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12.
12.1.
General
according to the
medium
situation.
Noncontaminating equipment is essential and care should be exercised in not only choosi
ng
non-contaminating steels for shovels, trowels, augers etc. but also in ensuring that
any
associated lubricants, adhesives, welds, and solders will not cause problems.
Leaded
gas can sometimes constitute a potential problem in field vehicles when samples
are
transported in proximity to leaking containers. This awareness of geochemical cleanliness
extends to the dress of the sampler who should avoid wearing metal buckles, rings, e
tc.
and handling coins which might lead to contamination by chipping or transfer of metal
on
fingers.
vary
Kraft p
aper
(with non-contaminating water-proof glue and closures), olefin, and plastic bag containers
of appropriate size are frequently used. Kraft and olefin allow samples to be dried witho
ut
transfer. Plastic bags are commonly used for larger samples. More rigid polypropyle
ne
and special glass bottles can be utilized in water sampling and a variety of sam
pling
devices, many of them patented, are available for the sampling of gases and particulate
s.
It is strongly
be allocated simple
unique sequ
ential
numbers which at least include a project (or regional office) designator prefix a
nd a
sample type designator suffix. These are best provided by pre-numbered Assa
y/
Geochemical Sample Tag Books. The potential for error and misunderstanding is thereb
y
minimized and problems in subsequent data management and interpretation are avoided
.
Some form of coordinates should also be assigned to every sample in order to a
ssist
sample location and computer plotting of sample locations and analytical data. In t
he
case of widely spaced regional reconnaissance samples (e.g. stream sediment) the
Universal Transverse Mercator (U.T.M.) grid location of each site can be determined using
topographic base maps of suitable scale or possibly, a locator instrument (e.g. Magellan)
.
90
In more detailed studies tine U.T.M. grid can be used to define the area boundaries, whils
t
individual samples are located by reference to a local grid.
12.2.
Sample Media
Some discussion of the potential role of available geochemical sample media in the
exploration sequence has been provided in previous chapters. Media selection will o
f
course be decided on the basis of orientation studies which will in turn be influenced
by
the local environment as well the nature of the exploration problem. Reiterating earli
er
statements concerning the applicability of the more widely used sample medi
a in
reconnaissance studies, the methods used might include:
(i)
(ii)
(iii)
(iv)
g
Follow-up studies of promising leads detected in the reconnaissance phase might involve:
dia
(i)
(ii)
(iii)
Ov)
(v)
(vi)
(vii)
and/or;
stream bank (residual soil or colluvium) surveys;
biogeochemical surveys;
soil gas surveys, or more rarely;
geobotanical surveys;
particulate surveys, and
microorganism surveys.
Exotic techniques such as surveys based on animal tissue sampling, are curre
ntly
primarily of academic interest, and unlikely to provide solutions to actual pract
ical
exploration problems.
12.2.1,
Rocks
determined by orientation surveys (see Chapter 8). Detection of syngenetic patterns may
necessitate the regional sampling of individual plutons or more detailed sampling of
specific parts of an exposed stratigraphic section. The latter patterns will require a
different approach. Surveys designed to detect leakage anomalies will focus on
systematic sampling of fault or fracture zones and, possibly, bedding structures. In
contrast, the preferred geochemical rock sample material for the detection of diffusion
naloes is likely to be unfractured and the scale of sampling much more detailed. In all
instances, analysis of geochemical rock survey material has the potential of delimiting
dispersion patterns beyond visible alteration associated with mineralization. Table 12.1
summarizes the elements determined and the sampling densities used in past exploration
programs for a variety of mineralization types.
A good example of a regional approach capable of discriminating between
productive and barren intrusions is provided by the work of Garrett (1973), which was
based on whole rock analysis of samples from felsic intrusions in the Yukon Territory,
Canada (Fig. 12.1). Using a variety of techniques, including residual scores from a
multivariate statistical analytical procedure (principal component analysis), comparisons
of metal concentrations (Fig. 12.2) and degree of skewness of frequency distributions, he
was able to demonstrate that most plutons associated with mineralization could be
recognized, and certain additional plutons with no known mineralization merited further
nvestigation. In strong contrast the work of Church et al (1976) demonstrates the
potential value of district scale geochemical rock sampling programs in the detection of
vein and replacement deposits. Their case history study was carried out in an area of
British Columbia, Canada which includes the Mesozoic volcanic sequence hosted Sam
Goosly replacement (?) massive sulfide deposit, and the Upper Cretaceous andesitic
volcanic sequence hosted Brandina vein type occurrences (Fig. 12.3). Both types of
mineralization are reflected by large As and somewhat more limited Cu anomalies (Fig.
