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By
Joseph Priestley, LL. D. F. R. S.; Communicated by Sir Joseph Banks, Bart. P. R. S.
Author(s): Joseph Priestley and Joseph Banks
Reviewed work(s):
Source: Philosophical Transactions of the Royal Society of London, Vol. 73 (1783), pp. 398-434
Published by:
Stable URL: http://www.jstor.org/stable/106498 .
Accessed: 04/11/2011 14:11
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SIR
JOSEPH BANE59
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SIRs
th@?erfeaI4loa
of 1ny ft41etlds
I beg you wouldlay
befbr@
the:RoyalSocietymy late obServations
01w
Phlo
fiC;ently
atScertatlledX
tfhough
Xdo notplefumevto
giveany opiZ
RiC9Il with refpeAto tile theory
of thelue
I arzzSwlththe;reateItxefpedX
&ce
+lSmIVga25
X pr1t;a T) X783.3
E?t#aBN
tS
hH28s
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399
ExperietZstvlalingto Phlogn
or
contraryS
ac
44tt
Fb9LWt87#(g
ta Pt^ors
t2 tESTtJEt S EtCrlaSe<;X:gSs
Dgt
oiSttniS
1>Ele
arE,u3atlet-;ts
in f1vot1Xo
WtCh
alc
tdarsvtl
t;^Oin
t11t
tfpCcivill tXzofn;
Opitli0t]?
'2&vpCUi.tCt-ltS
Of
:;4|4e t..zAJa)lSIER
finyfc35
:fo
SEl--Acit ;1 osvn I wwcls
i-wc3Wedy
t-l>v^l-d
1urgX>vva:b-XS
mllchinnlinetlto<ldoptitZ Db;ay-t
-Ll
u;rx2l
alnvayst-leldth.n.t
pEwlogitoul sstas the Iametilitig
nazy e:xpew
pRONTed -ttliS fl-om
xuabte
air9 atadhe ha-sftlXiCiCIltty
c35oftllersF
tny ossrtz
as sve11as thcJ4z
?zildoblerva-iotl)
3:d;dnota,lleN;-ev-l^)
alcedet:oit till ][ diiccveredit 1)yd;reRw
itadeterrmitatte
tXperitnents
n-a.de
xvjtll generala-t-<d
wilich haci
CQllUCrtZillg
a fubj-lEt
orderto afcert<wl
foLnething
lo S*UCtl trc3ubl
giVeIl
nyfelf alldotlnLers
theexperimen-ts
ill x-hlch]:hadfoutld
I be;anxvithlsepentirlg;
flint gars tulesX-gave
thatinEarntnable
e alfolbedR
and was in a greatmenIul
to be OWi11g to the calxof leadill tho
zz-hich
I haddiScove1-ed
aire As t1Rc
frotntiae itldatntmable
glalsattraEcing
plwTogi0otl
wasveryfrnall7tlloughI gaveit
quallt:ity
of airirlthefett1bes
refiduurn
in olaeof tE-epr(JC6{i@s WSls
tlsat
tsne
otl
I perceived
no marksof alcetlfoon
phlogiRicatcd becauSe
on
X I was t1OtX
pre:Cetltirlg
to it tizeflaltloof a fmR}lcutldle
of
andwas defirous
recolledionw
fa-tlS:Sed
withthis
Wittl
naorecareSefpeciallyasXin one
-epeaXtlg
tlaeexperitnent:
experinzerltsS
I found only a very
of the altove-nentiolled
airitl thetube1rlwllichil;had
s>3gmalLlybubble
of the itlflamrnable
snatle
on
tmel^clX3ry)
1>3K>i(3us)
are
ltaflaXn
14imetwi-s
viewsX
air9
tlaetn
as
my
lts.k
lmade
red-llot
ill
in
tinge9
capiniotwS
air9
conclufiorlX
beenL
heatedO
thereexpeX
itl repeal;ilag
I found9hosvever,greatdifficulties
air operatedupon
rlments andthe quantityof itwflammalDle
n r:hem
is Ilecefiarily
fo fmallStl<attherefultis alsrayslialJ1e
][ thoughtS
t:hereforeX
that throwing;
to
Inuch-uncertaintyO
the focus of a burningletasupon a quantityof poundedl
fiillt ,laSs Iilrroundcdwith iilanlmabIc airXor rather
9
o-n.
dnSzlpefSevnig
Casetffinof AYXer
;7Z
4a-
Xr
tta thealx
of leadalotleX
sn tlaefamecircumftances;
would
be a mucll eafiler
and miglatlarit-]g
rnenearerto
snyolUe&;and on makitagtlle eXpetiSGIlt it ituinediately
an
fweredfarbeyondmy expeEtation.
experiluclltS
rnantler5>
vived,atwd
thatitl a confideralule
at the lime titnt
thattheairssraS
dimilwiffied:,
I could1lotdoul3tbut that the:
salxwasaAuallyfimlJibing
femethirlg
m the air; atldfi:om
quatltityS
2
UrQ
Bt60
402
fDr PRIES1'LEY'S
relai>gto PhtogSar,
X4pFi7XSZ5
Otl
I t oulad
tnuch>tl.lXiC+\79 tlld 2;l- tla+>lt relmlitledw
froTntl:lsltill XYtsiCtl I began
tllatit czuldIlotbe cliftitlgtliflCd
fromirotl13y oil of
xvasair estz-ac-8ced
tlle expe^itnelltVEwit}l
that-rilislnflarnZ
ibl.tisfiCcl
I svalsrlleloefore
rvitl-<
csatnilailab,
prtty
vitriolZ
sJell
plllog,iflon3 for
lzcfoclWs
lnable a;1*cotlid lLlotcotltai1waiay tTlit-<g
at tllat titne I reducecl al;orlt 4S oullce meafuresof the air t:o
nve
r
to afcertclia faAof fo
\ 111ol4del^
of
fioma qvlaatity
caIefullyexpellecl
care,I aftersvards
greateiR
aIldeveryttlitlg elSethat could
nziniuma11the phlobiflol3)
Tlavea{Iumedtlaefolomof aile,:1)yg;Yit]g It a red heatwhen
txlixedwitll fpiritoitnitre, arldirnfnediatelyufi11lgit iN the
of
above,I reducedxor ouncemeafures
snallnermelltiollecl
airtO tA70. t0 judgeof its degreeof inffamma
ilaflammal)le
the flanaeoffd ftnallcandleto rllemouthof
bility, I preSellted
Sepa
thatit m(adevllirteen
it, atldobfervedn
a phialfilled
thoughw7eakolles(fi-Oppillgthe mouthof therateexplofiol-ls
explofloll)vlletl frethmade
aftereacT-l
pllialwith l:nyfiXlger
tlzadeorllyfour
airSill the famecircumRaLlcesX
flammable
ones9
tlloughItroLlger
teenexploi:iotls,
Inucl-l
irn;30rtance
str-ltil
tlle
w?itll
itJ
gorX in
aIld
of iWher?nf:Air
40J-:
A#dSDesMU]Z?C
COSFU/4JU4OS
atlyfioorza
tile
alldit tntlI}be uIed befbreit canhaveattta&ed
atmcxfphere
; and:in tlaellextplace thewateraifo(:acotafldei^able quantityof svtliclltnuR:lJeuiedyatld whicttsvillaifObe
as fiee frotlaairaspoflz
heatedill theprocefi)Ilaould
be xxwade
ble 1ntheSecircumftatlcesX
l-ladI iRutlcltIle fluallrefdumS
h.ve beetlph3ogiticated
o
of z oullcerneafures
from
; atldit svoulcl
1lot
sExed
air,I flaould
llothavebeenditappoitlted
have prevetltedmy colacluding
that tS>/tp08 svastlle t1ne
ill a combitled
RateiIz
thil}gwith inpawmzable cotataitled
ill challiad othercalca
rnetalsX
.uR as fisedair is cotXltairaed
reousfubllatlces,bo-thbeingequallycapableof beitlgexpelled
agaltl1nt le tormor alr
XzL
Afterwards
uXing
a calxof lead7svhichhadbeetlprepared
the farne
with the former7but svhlchhad remaitled
fotnewTeeks
expofed
to the airnI fourld,th:atwhetlby ui;tlgit:
of itlflammable
air:to XoS
I hadreducedt so outlcetneafures
thisrefiduum
wasphlogiRicated
air. Butexamitlingtlatsca1x
xct
to
-agrS
mallXtler
07eflelS
a
I found
it gave,by heatin a glaEs
air.
eonf1derabte
quantity
of phlogiRicated
Ihouldglotle teduced
to a
I muitobServe7
thatthemitlium
perfeEtly
colnpadgla of lead; forthenit wouldbe too reZd
feparatelyS
Ctlaat
fi*adoryto le eaEllyres7ived
1)ythis procefs MakinguSeof
olllymeltit; but thata co
lbmeof it I foULad
thatI coulcl;
the infideof the
piousblackfumecamefromit, and coalted
receiver:
an experimeIlt
whichI ffiallrepeatandrecotlfdero
I mull aISoolJfervethat the leadsvhichI-procuredzinttlO
from atly
abovesmeiltioiled
proceSs
wasNotto be ditapiIIled
airs^7as
all plocuredl
from
otherlead ancithatthe inflalutualJle
*
lron
.r
by 011 or vltrlot.
