Temperatura

C
F
100.00
212.00
98.10
208.58
95.20
203.36
91.80
197.24
87.30
189.14
84.70
184.46
83.20
181.76
82.00
179.60
81.00
177.80
80.10
176.18
79.10
174.38
78.30
172.94
78.20
172.76
78.10
172.58

Frac. Masa Etanol

wL
wV
0.0000
0.0200
0.0500
0.1000
0.2000
0.3000
0.4000
0.5000
0.6000
0.7000
0.8000
0.9000
0.9400
0.9600

0.0000
0.1920
0.3770
0.5270
0.6560
0.7130
0.7460
0.7710
0.7940
0.8220
0.8580
0.9120
0.9420
0.9590

Temperatura
C
F
100.00
212.00
91.80
197.24
84.70
184.46
82.00
179.60
80.10
176.18
78.30
172.94
78.30
172.94

x
0.0000
1.0000

y
0.0000
1.0000

Frac. Masa
0.0000
0.1000
0.3000
0.5000
0.7000
0.9000
1.0000

Entalpa (BTU/lbm)
Lquido
180.10
159.80
135.00
122.90
111.10
96.60
89.00

Vapor
1150.00
1082.00
943.00
804.00
664.00
526.00
457.50

Entalpa (kJ/kg)
Lquido
418.90
371.68
314.00
285.86
258.41
224.68
207.01

78.20
78.30

172.76
172.94

Temperatura
C
F
100.00
212.00
98.10
208.58
95.20
203.36
91.80
197.24
87.30
189.14
84.70
184.46
83.20
181.76
82.00
179.60
81.00
177.80
80.10
176.18
79.10
174.38
78.30
172.94
78.20
172.76
78.10
172.58
78.20
172.76
78.30
172.94

0.9800
1.0000

0.9780
1.0000

Frac. Mol Etanol

x
y
0.0000
0.0000
0.0496
0.3778
0.1186
0.6073
0.2212
0.7401
0.3898
0.8297
0.5227
0.8639
0.6301
0.8824
0.7188
0.8959
0.7931
0.9078
0.8564
0.9219
0.9109
0.9392
0.9583
0.9636
0.9756
0.9765
0.9840
0.9835
0.9921
0.9913
1.0000
1.0000

Entalpa (kJ/kg)
Vapor
2674.82
2516.66
2193.35
1870.05
1544.42
1223.44
1064.11

Diagrama Ebullicin Sist. Etanol-Agua, P = 101.325 kPa

102.00
101.00

f(x)
f(x)
==
-21.1766202385
80.9058942085ln(x)
x^-0.2376588699
+ 80.7826586346
RR
==
0.8143435696
0.7960309254

100.00
f(x) = - 17.4778592649x^3
+ 41.4797936398x^2
- 46.1735815227x
+ 100.1271325576
f(x) = - 44.1013585348x^4
+ 20.5218030799x^3
+ 2.4092500022x^2
- 6.6426436484x
+ 100.0035853989
R = 0.9995552444
99.00
R = 0.9985695667
98.00
97.00
96.00
95.00
94.00
93.00
92.00
91.00
90.00
T, Temperatura

89.00
88.00
87.00
86.00
85.00
84.00
83.00
82.00
81.00
80.00
79.00
78.00
77.00
76.00
0.05 0.15 0.25 0.35 0.45 0.55 0.65
0.75 0.85 0.95
0.00 0.10 0.20
0.30 0.40 0.50 0.60 0.70
0.80 0.90 1.00

x, y, fraccin mol de etanol en la fase lquida, y en la fase vapor

Diagrama de equilibrio del sistema Etanol-Agua, P = 101.325 kPa

1.00
0.95
0.90
0.85
0.80
0.75
0.70
0.65
0.60
0.55

wy, fraccin masa del etanol en el vapor

0.50
0.45
0.40
0.35
0.30
0.25
0.20
0.15
0.10
0.05
0.00

wx, Fraccin masa del etanol en el lquido

C.Eq.
Diagonal

RECTIFICACION DE UNA MEZCLA DE ETANOL-AGUA

Se desea destilar una mezcla lquida de etanol-agua en una torre fraccionadora a 101.325 kPa de presin.
La alimentacin es de 100 kg mol/h y est en estado lquido, a una temperatura de 40C y contiene el 25% mol de etanol.
Para este proceso se desea obtener un destilado que contenga el 86% mol de etanol y un residuo con el 5% mol de etanol.
La relacin de reflujo a usar en este proceso es de 3:1. La capacidad calorfica promedio de la alimentacin es de:
y el ca
latente promedio es de
kJ/kg mol.
Calcular: (1) Flujo de destilado, (2) Flujo de residuos, (3) Nmero de platos y Plato de alimentacin.

Datos Inciales del problema

kg mol/h
F* =
100.00
xF =
Kg mol EtOH/kg mol tot
0.2500
PF =
kPa
101.33

Destilado
24.69

TF =

40.00

yV =

0.8600

Kg mol EtOH/kg mol tot

D* =
yD =

xL =

0.0500

Kg mol EtOH/kg mol tot

TD =

87.80

R=

3.00

PD =

101.33

Cp*F,prom =

20.84

H*Vap =

10246.02

H*D = 12385.08
(1- yD) = 0.14000

Kcal/ kg mol K
Kcal/ kg mol

D* yD =
D*(1-yD) =

Alimentacin
F* = 100.00
xF = 0.2500
TF = 40.00
PF = 101.33
H*F = 805.12
(1- xF) = 0.7500
F* xF = 25.00

0.8600

kgmol/h
frac mol Et

3.46

Cp*D,L =

27.28

H*Vap =

9990.15

L* =

21.23

74.07

kPa

D* H*D = 305804.39

Kcal/Kg mo
frac mol ag
kgmol EtOH/h

F* (1-xF) =

75.00

kgmol agua

Cp*F =

20.13

Kcal/Kg mol

26.479

Fondo

18.011

F* H*F = 80511.93

Kcal/h

Q = -F* H*F + L* H*L + V* H*V

368684.29

0.0500

TL =

87.80

PL =

101.33

90.80

75.31

H*L =

1633.16

(1- xL) =

0.95000

L* xL =

SOLUCION DEL PROBLEMA

1. Clculo del valor TB :

L* =
xL =

L* (1-xL) =

3.77
71.54

2. Clculo del valor H*F,Lsat:

1827.621

3. Clculo del valor q :

1.121

Adimens.

4. Pendiente de q :

9.233

Adimens.

5. Pendiente de L.Op. Enriquec.:

6. Interc. de L.Op. Enriquec.:

Eje X

Eje Y

0.860
0.365

Eje X

Eje Y

0.250
0.275

0.250
0.481

Eje X

Eje Y

0.2680

0.4160

Eje X

Eje Y

0.050
0.268

0.050
0.416

Eje X

Eje Y

10. Trazado de las etapas :

0.860
0.508
0.508
0.114
0.114
0.020
0.020

0.860
0.860
0.595
0.595
0.159
0.159
0.020

11. Clculo del V* y de L* :

24.691
75.309

kgmol/h

8. Trazado de Linea "q" :

9. Calc. Interc. L.Op.E. y L. "q" :

9. Trazado de L.Op. Empobrecim. :

18.60

L* H*L = 143391.83

0.7500
0.2150
0.860
0.200

7. Trazado de L.Op. Enriquec.:

Cp*L =

Kcal/kg mol

kgmol/h

Kcal/Kg mol K

T
0.00
2.00
4.00
6.00
8.00
10.00
12.00

PEtOH (kPa)

PH2O (kPa)

1.545
1.783
2.052
2.356
2.698
3.083
3.515

0.609
0.704
0.811
0.933
1.071
1.226
1.401

CpEtOH (l)

CpH2O (l)

CpEtOH (v)

CpH2O (v)

2.537
2.533
2.529
2.524
2.520
2.515
2.509

25.378
25.453
25.534
25.620
25.711
25.808
25.911

17.965
17.970
17.974
17.979
17.984
17.988
17.993

7.183
7.178
7.173
7.168
7.162
7.157
7.151

7.682
7.688
7.693
7.699
7.705
7.711
7.716

14.00
16.00
18.00
20.00
22.00
24.00
26.00
28.00
30.00
32.00
34.00
36.00
38.00
40.00

3.999
4.539
5.141
5.812
6.557
7.382
8.296
9.306
10.420
11.646
12.994
14.473
16.094
17.868

1.597
1.817
2.063
2.337
2.643
2.983
3.361
3.780
4.243
4.755
5.320
5.942
6.626
7.377

2.504
2.498
2.493
2.487
2.481
2.475
2.468
2.462
2.456
2.449
2.442
2.436
2.429
2.422

26.019
26.133
26.252
26.377
26.508
26.644
26.785
26.932
27.085
27.243
27.407
27.576
27.751
27.931

17.997
18.002
18.006
18.011
18.016
18.020
18.025
18.029
18.034
18.038
18.043
18.047
18.052
18.057

7.145
7.139
7.133
7.127
7.121
7.115
7.109
7.102
7.096
7.089
7.082
7.076
7.069
7.062

7.722
7.728
7.734
7.739
7.745
7.751
7.757
7.763
7.768
7.774
7.780
7.786
7.791
7.797

42.00

19.806

8.200

2.415

28.117

18.061

7.055

7.803

44.00
46.00
48.00
50.00
52.00
54.00
56.00
58.00
60.00
62.00
64.00
66.00
68.00
70.00
72.00
74.00
76.00
78.00
80.00
82.00
84.00
86.00
88.00
90.00
92.00
94.00

21.921
24.224
26.730
29.453
32.407
35.608
39.073
42.818
46.861
51.222
55.918
60.971
66.401
72.230
78.482
85.180
92.347
100.010
108.195
116.929
126.240
136.158
146.711
157.932
169.851
182.503

9.102
10.087
11.163
12.337
13.614
15.004
16.513
18.150
19.924
21.844
23.920
26.161
28.578
31.182
33.986
37.000
40.237
43.710
47.434
51.422
55.688
60.249
65.119
70.317
75.857
81.759

2.408
2.401
2.394
2.387
2.380
2.373
2.366
2.359
2.352
2.345
2.338
2.331
2.323
2.316
2.309
2.302
2.295
2.288
2.281
2.274
2.267
2.260
2.253
2.246
2.239
2.232

28.309
28.506
28.708
28.916
29.130
29.349
29.574
29.804
30.040
30.282
30.528
30.781
31.039
31.303
31.572
31.847
32.127
32.413
32.704
33.001
33.303
33.612
33.925
34.244
34.569
34.899

18.066
18.070
18.075
18.079
18.084
18.088
18.093
18.097
18.102
18.106
18.111
18.115
18.120
18.124
18.129
18.133
18.138
18.142
18.147
18.151
18.156
18.160
18.165
18.169
18.174
18.178

7.048
7.040
7.033
7.025
7.018
7.010
7.002
6.995
6.987
6.979
6.970
6.962
6.954
6.945
6.937
6.928
6.920
6.911
6.902
6.893
6.884
6.875
6.865
6.856
6.847
6.837

7.809
7.814
7.820
7.826
7.832
7.837
7.843
7.849
7.855
7.861
7.866
7.872
7.878
7.884
7.889
7.895
7.901
7.907
7.912
7.918
7.924
7.930
7.935
7.941
7.947
7.953

2.394

29.139

18.072

7.027

7.817

in.
25% mol de etanol.
el 5% mol de etanol.
acin es de:
y el calor

estilado
kgmol/h
frac mol EtOH
C
kPa
Kcal/Kg mol
frac mol agua
kgmol EtOH/h
kgmol agua/h
Kcal/Kg mol K

28.777

9921.665

Kcal/Kg mol

18.065

10410.868

Kcal/Kg mol K

Kcal/h

Fondo
kgmol/h
frac mol EtOH
C
kPa
Kcal/Kg mol
frac mol agua
kgmol EtOH/h
kgmol agua/h

Kcal/Kg mol K

Kcal/h

HVap,EtOH

HVap,H2O

10714.866
10681.717
10648.395
10614.899
10581.226
10547.373
10513.338

10918.897
10896.973
10874.975
10852.903
10830.755
10808.532
10786.233

Constantes de Antoine (T C, P mmHg)

P = 10^(A- (B/(C+T)))
Compuesto
A
B
Etanol
8.04494
1554.3
Agua
8.10765
1750.286

C
222.65
235

10479.118
10444.712
10410.115
10375.325
10340.340
10305.157
10269.772
10234.183
10198.386
10162.379
10126.158
10089.720
10053.061
10016.177

10763.856
10741.402
10718.869
10696.257
10673.565
10650.792
10627.938
10605.002
10581.982
10558.879
10535.691
10512.418
10489.059
10465.613

9979.066

10442.079

9941.724
9904.146
9866.330
9828.270
9789.962
9751.404
9712.589
9673.515
9634.175
9594.566
9554.682
9514.520
9474.072
9433.335
9392.302
9350.968
9309.328
9267.374
9225.102
9182.505
9139.575
9096.307
9052.693
9008.726
8964.399
8919.703

10418.456
10394.743
10370.940
10347.046
10323.059
10298.979
10274.805
10250.535
10226.170
10201.707
10177.147
10152.487
10127.726
10102.865
10077.901
10052.833
10027.661
10002.384
9976.999
9951.506
9925.904
9900.191
9874.367
9848.430
9822.378
9796.210

9861.828

10374.085

Constantes de Cp (liq) (T K)
(Cp/R) = A + BT + CT2
Compuesto
A
B
33.866
-1.73E-01
Etanol
Agua
8.712
1.26E-03
Constantes de Cp (vap) (T K)
(Cp/R) = A + BT + CT2
Compuesto
A
B
3.518
2.00E-03
Etanol
Agua
3.47
1.45E-03

C
3.49E-04

-1.80E-07

C
-6.02E-06

0.00E+00

Hvap (T K)

Hv,2 = Hv,1 ((1-Tr2)/(1-Tr1))0.375

Compuesto

Tc

Tb

Hvap,Tb

Etanol
Agua

516.20

351.50

647.3

373.15

9260.00
9717.00

Diagrama de equilibrio del sistema Etanol-Agua, P = 101.325 kPa

y, fraccin mol del etanol en el vapor

x, Fraccin mol del etanol enDiagonal

el lquido

L.Op.Enr.

