Академический Документы
Профессиональный Документы
Культура Документы
(PART I)
PHYSICS
SECTION I
This section contains 9 multiple-choice questions numbered 1 to 9. Each question has 4 choices (A), (B), (C) and (D),
out of which Only One is correct
1.
q
, zero
2
q
2
B
A
q
2
(C) ,
(B) , zero
q
2
R
O
2R
R
O
2R
2.
The pitch of a screw gauge is 1 mm and there are 100 divisions on its circular scale. When
nothing is put in between its jaws, the zero of the circular scale lies 4 divisions below the
reference line. When a steel wire is placed between the jaws, two main scale divisions are
clearly visible and 67 divisions on the circular scale are observed. The diameter of the wire is
(a) 2.71 mm
(b) 2.67 mm
(c) 2.63 mm
(d) 2.65 mm
3.
If the ground state of hydrogen atom is chosen as zero potential energy level, the value of the
total energy in the second excited state (in eV) is
(A) 25.69
(B) 12.09
(C) 23.8
(D) 20.4
4.
In a sample of rock, the ratio of 206Pb to 238U nuclei is found to be 0.5. The age of the
rock is. (Assume that all the Pb nuclides in the rock was produced due to the decay of
Urarium nuclides and T1/ 2 ( 238 U) 4.5 109 year).
(A) 2.25 10 9 year
(B) 4.5 10 9 ln 3 year
(C) 4.5 10 9
5.
ln 32
ln 2
Interference pattern is observed at P due to superposition of two rays coming out from a
source S as shown in the figure. The value of l for which maxima is obtained at P is
2l
P
S
l/3
(A) l
(C) l
6.
3
(D) 2.25 10 9 ln year
2
year
2 n
(B) l
3 1
2n 1
4 2 3
30o
(D) l
2n 1
2 3 1
2n 1
3 1
A thin plane convex glass lens ( = 1.5) has its plane surface silvered and R is the radius of
curvature of the curved part. Then which of the following ray diagram is the correct
representation for an object placed at O.
2R
(A)
3R
(C)
2R
(B)
2R
(D)
7.
8.
(4) the maximum compression occur for the first time after
sec.
56
(A) Statements (2), (3), (4) are correct
(B) Statements (1), (2), (3) are correct
(C) Statements (2), (3) are correct.
(D) All the statements are correct
9.
Equilibrium
Position
(B) y 2 x0 sin
t
6
m
(D) y 2 x0 sin
t
3
12
x0
SECTION II
Assertion Reason Type
This section contains 4 questions numbered 10 to 13. Each question contains STATEMENT1 (Assertion) and
STATEMENT2 (Reason). Each question has 4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.
NOTE : (A)
Statement 1 is True, Statement 2 is True;
Statement 2 is a correct explanation for Statement 1.
(B) Statement 1 is True, Statement 2 is True; Statement 2 is NOT a correct explanation
for Statement 1.
(C) Statement 1 is True, Statement 2 is False.
(D) Statement 1 is False, Statement 2 is True.
10.
11.
Statement-1: A horizontal rim of a wheel is free to rotate about a vertical axis. A line charge
is glued onto the rim of the wheel. The shaded central region has a uniform magnetic field
pointing in vertical direction. If the field is switched off, the wheel starts rotating with certain
angular speed which does not depend on how fast or slow the field is switched off.
+
+
++
+ +
+ +
+ +
++
+
++ +
+
+
+
Statement-2: Induced electric field due to a time varying magnetic field does not depend on
time taken to change magnetic field.
12.
STATEMENT 1
Mirrors are free from chromatic aberration.
STATEMENT 2
The refractive index of the material of the mirror is independent of wavelength (color) of
light.
13.
STATEMENT 1
The kinetic energies of all particles, emitted by a sample containing active radiocobalt
nuclei, are identical.
STATEMENT 2
particles get their energy from the energy differences between the mother and daughter
nuclei, which is fixed for a particular decay scheme.