air froIn
woodS
I found}
WhenI madeuSeof inflallzzlable
that thoughI was able to reduce[ninillmwith itj,it
effcded
Mt&
.i4\Oisr PRISSTLEY9S
SIlddi1fficulty Fol4tyout<cemea5ureg
titne
rnore
svitll
keSewRed
>ofthis lsindof ;namrnableairI reducedto 25; vllen I fioutld
ef lrad,and :ao
that the heatof the lel;1sproducedotlly g/abyrs
and theae
Osevlc trtle air vas 024t;19 hosvevernilzxdatun:zableS
of itaXatMF
of fiXedait4 it-w ito This kitadl
finall Smixturc
%7{(18la
rea
flatu) 1:llaveScome
att*ss7t.ic1burnst! a latlbelw-t
rl<alule
Ot hxedairssfitlt
UIliOS
1on to l:llluk cotzLfoRs of ALlItltItllate
frotu3AzetalsTTJLe
wltibilts ofthe eJloJ9ve lsitlclextradted
tEwat
utla;icll1 tnadewith that lditidof
refult of ttxoSeexperina0;:ats
making
air which is colleEedin tile procefsfiQte
inflarvmable
A,.xpermez
rez>aZ@Sg
Zo
P/pXy/gsnb
:t10t
4OS
n of MazerznvoKr.
Con*erf
and:Se JreeBning
and lwotethe
not fttcceed;butI muRrepeatthe experimentsS
0
I reporttllem.:
befiore
lmoreaccuratelys
falzpearances
3[nalkalitleairIeadfeezlsto le fortnedfromrllemiziutnas
I thoughtrathermore
airg aIad
itaflamtmable
as z1w
readiSy
of
and 1lluRration
cntwfirmatlotl
fo; a1adtlliS iS -a retnalkatelein a
Epark
cle&t-ic
by takitagtEae
ill svlwich9
theSeexpet-itnetlts,
it itltc) threetiines as rrlucltc)falkalineait R I cotaver^ted
quatRtity
w-llich
, otl SCCOUIlt Of
pure itlfl;aLutnctblcn air; an exppritnetlt
t1lturt-of itv I have repeatedmvltlytitnesX
xtraordit-<ary
t:S>e
finceI firItpubliflledthe aCCOW'IlL Gt it, ild Al\VAys3 Wit- t1]t
f-mer-efult.
lightupon11QWEill sv1ach9
Sconle
a}i tIrosv-s
This experitnent
ail*I producedairon-stltil llitrcous
by fuper-pillogifiicat;-ng
experinaetlt whiclaI have
fmell of volatile
repeatedvith the fame refult. lUllerevivitlg
alfof^equelltly
of leaditl alkalitleairmayalSohelp tISto conceivehcowal11
aladto alkaltes7
vaidsIhouldhavcan affitlitybotlato phlogiftoz
fronz
to bethirlgsfoverydif3ierent
whiclahavehithertoappeared
thait
it is probable
eacheother;fillce, fromt-hefeexperimentsy
of thieother,or a cotulina
oneceEthetuis folnemodtfiicatiorl
elfe withrtheotherOTo tracethe cotanect
tionof fomethi-ng
is a cu
principles9
betweenthe alkalineand inflammable
tiOll
perhapsxlotbe
xiousfubje&;and fromtheSehints it
it to advalltageeIt is evident,hosv
to profecute
oerydifficult
thatallialilleairis tlac
e-ver,fromthe followingexperiments,
the moretitnple;
atr,or j?hlogiftotl,
andinfl-ammalDle
cornpound
of tlle two.
ilubIlance
a-irI gotn by meansof
of alkasline
meafures
From52 ourlcer
iothatsvasdifEelved
grainsof leadSbefides-folne
I7
llth-rgea
themercury,by whichthe airwasconfined Thereremairle
to be plllogiRicated
wlalchappeared.
22-ouncemeafuresb,
itlc?ieecl
firotlg
allSalXin
a11
rnayS
air9.
ata.&s
atldtoTlave
two hsedairill it
At anothertitneSill eiglltOUI1Ct
meafures
of alkalilleaito I g+ot5 graillsof lead beficles
svhat
svas diIlols7ed
itl the tnercuryuhich feemedto k a gooddeal
in plOp0ItiOt} tO it lt WARolzIerva'Dle thattilereremaitwed
in
tl:ais
procefs33 oul<cetneaIilres
of plllogiRicated
witTlollt
any
llAiXtUrt Qf fixedair:ttz eltotlgh
the maillcotwhichI uSedat
1.t5
T-3[avitlg
tilusproduced
leadtSw itlffatnmable
alr T proceeded
;11tnyattemptsto reviveot}lelX netals fromtheircalces1)ytle
rarne meatas; RndI fucceeded
s7ery with
bifmuthand
filveri tolerablysve11svitll copper irotlS atld regulus of cor
balt; butnot at all utitlaregulusof atltitnorayX
regulusof ar
iClliGv zirlcSor the tn&:tal
of rnangaefe
I wasdeElrous
alfoof aScertailwing
bythisnweans
the fav7Ztiey
of phlogiRotlthat etaterslnto vlhecornpofitiotl
of the feveral
3metals
n loutitz thlsI fotlndmored;fficulty
thanI lzadex3?eded
^
atldthisalofeclieffyfrom-the alIewance
thatwas to be made
ir the inflamluable
air wll;chE
etlteredilatothatpartof the
caix whlchwasonlypartiallyrevivedsatldit wasllot ta:fyt
revitethe svo1e of anyquatltityof calscomplete1y
\\?ell
OULlCtof
tin7
leadabSorbs
IOO OUllCO meafures
of lnflammal31e
airf
orperhaps
fomethingmore; ioritlotlerefultit Seemed
t{>have
Xubibed
ill the pro?ortiotl
of to8 OUIl(:DO
lBeAfUrtSo
f&nounceof tinabSo*bs
itlflammable
airill the propottion
of
37*7outlcemeafures
to the oUnC> H ounceof copperfiwoln
ve-rcliter
abSorbed
+O3 ottnce tut;s{ureS; froma folutiotl
of blue
vltriol precipltated
Ibyfalt of tartarS
andai-r-\^7ards;
madered
hotwitll fpiloit
of nitre 64O; 1tutfrotzlblut vitrol it:felf9O
vL}$zhBj
Jensstazg
CG}ZT'6rAS
6?FX
3gL1//S
Z6SZA
ArE
43 7
out1Ce
meaires. Ill thiscaCeS
IlosvevermUcil of tl-ltil:lflarn!
mableail svet1tto tt1C fOrlMStiOlI of ttld:E:-0VitUiQtiC (;cld tt<e
Emellof svlwicil
urasvery perctivable
ill t1-1e
cotlrSeof l;heexZ
periSnellt:
ThecoppertIxlat
I rnade
itl tliS
waS brittle7
ancl
tilerefore
Seen-wed
not to be perSeEtly
tmet:alizecl;
butbeitagftlzed
xvithborslxit l)ecameperfeRcopperS
alldXas I thitlk)svitholXt
anylofsof sveight.
BXftn?th abSorbed
itlflamtnal;le
airill tEleplOpOl4tiOl.l Of 1 8S
oulleelmeaful-es
to the OU11Ce. TEwe
cals I uSedsvasa plvecii
tatefromthefolutiorl
of tI-lismetalin fpiritof tlitre4
: Aroz
I got froma precipitate
of a foltltiotlof greetlvit^iolby
falt of tartarS
moiftellecl
vvitllfpil^it
of llitre,andexpofedto a
air9
\679y
bejexpeEtedf
thatperfiedirota9 colltaitz;tlg
its StlllproEcorLioll of
phlogiItoIl,
{laould
1)eproducecl
in tllis lmatlllerX
finceilaflanamableair may-l)eexpelledfrornperfet irotl ill lthisvery
procets.
Silver I evidlelltly
revivedfrotna folutionof it ill birit of
nitrept-ecipitated
l)y falt:of
and alfo from lanoz
A qualltityof tl-islaRfubIlatace
alforled33 outlcenaeafilres
(f
inflarramablc
air; bt:t:I could1lotget ttil2Y C9llX 05 fi9V0l frOwv
tartarS
cCrnev
uLXXlIt
1--l91
11
.t
qUali
40,3.
