100816

Safety Data Sheet
According to EC Directive 91/155/EEC

Date of issue:
Supersedes edition of
1.
06.05.2004
13.08.2003
Identification of the substance/preparation and of the company/undertaking

Identification of the product
Catalogue No.:
100816
Product name:
Manganese Cell Test Method: photometric 0.10 - 5.00 mg/l Mn 25

Tests Spectroquant
Reaktionskvette
Use of the substance/preparation

Reagent for analysis
Company/undertaking identification
2.
Company:
Merck KGaA * 64271 Darmstadt * Germany * Phone: +49 6151 72-0
Emergency telephone No.:
Please contact the regional Merck representation

in your country.
Composition/information on ingredients
Aqueous solution of inorganic and organic compounds.
Hazardous ingredients:
Name according to EC Directives:
CAS-No.
EC No.
EC-Index-No.
Classification
Content:
ammonia solution
7664-41-7
231-635-3
007-001-01-2
C; R34
N; R50
5 - < 10 %
Potassium cyanide
151-50-8
205-792-3
006-007-00-5
T+; R26/27/28
R32
N; R50/53
0.25 - < 1 %
(Full text of R-Phrases in heading 16)
3.
Hazards identification
Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system
and skin. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
4.
First aid measures

After inhalation: fresh air. Consult doctor if feeling unwell.
After skin contact: wash off with plenty of water. Remove contaminated clothing. Call in physician.
After eye contact: rinse out with plenty of water with the eyelid held wide open. Call in
ophtalmologist.
After swallowing: immediately make victim drink plenty of water. Call in physician.
The Safety Data Sheets for catalog items are also available at www.chemdat.info
Page 1 of 6
Merck Safety Data Sheet

Catalogue No.:
Product name:
5.
100816
Manganese Cell Test Method: photometric 0.10 - 5.00 mg/l Mn 25 Tests
Spectroquant
Reaktionskvette
Fire-fighting measures
Suitable extinguishing media:
In adaption to materials stored in the immediate neighbourhood.
Special risks:
Non-combustible. Ambient fire may liberate hazardous vapours. The following may develop in event of
fire: nitrogen oxides.
Special protective equipment for fire fighting:
Do not stay in dangerous zone without self-contained breathing apparatus. In order to
avoid contact with skin, keep a safety distance and wear suitable protective clothing.
Other information:
Contain escaping vapours with water. Prevent fire-fighting water from entering surface water or
groundwater.
6.
Accidental release measures

Person-related precautionary measures:
Avoid substance contact. Do not inhale vapours/aerosols. Ensure supply of fresh air in enclosed
rooms.
Environmental-protection measures:
Do not allow to enter sewerage system.
Procedures for cleaning / absorption:
Take up with liquid-absorbent and neutralizing material (e.g. Chemizorb OH, Art. No.
101596). Forward for disposal. Clean up affected area.
7.
Handling and storage

Handling:
No further requirements.
Storage:
Tightly closed. At +15C to +25C.
The data apply to the entire pack.
8.
Exposure controls/personal protection

Specific control parameter
EC
Name
Value
Ammonia
20 ml/m3
14 mg/m3
Personal protective equipment:

Protective clothing should be selected specifically for the working place, depending on
concentration and quantity of the hazardous substances handled. The resistance of the
protective clothing to chemicals should be ascertained with the respective supplier.
Page 2 of 6

Catalogue No.:
Product name:
100816
Spectroquant
Reaktionskvette
Respiratory protection:
required when vapours/aerosols are generated.
Eye protection:
required
Hand protection:
In full contact:
natural latex
0.6 mm
> 30 Min.
Glove material:
Layer thickness:
Breakthrough time:
In splash contact:
nitrile rubber
0.11 mm
> 60 Min.
Glove material:
Layer thickness:
Breakthrough time:
The protective gloves to be used must comply with the specifications

of EC directive 89/686/EEC and the resultant standard EN374, for
example KCL 706 Lapren (full contact), 740 Dermatril (splash
contact).
This recommendation applies only to the product stated in the safety
data sheet and supplied by us as well as to the purpose specified by
us. When dissolving in or mixing with other substances and under
conditions deviating from those stated in EN374 please contact the
supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Industrial hygiene:
Immediately change contaminated clothing. Apply skin- protective barrier cream. Wash hands and face
after working with substance.
9.
Physical and chemical properties

