See SYLLABUS materials

(red areas not covered in Sp 2012); Blue areas covered before mid term
I. Introduction (1.1)
II. Review of undergraduate Thermo (1.2)
Properties and Eq. of state (1.2)
How to use tables for steam R134A (1.2)
III. Mathematical back ground (1.3): implicit differentiation, exact and inexact
differential
IV. Microscopic thermo ( 1.4): GPE and IPE, what is ideal gas? real? Liquid? solid
CHAPTER 2. Ist LAW
I) Closed system Energy Cons (2.3)
II) QE process (2.4)
III) Enthalpy and specific heats (2.5)
IV) Adiabatic Rev Process with ideal gas as fluid
V) Open system Energy Conservation (2.7): steady, unsteady
VI) Applications of Energy Conservation (2.8)
CHAPTER 3: IInd LAW
I. Introduction, Reservoirs (3.1-3.2)
II. Statements of the Second Law: ( 3.3)
III. Consequences of the Second Law (3.4)
IV. Entropy and Entropy Balance Equation for a Closed System (3.6)
V. Entropy Evaluation (3.8)
VI. Third Law (3.11)
VII. Open system S balance ( 3.12)
VIII. Work vdP for open system (3.13)
IX. S max, Umin, Hmin and Gmin Principles (3.17, 3.18)
CHAPTER 4 : AVAILABILITY ( 3 Lectures)
I. Introduction (4.1)
II. Analysis-any system ( 4.4)

i) Open system and Applications ( 4.4.1 to 4.4.7)

ii) Closed System and applications ( 4.4.8 to 4.4.9)
III. Exergetic or availability (engg) /metabolic(biology) Efficiency (4.5)
CHAPTER 6 : REAL GAS /FLUID EQUATIONS
I. Introduction (6.1)
II. Real gas Eqs of State :
i) Z factor or Principle of Corresponding States (6.2),
ii) two parameter Eqs of state :a) VW equation of State(6.5), b) RK
equation of State (6.6), c) mixtures ( cahp 08,, 8.9.91.2, p 491,
iii) Three parameter Eq. of state ( 6.11)
iv) Pitzer Factor ( third factor, 6.11.2) and Lee Kesler Equation of
State(6.13.4) and Kesler table ( A.23 a and b)
III. Liquids and Solids (6.14)
CHAPTER 7 : THERMODYNAMIC PROPERTIES (
I. Introduction (7.1)
II. Maxwell Relations (7.3)
III. Property Relations:
i) Differential Form , ds (7.4.1), du (7.4.2), dh(7.4.3), da
ii) Evaluation Of Thermo Properties: ( 7.4.5): a, u,h,s , g (=h-Ts)
iii) Correction Charts (Figs B2a, B3, B4), Lee Kesler Tables (A23 To A25)
Iv). Vapor Liquid Equilibrium ( 7.10)
i) G Function And Sat Properties (7.10.2)
ii) Clasius Clapeyron (7.10.4)
V) Throttling (7.11.1)
Chapter 08 : Mixtures
I) Introduction, (8.1)
II). General Relations ( 8.2)
III) Partial Molal Property and Chracateristics (8.3)
IV) Ideal gas Mixture (8.54)

V). Ideal solution and Ideal Mix of Real gases

Chapter 09 : Phase Equilibrium of Mixtures
I) Introduction, (9.1)
II). Mixture Equilibrium ( 9.2)
III) P-T diagrams (9.5)
CHAPTER 11 : COMBUSTION
I. Introduction: 11.1
II. Chemical Reactions And Combustion 11.2, A:F , Excess Air, Gas Analyses
III. Thermo Chemistry Chemical And Thermal Enthalpies, 11.3,.1 To 11.3.4
IV. First Law Analyses 11.4, Q, Adiab Flame Temp-Open (E.G Boilers, Turbines, And Closed( e.g
Automotive), Biological Systems.
CHAPTER 12: CHEMICAL EQUILBRIUM
I.
II.
III.

INTRODUCTION
Equilibrium Constant ideal gas Mix (12.3.2.3)
Chem Equil Relations-Equil. Ideal gas Mixtures (12.4.5 )