Z
gualhtity
S-
RblmX>k(R-l)-Rv
atr^ 1)1>lt
t c0tz1d
t1O:t
peCtive atz;vtE-};tg
irli-tsvXcha
hs>id
tthb appe^Rr3laceo-t Illetal
1;Ct1t
I iontliIed I hV>at1aot heat:
;t-anf3--1l*<,1as
fo1 the plzpet-Cw
<>ldrxzixiSag
svitl-it i-Onze
cakiilwed
1O<
;ax o reDpensted the experivlmelwr)
whettthe7.ee
vva-s
ag;aillala-evi<
(>-1C->at
a9knio-b8
Toat
t tliz^,allditl the cotlrftof thatexperiment)g
fOt)t<.5f: th0u5glat t1)tt } ditlt
perceisre a SmIll @obuleof metaLw
Zifi/^rs
alld vzJ}nissve*eC3t11y
i-!lirlled io}rlaisp^OceESGv
Tht
me srast-hecctfev
svi-tllt1atglaSso-fvoZtizvont7) J2tlt tahO tXporinleilt
svas
attekA;cle:
NVitll
tiais
peC-uliat
fircuLnaTACe
tll-at
wCtt
tlwegJafslvasnaelt;ed
il1 itzfia-rulolzabl@
as it for9eKl itSelifinto-;
:neetllelilie
cl-yIl:lls
atol425tagred
iKlae
sf<
s?eloy
Ctlrtotls
rnata?aerS
though
licouldnX produceth-at:
a,lopearatxC-e
i) otherkills of air
ltlflarnmable
ait:beitl-$cleatS)yirx31)tLbeet
W-the calcesof me
thierel);y
thena is a; fuHicielltproofof itsX
corzZainZeoZg Nv:tSlat 1aS 1)CCt1 CCII1e4I
PIL1OgiRO}-1
95Z-Ll-dbit$S b-ei-lzg
abv
trlJeel
by t-km
vrwhout
t3ecolupotitiC)
a*p1
oof t3fitis
taXsS
ai1
revfiiz?i1lg
;;n
lJeing
notlaitlg
totoR
l)ertleS
isN
pblogiJ^ton
in te
for78
of CZZr73 uilles:
the-re
fhould-bei:olnethingIolid depoISted
f--o*ln
it a-tthe I>>lrne
tinaxeP
that tile properphlvgitlicp;Irtcf tt ozas abR)bt<;lor
Tth re;fpedto t-his 1Lcall otwly Cly thatj,3LwLJtlatrCourte of tlle experiK
ne<zvs,-:Idwd llotE
percti7euit-zy
tlailagof tlle kitaasl
o;for thollg;
:hA
4oi
zno AirX
fe>-S-;,Snqpefotof A>Zazer
andt,@e
S
fuffixiefiltly
lvy it wouI:d
airitnbibed
of-izflammslU1e
gllalltity
of a twatule
atld
proofs
tther
Of SttAiS
irAlatiOtR
the
Befides
o;f itRalu
curiousX
fsEcttIatly
I had
calces,
their
fiom
nO-t fufficielltly
tlloughperhaps
aircor3tainit-<g p-hlogi{ion)
-nzable
to itsbei]gwhollyar1dfmplyphlogiSo
withrtIic&:
co-twtufve
atSeli;Thus: by tneansOfit9 I swtSa4le mjakephoehorzas
ilaall of wEflch
ad fiIpharitSe;If;
v1r,liverot lpAsurs
7Zxtroas
Rto
to he
phlogiftonis acktwowledged
of tlz<Xt
ie1asupot a <1uaRtt.y
Throwirlgrlre icTasof atI-1e
a
glady
sviatll anSorangecoloured
Nvas covered
tlle receiver
whicll
calcilled
iotn
Sw i-lzflarnulabIt
of
is rnade
which
mfatter
ingreiliefnt.
prltlc]3al
rIthen
fu-ieRatlSces
wallted
Iulz-;Ihiwe
thatthelewas
-fatiysfied
the c:xperituttlta butl:Xsras
;Sltlats
beit3gaduallyfotemed
lXixietlt pt4oofof phofpllorus
to con:titlut
with
anere
rxlentielled
ulatter
t1we-vefi1
I fXuceeedezl n<uch
bertSel.
:betng ollly
fom
tEacglaSv4-
alJove7
svllit-e
S-11e-d witl-l
il
s durltlg
-\of :the
-C>lleiurtl;l
ceiRo
at1*
Ot1ct
I-l:l i
alkalil<e
the
?-ro
alld
Vt-l-li
flarne,e-Xa&1y
ilathe prOcers br XalsirlgphoI
Iike tllat -wllicllis produced
1 0
Pho ru$4
bura;Stlg;Nvlt}w
inflanz;ma131e,
N>ab
That
f thele
provedX
its bulk,,
fbe aty
that
The
tc) be
prillciples,
moIt
cafy
4 and
plalogiItotnl9
to
aluleE
tiz.
procefs
1 have
lnFake
nitrous
to
-howeverX
t-he
tlitrous
vapour
IS h h a
farther
in propgtFion
I havie-rsow9
air itSel
Vevoden-ts
wis frlfficiWtly
as phlogiRon
as-;tnucla
lt mtwtains
as ilflamm-able
coIlRituerlt
ble aire
COlltAtAS :phlOgiR021
tI-ling
fWX1<
latisEa&;ioll
ither
two
tlltlOUS 2;
lambellft
a veill(3Ev
air
and
:fiom-
its
gilwflamtna-
+t o
4$ireatn-
\\r]Lt
Dz->
tr 2St tzvs Bxperinents
trelX*sg
o PhlgXs:,
tf)l
aJ
pre)duCesi
13y
tl-le
l*apiCI
tollltlOlzw
O.5 bifilluttl
i11 :lpil.it
of
Hi+I-ey
na;*tlich
1t tl-lefametitne proulutes a quatAtity of llitfOUS Airs the
e.SZperi-n:weIat
is not quite7uIexceptiona1JleF
I t-helzef)e
attexnpted;
t1.teIatnething itl tIa-eillov>>rillg
tnaIlSatr0
tilitosvitig
of
tlaefocusof t}<eletws
Up0t1 Ity theresvasa dillalllutlotl
t]at inda1nmablealrXwhitl atnouwtedto about
t\v0-tlAiJ$t
of the
atwd
duringt-hlstltnt leadsvasrevivedfromthe
ca1X \eer tlaistlaerewasza)xnoredilmillutNoll
of tlle ail ole
revivalo:Sthg cab-iand
v;Ilattetuainedo
wlaeleX
tilen
exanaitlitig
the
fouladit to beall Rrollgly11itl0US atldX fio-1zl
tTlecir
cutm-ances
n sv}wclzit t>vas preduced)it tuuR 1anve
leen ior3zzedt
Som tlle nitmus va-pourconta-twed
in the calXXX
a-tIdthe inm
fl;lmmableairw
itl ttzereceiverZ:I:t1
orderto a>fiCertait:l
the puriC
of this xlitrotlsalrj,I rmixecl
iXtsvitil atltqualquatltityof cotaz
motl a;r?arldiottld t1Wa;t
tIzv occtped rlaeface of In33 mea
lvlrese Fre{hnitrous-irStmaden the uIual srayX atld tnixed.
with comazonaIrlTl- the fameproportion-:7
occupiedrlae9ace of
airX
Thts diffelenceatooSe
T1Ot Sernanyimpurity
l-tl the tli
tous airX,
ltut ota the nwixtvre
gf th@dephlogitlicated
a;rS
whichis a]totspelledt rotuthis calx1Zy
heate
Is26@
lXiverof {tllpl<ur
was procuredl^)y
throwingtile icus of tIae
3.ellS vlpoll vitrIolated
tartar i.Il itlManatnable
t-tirt
andTt appearel
e
to
5e peri2tY
+XVre11
irnat.
W
ta.a01ya.
Wir. - 4
the Socusof the lens or
La0:ly, to producelpltl?nvI threv^?
eartElelitl axl taosllosv
a quantityof oil of vitriol cetatained
ill a receiverfilled svitllia
it to clrftxlefs
reffeS,atldcvaporated
of wI-lichtlqeitlfde of tlle re
flamlnalgleairX:ita cotlSequetle
nvarmed
svhic?hu^then
ctiver acquireda whztith itacruftatiotl7
aladrepeatitlgthe prt3cefi 111t:ile
a Rlollg :Imellof ftllpl-l-ur;
Iwad
fame rectivervI was able>-this fecolld tirlle?to ScrapeoS
andto
enoughof the tnatterts put on a piece of hot
producethe get3tlitleblut fl-alueyas svellas tlle peculiarfmell of
dna7
tSefievt8Z'ng
of
Conveo-z
mfer
X X
a.-fo
iron7
rulplul.
tsN7C)
Witll
phlogiflcota
otl
01.3fervatiotws
I thallcoticludetlywefe
tnax;rm
all eIzcabli:thed
artlclesC olaeof wlwichfeetBsto contrasdiE
opinionof nzyC)\VIl
atnongclaetniRs;andtheothera fiormer
1)y
is illdeAruSil)leevxcept
clan1*conl
tTaat
iSaids
- It isgeilerally
a redheatfitlcorltadwith air. ButI fitldtilat it is perfe&ly
al;lfd lDy the Ilent of a
or decompofediya
deRruAible?