L.Op.Emp

Etapas

RECTIFICACION DE UNA MEZCLA DE ETANOL-AGUA

Se desea destilar una mezcla lquida de etanol-agua en una torre fraccionadora a 101.325 kPa de presin.
La alimentacin es de 100 kg mol/h y est en estado lquido, a una temperatura de 40C y contiene el 25% mol de etanol.
Para este proceso se desea obtener un destilado que contenga el 86% mol de etanol y un residuo con el 5% mol de etanol.
La relacin de reflujo a usar en este proceso es de 3:1. La capacidad calorfica promedio de la alimentacin es de:
y el ca
latente promedio es de
kJ/kg mol.
Calcular: (1) Flujo de destilado, (2) Flujo de residuos, (3) Nmero de platos y Plato de alimentacin.

Datos Inciales del problema

kg mol/h
F* =
100.00
xF =
Kg mol EtOH/kg mol tot
0.1500
PF =
kPa
101.33

Destilado
11.76

TF =

60.00

yV =

0.9000

Kg mol EtOH/kg mol tot

D* =
yD =

xL =

0.0500

Kg mol EtOH/kg mol tot

TD =

87.80

R=

3.00

PD =

101.33

Cp*F,prom =

19.73

H*Vap =

10297.25

H*D = 12403.13
(1- yD) = 0.10000

Kcal/ kg mol K
Kcal/ kg mol

D* yD =
D*(1-yD) =

Alimentacin
F* = 100.00
xF = 0.1500
TF = 60.00
PF = 101.33
H*F = 1156.87
(1- xF) = 0.8500
F* xF = 15.00

0.9000

kgmol/h
frac mol Et

1.18

Cp*D,L =

27.71

H*Vap =

9970.59

L* =

10.59

35.29

kPa

D* H*D = 145919.15

Kcal/Kg mo
frac mol ag
kgmol EtOH/h

F* (1-xF) =

85.00

kgmol agua

Cp*F =

19.28

Kcal/Kg mol

26.479

Fondo

18.011

TB,F =
F* H*F =

94.05
###

C
Kcal/h

Q = -F* H*F + L* H*L + V* H*V

173623.89

2. Clculo del valor H*F,Lsat:

0.0500

TL =

87.80

PL =

101.33

90.80
1750.731

C
Kcal/kg mol

88.24

H*L =

1633.16

(1- xL) =

0.95000

L* xL =

SOLUCION DEL PROBLEMA

1. Clculo del valor TB :

L* =
xL =

4.41

L* (1-xL) =

83.82

Cp*L =

18.60

1.069

Adimens.

4. Pendiente de q :

15.391

Adimens.

5. Pendiente de L.Op. Enriquec.:

6. Interc. de L.Op. Enriquec.:

0.7500
0.2250

3. Clculo del valor q :

Eje X

Eje Y

0.900
0.100

0.900
0.300

Eje X

Eje Y

0.150
0.165

0.150
0.381

Eje X

Eje Y

0.1628

0.3471

Eje X

Eje Y

0.050
0.163

0.050
0.347

Eje X

Eje Y

10. Trazado de las etapas :

0.900
0.740
0.740
0.280
0.280
0.062
0.062
0.010
0.010

0.900
0.900
0.778
0.778
0.435
0.435
0.080
0.080
0.010

11. Clculo del V* y de L* :

11.765
88.235

kgmol/h

7. Trazado de L.Op. Enriquec.:

8. Trazado de Linea "q" :

9. Calc. Interc. L.Op.E. y L. "q" :

9. Trazado de L.Op. Empobrecim. :

L* H*L = 143391.83

kgmol/h

Kcal/Kg mol K

T
0.00
2.00
4.00
6.00

PEtOH (kPa)

PH2O (kPa)

1.545
1.783
2.052
2.356

0.609
0.704
0.811
0.933

CpEtOH (l)

CpH2O (l)

CpEtOH (v)

CpH2O (v)

2.537
2.533
2.529
2.524

25.378
25.453
25.534
25.620

17.965
17.970
17.974
17.979

7.183
7.178
7.173
7.168

7.682
7.688
7.693
7.699

8.00
10.00
12.00
14.00
16.00
18.00
20.00
22.00
24.00
26.00
28.00
30.00
32.00
34.00
36.00
38.00
40.00

2.698
3.083
3.515
3.999
4.539
5.141
5.812
6.557
7.382
8.296
9.306
10.420
11.646
12.994
14.473
16.094
17.868

1.071
1.226
1.401
1.597
1.817
2.063
2.337
2.643
2.983
3.361
3.780
4.243
4.755
5.320
5.942
6.626
7.377

2.520
2.515
2.509
2.504
2.498
2.493
2.487
2.481
2.475
2.468
2.462
2.456
2.449
2.442
2.436
2.429
2.422

25.711
25.808
25.911
26.019
26.133
26.252
26.377
26.508
26.644
26.785
26.932
27.085
27.243
27.407
27.576
27.751
27.931

17.984
17.988
17.993
17.997
18.002
18.006
18.011
18.016
18.020
18.025
18.029
18.034
18.038
18.043
18.047
18.052
18.057

7.162
7.157
7.151
7.145
7.139
7.133
7.127
7.121
7.115
7.109
7.102
7.096
7.089
7.082
7.076
7.069
7.062

7.705
7.711
7.716
7.722
7.728
7.734
7.739
7.745
7.751
7.757
7.763
7.768
7.774
7.780
7.786
7.791
7.797

42.00

19.806

8.200

2.415

28.117

18.061

7.055

7.803

44.00
46.00
48.00
50.00
52.00
54.00
56.00
58.00
60.00
62.00
64.00
66.00
68.00
70.00
72.00
74.00
76.00
78.00
80.00
82.00
84.00
86.00
88.00
90.00
92.00
94.00

21.921
24.224
26.730
29.453
32.407
35.608
39.073
42.818
46.861
51.222
55.918
60.971
66.401
72.230
78.482
85.180
92.347
100.010
108.195
116.929
126.240
136.158
146.711
157.932
169.851
182.503

9.102
10.087
11.163
12.337
13.614
15.004
16.513
18.150
19.924
21.844
23.920
26.161
28.578
31.182
33.986
37.000
40.237
43.710
47.434
51.422
55.688
60.249
65.119
70.317
75.857
81.759

2.408
2.401
2.394
2.387
2.380
2.373
2.366
2.359
2.352
2.345
2.338
2.331
2.323
2.316
2.309
2.302
2.295
2.288
2.281
2.274
2.267
2.260
2.253
2.246
2.239
2.232

28.309
28.506
28.708
28.916
29.130
29.349
29.574
29.804
30.040
30.282
30.528
30.781
31.039
31.303
31.572
31.847
32.127
32.413
32.704
33.001
33.303
33.612
33.925
34.244
34.569
34.899

18.066
18.070
18.075
18.079
18.084
18.088
18.093
18.097
18.102
18.106
18.111
18.115
18.120
18.124
18.129
18.133
18.138
18.142
18.147
18.151
18.156
18.160
18.165
18.169
18.174
18.178

7.048
7.040
7.033
7.025
7.018
7.010
7.002
6.995
6.987
6.979
6.970
6.962
6.954
6.945
6.937
6.928
6.920
6.911
6.902
6.893
6.884
6.875
6.865
6.856
6.847
6.837

7.809
7.814
7.820
7.826
7.832
7.837
7.843
7.849
7.855
7.861
7.866
7.872
7.878
7.884
7.889
7.895
7.901
7.907
7.912
7.918
7.924
7.930
7.935
7.941
7.947
7.953

2.394

29.139

18.072

7.027

7.817

in.
25% mol de etanol.
el 5% mol de etanol.
acin es de:
y el calor

estilado
kgmol/h
frac mol EtOH
C
kPa
Kcal/Kg mol
frac mol agua
kgmol EtOH/h
kgmol agua/h
Kcal/Kg mol K

28.777

9921.665

Kcal/Kg mol

18.065

10410.868

Kcal/Kg mol K

Kcal/h

Fondo
kgmol/h
frac mol EtOH
C
kPa
Kcal/Kg mol
frac mol agua
kgmol EtOH/h
kgmol agua/h
Kcal/Kg mol K

Kcal/h

HVap,EtOH

HVap,H2O

10714.866
10681.717
10648.395
10614.899

10918.897
10896.973
10874.975
10852.903

Constantes de Antoine (T C, P mmHg)

P = 10^(A- (B/(C+T)))
Compuesto
A
B

10581.226
10547.373
10513.338
10479.118
10444.712
10410.115
10375.325
10340.340
10305.157
10269.772
10234.183
10198.386
10162.379
10126.158
10089.720
10053.061
10016.177

10830.755
10808.532
10786.233
10763.856
10741.402
10718.869
10696.257
10673.565
10650.792
10627.938
10605.002
10581.982
10558.879
10535.691
10512.418
10489.059
10465.613

9979.066

10442.079

9941.724
9904.146
9866.330
9828.270
9789.962
9751.404
9712.589
9673.515
9634.175
9594.566
9554.682
9514.520
9474.072
9433.335
9392.302
9350.968
9309.328
9267.374
9225.102
9182.505
9139.575
9096.307
9052.693
9008.726
8964.399
8919.703

10418.456
10394.743
10370.940
10347.046
10323.059
10298.979
10274.805
10250.535
10226.170
10201.707
10177.147
10152.487
10127.726
10102.865
10077.901
10052.833
10027.661
10002.384
9976.999
9951.506
9925.904
9900.191
9874.367
9848.430
9822.378
9796.210

9861.828

10374.085

Etanol
Agua

8.04494
8.10765

1554.3
1750.286

Constantes de Cp (liq) (T K)
(Cp/R) = A + BT + CT2
Compuesto
A
B
33.866
-1.73E-01
Etanol
Agua
8.712
1.26E-03
Constantes de Cp (vap) (T K)
(Cp/R) = A + BT + CT2
Compuesto
A
B
3.518
2.00E-03
Etanol
Agua
3.47
1.45E-03

222.65
235

C
3.49E-04

-1.80E-07

C
-6.02E-06

0.00E+00

Hvap (T K)

Hv,2 = Hv,1 ((1-Tr2)/(1-Tr1))0.375

Compuesto

Tc

Tb

Hvap,Tb

Etanol
Agua

516.20

351.50

647.3

373.15

9260.00
9717.00

Diagrama de equilibrio del sistema Etanol-Agua, P = 101.325 kPa

y, fraccin mol del etanol en el vapor

x, Fraccin mol del etanol en el lquido

Diagonal

L.Op.Enr.

L.Op.Emp

Etapas

RECTIFICACION DE UNA MEZCLA DE ETANOL-AGUA

Se desea destilar una mezcla lquida de etanol-agua en una torre fraccionadora a 101.325 kPa de presin.
La alimentacin es de 100 kg mol/h y est en estado lquido, a una temperatura de 40C y contiene el 25% mol de etanol.
Para este proceso se desea obtener un destilado que contenga el 86% mol de etanol y un residuo con el 5% mol de etanol.
La relacin de reflujo a usar en este proceso es de 3:1. La capacidad calorfica promedio de la alimentacin es de:
y el ca
latente promedio es de
kJ/kg mol.
Calcular: (1) Flujo de destilado, (2) Flujo de residuos, (3) Nmero de platos y Plato de alimentacin.

