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1. Introduction
The demand for data storage devices has never been
higher due to the exponential growth of new information. Up to now, hard disk drive (HDD) is still
the main storage device among various storage
technologies for its cost per gigabyte of data although solid state memories have gained momentum in personal computers and electronic devices
market.1 On the other hand, the fast developing
cloud storage market provides new demand for
HDD. Over the past several decades, there was
tremendous growth in the areal density of HDDs,
especially since the introduction of the giant magnetoresistance (GMR)2,3 head technology in 1996.
However, the rate of increase started to drop since
2003, partly due to the superparamagnetic behavior
of the longitudinal recording media, which made it
dicult to break 100 Gb/in.2.4 Thus CoCr-based
perpendicular magnetic recording (PMR) with the
magnetic moment of the bit oriented along the lm
normal was introduced to overcome the superparamagnetic eect.5 Moreover, both signal-to-noise
ratio (SNR) and areal density can be improved by
this recording structure. The rst CoCrPt perpendicular recording HDD with areal density of
133 Gbit/in.2 was rst demonstrated by Toshiba in
2004. The transition from longitudinal to perpendicular recording has resulted in rapid growth in
areal density for nearly another decade. However,
with the areal density approaching 1 Tbit/in.2
today, the CoCrPt perpendicular recording media is
still facing the superparamagnetic limit. In order to
overcome this limit on magnetic recording, the exploitation of new technology or new materials is
necessary.
It is well known that increasing the anisotropy
of the media can compensate for the superparamagnetic eect caused by the reduction in grain
size because the anisotropy barrier of magnetization
reversal is proportional to Ku V , where Ku and V are
the uniaxial magnetocrystalline anisotropy and grain
volume, respectively.6 Chemically ordered L10 -alloys
with a face-centered-tetragonal (fct) structure, such
as L10 -Fe(Co)Pt, have become one of the potential
materials due to their high magnetocrystalline anisotropy.7 Thus, L10 -Fe(Co)Pt grains with small
sizes can provide high SNR, which is determined by
the number of grains in each bit (SNR 10log(N),
where N is the number of grains in a bit.).810 However, the high anisotropy results in an increase in
Fig. 1.
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2. Approaches to Enhancing
Thermal Stability
The thermal stability depends on anisotropy barrier,
which is proportional to the Ku value of the material. It is known that Ku of L10 -ordered FePt and
CoPt are 6:6 10 7 erg/cm3 and 4:9 10 7 erg/cm3,
respectively, which are about 20 times higher than
that of CoCrPt used widely in the commercial recording media.6,7 It is estimated that L10 -FePt or
L10 -CoPt is thermally stable even for grain size as
small as 34 nm. If one can obtain such small
grains and write the information on them, L10 Fe(Co)Pt-based media with an ultrahigh areal
density can be readily achieved. Usually, FePt or
CoPt alloy lms deposited at room temperature
are a disordered face-centered-cubic (fcc) phase
that is magnetically soft. A high temperature
treatment, such as in situ substrate heating or
post-deposition annealing at temperatures as high
as 550750 C is necessary to obtain an ordered
L10 -Fe(Co)Pt phase.1315 However, it is dicult to
obtain (001) texture with perpendicular easy axis
orientation because the (111) plane is the closest
packed plane with the lowest surface energy. In
addition, such a high annealing temperature is not
suitable for practical applications. Therefore, many
attempts have been made to induce perfect fct
(001) texture and reduce the ordering temperature.
Here, two typical strategies are introduced to realize this goal, one is stress-assisted phase transformation, and the other is metal-doping-promoted
phase transformation.
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Fig. 3.
(a)
Fig. 4.
(b)
In-plane hysteresis loops of the thin lms: (a) 350 C and (b) 550 C.21
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underlayer results in the formation of the FePt ordered phase with c-axis orientation perpendicular to
the lm plane at a lower substrate temperature of
350 C. Figure 5 shows the out-of-plane and in-plane
hysteresis loops of Cr91 Ru9/Pt/FePt lm deposited
at 400 C.25 A thin Pt intermediate layer between
the FePt layer and the CrRu underlayer is introduced to eectively resist the Cr diusion from the
CrRu underlayer into the FePt layer. The out-ofplane loop shows a coercivity of 3.7 kOe with remanent magnetization squareness of 0.97, while the
in-plane coercivity is only 190 Oe. It indicates that
the fct (001) texture has been achieved at a lower
deposition temperature. They also found that a
critical lattice mismatch near 6.3% to be the most
suitable for improving the chemical ordering of the
FePt lms. Recently (001) textured FePt lm was
obtained on MoC/CrRu/glass at 380 C by using
magnetron sputtering, in which the MoC conductive
intermediate layer was used to resist the Cr diusion
at high deposition temperatures and promote the
epitaxial growth of the (001) texture FePt lm.26 In
addition, the FePt grains can be further separated
by excess carbon from MoC intermediate layer,
resulting in small intergrain exchange interaction.27
Other than these approaches, Bi,28 PtMn,29 and
AuCu30 underlayers were all used to induce the
phase transformation and reduce the ordering temperature of L10 -Fe(Co)Pt alloys. However, Hotta
et al. recently conrmed that there is no marked
dierence in the thickness dependence of Ku in
L10 -FePt (001) single-crystal lms grown epitaxially on dierent substrates, although the lattice
mismatch between FePt and the substrates is
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(a)
(b)
Fig. 7. In-plane coercivity Hc of FePt and (FePt)8Cu15 lms
as a function of the annealing temperature.36
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Fig. 9.