air; f)
burniilglellsaImoRsvllollyconverteditltQinflammable
that IlOXCtliL1g fElllAiRS loefidcsan exceedilhglyflnaIlquantityof
*nacvoX
ln very
vifible,exceptwlaetav
svhiteanzes,svhicharefe]>dc3m
as they flv
the fulawbeatnX
to;erof:s
theyhappe-tl
finalll3articles)
to colleAorabolltvitllin tizerecelver It Wouldbe impolElble
thefa{hesthus pro
to appea-ranee
weigll therlz;;bu=taccoralitzg
man5ypcsundscafsvood could lwothe fuppofedt(38
ducedfiXolal
sveiglltof afhesproducedby burw
weigh a graitl: Tlle glOeat
bTthem
itlg woodlill the OpC:Ll air-arifesfrolnsvhatiisattradEed
the airv The airsvhichI get ill tljis manneris wholly
frotn
ButSit
air iLl it.
withoutthe leaRparticleof L5xed
illflammable:,
svesllmadesor witIa
le perfE&ly
orderto thisSthe cilarcoaltnuLE
the woocls
fuclla heat as wouldexpelall t}le SsedairsvXlich
aiXM
till it yield ilaflamtnable
contaills,, and it tnuR l)ecotlt-inued
is I:ootlpl^oducecle
letol^tS
tuly whicb iIl a< cartI-wen
Brooda
4XX lDr.PRIFiS'rIJEY'S
E^per/;Ale#/S
relcting
toPlslo-iCov
\\rood or c}]arcoalg
ls even perfeElydeRludSible
ttlat;>
*>-efolvclble
ilwro
ituflamr3:lable
air in a goodeartherll
retoIt)atld
3 fis4t
tll2t\rouldabouttnelt irow It1 tlaefecil-cumilatlcess
tfrerallt11efixedairhadcorneover,I lzasefeveralttmescolltiz
rluedtheplofs duliitlga ssrhole
day)ill al1nvlaich
timeilaflatne
inableaillslaslten produced
equallyarldxsitllorltzlaly
appearatuce
of a tertnitlatiot.Nor did r srotldelfi at t6wisg
afterIeeiagit
wholly vatliffiilutoituflatnrlzal)le
air it tvcMa. A quatltity
o:f
cllal^coal
Inadeftolusoakg
vawd
weigllitlg,
aloutawouncesge1z-eZ
lslllygasrene a1Oout
fiveot11ace
tneafuresof iIldlalulualDle
ait itt
twelzre
tnitautese
The fec(3lld
al-ticlethatI thallnosr nzenttota
aSordsatz itlv
dilputableproofof tlle getleratloIz
or fiXMecl
airfiroladepl-llov
giRicated
airalldplllogiSl:onf
or inflamlual:)le I havefeve
ra1times
it as my
oariLliollg
tElatfiXed
faHatiovs
Juby6tanca,
allda modificato-l
ot tle nitrousatadVitliOliC acids
aly fotmerexperimerlts
greatltr
favoul^;lag
ti}<;lt
catlcluf<oil
X but
vllcltit was compoSed
of dephlogi0tcatejd
alralldphiogiRon,
rllougllmailltailled
by my fi-iendMr.KIRWAN' I sv.s f,lrfrotr.
l;eingfatisfiecl
with, till I wasforcedto corfiCat
to 1wis
prcotnf
ait4*
gisTell
it Irol:n
tny
a114
ORVI1 former
is
I-witn
leaveto
it9
as
irota s
3
air. TwouldobSeve,,
sroll,whichcouldolllygiveinflalumalJle
itfielfinto largeballsgwhicllapZ
ironformed
tllatthe 1nelted
alldwasIlo loogeriron
to bea merek
peared
the coITiZ
concernillg
to; put this hypotllefis
Afterwards)
prooi;I tnixeZe
alr to a tnorediteEt
of fiSsed
tueit principl>s
virrwitllredpreciw
oszlyLnflammatele
g;avte
v;*-hch
Xrotl filitlgs?
Azr.
of hzer Xazo
vad thefeem1ngGonauefon
+t
orglaJ2D
delrhlo
pitate svlltchI fatllldto glvetlothirlgbut tEselJul^eI}
glafsretorte
giltiated9a1sdwSletl10heatedtllelM iII a COated
{f fixedairviLl fOItlCApO-l^tiOnS Of
they gavez}greatq;uatltity
lJut
ly li-ne-Rv-lterX
abli30rbed
tere
whsh nltatettetl;-tssteoltieths
svhetlI tnixrdwit]
ti[ovreve-r;
J:Slad;
Ct3atC0ay tVllicll
^
ilOtl
fiorl:
producecl
otlly xlaflattlrbla5ie aXl* ttt-e
foundtos
tRIf
(f it re;Xwained
pas*t
oulyotwefol*tiettl
it srasblpure tI>at
re-6cluus
the
wtas
tnflarnmC1133fla
0t'
qilltity
fili!llgi
i-)oNvtitred
.0X-cdF
giv7e
<tir
red0pSlJecF
i- fised(air }9orale oanceof tTwis
ouilcemeailres
Klil*alldwlle]
tneai;lesd det}ogiItated
pitategave6ooulwce
withtWo OtEltlGES0 SU01t ifii'lilhgSx i.t gfitsrt 5011t 4<) 01lilft
znised
F wateT !O).
a-bIbarlDed
frxedar thatSwe-adua-llv
mestires-;-oiS
i fiad the i:Xae;p)
thratwas-tlfh;mttab-le.
fidesa reiiduum
];otiQ+stl NVh;Cll-
fEt(1'
1E;1}
alil w*11Cet
0-5
eatElt
of tE>
mateliillst
atldch,arcoa.l.
}
theit
al:llllOt C<3112C1Ufd5t
l3t)fiC1VLItlO{lSy\vitilOUl:
aklIlg
I+lOtlCCy
is a goodburl;
itw;pllfilofophy
xaia
illRrument
holrverywtalllulule
iI) {nay of nay
tuu> havebectlpercei-Vel
r]g lesso lZla;s;
6014tfJ,
_XM
Exper}Sents
tetI;g
theemizlg Xe+
hfer
gntoA<
SINCE mallyper{bns
haveexprelled
astrithto be acquainted
with the experitnetlts
i: havelately tnadeSwhichat firAfeemed
to ivour rlleideaof a converAn
of w4terxnto dir) but svhich
tertnilaated
ill the dikottet-y
of a
itl my opiniconllill snore
extraoldillarysT thallfubtawlt
t tlizeRa1 Societytlzereftlltof
the obirvattotlsI 11avealready1nade;thougla as yet9 I have
&y11o-meatls
l)eeilalJleto fatisClnyfelf {o Sllly as J cotlldwiiS
wltll rerpeEt
to IAtme
particulars
contle2edsvitTltlle ful)je&*A11
r<e/) sz7hlch
I fl}allfiatemay be depe1ldeel
upcta) but it is
proba}zIc7
that di;it-eIztpelZiot}s
;zla.ydrasv diS-rel<tcozv1?Wi0Ss
fiaS
2,
fi*OlM
andtkefee7ouing
Coozvef
onof tYateritto A4r. 4t 5
fromthem; a1ad
to mereopinionsI have never{hewnmyrClf
muchattachedO
Havil)gbrtmerlyoliervedfevelulremarkal:)le
challgesin fiuld
fufia3zces,ill confeqwence
of lotagexpofureto Ileatin glafsveflelsflermetically
fealed(Ofwllichan accoulatmaybe feell-:
in
fourtll
Of 1ny PllilofoplAical
I
then fortneda defigtlof expoflrlg
all kitldsof folid fuleJ}anc>s
to gleathears ill a f1lmilar
fl:ateof corlfi1aetnelltX
atldforthat
purpoSe
provided
mySelfstritlla caR-iron
vedel uthicllr coul(l
cloSeat one;endX
like a digeRerX
and of ftlch a letlgtla,that
otleof theE
elldsmig,-llt
l)e red-llot,whilethe otlaerss7as;fuffi
ciently ct)(31 to be h;llldlede
1>0this end theresvasa cock
cvilzed:ed
to (I tulDe,I)yrneansof svllichI couldlet off fieam,
air, ill allyperiodc)ftheploceI9*
I itnagiaed,tha-twhetlfubItances
coniL1Ritlg
of partsSorolatile as to fly of befiore
theyhadatt:ailled
anvconfiderable
degree
of heat, ill tlle ufualpreflilreoiTthe atlnobheresrerecom
pelledto beargreatheatsutade-r
a greaterpreffilre,
theymight
ailurne
l1e6^r
forms,anda
ut1dergo
remarkable
changes fimilarto
wlaatwe tnayfuppofeto be the cafessTithill
the lJowelsof the
earth,where9bymeans of {;lbterraneotls
fires,variousfub
Ilancesljealgreatheatsul1der
verygreat:
preIlures
>-I-l1avehadthis
butit rvasfo ill
