Test-3

Atomic Structure
1. Number of d-electrons present in Fe+2[Z = 26] are not equal to:
(A) Number of p-electrons in Ne [Z = 10]
(B)Number of s-electrons in Mg [Z
= 12](C) (C) Number of d-electrons in Fe [Z = 26]
(D)Number of
p-electrons in Cl [Z = 17]
2. Which orbital is designated by the quantum numbers [l = 2 and m = 0] ?
(B) dx2 y2

(A) dxy

(C) dz2 (D) dyz

3. The group not showing similarity in unpaired electrons is:

(A) d3, d7

(B) f4, f10

(C) d7, p3

(D) d4, d8

4. Which electron is associated with the least energy:

(A) n = 3, l = 2, m = 2, s = +

(C) n = 4, l = 1, m = 1, s = +

1
2

(B) n = 4, l = 0, m = 0, s = +

1
2

(D) n = 5, l = 0, m = 0, s = +

5. Following electronic configuration violates :

2s

2p

(A) Paulis rule

(B) Hunds rule

(C) Aufbau rule

(D) All of these

6. Number of unpaired electrons associated with

respectively are:
(A) 2, 3 and 4

(B) 1, 2 and 3

25

Mn+4,

24

Cr+2 and

(C) 3, 4 and 5

(D) 2, 3 and 1

7. Which atom is the largest:

(A) 1s2, 2s2, 2p6, 3s2
(C) 1s2, 2s2, 2p6, 3s2, 3p3

(B) 1s2, 2s2, 2p6, 3s2, 3p1

(D) 1s2, 2s2, 2p6, 3s2, 3p5

8. Match List-I with List-II and choose the correct codes given below:
ListI

ListI

l(l 1)
A. Orbital angular momentum

a.

B. No. of orbitals in a sub shells

b. n

Fe+3

26

h
2

1
2
1
2

C. No. of sub-shells in an orbit

c. 2l + 1

Codes:
A

(A)

(B)

(C)

(D)

9. Orbital angular momentum of d-electron is:

(A)

(B)

(C)

(D)

10.Match list-I with list-II and choose the answer from the code given below:
List-I

List-II

A. Total values of l for a given n

a. 0, 1, 2(n-1)

B. Actul values of l for a given n

b. +l, .+2, +1, 0, -1, -2,-l

C. Total values of m for a given l

c. (2l + 1)

D. Actual values of m for a given l

d. n

Code is
A.

C.

D.

(A)

(B)

(C)

(D)

11.Arrange the orbitals of H-atom in the increasing order of their energy:

3px, 2s, 4dxy, 3s, 4pz, 3py, 4s
(A) 2s < 3s = 3px = 3py < 4s = 4pz = 4dxy
= 4dxy

(B) 2s < 3s < 3px = 3py < 4s = 4pz

(C) 2s < 3s < 3px = 3py < 4s < 4pz = 4dxy

< 4dxy

(D) 2s < 3s < 3px = 3py < 4s < 4pz

12.Which of the following are not permissible sets of quantum numbers for an
electron in an atom:
n

(A)

(B)

(C)

(D)

1
2

1
2

1
2

1
2

-1

-2

13.The inter-electronic repulsion is minimum in the configuration:

(A) 2px22py1,2pz0
2pz1

(B) 2px12py2, 2pz0

(C) 2px22py0, 2pz1

(D) 2px12py1,

14.(A) 1s22s22p63s1
(B) 1s22s22p66s1
Review the configuration of the two atoms A and B given above and show that
which one is a incorrect statement:
(A) Energy is needed to convert A to B
(B) Configuration A represents sodium atom
(C) To remove one electron from B less energy is needed as compared to that of
A
(D) A and B represent two different elements
15.Which sub-shell of the hydrogen atom is capable of absorbing a photon but
unable to emit photon?
(A) 3s

(B) 2p

(C) 1s

(D) 2s

16.Magnetic moment of X3+ ion of 3d series is

X3+ ?
(A) 25

(B) 26

(C) 27

35

BM. What is atomic number of

(D) 28

17.Quantum numbers of 13th electron of silicon (Z = 14) are 3, 1, 1, + . Which one

of the following is true set of quantum numbers for the 14 th electron?
(A) 3, 1, 0, + 1/2

(B) 3, 0, 1, + 1/2

(C) 3, 1, 1, 1/2

18.Five valence electrons of nitrogen are shown as:

2p

2s
AB

(D) 3, 1, 1, +

If the spin quantum number of B and E is . The group of electrons with three
same quantum numbers are :
(A) Only AB
these

(B) Only CDE

(C) Both the above (D) None of

19.Using Hunds rule to decide which of the following is not the ground state
electronic configuration:
2s

2p

(A) [He]
(B) [He]
(C) [He]
(D) [He]
20.Four quantum numbers of 19th electron of

Cr are:

24

(A)

+1/2

(B)

1/2

(C)

1/2

(D)

+1/2 or