Datos Inciales del problema

kg mol/h
F* =
100.00
xF =
Kg mol EtOH/kg mol tot
0.1500
PF =
kPa
101.33

Destilado
11.76

TF =

90.00

yV =

0.9000

Kg mol EtOH/kg mol tot

D* =
yD =

xL =

0.0500

Kg mol EtOH/kg mol tot

TD =

87.80

R=

3.00

PD =

101.33

Cp*F,prom =

19.79

H*Vap =

10297.25
9861.828

H*D = 12403.13
(1- yD) = 0.10000

Kcal/ kg mol K
Kcal/ kg mol

D* yD =

10374.085

D*(1-yD) =

Alimentacin
F* = 100.00
xF = 0.1500
TF = 90.00
PF = 101.33
H*F = 1772.26
(1- xF) = 0.8500
F* xF = 15.00

kgmol/h
frac mol Et

27.71

H*Vap =

9970.59

frac mol ag
kgmol EtOH/h

Cp*F =

19.69

Kcal/Kg mol

28.895
18.068

###

Cp*F,TB =

19.73

35.29

D* H*D = 145919.15

Kcal/Kg mo

kgmol agua

F* H*F =

1.18

kPa

85.00

94.05

10.59

Cp*D,L =
L* =

F* (1-xF) =

TB,F =

0.9000

Fondo
C

L* =
xL =

88.24
0.0500

Kcal/h

TL =

87.80

PL =

101.33

Q
Kcal/Kg mol

= -F* H*F + L* H*L + V* H*V

112084.52

29.139
18.072

2. Clculo del valor H*F,Lsat:

1633.16

(1- xL) =

0.95000

L* xL =

SOLUCION DEL PROBLEMA

1. Clculo del valor TB :

H*L =

94.05
1973.215

C
Kcal/kg mol

4.41

L* (1-xL) =

83.82

Cp*L =

18.60

1.02414

Adimens.

4. Pendiente de q :

42.423

Adimens.

5. Pendiente de L.Op. Enriquec.:

6. Interc. de L.Op. Enriquec.:

0.7500
0.2250

3. Clculo del valor q :

L* H*L = 143391.83

y*xF = 0.0507
Eje X

Eje Y

0.900
0.100

0.900
0.300

Eje X

Eje Y

0.150
0.155

0.150
0.362

Eje X

Eje Y

0.1545

0.3409

Eje X

Eje Y

0.050
0.154

0.050
0.341

Eje X

Eje Y

10. Trazado de las etapas :

0.9000
0.7450
0.7450
0.2935
0.2935
0.0650
0.0650
0.0115
0.0115

0.9000
0.9000
0.7850
0.7850
0.4470
0.4470
0.0940
0.0940
0.0100

11. Clculo del V* y de L* :

11.765
88.235

kgmol/h

7. Trazado de L.Op. Enriquec.:

8. Trazado de Linea "q" :

9. Calc. Interc. L.Op.E. y L. "q" :

9. Trazado de L.Op. Empobrecim. :

kgmol/h

Kcal/Kg mol K

T
0.00
2.00

PEtOH (kPa)

PH2O (kPa)

CpEtOH (l)

CpH2O (l)

CpEtOH (v)

CpH2O (v)

1.545
1.783

0.609
0.704

2.537
2.533

25.378
25.453

17.965
17.970

7.183
7.178

7.682
7.688

4.00
6.00
8.00
10.00
12.00
14.00
16.00
18.00
20.00
22.00
24.00
26.00
28.00
30.00
32.00
34.00
36.00
38.00
40.00

2.052
2.356
2.698
3.083
3.515
3.999
4.539
5.141
5.812
6.557
7.382
8.296
9.306
10.420
11.646
12.994
14.473
16.094
17.868

0.811
0.933
1.071
1.226
1.401
1.597
1.817
2.063
2.337
2.643
2.983
3.361
3.780
4.243
4.755
5.320
5.942
6.626
7.377

2.529
2.524
2.520
2.515
2.509
2.504
2.498
2.493
2.487
2.481
2.475
2.468
2.462
2.456
2.449
2.442
2.436
2.429
2.422

25.534
25.620
25.711
25.808
25.911
26.019
26.133
26.252
26.377
26.508
26.644
26.785
26.932
27.085
27.243
27.407
27.576
27.751
27.931

17.974
17.979
17.984
17.988
17.993
17.997
18.002
18.006
18.011
18.016
18.020
18.025
18.029
18.034
18.038
18.043
18.047
18.052
18.057

7.173
7.168
7.162
7.157
7.151
7.145
7.139
7.133
7.127
7.121
7.115
7.109
7.102
7.096
7.089
7.082
7.076
7.069
7.062

7.693
7.699
7.705
7.711
7.716
7.722
7.728
7.734
7.739
7.745
7.751
7.757
7.763
7.768
7.774
7.780
7.786
7.791
7.797

42.00

19.806

8.200

2.415

28.117

18.061

7.055

7.803

44.00
46.00
48.00
50.00
52.00
54.00
56.00
58.00
60.00
62.00
64.00
66.00
68.00
70.00
72.00
74.00
76.00
78.00
80.00
82.00
84.00
86.00
88.00
90.00
92.00
94.00

21.921
24.224
26.730
29.453
32.407
35.608
39.073
42.818
46.861
51.222
55.918
60.971
66.401
72.230
78.482
85.180
92.347
100.010
108.195
116.929
126.240
136.158
146.711
157.932
169.851
182.503

9.102
10.087
11.163
12.337
13.614
15.004
16.513
18.150
19.924
21.844
23.920
26.161
28.578
31.182
33.986
37.000
40.237
43.710
47.434
51.422
55.688
60.249
65.119
70.317
75.857
81.759

2.408
2.401
2.394
2.387
2.380
2.373
2.366
2.359
2.352
2.345
2.338
2.331
2.323
2.316
2.309
2.302
2.295
2.288
2.281
2.274
2.267
2.260
2.253
2.246
2.239
2.232

28.309
28.506
28.708
28.916
29.130
29.349
29.574
29.804
30.040
30.282
30.528
30.781
31.039
31.303
31.572
31.847
32.127
32.413
32.704
33.001
33.303
33.612
33.925
34.244
34.569
34.899

18.066
18.070
18.075
18.079
18.084
18.088
18.093
18.097
18.102
18.106
18.111
18.115
18.120
18.124
18.129
18.133
18.138
18.142
18.147
18.151
18.156
18.160
18.165
18.169
18.174
18.178

7.048
7.040
7.033
7.025
7.018
7.010
7.002
6.995
6.987
6.979
6.970
6.962
6.954
6.945
6.937
6.928
6.920
6.911
6.902
6.893
6.884
6.875
6.865
6.856
6.847
6.837

7.809
7.814
7.820
7.826
7.832
7.837
7.843
7.849
7.855
7.861
7.866
7.872
7.878
7.884
7.889
7.895
7.901
7.907
7.912
7.918
7.924
7.930
7.935
7.941
7.947
7.953

96.00
98.00
100.00

195.919
210.137
225.190

88.040
94.719
101.817

2.225
2.219
2.212

35.235
35.576
35.923

18.183
18.187
18.191

6.827
6.818
6.808

7.958
7.964
7.970

2.384

29.518

18.079

7.015

7.826

in.
25% mol de etanol.
el 5% mol de etanol.
acin es de:
y el calor

estilado
kgmol/h
frac mol EtOH
C
kPa
Kcal/Kg mol
frac mol agua
kgmol EtOH/h
kgmol agua/h
Kcal/Kg mol K

28.777

9921.665

Kcal/Kg mol

18.065

10410.868

Kcal/Kg mol K

Kcal/h

Fondo
kgmol/h
frac mol EtOH
C
kPa
Kcal/Kg mol
frac mol agua
kgmol EtOH/h
kgmol agua/h
Kcal/Kg mol K

Kcal/h

HVap,EtOH

HVap,H2O

10714.866
10681.717

10918.897
10896.973

Constantes de Antoine (T C, P mmHg)

10648.395
10614.899
10581.226
10547.373
10513.338
10479.118
10444.712
10410.115
10375.325
10340.340
10305.157
10269.772
10234.183
10198.386
10162.379
10126.158
10089.720
10053.061
10016.177

10874.975
10852.903
10830.755
10808.532
10786.233
10763.856
10741.402
10718.869
10696.257
10673.565
10650.792
10627.938
10605.002
10581.982
10558.879
10535.691
10512.418
10489.059
10465.613

9979.066

10442.079

9941.724
9904.146
9866.330
9828.270
9789.962
9751.404
9712.589
9673.515
9634.175
9594.566
9554.682
9514.520
9474.072
9433.335
9392.302
9350.968
9309.328
9267.374
9225.102
9182.505
9139.575
9096.307
9052.693
9008.726
8964.399
8919.703

10418.456
10394.743
10370.940
10347.046
10323.059
10298.979
10274.805
10250.535
10226.170
10201.707
10177.147
10152.487
10127.726
10102.865
10077.901
10052.833
10027.661
10002.384
9976.999
9951.506
9925.904
9900.191
9874.367
9848.430
9822.378
9796.210

P = 10^(A- (B/(C+T)))
A
B
Etanol
8.04494
1554.3
Agua
8.10765
1750.286

Compuesto

Constantes de Cp (liq) (T K)
(Cp/R) = A + BT + CT2
Compuesto
A
B
33.866
-1.73E-01
Etanol
Agua
8.712
1.26E-03
Constantes de Cp (vap) (T K)
(Cp/R) = A + BT + CT2
Compuesto
A
B
3.518
2.00E-03
Etanol
Agua
3.47
1.45E-03

C
222.65
235

C
3.49E-04

-1.80E-07

C
-6.02E-06

0.00E+00

Hvap (T K)

Hv,2 = Hv,1 ((1-Tr2)/(1-Tr1))0.375

Compuesto

Tc

Tb

Hvap,Tb

Etanol
Agua

516.20

351.50

647.3

373.15

9260.00
9717.00

8874.630
8829.173
8783.323

9769.926
9743.523
9717.000

9801.076

10336.991

Diagrama de equilibrio del sistema Etanol-Agua, P = 101.325 kPa

y, fraccin mol del etanol en el vapor

x, Fraccin mol del etanol en el lquido

Diagonal

L.Op.Enr.

L.Op.Emp

Etapas

RECTIFICACION
DE UNA MEZCLA DE ETANOL-AGUA
Dtl_ME_3
Se desea destilar una mezcla lquida de etanol-agua en una torre fraccionadora a 101.325 kPa de presin.
La alimentacin es de 100 kg mol/h y est en estado lquido, a una temperatura de 40C y contiene el 25% mol de etanol.
Para este proceso se desea obtener un destilado que contenga el 86% mol de etanol y un residuo con el 5% mol de etanol.
La relacin de reflujo a usar en este proceso es de 3:1. La capacidad calorfica promedio de la alimentacin es de:
y el ca
latente promedio es de
kJ/kg mol.
Calcular: (1) Flujo de destilado, (2) Flujo de residuos, (3) Nmero de platos y Plato de alimentacin.

Datos Inciales del problema

kg mol/h
F* =
100.00
xF =
Kg mol EtOH/kg mol tot
0.1500
PF =
kPa
101.33

Destilado
11.76

TF =

90.00

yV =

0.9000

Kg mol EtOH/kg mol tot

D* =
yD =

xL =

0.0500

Kg mol EtOH/kg mol tot

TD =

87.80

R=

2.00

PD =

101.33

Cp*F,prom =

19.79

H*Vap =

10297.25
9861.828

H*D = 12403.13
(1- yD) = 0.10000

Kcal/ kg mol K
Kcal/ kg mol

D* yD =

10374.085

D*(1-yD) =

Alimentacin
F* = 100.00
xF = 0.1500
TF = 90.00
PF = 101.33
H*F = 1772.26
(1- xF) = 0.8500
F* xF = 15.00

kgmol/h
frac mol Et

27.71

H*Vap =

9970.59

frac mol ag
kgmol EtOH/h

Cp*F =

19.69

Kcal/Kg mol

28.895
18.068

###

Cp*F,TB =

19.73

23.53

D* H*D = 145919.15

Kcal/Kg mo

kgmol agua

F* H*F =

1.18

kPa

85.00

94.05

10.59

Cp*D,L =
L* =

F* (1-xF) =

TB,F =

0.9000

Fondo
C

L* =
xL =

88.24
0.0500

Kcal/h

TL =

87.80

PL =

101.33

Q
Kcal/Kg mol

= -F* H*F + L* H*L + V* H*V

112084.52

29.139
18.072

2. Clculo del valor H*F,Lsat:

1633.16

(1- xL) =

0.95000

L* xL =

SOLUCION DEL PROBLEMA

1. Clculo del valor TB :

H*L =

94.05
1973.215

C
Kcal/kg mol

4.41

L* (1-xL) =

83.82

Cp*L =

18.60

1.02414

Adimens.

4. Pendiente de q :

42.423

Adimens.