ltrud:ed,thatI could110tmaketheuSeof it that I lhadorigi
l1allyintended I tllereforelately fittedul?fomegun-l)arrels
t
ixlthe fatne
andma(letnyfirR:
experimel1t
svitl1limeZ
expeding-that svhenthe fixedair, alld otliervolatile
matters,thatmightle cotltaitwed
in it,, Illotlldbe compelled
to
beara red11eatwithouta poilbilityof rnaking
theirefcape,the
fubRanceitSelf-mightu1wdergo
fotnechange, but I laadtzo:
particular
expedatiotlconcerningtShe11ature
of that chat1geQ
V9EJ
LXXIIIX
Iii
; I hadX
tlhe
Volutale
()lerVatioIls);
014
il1titumetlt
rna:ntlerX
Rotle;
fiotne
years;
con
AI
A
b- attbttt atld1[team
thatur>)uid
irz;etttw;a to-^ai
li-{liculty
to anp;
S;rXM8tifhed
.ti llt >1tldCt410 gUtat a ptCrd
neigh
I s asnR>lltit>Jilitzgt-l&)ft idC-itStO I4>itX4
m1e3:w
hen 1A.e
t be 3ituXXae;d
I havetile T-lapluita>->yis
3)o-Vlllwood
of the
OfIliSytf1zthLttof tAktpolE51Tity
t-dea
a Iit<wilar
vtotic-d
ttl
AttrAt.T7
t < v
t11tit
icel
ii()
l)
fi
t } t
t.-} 8*
AA >
i.;
R-L
%zlaOre
t 1 t
1X
t2-
yi
t ]
1tl
Ibnae
cou(1 be
tTat if t}Ca1n
-Xtuto expeRt]wissHe tt-zoub77At
tile
(Rzrpear>(zilces
ot
u-OR:$kitag
tliJ
l^;Xad
tir-Ctzgine
I1eatffiiotel be cota-Vertnd
-naderedtworCothtlta]l ttS
ot}ter chcnge vould
;nto fel1ti)le1-1eattitl-er tI<isor Sc>ine
1Glte-3t
pCOl)AlUlFt tA1MstplRCt
lX)CX
1'2S
tIl itS
lr
C(DLl0ttCUltiOl
4 1acld<aRAft2S NCN73StO
to tzXyfotrnerprom
particu1adxr
lLed
LZ1t tO att>tldmwore
atwd
in
itu>fioz-)eX
t1atureand I began uXit-h
Of a t^Xtn1lar
ln xvhlchsvater
Of givitzg a redlzeattt3 lilme
to t11eeEEed
tt tnlglatpoiEoluly
tElit<kltag
cornlir1eclv
le previou{ly
o<ly tht3uld
thervatertitIS rd-hera
lmalsng;
havethe 1ametieA w1t:h
lIlg
rlXy
and mis
Accordilg;ly I took a quatltii y of vve11catciiAed
X-gwth it a littIc water o-Uto:5-Rvhicha11atv twadbeetl careSlily
limeS
carthen
in Xatn
I expofedlt grasduatly
b)XIed9
by 1X3X^*
wD1th
fupplied
as I lladleen ufually1;Xch
zerortS
by his>lovealadge:lle^ous
dtR1nt,uified
Wo0:D (uTho is as mucTx
1X1
his
of fcience as he ib1)yliis itnprovenzents
erlcou1agetnetwt
difL
arwy
OWS CUfiC>U5art)-not iSagi21I.lg t1AAt it couldIazake
ffiouldtectiveits heat
rewce svlzetherthe la:mefe p1*eparedS
glaXeProceed
of
ve-Eel
an earthen
Ifo.undthat-nothilagcanzeover
trag,he3weveri-wthistmat12er
quantityof sGrs
xrasaggreat
butthatutlaere
in theformo5J9Mvt7ZS
aadlat
6JfthewaterX
t;tuesmorethanthe 1)u1k
laundredi
-feveral
that
5
to
Rrotag
llent
XTE9G
retort
ot
ill
ircatl
or
X w"/-^ + 7
f ArmZ
O fiNrCd AiZ
pr-oportioll
therewasi:l it a confiderable
that tituW
hadtlOt been
whicIl 1 lmagitlednuighteitherbe tlwatwtlxich
of fome
be comp-oWed
or 3mxg:ht
beilae>ifficierttly expeLled
in the liluesalldthepureratrthat
eontai1wed
rnatter
plllogifEtc
tl1atthe
bythewater* fbrI owrlI thellconcIudetlS
svasyihelded
Aefer}Xzg
and
C>tverJWou
<
of
thewexght
asth fomeof theproce-iSe$
efpecially
the
theairI caughtwas ve tlearltrf;f not quite equalto that:ofX
waterS
a larg;eglafs ballxtzbetweenthe
the watersatldltlterpofing
that1tremailled
it the air, I obServed
and the recipietut
5rerort
periStly coo:landdryduringthe svholepr<efh and liveral
Cedin
cotlden
therewasnot the leaRltnoiRure
hoursafterwards
of tif made
prod-uce
a-quantityof another^
it I alSorecei^7ed
vlewedit w<tuthe
in mercury}a1<d;having
n this 3ma1lzer
greateRattentlotl obfervedthat att;erfevera1days,it never
the leaRmos-Rure.
depoEltd
litneRot1es^7iththts
3Ethetl calcineda quantityof natura1
and found1R0
in the famem;alwner9
interpofed
$lafi 13alIootl
s
taterS
8 Dr PuT
+X
EiSPrt- BYS
Exper1X8nSsre/ttmg n
w>/SzXIl4ara
alxra;)rs
folue lOlb of t1le ealtll IL1 ttit cloudinefiof tti aAS
nntlaenever
ttweprodulSiotl
of it svasrapideIraa tw1ture
precefiI
11ad
abtltldatlt
prooftiat tEleairdidno-tcornef}^otu
ataycartlay
luat-ter
svitll
wlaicil
the
beetlconSixaecl
LI;therto
I tladno ideblbt-tthata11tl1atvvasaecdaryto tI<e
coI<X7erOtl}
as I cotlcluded
it to be of waterz11t-o
alrX to
;ive ita redlleat) witllout wthicl-l it svouldI10t QUit tlle calca
touseartl-l;atadI imagI2led
lzyt:hislmeatls
the Illatteror priXcipleof heatsvasfo illtimately
cornbilled
withitnasnotto beIe
pal*ated
fi-omit bycooling7as itl the cafeof IleatmeBut IS aswell as all my frielldsX
sras a lo1agti.ne uttetlydtfcollcerted
1v7pOIl
fiIldingthat whetl T put the Whitill g 211d water illtO a
coatedglaHs
retort)the watercameove1^
iIl tEle
fotom
of tTeamS
andlittleorIloairsvasproduced TherefultsvasatfotI-lefame
svhenI nzadethe procefsin a gulz"lJarrel,
ilaa UJo;rcelairl
retort
c-ln eartlletl
retort
glazved
iratileitllide.
tIlat t:T<e
eartlllaadnot loR its property
of doig its partiLl
tlAehutineltsS
I foutldby puttingluorewaterto tllelafale
sz7hitlnb
utthich
fladSiled in tlle glatsretort9atldwllicllhadbeelluSed
-Xolefs tlwlan
four titnesl)eforeSand thetl hevating
it in atl
eslrtlleil
Xetort
n s^7Elell
agatnit gaveair only) alldrzosvaterthe
srater
lanWd
\\T98
or
ewven
fatzleaS
4tr
\\'t$
iuL
hetO^eO
ttly
t()
CatwtX1et
expreEs
lalyfttrprife
at my ullexped:ed
failurewltI
t.t1O glSS
rCtOJ*t t 9Ild -tBy ipCCUlatlOIlS
(:)Il the fubeAsvetoe
va
ricous,
but at that titne ealtogetller iilefFedualAJ>motag
other
thil3g;S ]1;1t
occurred
to .tMe tllajeS
poIElblya
foulepllsgalS etlkler
sotwtained
ln the tarthet-l
retort
or-cvnaitlg
thr6oug;I-l
it (theugh
3:couiclnottellhovwg
oron wllatprinciple)
fromtI-leErelnight
be necefiary
to watel^aiwd$11 otiler fulailcesS
aSutningthe
te3rtn
of a4trs But ^vvhen:
w-itlltllis idea)l put lpiritof zvlnea
j
o-1y
Arv
of 2S7t-l6r:Xato
fc?emtg.Casverfin
vvd tEua
+ ry
thefe
to tItelime,,I got notilirlgfiro;tm
oll- ol iroll-filitlgs
ail^frou
l)etdesRentuatd itlRarnInable
itl glClfS retorts
cOtltELiTlillg plllOgi2Oll
tleSefubRatlces
of
fI>Ilatthere sv^*s
s
the-ai>t
producecli
svasmadothtt lleceIlXtritly
retol^t
cartllern
svhellI pottaclda- b^roke
fucceedilwg
Inix
tures
tl-le
of
decof:llpotioll
irl
llotlairlg
tile
tnaterials
tIXe-
uZllicl}
\\rElS
er7iclellt
IlOt
Iny
fiotn:
of glafst
itl
-laixedss7itll
itS
ad 11eate(1
verytuucIs.
