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Simple cubic:
Lattice points are located only at the corners of the cube
8 corners (1/8) = 1
In BCC unit cells
cells, lattice points are located at the corners and the center of the cube:
8 corner (1/8) + 1 center (1) = 2
I FCC unit
In
it cells,
ll llattice
tti points
i t are llocated
t d att th
the corners and
d faces
f
off the
th cube:
b
8 corners (1/8) + 6 faces (1/2) = 4
CE 60
Instructor: Paulo Monteiro
2R + 2r= 2R sqrt(3)
r/R = 0.732
R
2R + 2r= 2R sqrt(3)
2R
CE 60
Instructor: Paulo Monteiro
The net energy curve (E) vs. inter-atomic spacing (r) curves are
shown below for three solids A,, B and C.
Which solid do you expect to have the largest elastic modulus? Explain.
Answer: Solid A (higher slope)
CE 60
Instructor: Paulo Monteiro
Problem
Calculate the change in volume that
occurs when
h BCC iiron iis h
heated
t d and
d
changes to FCC iron. The lattice
parameter
t off BCC iiron iis 2
2.863
863 A and
d off
FCC iron is 3.591 A
Volume of BCC cell = a3 = 2.863 = 23.467
Volume of FCC cell = a3 = 3.591 = 46.307
But the FCC unit cell contains four atoms and the BCC unit cell contains only two
atoms. Two BCC unit cells with a total volume of 46.934 will contain 4 atoms.
g
= ((46.307 -46.934)/46.934
)
= -1.34%
Volume change/atom
Steel contracts on heating!!
CE 60
Instructor: Paulo Monteiro
Problem
Calculate the radius of the largest
g
interstitial
void (Rvoid in the figure below) in the BCC
iron lattice. The atomic radius of the iron
atom in this lattice is 0.124 nm, and the
g
interstitial voids occur at the ((, ,
largest
0).
CE 60
Instructor: Paulo Monteiro
CE 60
Instructor: Paulo Monteiro
CE 60
Instructor: Paulo Monteiro
Answer
It is not possible to have a Cu-Ni
Cu Ni alloy
alloy, which at equilibrium
equilibrium, consists of a liquid
phase of composition 20 wt% Ni-80 wt% Cu and an phase of composition
37 wt% Ni-63 wt% Cu.
A single tie line does not exist within the + L region that intersects the
phase boundaries at the given compositions. At 20 wt% Ni, the L-( + L) phase
boundary is at about 1200C, whereas at 37 wt% Ni the (L + )- phase
boundary is at about 1225
CE 60
Instructor: Paulo Monteiro
Using this diagram, briefly explain how spreading salt on ice that is at a
temperature below 0C (32F) can cause the ice to melt.
CE 60
Instructor: Paulo Monteiro
Answer
CE 60
Instructor: Paulo Monteiro
CE 60
Instructor: Paulo Monteiro
CE 60
Instructor: Paulo Monteiro
Problem
CE 60
Instructor: Paulo Monteiro