5. Pendiente de L.Op. Enriquec.:

6. Interc. de L.Op. Enriquec.:

0.6667
0.3000

3. Clculo del valor q :

Eje X

Eje Y

0.900
0.100

0.900
0.367

Eje X

Eje Y

0.150
0.160

0.150
0.574

Eje X

Eje Y

0.1560

0.4040

Eje X

Eje Y

0.050
0.156

0.050
0.404

Eje X

Eje Y

10. Trazado de las etapas :

0.9000
0.7450
0.7450
0.3150
0.3150
0.0810
0.0810
0.0180
0.0180

0.9000
0.9000
0.7960
0.7960
0.5100
0.5100
0.1540
0.1540
0.0100

11. Clculo del V* y de L* :

11.765
88.235

kgmol/h

7. Trazado de L.Op. Enriquec.:

8. Trazado de Linea "q" :

9. Calc. Interc. L.Op.E. y L. "q" :

9. Trazado de L.Op. Empobrecim. :

L* H*L = 143391.83

kgmol/h

Kcal/Kg mol K

T
0.00
2.00
4.00
6.00

PEtOH (kPa)

PH2O (kPa)

1.545
1.783
2.052
2.356

0.609
0.704
0.811
0.933

CpEtOH (l)

CpH2O (l)

CpEtOH (v)

CpH2O (v)

2.537
2.533
2.529
2.524

25.378
25.453
25.534
25.620

17.965
17.970
17.974
17.979

7.183
7.178
7.173
7.168

7.682
7.688
7.693
7.699

8.00
10.00
12.00
14.00
16.00
18.00
20.00
22.00
24.00
26.00
28.00
30.00
32.00
34.00
36.00
38.00
40.00

2.698
3.083
3.515
3.999
4.539
5.141
5.812
6.557
7.382
8.296
9.306
10.420
11.646
12.994
14.473
16.094
17.868

1.071
1.226
1.401
1.597
1.817
2.063
2.337
2.643
2.983
3.361
3.780
4.243
4.755
5.320
5.942
6.626
7.377

2.520
2.515
2.509
2.504
2.498
2.493
2.487
2.481
2.475
2.468
2.462
2.456
2.449
2.442
2.436
2.429
2.422

25.711
25.808
25.911
26.019
26.133
26.252
26.377
26.508
26.644
26.785
26.932
27.085
27.243
27.407
27.576
27.751
27.931

17.984
17.988
17.993
17.997
18.002
18.006
18.011
18.016
18.020
18.025
18.029
18.034
18.038
18.043
18.047
18.052
18.057

7.162
7.157
7.151
7.145
7.139
7.133
7.127
7.121
7.115
7.109
7.102
7.096
7.089
7.082
7.076
7.069
7.062

7.705
7.711
7.716
7.722
7.728
7.734
7.739
7.745
7.751
7.757
7.763
7.768
7.774
7.780
7.786
7.791
7.797

42.00

19.806

8.200

2.415

28.117

18.061

7.055

7.803

44.00
46.00
48.00
50.00
52.00
54.00
56.00
58.00
60.00
62.00
64.00
66.00
68.00
70.00
72.00
74.00
76.00
78.00
80.00
82.00
84.00
86.00
88.00
90.00
92.00
94.00
96.00
98.00

21.921
24.224
26.730
29.453
32.407
35.608
39.073
42.818
46.861
51.222
55.918
60.971
66.401
72.230
78.482
85.180
92.347
100.010
108.195
116.929
126.240
136.158
146.711
157.932
169.851
182.503
195.919
210.137

9.102
10.087
11.163
12.337
13.614
15.004
16.513
18.150
19.924
21.844
23.920
26.161
28.578
31.182
33.986
37.000
40.237
43.710
47.434
51.422
55.688
60.249
65.119
70.317
75.857
81.759
88.040
94.719

2.408
2.401
2.394
2.387
2.380
2.373
2.366
2.359
2.352
2.345
2.338
2.331
2.323
2.316
2.309
2.302
2.295
2.288
2.281
2.274
2.267
2.260
2.253
2.246
2.239
2.232
2.225
2.219

28.309
28.506
28.708
28.916
29.130
29.349
29.574
29.804
30.040
30.282
30.528
30.781
31.039
31.303
31.572
31.847
32.127
32.413
32.704
33.001
33.303
33.612
33.925
34.244
34.569
34.899
35.235
35.576

18.066
18.070
18.075
18.079
18.084
18.088
18.093
18.097
18.102
18.106
18.111
18.115
18.120
18.124
18.129
18.133
18.138
18.142
18.147
18.151
18.156
18.160
18.165
18.169
18.174
18.178
18.183
18.187

7.048
7.040
7.033
7.025
7.018
7.010
7.002
6.995
6.987
6.979
6.970
6.962
6.954
6.945
6.937
6.928
6.920
6.911
6.902
6.893
6.884
6.875
6.865
6.856
6.847
6.837
6.827
6.818

7.809
7.814
7.820
7.826
7.832
7.837
7.843
7.849
7.855
7.861
7.866
7.872
7.878
7.884
7.889
7.895
7.901
7.907
7.912
7.918
7.924
7.930
7.935
7.941
7.947
7.953
7.958
7.964

100.00

225.190

101.817

2.212

35.923

18.191

6.808

7.970

2.384

29.518

18.079

7.015

7.826

in.
25% mol de etanol.
el 5% mol de etanol.
acin es de:
y el calor

estilado
kgmol/h
frac mol EtOH
C
kPa
Kcal/Kg mol
frac mol agua
kgmol EtOH/h
kgmol agua/h
Kcal/Kg mol K

28.777

9921.665

Kcal/Kg mol

18.065

10410.868

Kcal/Kg mol K

Kcal/h

Fondo
kgmol/h
frac mol EtOH
C
kPa
Kcal/Kg mol
frac mol agua
kgmol EtOH/h
kgmol agua/h
Kcal/Kg mol K

Kcal/h

HVap,EtOH

HVap,H2O

10714.866
10681.717
10648.395
10614.899

10918.897
10896.973
10874.975
10852.903

Constantes de Antoine (T C, P mmHg)

P = 10^(A- (B/(C+T)))
Compuesto
A
B

10581.226
10547.373
10513.338
10479.118
10444.712
10410.115
10375.325
10340.340
10305.157
10269.772
10234.183
10198.386
10162.379
10126.158
10089.720
10053.061
10016.177

10830.755
10808.532
10786.233
10763.856
10741.402
10718.869
10696.257
10673.565
10650.792
10627.938
10605.002
10581.982
10558.879
10535.691
10512.418
10489.059
10465.613

9979.066

10442.079

9941.724
9904.146
9866.330
9828.270
9789.962
9751.404
9712.589
9673.515
9634.175
9594.566
9554.682
9514.520
9474.072
9433.335
9392.302
9350.968
9309.328
9267.374
9225.102
9182.505
9139.575
9096.307
9052.693
9008.726
8964.399
8919.703
8874.630
8829.173

10418.456
10394.743
10370.940
10347.046
10323.059
10298.979
10274.805
10250.535
10226.170
10201.707
10177.147
10152.487
10127.726
10102.865
10077.901
10052.833
10027.661
10002.384
9976.999
9951.506
9925.904
9900.191
9874.367
9848.430
9822.378
9796.210
9769.926
9743.523

Etanol
Agua

8.04494
8.10765

1554.3
1750.286

Constantes de Cp (liq) (T K)
(Cp/R) = A + BT + CT2
Compuesto
A
B
33.866
-1.73E-01
Etanol
Agua
8.712
1.26E-03
Constantes de Cp (vap) (T K)
(Cp/R) = A + BT + CT2
Compuesto
A
B
3.518
2.00E-03
Etanol
Agua
3.47
1.45E-03

222.65
235

C
3.49E-04

-1.80E-07

C
-6.02E-06

0.00E+00

Hvap (T K)

Hv,2 = Hv,1 ((1-Tr2)/(1-Tr1))0.375

Compuesto

Tc

Tb

Hvap,Tb

Etanol
Agua

516.20

351.50

647.3

373.15

9260.00
9717.00

8783.323

9717.000

9801.076

10336.991

Diagrama de equilibrio del sistema Etanol-Agua, P = 101.325 kPa

y, fraccin mol del etanol en el vapor

x, Fraccin mol del etanol en el lquido

Diagonal

L.Op.Enr.

L.Op.Emp

Etapas

RECTIFICACION
DE UNA MEZCLA DE ETANOL-AGUA
Dtl_ME_3
Se desea destilar una mezcla lquida de etanol-agua en una torre fraccionadora a 101.325 kPa de presin.
La alimentacin es de 100 kg mol/h y est en estado lquido, a una temperatura de 40C y contiene el 25% mol de etanol.
Para este proceso se desea obtener un destilado que contenga el 86% mol de etanol y un residuo con el 5% mol de etanol.
La relacin de reflujo a usar en este proceso es de 3:1. La capacidad calorfica promedio de la alimentacin es de:
y el ca
latente promedio es de
kJ/kg mol.
Calcular: (1) Flujo de destilado, (2) Flujo de residuos, (3) Nmero de platos y Plato de alimentacin.

Datos Inciales del problema

kg mol/h
F* =
100.00
xF =
Kg mol EtOH/kg mol tot
0.1500
PF =
kPa
101.33

Destilado
11.76

TF =

90.00

yV =

0.9000

Kg mol EtOH/kg mol tot

D* =
yD =

xL =

0.0500

Kg mol EtOH/kg mol tot

TD =

87.80

R=

1.00

PD =

101.33

Cp*F,prom =

19.79

H*Vap =

10297.25
9861.828

H*D = 12403.13
(1- yD) = 0.10000

Kcal/ kg mol K
Kcal/ kg mol

D* yD =

10374.085

D*(1-yD) =

Alimentacin
F* = 100.00
xF = 0.1500
TF = 90.00
PF = 101.33
H*F = 1772.26
(1- xF) = 0.8500
F* xF = 15.00

kgmol/h
frac mol Et

27.71

H*Vap =

9970.59

frac mol ag
kgmol EtOH/h

Cp*F =

19.69

Kcal/Kg mol

28.895
18.068

###

Cp*F,TB =

19.73

11.76

D* H*D = 145919.15

Kcal/Kg mo

kgmol agua

F* H*F =

1.18

kPa

85.00

94.05

10.59

Cp*D,L =
L* =

F* (1-xF) =

TB,F =

0.9000

Fondo
C

L* =
xL =

88.24
0.0500

Kcal/h

TL =

87.80

PL =

101.33

Q
Kcal/Kg mol

= -F* H*F + L* H*L + V* H*V

112084.52

29.139
18.072

2. Clculo del valor H*F,Lsat:

1633.16

(1- xL) =

0.95000

L* xL =

SOLUCION DEL PROBLEMA

1. Clculo del valor TB :

H*L =

94.05
1973.215

C
Kcal/kg mol

4.41

L* (1-xL) =

83.82

Cp*L =

18.60

1.02414

Adimens.

4. Pendiente de q :

42.423

Adimens.

5. Pendiente de L.Op. Enriquec.:

6. Interc. de L.Op. Enriquec.:

0.5000
0.4500

3. Clculo del valor q :

Eje X

Eje Y

0.900
0.100

0.900
0.500

Eje X

Eje Y

0.150
0.160

0.150
0.574

Eje X

Eje Y

0.1589

0.5295

Eje X

Eje Y

0.050
0.159

0.050
0.529

Eje X

Eje Y

10. Trazado de las etapas :

0.9000
0.7450
0.7450
0.3750
0.3750
0.1345
0.1345
0.0600
0.0600
0.0120
0.0120

0.9000
0.9000
0.8230
0.8230
0.6380
0.6380
0.4200
0.4200
0.0950
0.0950
0.0000

11. Clculo del V* y de L* :

11.765
88.235

kgmol/h

7. Trazado de L.Op. Enriquec.:

8. Trazado de Linea "q" :

9. Calc. Interc. L.Op.E. y L. "q" :

9. Trazado de L.Op. Empobrecim. :

L* H*L = 143391.83

kgmol/h

Kcal/Kg mol K

T
0.00
2.00

PEtOH (kPa)

PH2O (kPa)

CpEtOH (l)

CpH2O (l)

CpEtOH (v)

CpH2O (v)

1.545
1.783

0.609
0.704

2.537
2.533

25.378
25.453

17.965
17.970

7.183
7.178

7.682
7.688

4.00
6.00
8.00
10.00
12.00
14.00
16.00
18.00
20.00
22.00
24.00
26.00
28.00
30.00
32.00
34.00
36.00
38.00
40.00

2.052
2.356
2.698
3.083
3.515
3.999
4.539
5.141
5.812
6.557
7.382
8.296
9.306
10.420
11.646
12.994
14.473
16.094
17.868

0.811
0.933
1.071
1.226
1.401
1.597
1.817
2.063
2.337
2.643
2.983
3.361
3.780
4.243
4.755
5.320
5.942
6.626
7.377

2.529
2.524
2.520
2.515
2.509
2.504
2.498
2.493
2.487
2.481
2.475
2.468
2.462
2.456
2.449
2.442
2.436
2.429
2.422

25.534
25.620
25.711
25.808
25.911
26.019
26.133
26.252
26.377
26.508
26.644
26.785
26.932
27.085
27.243
27.407
27.576
27.751
27.931

17.974
17.979
17.984
17.988
17.993
17.997
18.002
18.006
18.011
18.016
18.020
18.025
18.029
18.034
18.038
18.043
18.047
18.052
18.057

7.173
7.168
7.162
7.157
7.151
7.145
7.139
7.133
7.127
7.121
7.115
7.109
7.102
7.096
7.089
7.082
7.076
7.069
7.062

7.693
7.699
7.705
7.711
7.716
7.722
7.728
7.734
7.739
7.745
7.751
7.757
7.763
7.768
7.774
7.780
7.786
7.791
7.797