SECTION III
Linked Comprehension Type
This section contains 2 paragraphs P14-16, and P17-19 . Based upon each paragraph, 3 multiple choice questions have to
be answered. Each question has 4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.
v
m
norm
al
O
m
,
14.
The magnitude of the velocity of the centre of mass of the rod after collision is
2
2
v sin
(a) v cos
(b) v sin
(c) v cos
(d)
5
5
15.
The magnitude of change in angular momentum of the rod about the point O after collision is
mv cos
m v
6
sin
mv sin
(a) zero
(b)
(c)
(d)
5
5
5
16.
For the two given circuits at t = 0, a constant force F acts at the middle points of the rigid
conducting wires ab and cd. At t = 0 both wire are at rest. The electric resistance of the circuit
(a) is zero, while for the circuit (b) electrical resistance is R. The electrical resistance of the
horizontal rails is zero. There is no friction between rails and rigid wires ab and cd. Both the
circuits are placed in a vertical constant magnetic field B (as shown in the figure). The mass and
length of the each wire ab and cd is m, respectively
B
F
m,
a
Circuit (X)
17.
At t =
m
, electric current for circuit (X) is
F
F
m,
R
d
Circuit (Y)
BCF
BCF
(C)
2 2
m
(m B C)
At t = 0, acceleration of wire cd for circuit Y is
F
F
F
(B)
(B)
(C) 2 2
2 2
m
BC
(m B C)
At t = 0, acceleration of wire ab for circuit X is
F
F
F
(A)
(B)
(C) 2 2
2 2
m
BC
(m B C)
(A) zero
18.
19.
(B)
(D)
F
B
(D)
2F
BC
(D)
2F
BC
2 2
2 2
SECTION IV
The entries in Column I depict certain current distributions, while the entries in Column II
depict the variation of the magnetic field (B) as one moves along the xaxis for each of these
distributions, but in a different order. Match the entries in Column I with the proper entries in
Column II.
Column I
Column II
(A)
(P)
x
(perpendicular
tow
ire)
S
traightcurrent
carryingw
ire
(B)
(Q)
x
(ax
iso
fw
ire)
C
ircu
larcu
rren
t
carry
in
gw
ire
(C)
(R)
i
Parallel current carrying
wires in the same plane
x
(perpendicular to the
plane of the wires;
O being equidistant)
(D)
(S)
i
x
(parallel to one
of the wires)
21.
Reduces
Q(d 0 vt)
2d 0
Q(d 0 vt)
2d 0
QV
2d 0
(S)
22.
Column I
Column II
(A)
(P)
decay.
(B)
Binding
energy
increases.
per
nucleon
(Q)
decay.
(C)
Emitted particles
kinetic energy.
have
variable
(R)
+decay.
(D)
(S)
decay.
CHEMISTRY
Useful Data:
Gas Constant
Avogadro's Number
Plancks constant
1 Faraday
1 calorie
1 amu
1 eV
Atomic No:
PART - II
=
8.314 J K1 mol1
=
0.0821 Lit atm K1 mol1
=
1.987 2 Cal K1 mol1
Na =
6.023 1023
h
=
6.625 1034 J s
=
6.625 1027 erg s
=
96500 Coulomb
=
4.2 Joule
=
1.66 1027 kg
=
1.6 1019 J
H = 1, D = 1, Li = 3, Na = 11, K = 19, Rb = 37, Cs = 55, F = 9, Ca = 20, He = 2, O = 8,
Zn = 30, Cu = 29, Cl = 17, Br = 35, Cr = 24, Mn = 25, Fe = 26, S = 16, P = 15, C = 6, N = 7, Ag = 47.
R
Au = 79, Ni = 28,
Atomic Masses:
He = 4, Mg = 24, C = 12, O = 16, N = 14, P = 31, Br = 80, Cu = 63.5, Fe = 56, Mn = 55, Pb = 207, Au = 197,
Ag = 108, F = 19, H = 1, Cl = 35.5, Sn = 118.6, Na = 23, D = 2, Cr = 52, K = 39, Ca = 40, Li = 7, Be = 4,
Al = 27, S = 32.