Form:
Colour:
Odour:
pH value
Melting point
Boiling point
Ignition temperature
Flash point
Explosion limits
liquid
light yellow
not available
not available
not available
not available
not available
lower
not available
upper
Density
Solubility in Water
not available
(20 C)
~ 1.03
g/cm3
not available
Page 3 of 6

Catalogue No.:
Product name:
100816
Spectroquant
Reaktionskvette
10. Stability and reactivity

Conditions to be avoided
Strong heating.
Substances to be avoided
acids, anhydrides, halogenating agents, nitriles. Violent reactions possible with: oxidizing agent.
Hazardous decomposition products

in the event of fire: See chapter 5.
Further information
incompatible with various metals and metal alloys (i.a. zinc, copper).
11. Toxicological information

Acute toxicity
Quantitative data on the toxicity of this product are not available.
Further toxicological information

Property that must be anticipated on the basis of the components of the preparation:
After inhalation: Irritations of the mucous membranes, coughing, and dyspnoea.
After skin contact: Irritations. Danger of skin absorption.
After eye contact: Irritations.
After swallowing: irritations of mucous membranes in the mouth, pharynx, oesophagus and
gastrointestinal tract.
Other notes:
The following applies to cyanogen compounds/ nitriles in general: utmost caution! Release of
hydrocyanic acid is possible - blockade of cellular respiration. Cardiovascular disorders, dyspnoea,
unconsciousness.
The following applies to ammonium salts in general: after swallowing: local irritation
symptoms, nausea, vomiting, diarrhoea. Systemic effect: after the uptake of very large qantities:
drop in blood pressure, collapse, CNS disorders, spasms, narcotic conditions, respiratory
paralysis, haemolysis.
Under given conditions, contact with nitrites or nitric acid can lead to the formation of
nitrosamines, which have shown themselves to be carcinogenic in animal experiments.
Further data
Further hazardous properties cannot be excluded.
The product should be handled with the care usual when dealing with chemicals.
Page 4 of 6

Catalogue No.:
Product name:
100816
Spectroquant
Reaktionskvette
12. Ecological information

Ecotoxic effects:
Quantitative data on the ecological effect of this product are not available.
Biological effects:
Harmfull effect on aquatic organisms.
May cause long-term adverse effects in the aquatic environment.
Further ecologic data:
The following applies to cyanogen compounds in general: cyanide ions: biological effects: fish:
60 h. LC50: 0.08 mg/l; lethal as from 0.05 mg/l ; for lower organisms lethal as from 0.1 mg/l .
Crustaceans: D. magna EC50: 1.0 mg/l.
The following applies to ammonium ions in general: biological effects: fish: toxic as from
0.3 mg/l ; nourishment for fish: toxic as from 0.3 mg/l .
Do not allow to enter waters, waste water, or soil!
13. Disposal considerations

Product:
Chemicals must be disposed of in compliance with the respective national regulations. Under
www.retrologistik.de you will find country- and substance-specific information as well as
contact partners.
Packaging:
Merck product packaging must be disposed of in compliance with the country-specific regulations
or must be passed to a packaging return system. Under www.retrologistik.de you will find special
information on the respective national conditions as well as contact partners.
14. Transport information

Road & Rail ADR, RID
UN 3316 CHEMIE-TESTSATZ, 9, III
Inland waterway ADN, ADNR not tested
Sea IMDG-Code
UN 3316 CHEMICAL KIT, 9, III
Ems
F-A S-P
Air CAO, PAX
CHEMICAL KIT, 9, UN 3316, III
The transport regulations are cited according to international regulations and in the form
applicable in Germany . Possible national deviations in other countries are not considered.
THESE TRANSPORT DATA APPLY TO THE ENTIRE PACK !
Page 5 of 6

Catalogue No.:
Product name:
100816
Spectroquant
Reaktionskvette
15. Regulatory information

Labelling according to EC Directives
Symbol:
R-phrases:
Xn
Harmful
20/21/22-52/53
S-phrases:
contains:
36/37
Harmful by inhalation, in contact with skin and if

swallowed. Harmful to aquatic organisms, may cause
long-term adverse effects in the aquatic
environment.
Wear suitable protective clothing and gloves.
Potassium cyanide
16. Other information

Text of any R phrases referred to under heading 2:
26/27/28
32
34
50
50/53
Very toxic by inhalation, in contact with skin and if swallowed.