42.00

19.806

8.200

2.415

28.117

18.061

7.055

7.803

44.00
46.00
48.00
50.00
52.00
54.00
56.00
58.00
60.00
62.00
64.00
66.00
68.00
70.00
72.00
74.00
76.00
78.00
80.00
82.00
84.00
86.00
88.00
90.00
92.00
94.00

21.921
24.224
26.730
29.453
32.407
35.608
39.073
42.818
46.861
51.222
55.918
60.971
66.401
72.230
78.482
85.180
92.347
100.010
108.195
116.929
126.240
136.158
146.711
157.932
169.851
182.503

9.102
10.087
11.163
12.337
13.614
15.004
16.513
18.150
19.924
21.844
23.920
26.161
28.578
31.182
33.986
37.000
40.237
43.710
47.434
51.422
55.688
60.249
65.119
70.317
75.857
81.759

2.408
2.401
2.394
2.387
2.380
2.373
2.366
2.359
2.352
2.345
2.338
2.331
2.323
2.316
2.309
2.302
2.295
2.288
2.281
2.274
2.267
2.260
2.253
2.246
2.239
2.232

28.309
28.506
28.708
28.916
29.130
29.349
29.574
29.804
30.040
30.282
30.528
30.781
31.039
31.303
31.572
31.847
32.127
32.413
32.704
33.001
33.303
33.612
33.925
34.244
34.569
34.899

18.066
18.070
18.075
18.079
18.084
18.088
18.093
18.097
18.102
18.106
18.111
18.115
18.120
18.124
18.129
18.133
18.138
18.142
18.147
18.151
18.156
18.160
18.165
18.169
18.174
18.178

7.048
7.040
7.033
7.025
7.018
7.010
7.002
6.995
6.987
6.979
6.970
6.962
6.954
6.945
6.937
6.928
6.920
6.911
6.902
6.893
6.884
6.875
6.865
6.856
6.847
6.837

7.809
7.814
7.820
7.826
7.832
7.837
7.843
7.849
7.855
7.861
7.866
7.872
7.878
7.884
7.889
7.895
7.901
7.907
7.912
7.918
7.924
7.930
7.935
7.941
7.947
7.953

96.00
98.00
100.00

195.919
210.137
225.190

88.040
94.719
101.817

2.225
2.219
2.212

35.235
35.576
35.923

18.183
18.187
18.191

6.827
6.818
6.808

7.958
7.964
7.970

2.384

29.518

18.079

7.015

7.826

in.
25% mol de etanol.
el 5% mol de etanol.
acin es de:
y el calor

estilado
kgmol/h
frac mol EtOH
C
kPa
Kcal/Kg mol
frac mol agua
kgmol EtOH/h
kgmol agua/h
Kcal/Kg mol K

28.777

9921.665

Kcal/Kg mol

18.065

10410.868

Kcal/Kg mol K

Kcal/h

Fondo
kgmol/h
frac mol EtOH
C
kPa
Kcal/Kg mol
frac mol agua
kgmol EtOH/h
kgmol agua/h
Kcal/Kg mol K

Kcal/h

HVap,EtOH

HVap,H2O

10714.866
10681.717

10918.897
10896.973

Constantes de Antoine (T C, P mmHg)

10648.395
10614.899
10581.226
10547.373
10513.338
10479.118
10444.712
10410.115
10375.325
10340.340
10305.157
10269.772
10234.183
10198.386
10162.379
10126.158
10089.720
10053.061
10016.177

10874.975
10852.903
10830.755
10808.532
10786.233
10763.856
10741.402
10718.869
10696.257
10673.565
10650.792
10627.938
10605.002
10581.982
10558.879
10535.691
10512.418
10489.059
10465.613

9979.066

10442.079

9941.724
9904.146
9866.330
9828.270
9789.962
9751.404
9712.589
9673.515
9634.175
9594.566
9554.682
9514.520
9474.072
9433.335
9392.302
9350.968
9309.328
9267.374
9225.102
9182.505
9139.575
9096.307
9052.693
9008.726
8964.399
8919.703

10418.456
10394.743
10370.940
10347.046
10323.059
10298.979
10274.805
10250.535
10226.170
10201.707
10177.147
10152.487
10127.726
10102.865
10077.901
10052.833
10027.661
10002.384
9976.999
9951.506
9925.904
9900.191
9874.367
9848.430
9822.378
9796.210

P = 10^(A- (B/(C+T)))
A
B
Etanol
8.04494
1554.3
Agua
8.10765
1750.286

Compuesto

Constantes de Cp (liq) (T K)
(Cp/R) = A + BT + CT2
Compuesto
A
B
33.866
-1.73E-01
Etanol
Agua
8.712
1.26E-03
Constantes de Cp (vap) (T K)
(Cp/R) = A + BT + CT2
Compuesto
A
B
3.518
2.00E-03
Etanol
Agua
3.47
1.45E-03

C
222.65
235

C
3.49E-04

-1.80E-07

C
-6.02E-06

0.00E+00

Hvap (T K)

Hv,2 = Hv,1 ((1-Tr2)/(1-Tr1))0.375

Compuesto

Tc

Tb

Hvap,Tb

Etanol
Agua

516.20

351.50

647.3

373.15

9260.00
9717.00

8874.630
8829.173
8783.323

9769.926
9743.523
9717.000

9801.076

10336.991

Diagrama de equilibrio del sistema Etanol-Agua, P = 101.325 kPa

y, fraccin mol del etanol en el vapor

x, Fraccin mol del etanol en el lquido

Diagonal

L.Op.Enr.

L.Op.Emp

Etapas

RECTIFICACION DE UNA MEZCLA DE ETANOL-AGUA

Se desea destilar una mezcla lquida de etanol-agua en una torre fraccionadora a 101.325 kPa de presin.
La alimentacin es de 100 kg mol/h y est en estado lquido, a una temperatura de 40C y contiene el 25% mol de etanol.
Para este proceso se desea obtener un destilado que contenga el 86% mol de etanol y un residuo con el 5% mol de etanol.
La relacin de reflujo a usar en este proceso es de 3:1. La capacidad calorfica promedio de la alimentacin es de:
y el ca
latente promedio es de
kJ/kg mol.
Calcular: (1) Flujo de destilado, (2) Flujo de residuos, (3) Nmero de platos y Plato de alimentacin.

Datos Inciales del problema

kg mol/h
F* =
100.00
xF =
Kg mol EtOH/kg mol tot
0.1500
PF =
kPa
101.33

Destilado
11.76

TF =

90.00

yV =

0.9000

Kg mol EtOH/kg mol tot

D* =
yD =

xL =

0.0500

Kg mol EtOH/kg mol tot

TD =

87.80

R=

0.5000

PD =

101.33

Cp*F,prom =

19.79

H*Vap =

10297.25
9861.828

H*D = 12403.13
(1- yD) = 0.10000

Kcal/ kg mol K
Kcal/ kg mol

D* yD =

10374.085

D*(1-yD) =

Alimentacin
F* = 100.00
xF = 0.1500
TF = 90.00
PF = 101.33
H*F = 1772.26
(1- xF) = 0.8500
F* xF = 15.00

kgmol/h
frac mol Et

27.71

H*Vap =

9970.59

frac mol ag
kgmol EtOH/h

Cp*F =

19.69

Kcal/Kg mol

28.895
18.068

###

Cp*F,TB =

19.73

5.88

D* H*D = 145919.15

Kcal/Kg mo

kgmol agua

F* H*F =

1.18

kPa

85.00

94.05

10.59

Cp*D,L =
L* =

F* (1-xF) =

TB,F =

0.9000

Fondo
C

L* =
xL =

88.24
0.0500

Kcal/h

TL =

87.80

PL =

101.33

Q
Kcal/Kg mol

= -F* H*F + L* H*L + V* H*V

112084.52

29.139
18.072

2. Clculo del valor H*F,Lsat:

1633.16

(1- xL) =

0.95000

L* xL =

SOLUCION DEL PROBLEMA

1. Clculo del valor TB :

H*L =

94.05
1973.215

C
Kcal/kg mol

4.41

L* (1-xL) =

83.82

Cp*L =

18.60

1.02414

Adimens.

4. Pendiente de q :

42.423

Adimens.

5. Pendiente de L.Op. Enriquec.:

6. Interc. de L.Op. Enriquec.:

0.3333
0.6000

3. Clculo del valor q :

Eje X

Eje Y

0.900
0.100

0.900
0.633

Eje X

Eje Y

0.150
0.163

0.150
0.680

Eje X

Eje Y

0.1619

0.6540

Eje X

Eje Y

0.050
0.162

0.050
0.654

Eje X

Eje Y

10. Trazado de las etapas :

0.9000
0.7450
0.7450
0.4450
0.4450
0.2300
0.2300
0.1570
0.1570
0.1270
0.1270
0.0690
0.0690
0.0170
0.0170

0.9000
0.9000
0.8480
0.8480
0.7480
0.7480
0.6760
0.6760
0.6250
0.6250
0.4650
0.4650
0.1500
0.1500
0.0000

11. Clculo del V* y de L* :

11.765
88.235

kgmol/h

7. Trazado de L.Op. Enriquec.:

8. Trazado de Linea "q" :

9. Calc. Interc. L.Op.E. y L. "q" :

9. Trazado de L.Op. Empobrecim. :

L* H*L = 143391.83

kgmol/h

Kcal/Kg mol K

T
0.00
2.00
4.00
6.00
8.00
10.00
12.00
14.00
16.00
18.00
20.00
22.00
24.00
26.00
28.00
30.00
32.00
34.00
36.00
38.00
40.00

PEtOH (kPa)

PH2O (kPa)

CpEtOH (l)

CpH2O (l)

CpEtOH (v)

CpH2O (v)

1.545
1.783
2.052
2.356
2.698
3.083
3.515
3.999
4.539
5.141
5.812
6.557
7.382
8.296
9.306
10.420
11.646
12.994
14.473
16.094
17.868

0.609
0.704
0.811
0.933
1.071
1.226
1.401
1.597
1.817
2.063
2.337
2.643
2.983
3.361
3.780
4.243
4.755
5.320
5.942
6.626
7.377

2.537
2.533
2.529
2.524
2.520
2.515
2.509
2.504
2.498
2.493
2.487
2.481
2.475
2.468
2.462
2.456
2.449
2.442
2.436
2.429
2.422

25.378
25.453
25.534
25.620
25.711
25.808
25.911
26.019
26.133
26.252
26.377
26.508
26.644
26.785
26.932
27.085
27.243
27.407
27.576
27.751
27.931

17.965
17.970
17.974
17.979
17.984
17.988
17.993
17.997
18.002
18.006
18.011
18.016
18.020
18.025
18.029
18.034
18.038
18.043
18.047
18.052
18.057

7.183
7.178
7.173
7.168
7.162
7.157
7.151
7.145
7.139
7.133
7.127
7.121
7.115
7.109
7.102
7.096
7.089
7.082
7.076
7.069
7.062

7.682
7.688
7.693
7.699
7.705
7.711
7.716
7.722
7.728
7.734
7.739
7.745
7.751
7.757
7.763
7.768
7.774
7.780
7.786
7.791
7.797

42.00

19.806

8.200

2.415

28.117

18.061

7.055

7.803

44.00
46.00
48.00
50.00
52.00
54.00
56.00
58.00
60.00
62.00
64.00
66.00
68.00
70.00
72.00
74.00
76.00
78.00
80.00
82.00
84.00
86.00
88.00

21.921
24.224
26.730
29.453
32.407
35.608
39.073
42.818
46.861
51.222
55.918
60.971
66.401
72.230
78.482
85.180
92.347
100.010
108.195
116.929
126.240
136.158
146.711

9.102
10.087
11.163
12.337
13.614
15.004
16.513
18.150
19.924
21.844
23.920
26.161
28.578
31.182
33.986
37.000
40.237
43.710
47.434
51.422
55.688
60.249
65.119

2.408
2.401
2.394
2.387
2.380
2.373
2.366
2.359
2.352
2.345
2.338
2.331
2.323
2.316
2.309
2.302
2.295
2.288
2.281
2.274
2.267
2.260
2.253

28.309
28.506
28.708
28.916
29.130
29.349
29.574
29.804
30.040
30.282
30.528
30.781
31.039
31.303
31.572
31.847
32.127
32.413
32.704
33.001
33.303
33.612
33.925

18.066
18.070
18.075
18.079
18.084
18.088
18.093
18.097
18.102
18.106
18.111
18.115
18.120
18.124
18.129
18.133
18.138
18.142
18.147
18.151
18.156
18.160
18.165

7.048
7.040
7.033
7.025
7.018
7.010
7.002
6.995
6.987
6.979
6.970
6.962
6.954
6.945
6.937
6.928
6.920
6.911
6.902
6.893
6.884
6.875
6.865

7.809
7.814
7.820
7.826
7.832
7.837
7.843
7.849
7.855
7.861
7.866
7.872
7.878
7.884
7.889
7.895
7.901
7.907
7.912
7.918
7.924
7.930
7.935