SECTION - I
This section contains 9 multiple choice questions numbered 23 to 31. Each question has 4 choices (A), (B), (C) and
(D), out of which ONLY ONE is correct
CH 3 O
(i)t BuO
D.
(ii) H O
23.
D is
R
CH 3 O
(a)
(b)
N
R
t-BuO
(c)
(d)
N
24.
25.
How many grams of sucrose (Molecular weight = 342) should be dissolved in 100 gm water
in order to have a solution with sum of lowering of freezing point and elevation of boiling
point equal to 5oC (Kb = 0.51, Kf = 1.86)?
(a) 34.2 gm
(b) 72 gm
(c) 342 gm
(d) 460 gm
H
Cl
Cl
Br
Br
Cl
Br
Br
Cl
H
(D)
(B)
(A)
(C)
26.
Et
2
(A).
CH 3
H3O
(A) is
(a)
(c)
27.
Et
O
C
No reaction
O
H
(b)
(d)
Et
C CH N
O
Et
OH
CH 2NO
O
CH3
28.
Cl / AlCl 3
I2 / NaOH
(i)LDA
A
C D E (ppt.)
O B
(Acid)
(ii) Me
(II)
C CH 2 C
30.
(a) I only
(c) III only
29.
CH 3 C
(III)
Cl
(I)
(Acid)
A solution of 0.1 M Na2CO3 is titrated against HCl using (i) phenolpthalene as an indicator
and (ii) Methyl orange as an indicator. If Ka1 (H2CO3 ) 2 106 , Ka2 4 1010 , then
[pH(1) pH(2)] equals to? (Where pH1 is at end point with phenalpthalene and pH2 is at end
point with methyl orange) (gases are evolved off if any).
3
(a) 1
(b) 1 log 2
2
3
(c) 0
(d) 1 log 2
2
2
Cu (aq) NO3
NH 2OH Cu
2+
NH2OH + Fe Fe3+ + NH3
NH3 + HCl NH 4 + Cl
If 0.72 M of 100 ml Cu+ was required to completely reduce NO 3 to NH2OH; if Fe2+ was in
excess then volume of 0.1 M HCl needed to react with NH3 formed in ml will be?
(a)240
31.
(b)360
(c)120
(d)480
The molar conductivity at infinity dilution of AgNO3, NaCl and NaNO3 are 116, 110, 106
s-cm2-mol1 respectively. The conductivity of AgCl in water is 2.4 106 s/cm and that of
water is 1.2 106 s/cm. Find the value of x. Where x 106 is molarity of AgCl =
(a) 10
(b) 20
(c) 30
(d) 40
SECTION - II
Assertion - Reason Type
This section contains 4 questions numbered 32 to 35. Each q u e s t i o n contains STATEMENT-1 (Assertion) and
STATEMENT-2 (Reason). Each q u e s t i o n ha s 4 choices (A), (B), (C) and (D) out of which ONLY ONE is correct.
Note: (A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for
Statement-1
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for
Statement-1
(C) Statement-1 is True, Statement-2 is False
(D) Statement-1 is False, Statement-2 is True
32.
33.
34.
STATEMENT 1
Specific activity of the same radioactive substance is same for 10g radioactive substance as
well as 50 g radioactive substance.
STATEMENT 2
Since specific activity of a radioactive substance is its activity per g.
35.
STATEMENT 1
The value of equilibrium constant may have lower or higher value at different temperatures.
STATEMENT 2
The values of equilibrium constant depends on enthalpy of reaction.
SECTION - III
Linked Comprehension Type
This section contains 2 paragraphs C36-38 and C39- 41. Based upon each paragraph, 3 m u l ti p le choice q uestio ns have
to he a nswered. Each q uestion has-4 choices (A), (B), (C) and (D), o u t of which ONLY ONE is correct.
