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Question 1) For a reaction 2A + B 2C, with the rate equation: Rate = k[A][B]2
a)
b)
c)
d)
e)
s-1
s
dm3 mol-1 s-1
dm2 mol-2 s-1
dm3 s2 mol-2
product
catalyst
reactant
reaction intermediate
k[A]
k[B]
k[A][B]
k[B]2
k[A][B]2
Rate = k[A]2
Rate = k[A][B]
Rate = k[A]2[B]
Rate = k[A]3
Rate = k[A] [A2]
Question 7) At 300 K, the following reaction is found to obey the rate law: Rate = k[NOCl] 2:
2NOCl 2NO + Cl2
Consider the three postulated mechanisms given below. Then choose the response
that lists all those that are possibly correct and no others.
NOCl NO + Cl
Mechanism 1
slow
Cl + NOCl NOCl2
fast
NOCl2 + NO 2NO + Cl2
fast
Overall: 2NOCl 2NO + Cl2
Mechanism 2
2NOCl NOCl2 + NO
NOCl2 NO + Cl2
Overall: 2NOCl 2NO + Cl2
slow
fast
Mechanism 3
NOCl
NO + Cl
NOCl + Cl NO + Cl2
Overall: 2NOCl 2NO + Cl2
fast, equilibrium
slow
a)
b)
c)
d)
e)
2, 3
3
1
2
1, 2
Question 9) For the reaction, 2H2S(g) + O2(g) 2S(s) + 2H2O(l), which one of the
following statements is absolutely true?
a)
b)
c)
d)
e)
The reaction is first order with respect to H 2S and second order with respect to O2.
The reaction is fourth order overall.
The rate law is: rate = k[H2S]2[O2].
The rate law is: rate = k[H2S][O2].
The rate law cannot be determined from the information given.
Cu+
Cu2+
V3+
Fe3+
Step 1
Step 2
Step 3
a)
b)
c)
d)
Fast
Slow
Fast
H2
NO
N2O
H2O
r = k [H2O2] [HOI]
r = k [H3O+] [H2O2]
r = k [H2O2] 2 [HI]2
r = k [H2O2] [HI]
Fast
Slow
Fast
Fast
Question 13) The rate law for the reaction: 2NO2 + O3 N2O5 + O2 is rate = k[NO2][O3].
Which of the following mechanisms is consistent with this rate equation?
a)
2 NO2 N2O4 fast
N2O4 + O3 N2O5 + O2 slow
b)
c)
d)
Question 14) The reaction H2O2 (aq) + 3I- (aq) + 2H+ (aq) 2H2O (l) + I3- (aq) has an
observed rate law rate = k [H2O2] [I-] [H+]
A mechanism is proposed for the overall reaction. Which elementary reaction below
could be the rate-determining step of the proposed mechanism?
a) H2O2 (aq) + 3 I- (aq) + 2 H+ (aq) 2 H2O (l) + I3- (aq)
b) H2O2 (aq) + I- (aq) + 2 H+ (aq) H2O (l) + OI- (aq)
c) H2O2 (aq) + I- (aq) + H+ (aq) H2O (l) + HOI (aq)
d) none of these elementary steps can be the rate-determining step