of airdepelltS-ed:
tllatthe produEtiota
Beillg f>ltisfiPed
I tlloughtof utixlgthe retorttlly svith
upotlthe retortitfel:lE,
waterX
retortX
otwe
andI
fubRalace;
butsvithout
i'or svhellI puta fizlu
my expeEttcltiojn.
ir beyoaldX
it {Llcceed
to
andetldeavoured
quailtityof svateritltO oneof tlzeleretortsX:
ounce
aboutan11ualdred
I neverfailedtoprocure
diRtlit getat157
of air; atld tllis I coulddoasoftenas I pleafedsvith
1neaEllres
air
the fameretort,andwttlloutits long anyweight> andftheproduceditl tlis mannerhadnes7er ally portion of Exetlairin
it, aIld was always but:very little inferiorto that of the
armofphereX
thatverylittle of:tllis ail:
Ill all thefeproceSesI obi:erved,
orea3*tl-ly
al1ylimeS
waterS
foutSlc
was
itl the produce
retortwas evaporatedfor the differellce
retortto the firequitefullof
verylittle whetherI expofed;the
of wateri1a
water,or withouly aboutar;outlcemeafure
fora IhorttitneXalldthenpourw
evenafter
lng outall t:hatI couldfromit fo that it wasonlythatwater
of the retortS
as it weresin the p>-ores
which was entalagledS
of
unitedto thefllURance
andwhichhadbeenitl fomemearure
of atr
to thisproduEtion
it,, thatlladcontributed
it9
letting
it
remain
full
lue aremade
itaforrns
WEDGEWOOD
Thefe retorts(whichMre
plpeclay) are
aldof burtlt DesTonIkire
of: a mixtureof freffiL
tlloughs1otto air; fo tlzatwhlle the air is
to waterX
perYious
l.reduced
44O
Dr;
PRlEStLEYS
to/7eH089
Eerincen-tsreAatzizg
the1fleR
the
flonathatwaterwllichhasetateled
prod6Aced
ill the foXneiSa eopious
its eScape
vYSllytualiitzg
;s forutiwle!SS
fttele otltlle outSde It wasevidelltly
tllat air Ou1c1
the 1asvsof hydroRatics3
to aV11
atldcolltrvlrsT
po*eJsf
irnpolE1lDleS
houreverS
tI1e
retertX
tnayX
airS
allO
get.
:Air
of :[<ler :Xxtgndtte /Ser'ngCwtoe-Z/ToB
4z,l
tllatof the
worlet}la&<
Ilot;much
-atl-d
re--tort
got:intheearFthen
atlnfofrhere
sfirlactl
^11
07@el.
tfelRff
to
fame retort till I had got tfiom;it nearly atl ounce weight of aifr,
I ibunaltheat it hadIlOt 1d3:ffo-mtlch asor S-ooouncemeXaI;ure-s
juI}
it ssttiglled
grailaill weight. Afterthe firR proceEs
fit<-gle
to weigh
it c0X1tinzue<1
threegraitlsmore-thanit didat frR70fand
of
proceIk.This Snall addition
the fime till aEerrthe
:of tlwewateihav
havecome:froma 1t-ttle
eafilywelght-migl<t:
imbibedby the necl of -theretort w}Afere t-helaeatof
witig lzeen
wele over,,
a11the-plecetSes
not reacllit> Wherlthe:firecor-llFd
1 kept:
Xla0
Do>.
va TESTLEY5S
Phlogiflons
I ke}ztthe svholeretortin a redheatforfeveralllours,atadtllets
ioundt5zatS
befldeslofizg thoSetllreegraitls it weighedeight
gl aiNS lefsthallit didat SrRe
Befiore
tllisI 11ad
foulld9thatthe calcinedvvhitingwhichI
haduSedill tlle firilexperiluent
cotllclllOt9 AS fome fuppoIedS
attraEfrolntlie atmofphere
a1lyconflderable
part of the air
+zz
Experi7nents
reiZaZing
to
tlwougll
it hadloRmore-thallhalf its sveightill caltixRatiot
It hasbee1lilnaginedbygfovue7
tllatthe air which I got S}
tilcreearthellretortssrasthatwhicllhadbeen-attraded
fjo.-xl
tlle atillofphere
loy tlle itlfde fuloface
of thtlaloButslJefides
t1-latlsoaircoul(leverle produced
xvithoutwaterst(> oluviate
t.ltS O5gtaiOI}
[Moreparticula^lyS
whell one of tllefe letort)
v6ras
giving1ts1aLQ
pOltiON of air I ilnmerSed
the tmouthof it
@XIa
a baSetw
(3fwater; alidlettilig it cool itith-atfituationS hiled
l agaiS
sstithouta-dtnittillp;
ally acceEs
of ait to the infide, axld
3ret on repeatiligtlaeprocefswith it, the airsvasproduced
juI}
as freely as before. tRlaisoperatiotlI repeatedfeveral
If it befaid tl<atthe otltfideof the retortattradedthe air,:Ltill
the ir3fidelDeing cotupoledof the fame
tnuRhave:
attradedair alSo; atidit svouldhaveappeared
1)ythe aScelltof
the waterfromthe bafotlSt;heretortbeitigfufficietltlyimperZ
titilesi
tnaterialsS
0f
SlOllS
tO alro
3ByIomet
atl
tulJe9
rvedRet*Ontls:
W:ir.
at-znto
4oJ
..
atld putting a
iittle water ill its placedEitSfurroundectwith falldSitl a glafs
alfo utitll falld, in atl iron
v-eflelg, AIld tshis again:,ffnrroullded
o1ze; and ret the heat traniinittedthroup,llall tllefe futbllatIce6
witll
t}le retort,
enal31ed
stub.e
to give
air5
itl tile
llle
::prOpOI tiOtls
lefAs
ane
S0L.
_ _lrs*v
LJ29A11. .
^r
.i
i x,
rlom
tIzeretort;rhentheexperirnent
Thesveightof thewaterexpellded
ill this pl>edud3:io-n
of aiLo
I atcertainedX
in tl-we
moRullexceptionable
manner,
luysveigTw
sstas
over
tSwc
retortand tnoiItelledclay togetlaet lolt itx
\vCjigllt I OE. + dV^rtie I 2 gl-Sx ACS yieldig 74I O'ULlCiaIe:RrLrCS
oF ail^)svilicl1(l11tlle 3roportiC3tof r< graitls- te cal>ounce
meaSure)svouiLcl
laavewtejgtlecttS dui-ts.I: grsXatld CO1lCqut-1t1>7
thrpe-fcurtllsof the snrei,-ltof rllesvater
itl the otherpl*OCtfiS the Tofsof sveightwas I 5 d-tseI 8 grs
afteryielditig 556 c)uncemeaiuresof air, ssrIaicll
would have
weighed3ds-vts. zt grsO TloeproportiorsS
thereforebetsveen
the ^rsiglatof the air andthat of the watersvasI I I to s I 6>
tlaernX
or neal-ly
l<lle to telle
4z5
the air lefo<cotltailaed
itl
0lttnig,htbe faidtlautGE
(3nly
zthew1te-) tI:lough
hvo-1n
theIW
t;^}peritnetts
it al3penzecl
to c(3S1taitl muell rn(reair thatl it hal beentholugtitSszxpable
of cor
-taitlitg. t1fl{3
-Obv-iate
t1:liS
oVjeAin3n
I colitlivedto cat-thall the
<water
that -ekapetlthtot7ghtile pore,,6 of the /re-tt3lt
itl tIle -cvl
expPlle>el
'
10\vi L)g
ilaving;
n) allilOr.
put
l:e
t0iRtledrclay
lJ1 St] catrt-heIl
tluSe9to-Xvhich
I laadfi:tteda nc-ock
atwci
-a 30rig
tUit3t (by tnieatws
of -vvilich
I
<-Could
colleEta11ythW
Eairthat ccltntfrotnit) I 13t1tthis tstElill
glSa$
whxicla
svasclofedat the end
fire, but
opewat the-o-ther
end alldfo lo-lg that1 couldca{ilyknepthis
s3penatld grlitecool V hle;theothiel:vasitR the iEre;cotlSe
q;Ctlt^ly9
zsrhate-ver
wa<ter
eXcaped
dthrough
the ;poresof tiae
Qrtll!eil
tulSeit srouldbe co-ldmi<fEed
ill thecoolparLof t-tleiro
a1S-lsrotl tubeS
twex^t
tile
one tLkzswaterIca--refully
colleiSed and:alsrrays
fou*tid;tizat
tI<e reig;0Llt
of itS toge-ther
vxi:th-that--ofthe alrproduceditl tXhe
svas lbearlytlwatof tlle origitlalweigilt of tEle
water) eftimatedby the loEsvf weight in the earthetltulDe alacT
it-S CO-tlttIltS
I alfo foulldXthat tI1CX
water fo coll-edEed
fexved
for tl-leprsoduzAiotl
of more air juR as well as a-tlrothervater
tXperitneta--t5
fo -thattherehadbeellno decompefi>-tiotl
of l:hewater
in theocabSeO
InLthe laI procefstIaatI wetlt-tfihrotzgh
of tlliskirldgrtle
loSsof sveightinL
the e-arthen
tube, or rat1wer
of t-hesvaterCOT1zvhatesTer)
z6 L)rePrIE$TLEY $ XperiE7Xea/!