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Fig. 11. Hysteresis loops of samples with dierent structures before (insets) and after annealing at 600 C. Here represents out-ofplane hysteresis loops and represents in-plane ones.61
Fig. 12. Illustration of transition boundaries for the present GPM and PPM. The white dots in the PPM medium indicates
nonmagnetic columnar grains which act as domain wall pinning sites.64
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Fig. 13. Plan-view TEM image of CoPtSiO2 and FePtMgO thin lms. (a) As-deposited CoPtSiO2 lm; (b) annealed CoPtSiO2
lm; (c) (FePt)(MgO)/Pt/Cr lm and (d) FePt/Pt/Cr trilayer lm.67,68
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(a)
(b)
(c)
(d)
Fig. 14. MFM and SEM images of (Co/Pt)/Si (a), (Co/Pt)/AAO/Si lms with pore density of 3:3 10 1 cm 2 (b), and
11:6 10 10 cm 2 (c), (d) is the corresponding out-of-plane and in-plane hysteresis loops of (a) and (c).71
Fig. 15. (a) Initial magnetization states for two types of PPM, (b) domain wall displacement in an increasing eld H. The
magnetization states in (b) correspond to the same eld step H H Hd .72
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system. However, the possibility of controlled pinning of magnetic domain walls at even smaller
length scales, as required for storage densities beyond 10 Tbit/in.2, remains an open question.
In view of the drawbacks of top-down approaches, some bottom-up chemical template methods
were used to prepare BPM,80,81 for which the bits
are formed by electrochemical deposition or sputtering using the self-organized templates. A pioneering work was done by Kim et al. to push the
limit of the areal density of the magnetic nanodot
array.82 Ordered FePt nanodot arrays with a perfect perpendicular easy axis were deposited by
magnetron sputtering into AAO templates followed by a rapid thermal annealing. Figure 17
shows the SEM images, XRD pattern, and hysteresis loops of annealed FePt nanodots array.82
FePt nanodots with diameter of 18 nm and periodicity of 25 nm have been fabricated, resulting
in an areal density exceeding 1 Tbit/in.2. Rapid
thermal annealing converts the disordered fcc to
(001)-oriented L10 -FePt nanodot arrays with perpendicular anisotropy and large coercivity. L10 Fe(Co)Pt nanowires and nanorods were also prepared in AAO templates by electrochemistry
followed by annealing.83,84 These studies show that
self-organized templates are low-cost with high
uniformity and easily controllable structural parameters. In particular, for AAO templates, not only
the diameter and density can be adjusted, but also
the template can withstand high temperature of
Fig. 17. SEM images, XRD pattern, and hysteresis loops of annealed FePt nanodots array with dierent templates.82
650 C,85 which is favorable in fabricating L10 Fe(Co)Pt patterned media. However, it is hard to
obtain templates with small pore sizes less than
10 nm and thin pore wall less than 5 nm. It is thus
unfavorable to realize ultrahigh density L10 -FePtbased BPM.
In addition, the block copolymer template is used
to prepare BPM. Naito et al. combined a diblock
copolymer template to fabricate a long-range ordered CoPt patterned media with 40 nm sized dots,
where single magnetic domains with an almost
perpendicular orientation were obtained in each
Fig. 18. TEM image of template CoPtSiO2 magnetic media and EDS integrated intensity maps of Co, Pt and Ru for one grain.87
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exchange decoupling, writing information on L10 Fe(Co)Pt media is still a challenge due to its large
Hc and therefore requires a very high writing eld.
To overcome this problem, researchers are focusing
on the development of new recording paradigm.
A number of advanced approaches such as texturetilting-assisted media, domain-wall-assisted media,
and energy-assisted magnetic recording were proposed to reduce writing eld of L10 -Fe(Co)Pt-based
PMR media. Here we will briey review the progress
of texture-tilting-assisted magnetic recording media
and domain-wall-assisted magnetic recording media
by manipulating the structures and magnetic
properties of L10 -Fe(Co)Pt materials.