12.4).
Scale
Target
Regional
identification of
productive
massive
plutons
sulphides
vein and
Elements___Sampling density
min. 30/intrusion
but see Appendix
3, 0.2-5/krT?
e.g. Cu,
Au, Ag
K.
2-30/krT
Cu,
150-200 rn Interval
l-10/kn
replacement
Local and Mine
porphyry
massive sulphides
Ca, Rb,
Mn, (MG)
Fe, Mn.
Sr.
Na,
K.
vein and
replacetnent
TABLE 12.1
Ca,
Mg, (Rb). (Sr)
(hO).
e.g. Cu,
Aii, Ag
5-10 m interval
Pb, 2n.
93
138'
I34<
130'
3
64=
6435
36
38
21
4r090
O T)
2 JcT
025
I90)
-2'
62'
138'
_J_
FIG 12.1
134=
130=
Cretaceous granitoids in the Canadian Cordillera sampied by Garrett, 1973. Black circles
are granitoids containing mineralization of the following type: 2 = Ag-Pb: 3 = Cu-Sb; 4=Au;
5 = Au-Pb; 6=Au: 8 = Pb-Zn; 9=W, Au-Pb; 11=no data; 12 = Zn-Ag-Pb; 13 = W; 16 = Cu-W:
17 = Cu-Zn; 21 =W: 22 = Cu-Zn-W; 25 = Sb (Govett, 1983)
*
taCeous
- jhost
rocks A(Up.Cf
-
ralization
....
(ocation
e
f
ir lH I a
Li
C r, T n
'
7*
*
1y
t-
.
source rocks
cover rocks
.i*
(FDrtPHf, Mionn}
fF-
/ .1**'
'
---
IkJadina*.
7 '
'.'i
FIG 12.3
FIG 12.2
94
V"-.'
X'fsv.-.
4
km
1
1
mine
- sampl
5.
-/
%
1~
'
X
-/
8
y
,?
FIG
12.4
95
Additional indications of some possible roles rock geochemistry might play in
exploration are provided by the discussion in Chapter 8 of the large primary haloes
associated with various types of mineralization. Many of these haloes should be readily
detectable by systematic geochemical rock sampling, if there is sufficient outcrop. The
hot spring-type gold mineralization (i.e. Round Mountain - Figure 8.11) and the sediment
hosted fine disseminated gold deposit (Pinson - Figure 8.12) examples are of particular
relevance in terms of current exploration priorities. The extensive nature of the
geochemical haloes commonly associated with sediment hosted fine disseminated gold
deposits are also illustrated by data from the Carlin District. Nevada, which was obtained
by Evans and Peterson (1986) in the course of a routine geological mapping program
(Figs. 12.5a, 12.5b and 12.5c). They provide further evidence of the potential value of
systematic geochemical rock surveys in exploration for this type of mineralization.
An
attention must frequently be concentrated on their surficlal derivative products (e.g. soils,
stream sediments, etc.).
C
(0
U
1a
V)
re
0)
re
CO
o
(0
>
<v
Z
w
b
_w
0
XI
E
>1
U)
0
"5)
_o
0
0)
D1
CO
<D
>
_o
re
E
o
c
re
o
~
"a
0)
o
H"C
=
tn
~
TO
U
O
O
n
tn
evj
(O
Oi
(3
01
Taitingis pond
S;
O
c
a
"D D)
fl
U>
<D LL UJ
(B
re
(U
i_
c
0)
u
2 I
c
o
w
u
E
CO
+J
U
o
OJ
vo
c
0
Emm
W "
CO 3
c .s'
(9
Qi
a.
X Q>
0) Q.
O
i L:.
X
o
LO
a.