90.00
92.00
94.00
96.00
98.00
100.00

157.932
169.851
182.503
195.919
210.137
225.190

70.317
75.857
81.759
88.040
94.719
101.817

2.246
2.239
2.232
2.225
2.219
2.212

34.244
34.569
34.899
35.235
35.576
35.923

18.169
18.174
18.178
18.183
18.187
18.191

6.856
6.847
6.837
6.827
6.818
6.808

7.941
7.947
7.953
7.958
7.964
7.970

2.384

29.518

18.079

7.015

7.826

in.
25% mol de etanol.
el 5% mol de etanol.
acin es de:
y el calor

estilado
kgmol/h
frac mol EtOH
C
kPa
Kcal/Kg mol
frac mol agua
kgmol EtOH/h
kgmol agua/h
Kcal/Kg mol K

28.777

9921.665

Kcal/Kg mol

18.065

10410.868

Kcal/Kg mol K

Kcal/h

Fondo
kgmol/h
frac mol EtOH
C
kPa
Kcal/Kg mol
frac mol agua
kgmol EtOH/h
kgmol agua/h
Kcal/Kg mol K

Kcal/h

HVap,EtOH

HVap,H2O

10714.866
10681.717
10648.395
10614.899
10581.226
10547.373
10513.338
10479.118
10444.712
10410.115
10375.325
10340.340
10305.157
10269.772
10234.183
10198.386
10162.379
10126.158
10089.720
10053.061
10016.177

10918.897
10896.973
10874.975
10852.903
10830.755
10808.532
10786.233
10763.856
10741.402
10718.869
10696.257
10673.565
10650.792
10627.938
10605.002
10581.982
10558.879
10535.691
10512.418
10489.059
10465.613

9979.066

10442.079

9941.724
9904.146
9866.330
9828.270
9789.962
9751.404
9712.589
9673.515
9634.175
9594.566
9554.682
9514.520
9474.072
9433.335
9392.302
9350.968
9309.328
9267.374
9225.102
9182.505
9139.575
9096.307
9052.693

10418.456
10394.743
10370.940
10347.046
10323.059
10298.979
10274.805
10250.535
10226.170
10201.707
10177.147
10152.487
10127.726
10102.865
10077.901
10052.833
10027.661
10002.384
9976.999
9951.506
9925.904
9900.191
9874.367

Constantes de Antoine (T C, P mmHg)

P = 10^(A- (B/(C+T)))
Compuesto
A
B
Etanol
8.04494
1554.3
Agua
8.10765
1750.286

Constantes de Cp (liq) (T K)
(Cp/R) = A + BT + CT2
Compuesto
A
B
33.866
-1.73E-01
Etanol
Agua
8.712
1.26E-03
Constantes de Cp (vap) (T K)
(Cp/R) = A + BT + CT2
Compuesto
A
B
3.518
2.00E-03
Etanol
Agua
3.47
1.45E-03

C
222.65
235

C
3.49E-04

-1.80E-07

C
-6.02E-06

0.00E+00

Hvap (T K)

Hv,2 = Hv,1 ((1-Tr2)/(1-Tr1))0.375

Compuesto

Tc

Tb

Hvap,Tb

Etanol
Agua

516.20

351.50

647.3

373.15

9260.00
9717.00

9008.726
8964.399
8919.703
8874.630
8829.173
8783.323

9848.430
9822.378
9796.210
9769.926
9743.523
9717.000

9801.076

10336.991

Diagrama de equilibrio del sistema Etanol-Agua, P = 101.325 kPa

y, fraccin mol del etanol en el vapor

x, Fraccin mol del etanol en el lquido

Diagonal

L.Op.Enr.

L.Op.Emp

Etapas

RECTIFICACION DE UNA MEZCLA DE ETANOL-AGUA

Se desea destilar una mezcla lquida de etanol-agua en una torre fraccionadora a 101.325 kPa de presin.
La alimentacin es de 100 kg mol/h y est en estado lquido, a una temperatura de 40C y contiene el 25% mol de etanol.
Para este proceso se desea obtener un destilado que contenga el 86% mol de etanol y un residuo con el 5% mol de etanol.
La relacin de reflujo a usar en este proceso es de 3:1. La capacidad calorfica promedio de la alimentacin es de:
y el
calor latente promedio es de
kJ/kg mol.
Calcular: (1) Flujo de destilado, (2) Flujo de residuos, (3) Nmero de platos y Plato de alimentacin.

Datos Inciales del problema

kg mol/h
F* =
100.00
xF =
Kg mol EtOH/kg mol tot
0.1500
PF =
kPa
101.33
TF =

90.00

yV =

0.9000

Kg mol EtOH/kg mol tot

xL =

0.0500

Kg mol EtOH/kg mol tot

R=

0.47

0.47

Cp*F,prom =

19.79

Kcal/ kg mol K

H*Vap =

10317.63
9892.321

Kcal/ kg mol

10392.688

Alimentacin
F* = 100.00
xF = 0.1500
TF = 90.00
PF = 101.33
H*F = 1770.35
(1- xF) = 0.8500
F* xF = 15.00

kgmol/h
frac mol Et
C

Destilado
D* = 11.76 kgmol/h
yD = 0.9000 frac mol EtOH
TD =

87.80

PD = 101.33
H*D = ###
(1- yD) = 0.1000
D* yD = 10.59
D*(1-yD) =
Cp*D,L =

1.18
27.64

H*Vap = 9980.50

C
kPa
Kcal/Kg mol
frac mol agua
kgmol EtOH/h
kgmol agua/h
Kcal/Kg mol

28.708

9931.99

Kcal/Kg mol

18.064

10417.13

L* =

5.53

kgmol/h

D* H*D =

###

Kcal/h

kPa
Kcal/Kg mo
frac mol ag
kgmol EtOH/h

F* (1-xF) =

85.00

kgmol agua

Cp*F =

19.67

Kcal/Kg mol

28.766
18.065

Fondo

TB,F =

94.05

W* = 88.24
xw = 0.0500

kgmol/h
frac mol EtOH

F* H*F =

###

Cp*F,TB =

19.70

TW =

Kcal/h

=
Kcal/KgQ
mol

28.945

87.80

-F* H*F + L* H*L + V* H*V PW = 101.33

H*W = 1632.77
112293.77
(1- xW) = 0.9500
W* xW = 4.41

18.069

SOLUCION DEL PROBLEMA

C
kPa
Kcal/Kg mol
frac mol agua
kgmol EtOH/h

1. Clculo del valor TB,R :

94.05

W*(1-xW) =

83.82

kgmol agua/h

Clculo del valor TR,F :

99.10

Cp*W =

18.60

Kcal/Kg mol K

2. Clculo del valor H*F,Lsat: 1970.023 Kcal/kg mol

3. Clculo del valor q : 1.02392
4. Pendiente de q :

42.806

5. Pendiente de L.Op. Enriquec.:

6. Interc. de L.Op. Enriquec.:

0.3197
0.6122

7. Trazado de L.Op. Enriquec.:

8. Trazado de Linea "q" :

9. Calc. Interc. L.Op.E. y L. "q" :

9. Trazado de L.Op. Empobrecim. :

10. Trazado de las etapas :

y = -44.101x4 + 20.522x3 + 2.4092x2 - 6.6426x + 100

Adimens.
Adimens.

W* H*W =

###

Kcal/h

5'. Pendiente Mnima de L.Op.

Enriquec.:
5b. Valor mnimo de reflujo.:

Eje X

Eje Y

0.900
0.100

0.900
0.644

Eje X

Eje Y

0.150
0.163

0.150
0.685

Eje X

Eje Y

0.1620

0.6640

Eje X

Eje Y

0.050
0.162

0.050
0.664

Eje X

Eje Y

0.9000
0.7450
0.7450
0.4450
0.4450
0.2300
0.2300
0.1570

0.9000
0.9000
0.8480
0.8480
0.7480
0.7480
0.6760
0.6760

0.3160
0.4620

y*xF = 0.6630
6. Interc. de L.Op. Enriquec.:

0.6156

11. Clculo del V* y de L* :

0.1570
0.1270
0.1270
0.0690
0.0690
0.0170
0.0170

0.6250
0.6250
0.4650
0.4650
0.1500
0.1500
0.0000

11.765
88.235

kgmol/h
kgmol/h

Kcal/Kg mol K

Prom

CpEtOH (l)

CpH2O (l)

2.537
2.535
2.533
2.531
2.529
2.527
2.524
2.522
2.520
2.517
2.515
2.512
2.509
2.507
2.504
2.501
2.498
2.496
2.493
2.490
2.487
2.484

2.536
2.535
2.534
2.533
2.532
2.531
2.530
2.529
2.528
2.526
2.525
2.524
2.523
2.522
2.520
2.519
2.518
2.516
2.515
2.514
2.512

25.378
25.415
25.453
25.493
25.534
25.576
25.620
25.665
25.711
25.759
25.808
25.859
25.911
25.964
26.019
26.075
26.133
26.192
26.252
26.314
26.377
26.442

17.965
17.968
17.970
17.972
17.974
17.977
17.979
17.981
17.984
17.986
17.988
17.990
17.993
17.995
17.997
18.000
18.002
18.004
18.006
18.009
18.011
18.013

25.397
25.416
25.435
25.455
25.475
25.496
25.517
25.538
25.560
25.583
25.606
25.629
25.653
25.678
25.703
25.728
25.754
25.780
25.807
25.834
25.861

2.643

2.481

2.511

26.508

18.016

2.809
2.983

2.478
2.475

2.510
2.508

26.575
26.644

18.018
18.020

PEtOH (kPa)

PH2O (kPa)

0.00
1.00
2.00
3.00
4.00
5.00
6.00
7.00
8.00
9.00
10.00
11.00
12.00
13.00
14.00
15.00
16.00
17.00
18.00
19.00
20.00
21.00

1.545
1.660
1.783
1.913
2.052
2.199
2.356
2.522
2.698
2.885
3.083
3.293
3.515
3.750
3.999
4.261
4.539
4.832
5.141
5.468
5.812
6.175

0.609
0.655
0.704
0.756
0.811
0.870
0.933
1.000
1.071
1.146
1.226
1.311
1.401
1.496
1.597
1.704
1.817
1.936
2.063
2.196
2.337
2.486

22.00

6.557

23.00
24.00

6.959
7.382

H*V,EtOH

H*V,H2O

H*V,EtOH,Pr

17.966
17.968
17.969
17.970
17.971
17.972
17.973
17.974
17.976
17.977
17.978
17.979
17.980
17.981
17.982
17.984
17.985
17.986
17.987
17.988
17.989

10714.87
10698.31
10681.72
10665.08
10648.40
10631.67
10614.90
10598.08
10581.23
10564.32
10547.37
10530.38
10513.34
10496.25
10479.12
10461.94
10444.71
10427.44
10410.11
10392.74
10375.33
10357.86

10918.90
10907.94
10896.97
10885.98
10874.97
10863.95
10852.90
10841.84
10830.76
10819.65
10808.53
10797.39
10786.23
10775.05
10763.86
10752.64
10741.40
10730.15
10718.87
10707.57
10696.26
10684.92

10706.59
10698.30
10689.99
10681.67
10673.34
10664.99
10656.63
10648.25
10639.86
10631.45
10623.03
10614.59
10606.14
10597.67
10589.19
10580.69
10572.17
10563.64
10555.10
10546.54
10537.96

25.890

17.990

10340.34 10673.56

10529.37

25.918
25.947

17.992
17.993

10322.77 10662.19
10305.16 10650.79

10520.76
10512.14

CpEtOH,Pr (l) CpH2O,Pr (l)

25.00
26.00
27.00
28.00
29.00
30.00
31.00
32.00
33.00
34.00
35.00
36.00
37.00
38.00
39.00
40.00
41.00
42.00
43.00
44.00
45.00
46.00
47.00
48.00
49.00
50.00
51.00
52.00
53.00
54.00
55.00
56.00
57.00
58.00
59.00
60.00
61.00
62.00

7.828
8.296
8.789
9.306
9.849
10.420
11.018
11.646
12.304
12.994
13.716
14.473
15.265
16.094
16.962
17.868
18.816
19.806
20.841
21.921
23.048
24.224
25.451
26.730
28.064
29.453
30.900
32.407
33.976
35.608
37.307
39.073
40.909
42.818
44.801
46.861
49.001
51.222

3.167
3.361
3.565
3.780
4.006
4.243
4.493
4.755
5.031
5.320
5.624
5.942
6.276
6.626
6.993
7.377
7.779
8.200
8.641
9.102
9.584
10.087
10.614
11.163
11.737
12.337
12.962
13.614
14.295
15.004
15.743
16.513
17.315
18.150
19.020
19.924
20.865
21.844

2.472
2.468
2.465
2.462
2.459
2.456
2.452
2.449
2.446
2.442
2.439
2.436
2.432
2.429
2.426
2.422
2.419
2.415
2.412
2.408
2.405
2.401
2.398
2.394
2.391
2.387
2.384
2.380
2.377
2.373
2.370
2.366
2.363
2.359
2.356
2.352
2.348
2.345

2.507
2.505
2.504
2.502
2.501
2.500
2.498
2.497
2.495
2.494
2.492
2.491
2.489
2.487
2.486
2.484
2.483
2.481
2.480
2.478
2.476
2.475
2.473
2.472
2.470
2.468
2.467
2.465
2.464
2.462
2.460
2.459
2.457
2.455
2.454
2.452
2.450
2.449

