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Japan Nuclear Energy Safety Organization (JNES), 3-17-1 Toranomon, Minato-ku, Tokyo, 105-0001, Japan
2
Toshiba Corporation, 8 Shinsugita-cho, Isogo-ku, Yokohama, 235-8523, Japan
3
Hitachi Ltd., 7-1-1, Omika-cho, Hitachi-shi, Ibaraki-ken, 319-1292, Japan
Keywords: nickel-based alloy, stress corrosion cracking, crack growth rate, BWR
Abstract
Introduction
SCC growth tests has been carried out on Alloy 182,
DNiCrFe-1J (JIS, denoted as DNCF-1J), Alloy 82 and Alloy 600
(HAZ). Alloy 600 plates were welded under constrained
conditions by shielded metal arc welding (SMAW) with Alloy
182 and DNCF-1J electrodes. The chemical composition of
materials, welding conditions and post weld heat treatments
(PWHT) were chosen based on the fabrication condition of the
plants.
The tests were conducted in an autoclave equipped with
a re-circulating loop at 288C. The crack length was monitored
by the reversing DC Potential Drop Method (PDM).
Interdendritic (ID) and intergranular (IG) pre-cracking by gentle
cyclic loading was induced in the NWC before the SCC growth
test under a constant load. The tests were continued for about
6000 h, at a stress intensity factor K of between 15 and 50 MPam0.5. Crack growth rates (CGRs) were determined over a longer
testing time to ensure the precision of PDM. The results were
analyzed in terms of the materials, test conditions and change in
crack shape with the advance of cracks, to clarify the
characteristics of SCC growth behavior of test materials.
All SCC cracks showed interdendritic and intergranular
morphology. The CGRs in weld metals in NWC were slightly
higher than the CGRs in HWC (1). The CGRs in HWC (1) and
HWC (2) were dependent on the value of K. The CGRs at a K of
between 15 and 40 MPa-m0.5 in HWC (1) were about ten times
higher than those in HWC (2).
The CGRs in HAZ, Alloy 600, in NWC were almost the
same as the CGR in HWC (1). The CGRs in HWC (1) and HWC
(2) were shown to depend on K. The CGRs at a K of between 20
and 40 MPa-m0.5 in HWC (1) were about fifty times those for
HWC (2).
The CGRs in the Alloy 182 were almost the same as for
DNCF-1J under all conditions. The CGRs in modified Alloy 182
and modified DNCF-1J were almost the same or higher than the
original alloys.
The CGRs of Alloy 82 in NWC were
approximately 1/5 to 1/100 times lower than the CGRs of Alloy
182.
Under the conditions used in this study, it was found
that the SKIF curve for Alloy 182 was too conservative and that
some risks were associated with the TENPES curve for low K.
Experimental Procedure
The flow diagram for the experimental procedure of this
study is shown in Fig. 1. The details are as follows.
Materials
Alloy 600 plates 70 mm thick were welded under a
constrained conditions using shielded metal arc welding (SMAW)
with Alloy 182 and D-NiCrFe-1J (JIS) (DNCF-1J) electrodes.
651
Fe
Ti
Nb
Alloy 182
8.2
0.21
1.76
Modified 182
6.9
0.04
3.90
DNCF-1J
crack propagation
detectable on PDM
or
Test time > 6000 h
No
Mn
Cr
1.86
0.05
3.73
Alloy 82
2.73
9.8
Alloy 600
1.87
2.51
70 mm
100h
Si
Modified DNCF-1J
Materials
Activation operation to
crack (Trapezoidal
mode loading)
Yes
Fig.
2 Sampling position of 1TCT specimen in welds of Nibased alloy.
crack propagation>3
(: Dispersion in PDM)
and stable crack growth
recirculation loop. During the test, the water in the autoclave was
refreshed two to three times in one hour with pure water.
