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DYES
(1) acid dyes, (2) direct (substantive) dyes,
(3) azoic dyes, (4) disperse dyes,
(5)sulfur dyes, (6) fiber reactive dyes,
(7) basic dyes,(8)oxidation dyes,
(9) mordant (chrome) dyes, (10) developed dyes,
(11) vat dyes, (12) pigments,
(13) optical/fluorescent brighteners, and
(14) solvent dyes.
TO XICOLOGY
OF
TE XTILE
DY ES *
Skin Sensitisation
Reactive dyes can, however, cause problems in plant workers who manufacture the dyes
and textile workers.
Fig: A list of reactive dyes that have caused respiratory or skin sensitisation in
Workers on occupational exposure has been compiled by Ecological
and Toxicological Association of Dyes and Organic Pigment Manufacturers [ ETAD ]
3)
Ge
not
oxi
city
Mutagens
Carcinogens
Teratogens
Toxicants must reach the DNA (which resides
in the nucleus of the cell) in order for the
chemical to interact with the DNA.
It must possess the ability to interact
with the DNA, usually by a chemical
reaction.
So the toxicants must be able to transport
across the protective cell membranes.
Carcinogenic Dyes
Active species of most carcinogens, known as the ultimate carcinogen,
is an electrophile, E.
Nitrenium ion [R2N+]
Examples
E + [DNA] E[DNA]
AZO DYES
Water-soluble azo dyes most widely used by textile fabric Industries
Water soluble azo dyes are produced the various metabolites .These metabolites only
Develop the Carcinogenic Effects.
Benzidine
Metabolites of Benzidine
Bladder Cancer
Benzidine
Disperse Orange 11
Disperse Blue 1
Disperse Violet 1
DY E TOXI CI TY
RISK
ASSE SS ME NT
RESULT
The fish toxicity at 5ppm of methyl red was also higher in short term experimental study
By the long term experimental studies we can understood the response of the biotic
community in an aquatic eco system receiving pollutants which will guide its restoration.
* Impact of Textile Dye Industry Effluent on the Neurosecretory Cells in Fresh Water
Female Crab Spiralothelphusa hydrodroma (Herbst)
1 Sekar, 2S. Hariprasad, 3M. Deccaraman
Contin..
Contin.
The Health Status of the villages around the NOYYAL river assessed through three medical camps.
Doctors participated in the medical camps were able to identify the symptoms of waterborne
diseases.
Health problems such as skin allergy, Respiratory infections, general allergy, Gastritis
and Ulcer were scanning among the villagers who attended the medical camp.
It was medically accepted that the polluted water had significant influence on these diseases.
It was assessed that one-fourth of the villagers has any one of the listed of diseases. Most of the
identified patients accepted that they were using either the river water or well water or both for
washing purpose, cleaning the cattle or fishing in the tank etc.
After realizing the ill effects of the water they started avoiding the use of it.
INDUSTRIAL EFFLUENT AND HEALTH STATUS A CASE STUDY OF NOYYAL RIVER BASIN
RESULT
The conc. of K+, Ca2+ and Mg2 + ions are increased after the treatment with textile dyes.
The increase in K+ ion concentration of the sample is attributed to the reduction in the
extra cellular space.
The decrease in Na+ concentration suggests a change in permeability properties of
different biological membrane system.
Appropriate decrease of Cl ion concentration in fish might be due to reduced activity of
carbonic anhydrase by the uptake of high Textile Effluents
Flow diagram of E
TP
Collection Tank
Lime & Ferrous Dosing
Flash Mixing Tank
Primary Clarifier
HCL Acid Dosing
Aeration Tank
Secondary Clarifier
Dual Media Filter
Ultra Filter
Contin..
Reverse Osmosis
Primary Clarifier
Aeration Tank
Secondary Clarifier
Ul tra F il tratio n [ UF ]
UF system is made by hollow fiber type model membranes
This system is automatically working with the following pumps such as:
Flo w d iag ram of ze ro dis cha rge in tex til e d yei ng uni t u sing
ad vanc ed trea tmen t
Note:
KLD = Kilo Liters per Day
1 KLD = 1000 Liter
DI SCUSS ION
Can we Create the Green Earth Again?