26.714
26.785
26.858
26.932
27.008
27.085
27.163
27.243
27.324
27.407
27.491
27.576
27.663
27.751
27.840
27.931
28.023
28.117
28.212
28.309
28.406
28.506
28.606
28.708
28.811
28.916
29.022
29.130
29.239
29.349
29.461
29.574
29.688
29.804
29.921
30.040
30.160
30.282

18.022
18.025
18.027
18.029
18.032
18.034
18.036
18.038
18.041
18.043
18.045
18.047
18.050
18.052
18.054
18.057
18.059
18.061
18.063
18.066
18.068
18.070
18.072
18.075
18.077
18.079
18.081
18.084
18.086
18.088
18.091
18.093
18.095
18.097
18.100
18.102
18.104
18.106

25.977
26.007
26.037
26.068
26.099
26.131
26.163
26.196
26.229
26.263
26.297
26.331
26.366
26.402
26.438
26.474
26.511
26.549
26.586
26.625
26.663
26.703
26.742
26.782
26.823
26.864
26.906
26.947
26.990
27.033
27.076
27.120
27.164
27.209
27.254
27.300
27.346
27.393

17.994
17.995
17.996
17.997
17.998
18.000
18.001
18.002
18.003
18.004
18.005
18.006
18.008
18.009
18.010
18.011
18.012
18.013
18.014
18.016
18.017
18.018
18.019
18.020
18.021
18.022
18.024
18.025
18.026
18.027
18.028
18.029
18.030
18.031
18.033
18.034
18.035
18.036

10287.49
10269.77
10252.00
10234.18
10216.31
10198.39
10180.41
10162.38
10144.30
10126.16
10107.97
10089.72
10071.42
10053.06
10034.65
10016.18
9997.65
9979.07
9960.42
9941.72
9922.96
9904.15
9885.27
9866.33
9847.33
9828.27
9809.15
9789.96
9770.71
9751.40
9732.03
9712.59
9693.08
9673.51
9653.88
9634.18
9614.40
9594.57

10639.38
10627.94
10616.48
10605.00
10593.50
10581.98
10570.44
10558.88
10547.30
10535.69
10524.07
10512.42
10500.75
10489.06
10477.35
10465.61
10453.86
10442.08
10430.28
10418.46
10406.61
10394.74
10382.85
10370.94
10359.00
10347.05
10335.06
10323.06
10311.03
10298.98
10286.90
10274.80
10262.68
10250.54
10238.36
10226.17
10213.95
10201.71

10503.50
10494.84
10486.17
10477.48
10468.77
10460.05
10451.31
10442.56
10433.78
10424.99
10416.19
10407.36
10398.52
10389.67
10380.79
10371.90
10362.99
10354.06
10345.11
10336.15
10327.17
10318.17
10309.15
10300.11
10291.05
10281.98
10272.89
10263.78
10254.64
10245.49
10236.33
10227.14
10217.93
10208.70
10199.46
10190.19
10180.90
10171.59

63.00
64.00
65.00
66.00
67.00
68.00
69.00
70.00
71.00
72.00
73.00
74.00
75.00
76.00
77.00
78.00
79.00
80.00
81.00
82.00
83.00
84.00
85.00
86.00
87.00
88.00
89.00
90.00
91.00
92.00
93.00
94.00
95.00
96.00
97.00
98.00
99.00
100.00

53.526
55.918
58.398
60.971
63.637
66.401
69.264
72.230
75.302
78.482
81.774
85.180
88.703
92.347
96.115
100.010
104.036
108.195
112.492
116.929
121.511
126.240
131.121
136.158
141.353
146.711
152.236
157.932
163.802
169.851
176.083
182.503
189.113
195.919
202.926
210.137
217.556
225.190

22.862
23.920
25.019
26.161
27.347
28.578
29.856
31.182
32.558
33.986
35.466
37.000
38.589
40.237
41.943
43.710
45.540
47.434
49.394
51.422
53.519
55.688
57.931
60.249
62.644
65.119
67.676
70.317
73.043
75.857
78.762
81.759
84.851
88.040
91.329
94.719
98.215
101.817

2.341
2.338
2.334
2.331
2.327
2.323
2.320
2.316
2.313
2.309
2.306
2.302
2.299
2.295
2.292
2.288
2.284
2.281
2.277
2.274
2.270
2.267
2.263
2.260
2.256
2.253
2.249
2.246
2.243
2.239
2.236
2.232
2.229
2.225
2.222
2.219
2.215
2.212

2.447
2.445
2.444
2.442
2.440
2.439
2.437
2.435
2.433
2.432
2.430
2.428
2.427
2.425
2.423
2.421
2.420
2.418
2.416
2.415
2.413
2.411
2.409
2.408
2.406
2.404
2.403
2.401
2.399
2.397
2.396
2.394
2.392
2.391
2.389
2.387
2.385
2.384

30.404
30.528
30.654
30.781
30.909
31.039
31.170
31.303
31.437
31.572
31.709
31.847
31.986
32.127
32.269
32.413
32.558
32.704
32.852
33.001
33.152
33.303
33.457
33.612
33.768
33.925
34.084
34.244
34.406
34.569
34.733
34.899
35.066
35.235
35.405
35.576
35.749
35.923

18.109
18.111
18.113
18.115
18.118
18.120
18.122
18.124
18.127
18.129
18.131
18.133
18.136
18.138
18.140
18.142
18.145
18.147
18.149
18.151
18.154
18.156
18.158
18.160
18.162
18.165
18.167
18.169
18.171
18.174
18.176
18.178
18.180
18.183
18.185
18.187
18.189
18.191

27.440
27.487
27.535
27.584
27.633
27.682
27.732
27.782
27.833
27.884
27.936
27.988
28.040
28.094
28.147
28.201
28.255
28.310
28.366
28.422
28.478
28.535
28.592
28.650
28.708
28.766
28.826
28.885
28.945
29.006
29.066
29.128
29.190
29.252
29.315
29.378
29.442
29.506

18.037
18.038
18.039
18.041
18.042
18.043
18.044
18.045
18.046
18.047
18.048
18.050
18.051
18.052
18.053
18.054
18.055
18.056
18.058
18.059
18.060
18.061
18.062
18.063
18.064
18.065
18.067
18.068
18.069
18.070
18.071
18.072
18.073
18.074
18.076
18.077
18.078
18.079

9574.66
9554.68
9534.64
9514.52
9494.33
9474.07
9453.74
9433.33
9412.86
9392.30
9371.67
9350.97
9330.19
9309.33
9288.39
9267.37
9246.28
9225.10
9203.84
9182.50
9161.08
9139.58
9117.98
9096.31
9074.54
9052.69
9030.75
9008.73
8986.61
8964.40
8942.10
8919.70
8897.21
8874.63
8851.95
8829.17
8806.30
8783.32

10189.44
10177.15
10164.83
10152.49
10140.12
10127.73
10115.31
10102.86
10090.40
10077.90
10065.38
10052.83
10040.26
10027.66
10015.04
10002.38
9989.70
9977.00
9964.27
9951.51
9938.72
9925.90
9913.06
9900.19
9887.29
9874.37
9861.41
9848.43
9835.42
9822.38
9809.31
9796.21
9783.08
9769.93
9756.74
9743.52
9730.28
9717.00

10162.27
10152.92
10143.55
10134.16
10124.75
10115.32
10105.87
10096.40
10086.91
10077.39
10067.85
10058.30
10048.72
10039.11
10029.49
10019.84
10010.17
10000.48
9990.76
9981.03
9971.27
9961.48
9951.67
9941.84
9931.99
9922.11
9912.20
9902.27
9892.32
9882.34
9872.34
9862.31
9852.26
9842.18
9832.08
9821.95
9811.79
9801.61

2.384

29.506

18.079

9801.61

10337.19

H*V,H2O,Pr
10913.42
10907.94
10902.45
10896.95
10891.45
10885.95
10880.43
10874.91
10869.39
10863.85
10858.32
10852.77
10847.22
10841.66
10836.10
10830.53
10824.95
10819.37
10813.78
10808.18
10802.58
10796.97
10791.35
10785.73

Constantes de Antoine (T C, P mmHg)

P = 10^(A- (B/(C+T)))
Compuesto
A
B
Etanol
8.04494
1554.3
Agua

8.10765

1750.286

Constantes de Cp (liq) (T K)
(Cp/R) = A + BT + CT2
Compuesto
A
B
33.866
-1.73E-01
Etanol
Agua
8.712
1.26E-03
Constantes de Cp (vap) (T K)
(Cp/R) = A + BT + CT2
Compuesto
A
B
3.518
2.00E-03
Etanol
Agua
3.47
1.45E-03

C
222.65
235

C
3.49E-04

-1.80E-07

C
-6.02E-06

0.00E+00

Hvap (T K)

Hv,2 = Hv,1 ((1-Tr2)/(1-Tr1))0.375

Compuesto

Tc

Tb

Hvap,Tb

Etanol

516.20

351.50

9260.00

10780.10
10774.47
10768.82
10763.18
10757.52
10751.86
10746.19
10740.51
10734.83
10729.14
10723.44
10717.74
10712.03
10706.31
10700.59
10694.86
10689.12
10683.37
10677.62
10671.86
10666.10
10660.32
10654.54
10648.75
10642.96
10637.16
10631.35
10625.53
10619.71
10613.88
10608.04
10602.19
10596.34
10590.48
10584.61
10578.73
10572.85
10566.96

Agua

647.3

373.15

9717.00

10561.06
10555.15
10549.24
10543.32
10537.39
10531.45
10525.50
10519.55
10513.59
10507.62
10501.65
10495.66
10489.67
10483.67
10477.66
10471.65
10465.62
10459.59
10453.55
10447.50
10441.44
10435.38
10429.30
10423.22
10417.13
10411.03
10404.93
10398.81
10392.69
10386.56
10380.41
10374.27
10368.11
10361.94
10355.76
10349.58
10343.39
10337.19

Diagrama de equilibrio del sistema Etanol-Agua, P = 101.325 kPa

y, fraccin mol del etanol en el vapor

x, Fraccin mol del etanol en el lquido

Diagonal

L.Op.Enr.

L.Op.Emp

Etapas

PAREJA

xF

yV (xD)

DATOS
xW

1
2
3
4
5
6
7
8
9
10
11

0.25
0.25
0.25
0.35
0.35
0.35
0.4
0.4
0.45
0.45
0.45

0.88
0.88
0.88
0.94
0.94
0.94
0.95
0.95
0.96
0.96
0.96

0.08
0.08
0.08
0.12
0.12
0.12
0.15
0.15
0.18
0.18
0.18

TF

R
4
2
1
4
2
1
4
2
4
2
1

60
91
95
85
88.3
93
80
87.05
80
85.9
90

H F ,V L H F , L sat H L , TB ...TF Z L (1 Z L )HVap,T

Andrea + Veronica
Tzitzijani + Yadira
Diana + Alejandro
Gaby + Maricruz
Alexandra + Mariela
Carolina + Martha
Maricarmen + Lorena
Nayeli + Ricardo
Silvia Yol + Manuel Ale
Oscar

TF

PAREJA 1
Valor de la pendiente de L.Op.Enr.
Valor del Intercepto de L.Op.Enr.

Valor de q =
Valor de la pendiente de Linea "q"
Valor del Intercepto de Linea "q"

0.800
0.1760

1.066
16.256174
-3.814044

Soluc. De la Ec. L.Op.Enr. Y Lnea "q"

PAREJA 2

L. Op. De la zona de Enr.

Eje X

Eje Y

0.880
0.200

0.880
0.336

Linea "q"

0.667
0.2933

Valor del Intercepto de L.Op.Empobr.

Trazado de las etapas:

Clculo de la fraccin de etapa:

1.698
-0.0558

Eje X

0.880
0.200

1.000

Linea "q"

Eje X

Eje Y

Eje X

0.250
0.260

0.250000
0.412562

0.250
0.250

Valor x

Valor y

Valor x

0.258

0.382522

0.250

L.Op. Z. Empobrec.
Valor de la pendiente de L.Op.Empobr.

L. Op. De la zona de Enr

Eje X

Eje Y

0.080
0.258

0.080000
0.382522

L.Op. Z. Empobrec.

2.235
-0.0988

Eje X

0.080
0.250

Eje X

Eje Y

Eje X

0.880
0.617
0.617
0.155
0.155
0.025
0.025

0.880000
0.880000
0.669600
0.669600
0.207358
0.207358
-0.013396

0.880
0.617
0.617
0.184
0.184
0.039
0.039

Area de la ltima etapa total

Area de la frac. De etapa ltima
Fraccin de etapa ltima

0.01434902
0.01178063
0.82100592

0.02349853
0.01656094
0.704765

TB

TR

91
91
91
88.3
88.3
88.3
87.05
87.05
85.9
85.9
85.9

98.8
98.8
98.8
98.8
98.35
98.35
97.9
97.9
97.4
97.4
97.4

PAREJA 2

HF

HL

HV

1221.016 1891.6952 12123.696

1891.6952 1891.6952 12123.696
4344.6563 1891.6952 12123.696
1848.5374 1925.8906 12123.696
1925.8906 1925.8906 12123.696
5047.199 1925.8906 12123.696
1772.6393 1943.1033 12123.696
1943.1033 1943.1033 12123.696
1813.6555 1960.8459 12123.696
1960.8459 1960.8459 12123.696
5231.765 1960.8459 12123.696

PAREJA 3

. Op. De la zona de Enr.