The water chemistry was controlled by ECP. A normal
water chemistry (NWC, ECP; +160 to +190 mVSHE), a hydrogen
water chemistry (1) (HWC (1), ECP; 0 to -90 mVSHE), HWC (1)
(ECP; -110 to -80 mVSHE) and HWC (2) (ECP; -480 to -380
mVSHE) were used. The ECP was controlled by dissolved oxygen
and hydrogen. The conductivity of inlet water was kept to less
than 0.1 S/cm and the conductivity of outlet water was kept to
less than 0.2 S/cm during the test. The concentration of SO42- in
the water was controlled to be 5 ppb. The concentrations of Cland NO3- were both less than 3 ppb.
Evaluate CGR
Test specimens
1TCT specimens with side grooves were machined from
the weld joints. A notch was made, as shown in Fig. 2, so that the
SCC in weld metal was propagated parallel to the weld dendrite
direction and the SCC in the heat affected zone was propagated
parallel to the fusion line. Prior to the tests in high temperature
water, a fatigue pre-crack with a length of about 3 mm was
induced in the specimen by cyclic loading at room temperature in
air. The Kmax values of the pre-cracks were adjusted to 0.8 times
the target K values of the following SCC growth tests in high
temperature water.
Water chemistry
SCC growth tests were carried out at 288C and
approximately 8.8 MPa in an autoclave equipped with a
652
27
Alloy 182
Gentle
cycle load
Constant load
(R=0.9,
F=0.01Hz)
EAC
P
Fatigue
pre-crack
in air
AECL00A
1mm
P
653
SCC crack
Pre-crack
in air
Figure6. Fracture surface after the SCC test in modified DNCF-1J at initial K of 38.6 MPam0.5 in NWC (ECP; 130-140 mVSHE).
654
26.0
Alloy 182
Gentle
cycle load
25.5
25.0
24.5
24.0
CGRmax/CGRmean
R=0.9,
F=0.01Hz
1:&
+:&
+:&
'1&)-1:&
'1&)-+:&
'1&)-+:&
0RG1:&
0RG'1&)-1:&
Constant load
Interruption
in the test
23.5
NWC
Initial K: 15MPa-m0.5
HWC (1) (ECP: 0 - 40 mVSHE)
Adjustment
of ECP
23.0
0
500
1000
1500
2000
3000
2500
Time (h)
Material
CGRmeanCGRmax
(
GD GWP V
Crack
growth rate (m/s)
BWR
NWC
Alloy 182
DNCF-1J
(
HWC(1)
HWC(2)
NWC
HWC(1)
HWC(2)
Modified182
NWC
Modified DNCF-1J NWC
(
(
(
(
.03D P
m1/2)
Figure8. Comparison between CGRmean (closed symbols) and CGRmax (open symbols) in SMAW weld metals tested in various
environmental conditions (NWC; ECP about 150 mVSHE, HWC (1): 0 - -90, HWC (2): <-230 mVSHE)
655
HWC(1)ECP=0 - -90mVSHE
HWC(1')ECP=-80 - -110mVSHE
HWC(2)ECP=-380 - -480 mVSHE
NWC ECP=+160 - +190 mV SHE
10-8
Alloy 182
Crack growth rate (m/s)
Alloy 182
10-9
10-10
10
-11
10
-12
10-8
10-9
10-10
10-11
K=33-45 MPam1/2
-12
30
20
10
40
50
1/2
10
100 -600
-500
-400
K (MPa m )
182
DNCF-1J
Mod. 182
Mod. DNCF-1J
10
100
200
600
Mod 600(Low Nb)
Mod 600(High Nb)
-8
NWC
Crack growth rate (m/s)
Alloy 600
10-9
10-10
10-11
10
-100
10-12
-200
ECP (mVSHE)
10-8
-300
20
30
40
50
100
K (MPa m1/2)
Figure11. Relationship between K (and ECP) and CGR in Alloy 600.