telvgiSg
to p+Xs
cJ7lindlelca1
glafstulze dividedaccol@ding
to outacesandpatsof
outces of nraterfit svas not eafy to avoida trOr of a few
eScapedinviflblyat
rot1tUIetlt-1all
I was avvare OfBe
9atN
haXrt
Il1U
tShO
oTtICtz
t-noutho f
tla-e
coulctentet ty t;l-ae
poresoiFthLe r@to3Xt at the
iatme tine t11at tt1e svater was raakitag its elwape
out of thetn9I
t}aoubht I afcerta;led
pretty fatisfadiorily
I:>yRINmOrX;tLg thO
Tvulb
of it iw H}eRGllys COt'blinCd iN 1] iloll V6ffi@ie Il t11CO
- l Iant tlothiz<g
cilcurnItances
I olJtaiLacd ail
-.ifOrOlpial
as
of airfro1nlazolRetled
clay atldI diScontzIlued
the proceiirvlthoutperctis7itag
awyterrnirlatioll
of ;t@ 13utthe
rnomentthe rerortsvasxaifedout of t1zeme1-c-vlrvS
1t gave air
threetitnes as faR as it lad dolaebeiSoreoT1Aequalityof the-nirwas the fatneXl bot1wcaSesSviz. a little s7(>Xfe
rlaa)<
that of
the atmofphe1*ee
I even colleEtedthirtyOv1tlCe
lneafure3of air Whell the bulb
OUt1CC' meaIures
of tIa@
fame retort:was iLnalerIed
1Il 1A0t lit-lfeedoils but the pro
dU&iOI] Of air gradually ceafedSatid tlle tlext clay I foutadthe
;retortaltnoR fu11 of the oils which l:zadfoaked through ita
on1y
phlogifl:ictCde
nosv
gave
reXconverilotl
\47att
d020lnp0fil-lg
1Il
4z7
of 7zZer*arto fr.
te tref7rsgCar-;;erfn
v;ssrf
I
afterits formatiolla
fflf-andI10t what it mighth-aveitlabibed
air
alld itwflalutnable
of both dephlogifticated
madea
everjcomeinto
il fucha malltlerasthattleitherof thelnIhoulcl
iil
contadt urith l^7ater, receivwing thetu as tlley sveleproduced
mercury;. tlA.e forlner firom llitre, alld itw tlle middleof the
\vslS COlMC os er)!
procefs (10I1g afitel the waterof cryfiallizatioll
chalcoul. TIletsroliinds.
alldthe latterf;-otnperfeflcly-made
tlaelntogetherby.
by fis-ilzg
I decom?ofed
of airthusproduced
of sv-aters
depofitioll
explofil*andfoutldatnallifiefl
t4eeletotric
as if bothtlle ltilldso
ill tlle falue;aantit5*r
aIldto -appearallce
confilltdbvsvater.*
ar Ilasll)eeIlprexrou{ly
ofwater
of tlze(lt-latatity
tnol-eaccurcltely
II1orderto Jvudg$
it withtlle sveightof the air defo depofited,aildto compare
?ieceof filtcrilzgpaper,aIld
compofed.I carefillly
iil
tle lllf-deof the glaIssZeiScl
it agaitl,aIad1
xveig,lled
tlle air had 13eendecompofed,<
w1aicll-4
tlaesreiglltof the
alwaysfoutld,as llearlyas I.could
ty tl-le?a?e-..
airi them-ifiureacqpired
decompofed
t, ill the
;11tllis exl?eriinell
As tllereis a fourceo deceptiots
to adheleto-tl e illfde
melctll-y.vilicil areaptX
finalI;lobules;.of
t11?1)y tlle p.swrersvitll xvl)icll.
teV)
of the glaSsvefiel,
tlle izapervitll tlleInoiRul-c
ssreitlled
I fametitl3es
it is vip@do
qualltitby
ssTeiU>lacd
1laVitg
thetl
BtipCd
\itiloittall
jutlge
alibl
lvhele
lDetallietl
t)tltlsottlle
it il]
svarin
naerct1ly,
ttle
;t-*
A-lotllcrs
4 78
Dre
PA IE$ T L EY $ XperiE7Xea/!
(
relvgiSg
to P+Xs
Atlotherp-eI5tlmptioll
ill f:avotlr-of
-thegeneration
of ttz<4
a.tnwoSphere
fiotnfwater wasX tIla;f
=the
-purityof tIseair that1:
pOiucix frotnit is :fo veryillcarly
the ramevwlththat of t$A*>
atmoSphereO
ALlcl
the-degree
vf lleatrequirlte
to produces
t
ereig,reateL
-tha m-aybegivenby the raysos
fun
cvitcvX-<l0;an^eso
Stll)terraneous
fites, laowever9
w0ui63
be >tStX<
,
it''t
tlflt
3!tl
C-81^63tt).
ciL1tlely
tvlfFicielltfor tlle purpoSe9as it appcarsto bw fuicnFiX5t
tor tI-e converfiotl of svater into refpir611)1e
airs tEat ie con*Re
\vittl
cl9y
cot:lxJelfioll
Lofwater into alrin this proceSseIlu
favetlrof hic1)5, hosveverst ;maynot be amifs to obServeS
tElatthe greatdificulty Mr. zDztuc Satad
otlhershave foutldit
was
ne
1oCal
expellillga:11
air :fromw<ter9 is be{taccountedl
forOI1 the fupo
pOiitioli
of the gelaeratioll
of air flornwater,tlloughn other
ircuinllacestlaantllofe that 1 have obfe-rved0
I l-lave the
pleafure
to addXthatMt*.DE LUC hitnfelfconcurssvithme ita
s
tIl1S
Opllle10t16
the-diSicultytlnat Ariakes
tnallyperSotls
tlaelmOfi
foleclL)IyX
i&
the xvatatof analog-vltetnareen
the collverrlon
of zvaterinto air
vith hny oLheld
kRosvtlfadw:s
n ptliloSoplly
ox i nature Bv
-adlmittilg
that this coWe{1Oais e:ffiUded
l)y t1le iI1titMtO UIliOtl
rPtheJneatszag
Convefor
of Mater
28/0 Air
4tg
or wh-atis called;the principle
of hearwith the water, it ap
gpears
to lmeto be frifficiellotly
allalogousto: other changes, OLX
-atllercotntiiXnatiolls
of ftlbRalaces.Is laot th:e acid of nitley
and alSothat:of vitriol, Xathitlg as ullilte to alr as vater is
rlatirpropertiesbeilagas remsarkably
different> And yet it is
detnollfir.ll)le,t-hatt}le acid of itre is coalvertibleitltO tlle
a.lldprol3ably
by tlle uzliot-w
vf tlle fatz-XeJ
pritaciple
of heatj
It is trtle, vllatReamis a tluingveloydifEere]tfrOIM SX1, atld;
I 8fillcitElatit is tnotable to decompofenitrousair; but theIlX
thoughit has acqllired
fetlfiblelleat,it 11aagot llO latentlaeatfe
gtw.ituatelycotmlitled
svitIait as it is
air; and for the fame
reaSo-nS
perllapsnthe rapourof 1aitrotls
acidis xlotzdephlogiRi
catedair.
By the fame procefsby svhich reEpiral)le
air is tnade t3y
means of water, itlflamnable
fair tnay be made frotn liquicl
purett
tefpilealule
air7
t\titl]
fiubRances
contaitlitlg
plllogifiotlvMakitlgfpiritof svtneto boit
iz a glafsretort,I rnade
tilevapour
pafsthroughtheRenof aTaot
tobacco-pipeg
:atldfourudthat it ixvasall feemillglyconveltec3
intoitlflatn1nable
air andit wasof thatkitldxvllicllL)urns
svitl-z
a lambent
wiliteflame. 13utwhetlI let 0theDpipecoolno airx
xvas producedZ
but ola]y vapoul"svllich nvas itwlItaIltlycot1
denfedin the water.
BeitagIlosvtnaRerof a tlewalldeatt procefsgi was willltlg
to exteildit to otherliqtlidfdi3Iarlces;
atld I preSetltlyfolltad9
as I thetl itnagz}ed7
by this tnealls,
I could give a per
snallelltnerialforn to atly liqtlid fubStallce
that 1wad13eetl
pre-:
vlouflytlwrovvn
into the formof vapour.
