogen bond
Sol.

(2) ion-ion interaction (3) ion-dipole interaction

(4) London force

(3) Ion-dipole interaction

Q.74 In the context of the Hall-Heroult process for the extraction of AI, which of the following statement
is false ?
(1) Na3AIF6 serves as the electrolyte
(2) CO and CO2 are produced in this process
(3) Al2O3 is mixed with CaF2 which lowers the melting point of the mixture and brings conductivity
(4) Al3+ is reduced at the cathode to form AI
Sol.

(3) Al2O3 is mixed with CaF2 which lowers the M.P of the mixture and brings conductivity is false,
(Na3 AlF6) is used.

Q.75 Which of the following compounds will exhibit geometrical isomerism ?

(1) 1,1 - Diphenyl - 1 propane

(2) 1 - Phenyl - 2 - butene

(3) 3 - Phenyl - 1 - butene

(4) 2 - Phenyl -1 - butene

Sol.

CH3

C == C

(2) I - phenyl - but - 2 -ene

H
C == C

(Cis)

CH3

(trans)

Q.76 The ionic radii (in A ) of N3, O2 and F are respectively :

Sol.

(1) 1.71, 1.36 and 1.40

(2) 1.36, 1.40 and 1.71

(3) 1.36, 1.71 and 1.40

(4) 1.71, 1.40 and 1.366

(4) For isoelectronic species, size

(N3 > P2 > F)

1
Atomic number

N3 O3 F-1.71 1.40 1.36

Q.77 From the following statements regarding H2O2, choose the incorrect statement :
(1) It has to be kept away from dust
(2) It can act only as an oxidizing agent
(3) It decomposes on exposure to light
(4) It has to be stored in plastic or wax lined glass bottle in dark
Sol.

(2) It can act as oxidising agent only, is false. H2O2 acts as an oxidant as well as reductant.

Q.78 Higher order (> 3) reactions are rare due to :

(1) loss of active species on collision
(2) low probability of simultaneous collision of all the reacting species

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(3) increase in entropy and activation energy as more molecules are involved
(4) shifting of equilibrium towards reactants due to elastic collision.
Sol.

(2) Low probability of simultaneous collision of all the reacting species.

Q.79 Match the catalyst to the correct processes :

Catalyst

Sol.

Process

(A) TiCI3

(i) Wacker process

(B) PdCI2

(ii) Ziegler-Natta polymerization

(C) CuCI2

(iii) Contact process

(D) V2O5

(iv) Deacons process

(1) (A) - (iii), (B) - (i), (C) - (ii), (D) - (iv)

(2) (A) - (iii), (B) - (ii), (C) - (iv), (D) - (i)

(3) (A) - (ii), (B) - (i), (C) - (iv), (D) - (iii)

(4) (A) - (ii), (B) - (iii), (C) - (iv), (D) - (i)

(3)

Ticl3

Ziegler - Natto Polymerisation

Pdcl2 Wacker process

Cucl2 Deacons process
V2O5 Contact process
[Hint : V2O5 is used in contact process] only one option is correct.
Q.80 Which one has the highest boiling point ?
(1) Xe
Sol.

(2) He

(3) Ne

(4) Kr

(1) Xe is the heaviest has highest B.pt.

NH2
NaNO2 / HCI
CuCN / KCN

D
E N2

0 5o C

Q.81 In the reaction

CH3

the product E is :
COOH

CH3

(1)

(2)

CN

(3) H3C

CH3

(4)

CH3

N+
2 CI

NH2

Sol.

CH3

CuCN / KCN

NaNO2 HCI

0 5o C

(4)
CH3

CH3

+ N2
CH3

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Q.82 Which of the following compounds is not colored yellow ?

(1) BaCrO4
Sol.

(2) Zn2 [Fe(CN)6 ]

(3) K3 [Co(NO2)6]

(4) (NH4)3[As (Mo3 O10)4]

(2) Zn2 [Fe (CN)6 ] is bluish - white.

Q.83 Sodium metal crystallizes in a body centred cubic lattice with a unit cell edge of 4.29 A . The
radius of sodium atom is approximately :
o

(1) 0.93 A
Sol.

(2) 1.86 A

(2) 4r 3 a,

(3) 3.22 A

(4) 5.72 A

o
o
3
3
a
x4.29 A 1.86 A . for (BCC)
4
4

Q.84 The standard Gibbs energy change at 300 K for the reaction 2A
B C is 2494.2 J. At a
given time, the composition of the reaction mixture is [A] = 1/2, [B] = 2 and [C] = 1/2. The reaction
proceeds in the : [R = 8.314 J/K/mol, e = 2.718]

Sol.

(1) reverse direction because Q > KC

(2) forward direction becasue Q > KC

(3) reverse direction because Q > KC

(4) forward direction because Q < KC

(3) Go RTl nK
2494.2 = (8.31 x 300) l nK ,

l nK = 1,

Qc

BC
A 2

K=

1
e

1
2 2

2
1
2
2x

Q > K, hence (reverse)

Q.85 Which compound would give 5-keto-2-methyl hexanal upon ozonolysis ?
CH3
H3C

CH3

CH3

CH3
CH3

(1)

(2)

(3)

(4)
CH3

Sol.

C
(3) C C C C C C

CH3

O3

A
Zn/H2O

CH3
CC

CC
CC
C

CH3

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Q.86 Which of the following compounds is not an antacid ?

(1) Ranitidine
Sol.

(2) Aluminium hydroxide

(3) Cimetidine

(4) Phenelzine

(4) Phenelzine is not an antacid.

Q.87 In the following sequence of reactions :

KMnO 4
SOCI2
H2 / Pd
Toluene
A
B

C , the product C is :
BaSO 4

(1) C6H5CHO

(2) C6H5COOH

(3) C6H5CH3

CH3
Sol.

COOH
KMnO4

(1)

SOCl2

O
C

(4) C6H5CH2OH

CI

Pd / H2

BaSO 4

[Rosenmund reduction]
Q.88 Which of the following vitamins given below is water soluble ?
(1) Vitamin K
Ans.

(2) Vitamin C

(3) Vitamin D

(4) Vitamin E

(2) Vitamin C is soluble in water. (NCERT)

Q.89 The color of KMnO4 is due to :

Sol.

(1) * transition

(2) M L charge transfer transition

(3) d d transition

(4) L M charge transfer transition

(4) L M charge transfer O2 ions transfer charge to Mn2+ which causes purple colour..

Q.90 Two Faraday of electricity is passed through a solution of CuSO4.The mass of copper deposited
at the cathode is :
(at. mass of Cu = 63.5 amu)
(1) 127 g
Sol.

(2) 0 g

(3) 63.5 g

(4) 2 g

(3) No. of gm-eg = No. of faradays

Cu2 2e Cu

W
2
63.5 / 2

W 63.5 g

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