Академический Документы
Профессиональный Документы
Культура Документы
SPECTRUM
This page explains how to use an infra-red spectrum to identify the
presence of a few simple bonds in organic compounds.
Note: This page follows directly on from the introductory
page on infra-red spectra. If you haven't already done so, you
should read that page before you go on.
pdfcrowd.com
pdfcrowd.com
is that you can ignore a trough just under 3000 cm-1, because that
is probably just due to C-H bonds.
The carbon-oxygen double bond, C=O, is one of the really useful
absorptions, found in the range 1680 - 1750 cm-1. Its position
varies slightly depending on what sort of compound it is in.
The other really useful bond is the O-H bond. This absorbs
differently depending on its environment. It is easily recognised in
an acid because it produces a very broad trough in the range 2500
- 3300 cm-1.
Note: You will never have to remember where these
absorptions occur. You will always be given this data in an
A'level exam.
pdfcrowd.com
pdfcrowd.com
pdfcrowd.com
pdfcrowd.com
You will find that this is very similar to the infra-red spectrum for
ethyl ethanoate, an ester. Again, there is no trough due to the O-H
bond, and again there is a marked absorption at about 1700 cm-1
due to the C=O.
open in browser PRO version
pdfcrowd.com
pdfcrowd.com
pdfcrowd.com
Primary amines contain the -NH2 group, and so have N-H bonds.
These absorb somewhere between 3100 and 3500 cm-1. That
double trough (typical of primary amines) can be seen clearly on
the spectrum to the left of the C-H absorptions.
pdfcrowd.com
pdfcrowd.com