For an ideal solution in which pA0 > pB0, the plot of total pressure (p) verses the mole fraction
of A at constant temperature in the vapour phase is :
pA0
pA0
(a)
(b)
p
pB0
pB0
0
1
yA
yB
1
0
0
1
yA
yB
1
0
(c)
pA0
(d)
pB0
yA
yB
1
0
0
1
yA
yB
1
0
pB0
0
1
37.
pA0
1
p B0
1
1
0
0
pB
pA
Two liquids A and B form an ideal solution at temperature T. When the total vapour pressure
above the solution is 600 torr, the amount fraction of A in the vapour phase is 0.35 and in the
liquid phase is 0.70. The vapour pressures of pure B and A are
(a) 800 torr; 1300 torr
(b) 1300 torr; 300 torr
(c) 300 torr; 1300 torr
(d) 300 torr; 800 torr
C39 - 41: Paragraph for Question Nos. 39 to 41
When CH3CH=CH2 is treated with Br2 it forms an optically active product, further the same
compound when treated with HBr forms optically inactive product.
CH3CH=CH2 + Br2 Product
CH3CH=CH2 + HBr Product
When HBr adds to 2-methyl-1-butene in the presence of benzoyl peroxide, the product is
racemic mixture.
CH 3
CH 3CH 2 C
Peroxide
CH 2 + HBr
Racemic mixture
However, when HBr adds on 3-chloro-1-butene, the product is found to be optically active.
CH 3
Cl
H
CH
Optically active
+ HBr
CH 2
39.
Formation of optically inactive product by the additions HBr on in presence and absence of
peroxide to CH3CH=CH2 is
(a) of same type
(b) of different type
(c) due to formation of carbocation in I reaction and free radical in II reaction
(d) due to formation of carbocation in both reactions.
40.
41.
A
B
C
D
42.
(i) I2 / NaOH
SO2 Cl2
EtOH / H
EtMgBr
A1
B1
C1
D1
(ii) H
Reaction sequence I
O
SO 2 Cl 2
[O]
EtOH
EtMgBr
A 2
B2
C2
D2
Reaction sequence II
H
P2O5
(i)I2 / NaOH
EtMgBr
MeOH
A3
B3
C3
D3
(ii)H
H
NH2
Reaction sequence IV
Cl
H3O
KCN
MeOH / H
MeMgBr
A 4
B4
C4
D4
Match the compounds given in Column I with respect to the sequences in which there are
found in Column II
Column I
Column II
O
(A)
(B)
CH 3 C
O
Cl
CH 3 C
O
Et
Et
C
O
OH
Et
(C)
(D)
Me
(P)
Sequence I
(Q)
Sequence II
(R)
Sequence III
(S)
Sequence IV
43.
44.
(P)
(Q)
(R)
(S)
Column II
(P) RI
(Q) CHCl3
(R) Isoprene
(S) 2-methyl buta-1, 3-diene
Column II
H = ve
G = +ve
Stotal = +ve
G = ve
MATHEMATICS
PART - III
SECTION I
This section contains 9 multiple-choice questions numbered 45 to 53. Each question has 4 choices (A), (B), (C) and
(D), out of which Only One is correct
sec2 x
f t dt
45.
lim
x
4
(a)
46.
47.
2
x
16
8
f 2
(b)
2
f 2
(c)
2 1
f
2
(d) 4f 2
d2 y
at t =
is
2
4
dx
a
2 2
(b)
a
2 2
(c)
2 2
a
(d)
2 2
a
x 1 y 1 z 10
is
2
3
8
(c) (1, 1, 10)
(d) (2, 3, 8)
49.
equals
(a)
48.
(b) (5, 8, 4)
(d) (3, 3)
50.
The line x + y = 1 meets x-axis at A and y-axis at B. P is the mid-point of AB. P1 is the foot
of the perpendicular from P to OA; M1 is that from P1 to OP; P2 is that from M1 to OA and so
on. If Pn denotes the nth foot of the perpendicular on OA from Mn-1, then OPn =
(a) 1/2
(b) 1/2n
(c) 1/2n/2
(d) 1/ 2
51.