Contact with acids liberates very toxic gas.
Causes burns.
Very toxic to aquatic organisms.
Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Reduced labelling on the container due to small quantity.
Reason for alteration

Chapter 2: change in composition data.
Chapter 8: personal protective equipment.
Chapter 10: stability and reactivity.
Chapter 11: toxicological information.
Chapter 14: transport information.
General update.
Regional representation:
This information is given on the authorised Safety Data Sheet
for your country.
The information contained herein is based on the present state of our knowledge. It
characterizes the product with regard to the appropriate safety precautions. It does not
represent a guarantee of the properties of the product.
Page 6 of 6
Safety Data Sheet

Date of issue:
1.
26.08.2004
06.05.2004

Catalogue No.:
100816
Product name:

Tests Spectroquant
Mn-1K

2.
Company:

in your country.
Aqueous solution.
CAS-No.
EC No.
EC-Index-No.
Classification
Content:
Hydroxylammonium chloride
5470-11-1
226-798-2
612-123-00-2
Xn; R22-48/22
Xi; R36/38-43
N; R50
5 - < 10 %
Formaldehyde
50-00-0
200-001-8
605-001-00-5
Carc. Cat. 3; R40

T; R23/24/25
C; R34
Xi; R43
1-<3%
methanol
67-56-1
603-001-00-X
F; R11
T; R23/24/25-39/23/24/25
0.1 - < 1 %
200-659-6
3.
Limited evidence of a carcinogenic effect. May cause sensitization by skin contact.
4.
First aid measures

After inhalation: fresh air. Consult doctor if feeling unwell.
After skin contact: wash off with plenty of water. Remove contaminated clothing. Call in physician.
After eye contact: rinse out with plenty of water with the eyelid held wide open.
Page 1 of 6

Catalogue No.:
Product name:
5.
100816
Spectroquant
Mn-1K
Special risks:
Non-combustible. Ambient fire may liberate hazardous vapours.
Other information:
Prevent fire-fighting water from entering surface water or groundwater.
6.

rooms.
Take up with liquid-absorbent material (e.g. Chemizorb ). Forward for disposal. Clean up affected
area.
7.

Handling:
Notes for safe handling:
Work under hood . Do not inhale substance. Avoid generation of vapours/aerosols.
Storage:
8.

EC
Name
Carcinogenic
Sensitization
Formaldehyde
C 3:owing possible carcinogenic effects for man
Sh Danger of sensitization of the skin
Name
Sensitization
Page 2 of 6

Catalogue No.:
Product name:
100816
Spectroquant
Mn-1K

Eye protection:
required
Hand protection:
In full contact:
butyl rubber
0.7 mm
> 480 Min.
Glove material:
Layer thickness:
Breakthrough time:
In splash contact:
butyl rubber
0.7 mm
> 480 Min.
Glove material:
Layer thickness:
Breakthrough time:

example KCL 898 Butoject (full contact), 898 Butoject (splash
contact). The breakthrough times stated above were determined by
KCL in laboratory tests acc. to EN374 with samples of the recommended
glove types.
Industrial hygiene:
Change contaminated clothing. Apply skin-protective barrier cream. Wash hands after working with
substance.
9.

Form:
Colour:
Odour:
pH value
Melting point
Boiling point
Flash point
Explosion limits
Density
Solubility in
water
liquid
colourless
odourless
not available
not available
not available
not available
not available
lower
not available
upper
not available
(20 C)
1.03
(20 C)
soluble
g/cm3
Page 3 of 6

Catalogue No.:
Product name:
100816
Spectroquant
Mn-1K

Heating.
The generally known reaction partners of water.

not known to date.

Acute toxicity
Quantitative data on the toxicity of this product are not available.
Subacute to chronic toxicity

Applicable to partial component(s):
The carcinogenic potential requires further clarification.

Property that must be anticipated on the basis from the components of the preparation:
After inhalation: Irritations of the mucous membranes, coughing, and dyspnoea. Inhalation may
lead to the formation of oedemas in the respiratory tract.
After skin contact: Slight irritations. Risk of skin sensitization. Danger of skin absorption.
After eye contact: Slight irritations.
After swallowing: Irritations of mucous membranes in the mouth, pharynx, oesophagus and
gastrointestinal tract.
Systemic effects: Methaemoglobin formation after intensive contact with skin cannot be excluded.
Other notes: The following applies to aldehydes in general: irritations after contact with eyes and
skin. Mucosal irritations, coughing, and dyspnoea after inhalation.
Further data

