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1
What is the band structure of solids? 2
What is a nanocrystal? 3
Give three examples of applications of nanofibers. 3
Describe the fabrication method called self-organizations, and tell which
materials can be obtained that way. 4
What is the carbon nanotube? 4
What is the crystal structure of a diamond. 5
Define the coefficient of variation and explain why this is necessary to
be used to describe the properties of nanometals? 5
How would you define nanotechnology? 7
What is the characteristic size of semiconductor quantum dot? 7
What does it mean energy gap in the band structure theory of solids 7
What is the necessary condition to be fulfilled to create a quantum well
of two semiconductor materials? 7
The energy of electron in a quantum well with infinite barriers is 25 meV.
What would be this energy if the quantum well width is decreased
twice? 8
What does it mean that the light is linearly polarized? 8
Explain shortly what are the electrostatically formed quantum dots? 9
What can You tell about the term wave function? 9
What is the crystallographic structure of graphite? 10
How to obtain/fabricate graphene? 10
List, please, at least three characteristic physical properties of graphene
10
List, please, at least three methods of fabrication of carbon nanotubes 11
Define shortly the group of materials called nanofibers? 11
Define shortly nanofiber fabrication technique called drawing the
nanofibers? 11
Give at least three reasons making the electrospinning a large scale
production (industrial) techniques of fabricating nanofibers? 11
What is the dependence of the specific surface area on the grain size in
e.g. nanometals? 12
What is the dependence of yield stress on the grain size of nanometal 12
Give the three examples of fabrication techniques of nanometals. 13
Select on application of nanometals and explain it more in detail,
underlining the physical property of a nanometal which is explored in
this given application. 13
1 /2
Where:
y limiting strain; Yield stress,
0
proportionality constant,
grain size.
3. What is a nanocrystal?
Nanocrystalites (usually made of semiconductors, e.g. Si, CdSe) aggregated after
reactions from a chemical solution. - many fabrication techniques, many materials
used, and many forms of nanocrystals.
Main advantage: many can be easily solved in water bio-medical applications
(labeling the disease affected areas, or drag transportation)
Fundamental properties:
crystallite (of semiconductor) in insulating matrix (often amorphic or liquid)
strong carrier confinement in 3D
cheap technology and many applications (mainly in biology and medicine, but
also (opto)electronics)
strong surface effects
A nanocrystal is a crystalline nanoparticle. Some sources define it as any
singlecrystalline nanomaterial with at least one dimension 100 nm., while others
define it as a nanoparticle with any kind of crystalline structure including e.g.,
multiply twinned configurations.
A material object that measures less than 1 micrometer, i.e., 1000 nanometers in all
dimensions is a nanoparticle, not a nanocrystal. Only single-crystalline or
polycrystalline materials are nanocrystals.
Methods of fabrication:
Burning process (e.g. hydrocarbons)
Electric arc method
Laser ablation
Gas phase deposition
CV ( d ) =
CV
- coefficient of variation,
- standard deviation,
- mean value.
The yield stress increases for smaller values of CV (more uniform distribution)
What does it mean energy gap in the band structure theory of solids?
The energy range of electrons in solid in which theres strong scattering of electrons
on the atoms. As a result electrons of this energy range are not in the system.
electrons and holes), leading to energy levels called "energy subbands", i.e., the
carriers can only have discrete energy value.
Quantum wells are formed in semiconductors by having a material, like gallium
arsenide sandwiched between two layers of a material with a wider bandgap, like
aluminium arsenide.
The energy of electron in a quantum well with infinite barriers is 25 meV. What
would be this energy if the quantum well width is decreased twice?
With increasing L (potential well width, increasing size of the quantum box also in
3D) the energy of the confined electron states decreases.
n2
E n=
2
8mL
Describes the wave of probability, where the probability density means probability if
2
finding the particle in a given space | |
In order to find the wave function (and probability density) it is necessary to know its
energy and solve the Schrdinger equation:
=E
10
Large mobility of charge carriers ( 104 cm2/Vs at room temp.) and high
11
What is the dependence of the specific surface area on the grain size in e.g.
nanometals?
Nanometals polycrystaline materials made of common metal atoms (metallic
chemical elements) with crystalites smaller than 1 m. similarly as in conventional
metals these are polycrystalline materials but the grain size is in nm range (at least
in one direction of below 100 nm) Drastic increase of the specific surface area
(surface area divided by the volume)
12
Where:
y limiting strain; Yield stress,
0
proportionality constant,
grain size.
13