Eje Y

0.500
0.4400

0.880
0.427

0.760
Eje Y
-3.171285
0.250000 1.0428213

Linea "q"

ZL

0.7500

0.6790

Eje X

Eje Y

0.880
0.150

0.880
0.515

0.800
0.1880

1.008
Eje Y
132.83429
0.250000 -46.142

Linea "q"

PAREJA 5

L. Op. De la zona de Enr.

Eje X

Eje Y

0.940
0.150

0.940
0.308

Eje X

Eje Y

0.567129

0.3500
0.3515

0.350000
0.549251

Valor y

Valor x

Valor y

Valor x

Valor y

0.460000

0.164

0.522099

0.35089

0.468715

0.080000
0.460000

L.Op. Z. Empobrec.

5.251
-0.3401

Eje X

Eje Y

0.080
0.164

0.080000
0.522099

0.667
0.3133

1.000

Linea "q"

0.250
0.150

Eje Y

2.821
2.705
2.377
4.089
4.862
5.974
4.964
5.575
6.966
8.547

0.6593

0.500000

L.Op. Z. Empobrec.

NTeo

PAREJA 4

L. Op. De la zona de Enr.

Eje X

q
1.066
1.000
0.7603
1.008
1.000
0.6939
1.017
1
1.014
1
0.6781

L.Op. Z. Empobrec.

1.510
-0.0612

Eje X

Eje Y

0.12000
0.35089

0.120000
0.468715

Eje Y

Eje X

Eje Y

Eje X

Eje Y

0.880000
0.880000
0.704667
0.704667
0.312471
0.312471
-0.011647

0.880
0.617
0.617
0.232
0.232
0.096
0.096
0.020
0.020

0.880000
0.880000
0.748500
0.748500
0.556000
0.556000
0.164010
0.164010
-0.235039

0.940
0.915
0.915
0.850
0.850
0.545
0.545
0.125
0.125
0.015
0.015

0.940000
0.940000
0.920000
0.920000
0.868000
0.868000
0.624000
0.624000
0.127551
0.127551
-0.038580

1.855
-0.1026

0.01516388
0.00571271
0.3767313

0.00913722
0.00081178
0.08884298

0.03784719
0.0326298
0.86214587

NReal

PAREJA 5

PAREJA 6

L. Op. De la zona de Enr.

Eje X

Eje Y

0.940
0.150

0.940
0.413

0.500
0.4700

0.694
Eje Y
-2.267157
0.350000 1.143505

Linea "q"
Eje X

0.350
0.350

PAREJA 7

L. Op. De la zona de Enr.

Eje X

Eje Y

0.940
0.150

0.940
0.545

0.800
0.1900

1.017
Eje Y
60.722832
0.350000 -23.88913

Linea "q"
Eje X

L. Op. De la zona de Enr.

Eje X

Eje Y

0.950
0.150

0.950
0.310

Linea "q"
Eje X

Eje Y

0.644730

0.400
0.402

0.400000
0.521446

0.546667

0.350
0.220

Valor x

Valor y

Valor x

Valor y

Valor x

Valor y

0.350

0.546667

0.243

0.591696

0.402

0.511469

L.Op. Z. Empobrec.
Eje X

Eje Y

0.120
0.350

0.120000
0.546667

L.Op. Z. Empobrec.

3.823
-0.3387

Eje X

Eje Y

0.120
0.243

0.120000
0.591696

L.Op. Z. Empobrec.

1.435
-0.0653

Eje X

Eje Y

0.150
0.402

0.150000
0.511469

Eje X

Eje Y

Eje X

Eje Y

Eje X

Eje Y

0.940
0.915
0.915
0.862
0.862
0.668
0.668
0.247
0.247
0.045
0.045

0.940000
0.940000
0.923333
0.923333
0.888000
0.888000
0.758667
0.758667
0.355594
0.355594
-0.019130

0.940
0.915
0.915
0.878
0.878
0.802
0.802
0.558
0.558
0.235
0.235
0.098

0.940000
0.940000
0.927500
0.927500
0.909000
0.909000
0.871000
0.871000
0.749000
0.749000
0.559614
0.559614

0.950
0.933
0.933
0.905
0.905
0.823
0.823
0.450
0.450
0.094
0.094

0.950000
0.950000
0.936400
0.936400
0.914000
0.914000
0.848400
0.848400
0.550000
0.550000
0.069621

0.03587444
0.03494934
0.9742128

0.098

0.035900 0.08550742
0.0824
0.96365908

PAREJA 8
0.667
0.3167

1.000

PAREJA 9

L. Op. De la zona de Enr.

Eje X

Eje Y

0.950
0.150

0.950
0.417

0.800
0.1920

1.014
Eje Y
70.045589
0.400000 -31.07051

Linea "q"
Eje X

L. Op. De la zona de Enr.

Eje X

Eje Y

0.960
0.150

0.960
0.312

Linea "q"

0.667
0.3200

L. Op. De la zona de Enr.

Eje X

0.960
0.150

1.000

Linea "q"

Eje X

Eje Y

Eje X

0.583333

0.450
0.452

0.450000
0.590091

0.450
0.450

Valor x

Valor y

Valor x

Valor y

Valor x

0.400

0.583333

0.451

0.553178

0.450

0.400
0.400

L.Op. Z. Empobrec.

1.733
-0.1100

PAREJA 10

Eje X

Eje Y

0.150
0.400

0.150000
0.583333

L.Op. Z. Empobrec.

1.375
-0.0674

Eje X

Eje Y

0.180
0.451

0.180000
0.553178

L.Op. Z. Empobrec.

1.630
-0.1133

Eje X

0.180
0.450

Eje X

Eje Y

Eje X

Eje Y

Eje X

0.950
0.933
0.933
0.905
0.905
0.845
0.845
0.624
0.624
0.214
0.214
0.030

0.950000
0.950000
0.938667
0.938667
0.920000
0.920000
0.880000
0.880000
0.732667
0.732667
0.260933
0.260933

0.960
0.955
0.955
0.945
0.945
0.931
0.931
0.906
0.906
0.8415
0.8415
0.5300

0.960000
0.960000
0.956000
0.956000
0.948000
0.948000
0.936800
0.936800
0.916800
0.916800
0.865200
0.865200

0.960
0.955
0.955
0.947
0.947
0.936
0.936
0.922
0.922
0.9000
0.9000
0.8500

0.02934187
0.01686187
0.57466919

0.030

-0.058000 0.10467117
0.101152
0.96637882

0.5300
0.1230
0.1230

0.616000 0.03731526
0.616000 0.02041926
0.101645 0.54720936

0.8500
0.6600
0.6600
0.2500
0.2500
0.0360
0.0360

AREJA 10

PAREJA 11

. Op. De la zona de Enr.

Eje Y

0.500
0.4800

0.960
0.420

0.678
Eje Y
-2.107032
0.450000 1.3981643

Linea "q"

L. Op. De la zona de Enr.

Eje X

Eje Y

0.960
0.150

0.960
0.555

Linea "q"
Eje X

Eje Y

0.620000

0.450
0.330

0.450000
0.702844

Valor y

Valor x

Valor y

0.620000

0.352

0.656094

L.Op. Z. Empobrec.
Eje Y

0.180000
0.620000

L.Op. Z. Empobrec.

2.765
-0.3177

Eje X

Eje Y

0.180
0.352

0.180000
0.656094

Eje Y

Eje X

Eje Y

0.960000
0.960000
0.956667
0.956667
0.951333
0.951333
0.944000
0.944000
0.934667
0.934667
0.920000
0.920000

0.960
0.955
0.955
0.947
0.947
0.936
0.936
0.922
0.922
0.9000
0.9000
0.8500

0.960000
0.960000
0.957500
0.957500
0.953500
0.953500
0.948000
0.948000
0.941000
0.941000
0.930000
0.930000

0.886667 0.000049
0.886667 -0.430392
0.760000 -8783.5102
0.760000
0.294074
0.294074
-0.054667

0.8500
0.6600
0.6600
0.2500
0.2500
0.0360
0.0360

0.905000
0.905000
0.810000
0.810000
0.373548
0.373548
-0.218156

1.00
Diagrama
de equilibrio del sistema Etanol-Agua, P = 101.325 kPa
0.95
0.90
0.85
0.80
0.75
0.70
0.65
0.60
0.55
0.50
y, fraccin mol del etanol en el vapor
0.45
0.40
0.35
0.30
0.25
0.20
0.15
0.10
0.05
0.00
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.00

-0.05
x, Fraccin mol
del etanol en el lquido
Diagonal
L.Op. Enr.

1.00
Diagrama
de equilibrio del sistema Etanol-Agua, P = 101.325 kPa
0.95
0.90
0.85
0.80
0.75
0.70
0.65
0.60
0.55
0.50
y, fraccin mol del etanol en el vapor
0.45
0.40
0.35
0.30
0.25
0.20
0.15
0.10
0.05
0.00
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.00

-0.05
x, Fraccin mol del etanol en el lquido
Diagonal

1.00
Diagrama
de equilibrio del sistema Etanol-Agua, P = 101.325 kPa
0.95
0.90
0.85
0.80
0.75
0.70
0.65
0.60
0.55
0.50
y, fraccin mol del etanol en el vapor
0.45
0.40
0.35
0.30
0.25
0.20
0.15
0.10
0.05
0.00
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.00

-0.05
x, Fraccin mol del etanol en el lquido
Diagonal

1.00
Diagrama
de equilibrio del sistema Etanol-Agua, P = 101.325 kPa
0.95
0.90
0.85
0.80
0.75
0.70
0.65
0.60
0.55
0.50
y, fraccin mol del etanol en el vapor
0.45
0.40
0.35
0.30
0.25
0.20
0.15
0.10
0.05
0.00
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.00

-0.05
x, Fraccin mol del etanol en el lquido
Diagonal

1.00
Diagrama
de equilibrio del sistema Etanol-Agua, P = 101.325 kPa
0.95
0.90
0.85
0.80
0.75
0.70
0.65
0.60
0.55
0.50
y, fraccin mol del etanol en el vapor
0.45
0.40
0.35
0.30
0.25
0.20
0.15
0.10
0.05
0.00
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.00

-0.05
x, Fraccin mol del etanol en el lquido
Diagonal

1.00
Diagrama
de equilibrio del sistema Etanol-Agua, P = 101.325 kPa
0.95
0.90
0.85
0.80
0.75
0.70
0.65
0.60
0.55
0.50
y, fraccin mol del etanol en el vapor
0.45
0.40
0.35
0.30
0.25
0.20
0.15
0.10
0.05
0.00
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.00

-0.05
x, Fraccin mol del etanol en el lquido
Diagonal

1.00
Diagrama
de equilibrio del sistema Etanol-Agua, P = 101.325 kPa
0.95
0.90
0.85
0.80
0.75
0.70
0.65
0.60
0.55
0.50
y, fraccin mol del etanol en el vapor
0.45
0.40
0.35
0.30
0.25
0.20
0.15
0.10
0.05
0.00
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.00

-0.05
x, Fraccin mol del etanol en el lquido
Diagonal

1.00
Diagrama
de equilibrio del sistema Etanol-Agua, P = 101.325 kPa
0.95
0.90
0.85
0.80
0.75
0.70
0.65
0.60
0.55
0.50
0.45 mol del etanol en el vapor
y, fraccin
0.40
0.35
0.30
0.25
0.20
0.15
0.10
0.05
0.00
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.00

-0.05
-0.10
x, Fraccin mol del etanol en el lquido
Diagonal

1.00
Diagrama
de equilibrio del sistema Etanol-Agua, P = 101.325 kPa
0.95
0.90
0.85
0.80
0.75
0.70
0.65
0.60
0.55
0.50
y, fraccin mol del etanol en el vapor
0.45
0.40
0.35
0.30
0.25
0.20
0.15
0.10
0.05
0.00
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.00

-0.05
x, Fraccin mol del etanol en el lquido
Diagonal

1.00
Diagrama
de equilibrio del sistema Etanol-Agua, P = 101.325 kPa
0.95
0.90
0.85
0.80
0.75
0.70
0.65
0.60
0.55
0.50
0.45 mol del etanol en el vapor
y, fraccin
0.40
0.35
0.30
0.25
0.20
0.15
0.10
0.05
0.00
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.00

-0.05
-0.10
x, Fraccin mol del etanol en el lquido
Diagonal

1.00
Diagrama
de equilibrio del sistema Etanol-Agua, P = 101.325 kPa
0.95
0.90
0.85
0.80
0.75
0.70
0.65
0.60
0.55
0.50
0.45 mol del etanol en el vapor
y, fraccin
0.40
0.35
0.30
0.25
0.20
0.15
0.10
0.05
0.00
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.00

-0.05
-0.10
x, Fraccin mol
del etanol en el lquido
Diagonal
L.Op. Enr.