Ecotoxic effects:
Page 4 of 6

Catalogue No.:
Product name:
100816
Spectroquant
Mn-1K

Product:
contact partners.
Packaging:

Sea IMDG-Code
Ems
F-A S-P
Air CAO, PAX

Symbol:
R-phrases:
Xn
Harmful
40-43
Limited evidence of a carcinogenic effect. May

cause sensitization by skin contact.
S-phrases:
contains:
36/37
Wear suitable protective clothing and gloves.
Formaldehyde
Page 5 of 6

Catalogue No.:
Product name:
100816
Spectroquant
Mn-1K

11
22
23/24/25
34
36/38
39/23/24/25
40
43
48/22
50
Highly flammable.
Harmful if swallowed.
Toxic by inhalation, in contact with skin and if swallowed.
Causes burns.
Irritating to eyes and skin.
Toxic: danger of very serious irreversible effects through inhalation, in contact
with skin and if swallowed.
Limited evidence of a carcinogenic effect.
May cause sensitization by skin contact.
Harmful: danger of serious damage to health by prolonged exposure if swallowed.

Chapter 2: change in ingredients data.
General update.
for your country.
Page 6 of 6
Safety Data Sheet

Date of issue:
1.
06.05.2004
03.09.2003

Catalogue No.:
100816
Product name:

Tests Spectroquant
Mn-2K

2.
Company:

in your country.
Aqueous solution of organic compounds.
CAS-No.
EC No.
EC-Index-No.
5470-11-1
226-798-2
612-123-00-2
Classification
Content:
Xn; R22-48/22
Xi; R36/38-43
N; R50
10 - < 25 %
3.
May cause sensitization by skin contact. Harmful: danger of serious damage to health by prolonged
exposure if swallowed.
4.
First aid measures

After inhalation: fresh air.
After skin contact: wash off with plenty of water. Remove contaminated clothing.
After eye contact: rinse out with plenty of water with the eyelid held wide open. Call in
ophtalmologist if necessary.
Page 1 of 5

Catalogue No.:
Product name:
5.
100816
Spectroquant
Mn-2K
Special risks:
Non-combustible. Ambient fire may liberate hazardous vapours. The following may develop in event of
fire: hydrochloric acid, nitrogen oxides.
Other information:
Contain escaping vapours with water. Prevent fire-fighting water from entering surface water or
groundwater.
6.

rooms.
Take up with liquid-absorbent material (e.g. Chemizorb ). Forward for disposal. Clean up affected
area.
7.

Handling:
Storage:
8.

EC
Name
Sensitization

Page 2 of 5

Catalogue No.:
Product name:
100816
Spectroquant
Mn-2K
Eye protection:
required
Hand protection:
In full contact:
nitrile rubber
0.11 mm
> 480 Min.
Glove material:
Layer thickness:
Breakthrough time:
In splash contact:
nitrile rubber
0.11 mm
> 480 Min.
Glove material:
Layer thickness:
Breakthrough time:

example KCL 740 Dermatril (full contact), 740 Dermatril (splash
contact).
Industrial hygiene:
Change contaminated clothing. Apply skin-protective barrier cream. Wash hands after working with
substance.
9.

Form:
Colour:
Odour:
pH value
Melting point
Boiling point
Flash point
Explosion limits
liquid
colourless
odourless
not available
not available
not available
not available
not available
lower
not available
upper
Density
Solubility in
water
not available
(20 C)
1.13
(20 C)
soluble
g/cm3
Page 3 of 5

Catalogue No.:
Product name:
100816
Spectroquant
Mn-2K

Heating.

in the event of fire: See chapter 5.

Acute toxicity
LD50 (oral, rat): 141 mg/kg (toxicologically determinant component).
The literature data available to us do not conform with the labelling prescribed by the
EC. The EC has dossiers which have not been published.

Property that must be anticipated on the basis from the components of the preparation:
After inhalation: mucosal irritations.
After skin contact: Slight irritations. dermatitis. Risk of skin sensitization.
After eye contact: Slight irritations.
After swallowing: Irritations of: gastrointestinal tract.
After absorption: drop in blood pressure, cyanosis, Risk of methaemoglobin formation.
Further data

Ecotoxic effects:

Product:
contact partners.
Packaging:
Page 4 of 5

Catalogue No.:
Product name:
100816
Spectroquant
Mn-2K

Sea IMDG-Code
Ems
F-A S-P
Air CAO, PAX

Symbol:
R-phrases:
Xn
Harmful
43-48/22
S-phrases:
contains:
24-37
May cause sensitization by skin contact. Harmful:

danger of serious damage to health by prolonged
exposure if swallowed.
Avoid contact with skin. Wear suitable gloves.