Fig. 19. The schematic drawing of EMP process: (1) L10 -FePt
continuous layer was deposited on the substrate, (2) mask layer
RuSiO2 with a ne granular structure was deposited on the
FePt layer, (3) the SiO2 of mask layer was removed using a
reactive ion etching process (RIE), (4) the Ru dots array pattern was transferred to FePt layer using a RIE process.88
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(a)
(b)
Fig. 20. (a) Schematic illustration of the tilted magnetic media with a single-pole writing head, (b) normalized switching eld
(Hs =Hk ; Hk , magnetic anisotropy eld) versus the angle () between the external eld and easy axis of a grain exhibiting uniform
magnetization reversal.93
natural-tilted textures with tilted easy magnetization axis, such as (101) or (111) textures of
L10 -FePt, can be used as tilted media, wherein
the easy magnetization axis is directly oriented by
36 45 with respect to the medium surface normal.
Natural-tilted media has the similar advantages
with the articial-tilted media.98,99 High-anisotropy
L10 -CoPt or L10 -FePt lms having natural-tilted
(111) texture have been reported.100,101 Room-temperature angular remanence measurements (ARM)
of L10 -CoPt were carried out in order to determine
the geometrical arrangement of the easy axis in the
lm, as shown in Fig. 21.100 The ARM curves provided the evidence of four out-of-plane maxima at
36 and 144 , within both the (110)
and the ( 110) planes. The maximum coercivities
( 4.8 kOe) were observed, when the eld was applied along each maxima direction of the ARM
curves [Fig. 21(c)]. The observed behavior is consistent with the presence of four easy axes with
mutually orthogonal in-plane projections, symmetrically tilted at an angle of 36 with respect to the
lm plane. Such methods can result in approximately 75% reduction of the writing eld without a
loss of thermal stability.
Therefore, both the articial and naturally-tilted
media play a certain role in improving the writability of PMR without decreasing its thermal
stability. However, the articial-tilted media can
negatively inuence the magnetic properties due to
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(a)
(b)
(c)
Fig. 21. ARM curves in the planes of the MgO substrate: (a) ( 110) and (b) (001), (c) schematic illustration of the four tilted easy
axis model.100
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1 2Khard Ksoft
;
4
Jhard
Fig. 23. Magnetic reverse process and hysteresis loop of the exchange spring media.105
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coupling strengthen between the two magnetic layers, leading to the reduction in coercivity of the ECC
media.121,122 In a word, ECC media can further
improve the writability compared to the corresponding ES media.
On the basis of the studies of ES and ECC media,
researchers proposed theoretically ECG media with
a multilayer structure,123 where the anisotropy
varies layer by layer from the hard to soft layer.
Thermal stability of graded media is dependent on
the anisotropy of the hardest layer. If the number of
layers in exchange spring media is increased from
two layers to N layers to form the multilayer
structure of ECG media, the anisotropy dierence of
adjacent layers will be decreased, resulting in a
smaller pinning eld at the interface,
Hp
1 2K n1 K n
1
2Khard
;
4
Js
4N 1 Js
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(a) Bilayer lm
(b) Sandwich-like lm
(c) Multilayer lm
Fig. 25. Schematic of the three structures before and after annealing.102
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(a)
(b)
(c)
(d)
Fig. 26. (a) and (b) Compositional depth proles of FeAu/FePt lms before and after annealing at 550 C, (c) and (d) simulated
hysteresis loops and magnetization reversal process of the multilayer graded lms.134,138
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Fig. 27. Development of the recording density in conventional and advanced magnetic hard disk drives.155
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6. Summary
In summary, many proposals have been made on
media materials engineering for L10 -Fe(Co)Pt in
order to balance the trilemma of perpendicular recording media. For the thermal stability, stressassisted growth and metal-doping methods are used
to reduce the ordering temperature of L10 -Fe(Co)
Pt lm and obtain the perfect fct (001) texture that
ensure high thermal stability of the media. For the
SNR, GPM, PPM and BPM were designed to enhance it from dierent levels. Among them, BPM is
considered to be the most promising scheme to realize high SNR without a loss of thermal stability.
For the writability, both texture-tilting-assisted
media and domain-wall-assisted media can realize
its improvement on materials engineering. In contrast, the domain-wall-assisted media, especially for
ECG media, is thought to be a more eective
approach. However, it is necessary to combine
some alternatives to balance the trilemma for
L10 -Fe(Co)Pt perpendicular recording media due
to the shortages of single technology. Based on the
progress of ECG and BPM, it is predicted that
L10 -Fe(Co)Pt based ECG/BPM should be one of
the most eective paths to balance the trilemma
from the materials design, which would open up
a new avenue to realize an areal density of
510 Tbit/in.2 in the coming years. Certainly, there
exists still a great challenge in production technology, needing a synergic advance on the key technologies of media and heads.
Acknowledgments
The authors would like to acknowledge the useful
discussions with Prof. Hao Zeng of University at
Bualo-SUNY and Prof. Dan Wei of Tsinghua
University. The work was supported by the National Natural Science Foundation of China (Grant
Nos. 51025101, 51101095, 11274214, 61434002), the
863 Program (Grant No. 2014AA032904), Foundations from the Ministry of Education of China
(Grant Nos. IRT1156, 20121404130001), Shanxi
Province Foundations (Grant Nos. [2012]12, [2012]
10, [2013]9).
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