656
10
10
Weld metal
-9
-10
Base metal
10
-11
10
-12
Modified alloys
Nb concentration (%)
20
18
Analyzed
line
Boundary
Cr cincentration (wt%)
16
14
12
10
8
6
0
10 nm
-50
-40
-30
600,000
-20
-10
10
20
30
40
50
30
40
50
(a) DNCF-1J
20
18
Analyzed line
Cr cincentration (wt%)
16
Boundary
14
12
10
8
6
4
2
0
10 nm
-50
-40
-30
-20
-10
10
20
-8
Weld metal
Crack growth rate (m/s)
10
-9
-10
10
-11
10
10
10
20
30
40
50
100
K (MPa m1/2)
Figure14. Comparison of CGRs of Alloy 182 and 82 in NWC
and HWC (1) at an initial K of 15 to 30 MPa m0.5.
657
182, HWC(1)
182, NWC
DNCF, HWC(1)
DNCF, NWC
Modified182, NWC
Modified DNCF, NWC
10-8
Weld metal
SKIFS
(Sweden, 1996)
10-9
Base metal
10-9
SKIFS
(Sweden, 1996)
10-10
10-10
JSME S NAI-2004
(Japan, 2004)
10-11
10-12
600 HWC(1)
600 NWC
10-8
10
20
30
40
50
10-11
10-12
10
100
1/2
K (MPa m )
20
30
40
50
100
K (MPa m1/2)
Figure15. Comparison of our CGR data with the SKIFS and JSME S NA1-2004.
curve. The CGRs at a K of 20 to 30 MPa-m0.5 in HWC (1) were
equal or slightly higher to the SKIFS curves. There is the
difference of conductivity between SKIFS and this study
mentioned above. However the SKIFS curve for Alloy 600 in
NWC seemed to be appropriate to the evaluation of CGR of this
alloy 600. In this study, the specimens of Alloy 600 were made
so that the SCC in the heat affected zone was able to propagate
parallel to the fusion line. On the other hand, the SKIFS-curve
may have been made by the heat-treated Alloy600 which
simulated HAZ. Therefore it was thought that relationship of
alloy 600 between the data of this study and SKIFS curve above
was caused by the difference in the materials.
40 MPa-m0.5 in HWC (1) were about fifty times those for HWC
(2).
4. The CGRs in the Alloy 182 were almost the same as for DNCF1J under all conditions. The CGRs in modified Alloy 182 and
modified DNCF-1J were almost the same or higher than the
original alloys.
5. The CGRs of Alloy 82 in NWC were approximately 1/5 to
1/100 times lower than the CGRs of Alloy 182.
6. In comparison with this study, the SKIF curve for Alloy 182 in
NWC was conservative, and that there were some risks associated
with the JSME S NA1-2004 curve for low K. SKIFS curve for
Alloy 600 in NWC seemed to be appropriate to the evaluation of
CGR of this alloy 600.
Summary
SCC crack growth experiments were carried out in
simulated BWR environments on Alloy 182, DNiCrFe-1J (JIS,
denoted as DNCF-1J) and Alloy 600 (HAZ). Crack growth rates
were determined from long-term tests of between 1,000 and 6,000
h. The CGRs were evaluated by considering their relationship
with K and the environment (ECP). The CGRs were compared
with the curves of CGR against K proposed by SKIFS (1996) and
the JSME S NA1-2004. The results were as follows.
References
1. All SCC cracks showed interdendritic and intergranular
morphology.
2. The CGRs in weld metals in NWC were slightly higher than the
CGRs in HWC (1). The CGRs in HWC (1) and HWC (2) were
dependent on the value of K. The CGRs at a K of between 15 and
40 MPa-m0.5 in HWC (1) were about ten times higher than those
in HWC (2).
3. The CGRs in HAZ, Alloy 600, in NWC were almost the same
as the CGR in HWC (1). The CGRs in HWC (1) and HWC (2)
were shown to depend on K. The CGRs at a K of between 20 and
658
659