22
36/38
43
48/22
50
Harmful if swallowed.
Irritating to eyes and skin.
May cause sensitization by skin contact.
Harmful: danger of serious damage to health by prolonged exposure if swallowed.

Chapter 2: change in ingredients data.
General update.
for your country.
Page 5 of 5
Safety Data Sheet

Date of issue:
1.
06.05.2004
13.08.2003

Catalogue No.:
100816
Product name:

Tests Spectroquant
Packungsblindkvette

2.
Company:

in your country.
CAS-No.:
M:
Formula Hill:
3.
7732-18-5
18.02 g/mol
H2O
EC-No.:
231-791-2
No hazardous product as specified in Directive 67/548/EEC.
4.
First aid measures

No special precautionary measures necessary.
5.
Special risks:
none
6.

Pour into drain.
Page 1 of 4

Catalogue No.:
Product name:
7.
100816
Spectroquant
Packungsblindkvette

Handling:
Storage:
8.

not required
Eye protection:
not required
Hand protection:
not required
Industrial hygiene:
not required
9.

Form:
Colour:
Odour:
pH value
Viscosity dynamic
Melting point
Boiling point
Flash point
Explosion limits
liquid
colourless
odourless
(20 C)
neutral
(20 C)
0.952
mPa*s
100
not applicable
not applicable
lower
not applicable
upper
Vapour pressure
Density
Solubility in
ethanol
not applicable
(20 C)
23
hPa
(20 C)
1.00
g/cm3
(20 C)
soluble
Page 2 of 4

Catalogue No.:
Product name:
100816
Spectroquant
Packungsblindkvette

none

none
Further information
none

Acute toxicity
No toxic effects are to be expected when the product is handled appropriately.

not required

Product:
contact partners.
Packaging:

Sea IMDG-Code
Ems
F-A S-P
Air CAO, PAX
Page 3 of 4

Catalogue No.:
Product name:
100816
Spectroquant
Packungsblindkvette

Symbol:
R-phrases:
S-phrases:
-------

General update.
for your country.
Page 4 of 4

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Safety Data Sheet

According to EC Directive 91/155/EEC

Identification of the substance/preparation and of the company/undertaking

Manganese Cell Test Method: photometric 0.10 - 5.00 mg/l Mn 25

Use of the substance/preparation

Merck KGaA * 64271 Darmstadt * Germany * Phone: +49 6151 72-0

Emergency telephone No.:

Please contact the regional Merck representation

(Full text of R-Phrases in heading 16)

First aid measures

Merck Safety Data Sheet

Accidental release measures

Handling and storage

Exposure controls/personal protection

Personal protective equipment:

Merck Safety Data Sheet

required when vapours/aerosols are generated.

The protective gloves to be used must comply with the specifications

Physical and chemical properties

Merck Safety Data Sheet

10. Stability and reactivity

Hazardous decomposition products

11. Toxicological information

Further toxicological information

Merck Safety Data Sheet

12. Ecological information

13. Disposal considerations

14. Transport information

Merck Safety Data Sheet

15. Regulatory information

Harmful by inhalation, in contact with skin and if

16. Other information

Very toxic by inhalation, in contact with skin and if swallowed.

Reduced labelling on the container due to small quantity.

Reason for alteration

Safety Data Sheet

Identification of the substance/preparation and of the company/undertaking

Manganese Cell Test Method: photometric 0.10 - 5.00 mg/l Mn 25

Use of the substance/preparation

Merck KGaA * 64271 Darmstadt * Germany * Phone: +49 6151 72-0

Emergency telephone No.:

Please contact the regional Merck representation

Carc. Cat. 3; R40

(Full text of R-Phrases in heading 16)

First aid measures

Merck Safety Data Sheet

Accidental release measures

Handling and storage

Exposure controls/personal protection

Merck Safety Data Sheet

Personal protective equipment:

required when vapours/aerosols are generated.

The protective gloves to be used must comply with the specifications

Physical and chemical properties

Merck Safety Data Sheet

10. Stability and reactivity

Hazardous decomposition products

11. Toxicological information

Subacute to chronic toxicity

Further toxicological information

12. Ecological information

Merck Safety Data Sheet

13. Disposal considerations

14. Transport information