(d) 3
52.
If a1 > 0 for i = 1, 2, , n and a1a2.an = 1, then (2 + a1)(2 + a2).(2 + an) is greater than
(a) 2n/2
(b) 23n/2
(c) 22n
(d) none of these
53.
If the ratio
1 z
is purely imaginary, then
1 z
(a) 0 < |z| < 1
(c) | z | 1
(b) | z | 1
(d) bounds for |z| can not be decided
SECTION II
Assertion Reason Type
This section contains 4 questions numbered 54 to 57. Each question contains STATEMENT1
(Assertion) and STATEMENT2 (Reason). Each question has 4 choices (A), (B), (C) and (D), out
of which ONLY ONE is correct
Note: (A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for
Statement-1
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct
explanation for Statement-1
(C) Statement-1 is True, Statement-2 is False
(D) Statement-1 is False, Statement-2 is True
y
54.
Statement-1: Curve satisfying the differential equation y '
passing through (2, 1) is a
2x
1
parabola with focus , 0 .
4
y
Statement-2: The differential equation y '
is of variable separable.
2x
55.
2x 1, 1 x 0
x 0
Let f x 2 x ,
2x 1, 0 x 1
56.
57.
SECTION III
Linked Comprehension Type
This section contains 2 paragraphs P58-60 and P61-63. Based upon each paragraph, 3 multiple choice questions have to
be answered. Each question has 4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.
58.
x a
1
lim x 4 sin
is
x 0
3 x
x a
(a) 0
1
(c)
3
59.
(b) 1
(d) does not exist
e1/ x e1/ x
, x 0 and f(0) = 1 then
e1/ x e1/ x
(a) lim f x does not exist
(b) lim f x does not exist
Let f x x 2
x 0
x 0
(d) f is continuous at x = 0.
x 0
60.
1
Let f x x 5 3 , x 0 and f(0) = 0 ([.] denotes the greatest integer function)
x
(a) lim f x does not exist
(b) f is not continuous at x = 0
x 0
(c) lim f x = 1
(d) lim f x = 0
x 0
61.
62.
63.
x 0
(c) 3a,
(d) none of these
,
,
3 9
18
(b) tan 1 40 / 9
(c) tan-1(84/187)
(d) /4
If C1, C2 are the centres of these circles then area of OC1C2, where O is the origin, is
(a) a2
(b) 5a2
(c) 10a2
(d) 20a2
SECTION IV
p
64.
The anti-derivative of
COLUMN I
sec x
(A)
2
sec x tan x
(B)
cos x
sin x 1 sin x 2
(C)
sin 1
2x
,|x| < 1
1 x2
(P)
(Q)
(R)
A
B
C
D
COLUMN II
sin x 2
log
C
sin x 1
cos 2 x
2 1 sin x
2x tan 1 x log 1 x 2 C
(D)
tan x cot x
(S)
tan x 1
2 tan 1
C
2 tan x
65.
Letters of the word INDIANOIL are arranged at random. Probability that the word formed
COLUMN I
COLUMN II
(P)
1
(A) Contains the word INDIAN
9
C5
(Q)
1
5
(B) Contains the word OIL
C2 7C2 9!
(C)
(R)
(S)
(D)
66.
1
24
C3 9 C2
sin 2 1 1
cos
sin cos
2 sin cos
Let p 1
cos sin , q cos 2 4 3 , r sin cos sin
2
7 5
cos sin cos
1 sin cos
sec 2
1
1
2
2
and s cos cos cos ec 2
1
cos 2 cot 2
Match the functions on the left with their range on the right.
COLUMN I
(P) [0, 1]
(A) p
COLUMN II
(Q)
(B)
0, 2 2
(C)
(R)
[2, 2]
(D)
(S)
5 2, 5 2