- VVhetl1[lr.adethe VApOUl of fpiloit of tlitret llenteditl a
glafs retort7pafs tl-wrougil
tlle Re*n:
of the Elottoleacco-pipe,I
got as pl.lredeplllogiIticated
air as ever I llaveproctlredfrom
K1 k 4
aitreX
tlwatS
to
Dr. PRIES14LE,S
.Evatgrgf72aS!s
re.ld-;;r3C
/a^PtXinn
retort
utas
conile&e}
haarecontriSuted
to
COleltam11late itv alld giVe it d 0;g1lt
a^lixture
of fi edair
SY1t1:1
Q11
oi virio3i S(?L
a*8:r
coilEdercbly
plllogifticated7
i
with
the
plpe)
Bras
cliOlve)
alld
tnuti
a catldlemtouldnot tanveloul*lled
itl it; but this1 alfeattrX
hv1teto the covXS >tlwicTl
wab dttioVedirttE1e
prcCeS. tI8here
futt
was
Ilearly
tI+ StnQw}wetl GL
vlfed w*(1ter ltnptegllated
woitIl
witriol acidail) tilouglltne corkxvasLl()t difiolved But tl<;s
acidis known riocolitaill
ulucil
phle3giRo3lX
Spiritof filt gaveair Ilo purerthatl the beI}atinofpherical
air But tasby ti;s proceIiI tlevergot air 18pureas this from
water ouly I collcltlded t1latts7enttls acid9as sntellas the
tlt<at
nitrousatldvitrioitcS
is capableof beingturnedsuto dephIoX
giflticated
aIr.
WheXlI uSedsvaterimpreguated
with fxed air this air was
expelledby theheat atadcame 0A7er
wlthoutany chatagethat:I
could
exceptthat the refiduunzwas larger Som the
watert}at camealongwith ite tI*lleair I got aRerwarals
was
oxllJr
that fiotn thewaterSaladof the tne qualityas if it 11ad
perceiveX
notbeewlmpregnatec
t W1th
hXec
alrO
Waterimpregnated
with alkalirleair gave neitherfixednor
inXarnmal:le
airSwhich I had ratller expeAedX
but only air
contiderablyphlogiRicated;though IRoule
of it was fo pure
that a catldlewouldlaaveburnedin it
N :B II1all thei tspertmetltssviththe t:obaccowpipe
all the
atirwas remarkably
turbidSlike milk>-atldaventlle comrnonair
X}tlle-retorttxeire vlleprocefsproperlybeban@
In thls Rate of tlle experimentsI tllilll [ nzayventureto
fay that no perfotlcouldtave f9enthenzwitlloutcocluding
thattherewasa realconvertiotl
cf waterinto therebeing
1o hnoznprilcwleor d X1phlloipl<yX
thatcou}(1
haveled
airS
XP
.4
ang
,.v
tX
.st.JiX
].
2,<-*.
znfo241vr 434
ff tYater
ud tbeewttg ConqJerfon
a fillacyillthecaIb. Irlthis therefbreS
to fuIi?e&
perAlu
nany
I lnuRhaveacquiekedas illdeeddid all tny acquaintalwe,
on the i:ubJe&>
eventhofewhohadbeerlrllemo itlcredulolls
ButI wa-s1ecl
Seentheexperimetlts.
efterthetrhadthetnSelves
of
irlcolltiquenfce
to the fartherprofecutsnof tlllsbulineSs,
de
havitlgobirvedthatthepUttt of theairwhichI procured
contit
pendedupon the Rateof thatwhichwasilnmediately
I ippolddthe
retortortube ill wlwich
guousto theearthen
havebeerlmade;atldthatfoluecommllicatior}
converfionxto
of any
to theptoduEtiotl
was neceSary
with the attnofphere
withtlw-e
andthoWe
withthedigeRerS
airSasin theexperitnetlt
airssras
clayandthe burninglens. AndEncepureest:ernal
by
in orderto procuregoodatrfit was concludedznecelSary
WIr%rttt7 thattheope
iveralof myfrielldsandefpecially
rationof the carthenretortwasyto tranfmitphlogiflorlfrom
ill theclaytothe exterllal aiL ; arldtllatthe
thewatercotltained
ssrascapableof beillgeollverted
water5thus depllloglfticated,
of
air by the illtimateutliorlof tlle p3+ttlciple
into refipiralble
;
heat
of the externalairia
whatthei-tlfluence
to afcertEaill
II1orclex
this cafe really:was,I inclofedan earthenretortfilledwith
ttlrough
openatbothelldsy
clayirla largeglafireceiver,
moiRenec:l
I tllruRthe nccko;
the upperorificeof svllictl(leillg 1larrow)
plAClI3g
) 2;tad
air-tigiat
it fo asto be pet-fE2ly
lutill>
the
by whiclltIe atl-witin svas
ill a bain of wtaterX
xtilerece;srer
airXl fitted
extertw.R1
with vlwlte
al1cornInutwicatioll
c-uteiTfrcXaa
whicht co}all
oS t-heretorta gla1ittlb t11toug31
rwouth
to t1ze
It1tElisf*Vlatkotz
w;s plodzeedill theproceSO
receivewlwatever
llr:l
CSCe1LCL<
tlle retortby zueansof
lzeated
retortX
*MI'o
t}tEEtRS
ttlletubecomrxlulwi
tllroug;ll
tvceived
) but aFt11eIne
as vlltu4)l
reC;rt
a:ftl-S-e
the itltie-e
catillgwit'ttt
air
wllell
lells7
;Xng
was
aFp2Cnn
rel-;;r3
Dr. PRIES14LE,S E>ttgr*f2azZs
tiluethe xvater llo{e svlthintheftCtiYC5e tt'his effczA mightbe
t}:e rectirter;tt
O>vAf'itlg
to a p}11Ol0-iCiitiOll 0 ttld airwitl-zitl
4J2
9 svlile the
pl-tITilre
of the atlnoSpllere
have beetlbrced by t};we
svct1tFheother
\vttiaS
Witl]
vvlaichtI-Se-C1aysvas troi{letwed,:
ssray lSor had the retol*tbeexwperviousto ai1*as tIzeixllide
eXthe svater
vitta tlle (<ttno{9hei
llad a f-ee cotnnauilCatiotl
tnoxveverX apr
couldnot haverfiCtl nvitlain vlae
experitnetltse
decif1ve
pearedto be tlle caSehy the f0110X^7illg
clay ss
retortwlth tlaemoiNCtled
Havingfilled-tlaeeartSwelz
efiQrC
I azadetlaeilzlfldeof the receiverperfeSIydry and
UpOllj heatingtho
placedit lil a baSotlof mercury+snrheneg
snras
Kall
coveredwxtilclewswhich
retortas beS1*ey
tE}elXeceiver
dzn the ilatideo the receive
colled:i<g
intodropstriclSled
aladretnalned
upon the xnercuryhich xofewithin
I had
receivedfretllthe retert
CeiYCrx shile air svaXs
receiverv
14^1lis
tlhe
aS
re-
fU2I-
atr atadupo
I thetz-fillecithe receiverwith=tzflamnzable
hcatingthe retortit wasall drawIlthroughit> anddeliveredls
5
a.S.,
Lf
6433
as;Rrongly it-aflalminable
as ever by t11etu1oec:Ornmuljiccti]g
vith the illE;deof t svlailethe watcrrofewithitl rlaereceiver9
atidterellcoveredtile retort,Whicilvvasfixed at tile very to
of itXfo thwt Eltrdlyally of tile iIflal<]t:nable
air rem<zilled
^rithinit/ -1t1like rnatltlerlaitrousairpaICed
threlightE1e
rt-tort
dal thcvffliolffi,r Corzverflon af 3mfer
ti
into Air.
ulllchaInged.
Fron tEaefe
:expt-it-nWnts
it iSsitnpofiSble
IlOt to ilifer, that t1n1(>
clay of tlse eatthell
beirxgtllvis-heater37
deltroysfcor-a
titlle
the atriXal
fDrlalof vvllates7elo
ait is expvSedto the outflde
of it; svlicil aeral fortmit recoversafterit has beetl v-ral-lrif:
retortX
tt
&o
*34 l)Z^
PRIESTt.EY9S }Exper?Xetts
rGlAtXeGg Pbtogt/dogg
011 ftldlng wateron the
tilaN
NIra
CAVENI:MISH S eXpefirnltilt
-tlecompolittoxl
of air
mLy
l Cal.l20t COIlClLUdOttAiS Sccount: wlthoutackrzow1edgin;
lensS
oUligation
to Mr@
vaRx:Er
forthe uSeof lhisillcomparable
ofto ItldeedS
andls ohllgigIJrailIlingmein themanagement
thanmy
srrithout
thisarerv
inRrurnexltg
ol oneof greaterpower
experiments
could
ownSI donotltllOW thattlle laftmentior3ed
Xavebeen-Xmade
at a112 certailllynot to fo muchIiatisi&xono