<13 HiS
t_
CO
CN
4- IS
0 CO
01
C T
0
c
re 0
c 01
_re
c
0)
k>
n
oi
c
O
"
re
re
3
o
0)
a>
o
o
O)
01
Mine du mp at
Cariin mine
o
Qaf
Alluvium
- QU ATER N ARY
Landslide deposits
Qf
Fan glome ra te
Ts
Siltsone
Pliocene
and (or)
MIoccnc
Tc
Cariin Fo r ma t i on of Rcgnier (1960)
Trt
TERTIARY
Ti b
Intrusive breccia
Q u a r t s latlte
Tgd
Granodlorite
Oligocene
TERTIARY
OR
C R E TAC E O U S
TKrd
Rh yodacite
Kqm
Q u a r t z monzonite
C R E TAC E O U S
Kgd
Granodlorlte
SIUCEOUS (WESTERN) ASSEMB LAGE
i- Upper Devonian
Unnamed limestone
Popovich For ma ti on
DSI
Undifferentiated limestone
DSI, li mestone
DSa, h yd r ot her ma l l y
altered- limestone
DOb
Brecciated
and altttred
ca r b ona t e
rocks
S2LURKAN
SOc
Chert and shle
AN D
ORDOV C IAN
D Sr m
Roberts Mountains For ma ti on
SOh
DEVON IAN
DEVONIAN
AND
SILURIAN
SILURIAN
AND
ORDOVIC IAN
H an s on Cr eek For ma ti on
Oe
- ORDOVIC IAN
CAMBRIAN
Ch
H a mb u r g Dolomite
C O N TAC T
FAULTDotted where concea led
THRUST FAULTDotted where concea led
Tee t h on upper plate
LOC ATIO N O F MINE AND (OR) DEPOSIT
FIG 12.5c
Cariin District.
98
12.2.2.
Geological Legen(j
Soils
Soils vary considerably in composition and appearance according to their genetic,
climatic, and geograpiiic environment. Classified into residua l and transported types
according to their relationship to their substrate, soils are mixtures of mineral and biologic
matter and may be distinctively differentiated into a series of soil horizons.
Soils are most often sampled alona traverses or grids in the follow-up or detaile
d
prospecting stages of geochemical programs. In rugged terrain initial follow-up surveys
of reconnaissance stream sediment anomalies is sometimes most readily achieved b
y
sampling soils along ridge and spur (Fig. 12.6), and/or base of slope (Fig.
12.7)
traverses, in recent years increasing attention has been given to low densitv s
oil
sampling (i.e.1 sample per km) in geochemical reconnaissance survevs and aeochemica l mapping. As has been previously stressed, orientation programs define criteria such
as sample depth or soil horizon to be sampled, sample interval, and the size-fraction f
or
analysis. It is essential that these criteria be observed resolutely through the survey.
Residual soils characteristically contain detectable dispersion patterns developed
during the weathering of mineralization in the underlying bedrock, and these patterns are
revealed by careful sampling of appropriate soil horizons. As might be expected, in vie
w
of the size of the deposits and associated primary geochemical haloes, near surfa
ce
sediment hosted fine disseminated gold deposits in semi-arid areas, such as Nevada, are
commonly reflected by extensive geochemical anomalies in the immature residual soils.
It is therefore not surprising that geochemical soil (generally C - horizon) sampling h
as
assisted in the discovery of a number of these deposits (e.g. Alligator Ridge, Je
rritt
Canyon, etc.). Some indication of the size and nature of soil anomalies which might
be
expected in the vicinity of such mineralization is provided by Bagby, et al., (1984) i
n a
study of soils over the Dee Deposit, Nevada. The minus 80 mesh sieved fraction of 1
59
C horizon soil samples were analyzed for a number of elements including Au, As, Sb, Ag
,
and Hg. The resultant geochemical data display anomalous patterns over and in th
e
immediate vicinity of the known "shallow" (>100 feet - 40 m) and "deep" (>300 feet - 1
20
These could be readily detected in ro
m) ore zones (Figs. 12.8 and 12.9).
utine
geochemical soil surveys based on, say, a 30 m grid.
Deeply weathered residua l soils can also provide useful geochemical sampling
media. An example of use of lateritic soils as a regional geochemical reconnaissanc
e
sample medium is provided by Lewis et al (1989). Lateritic soils were sampled on a 4
00
m grid in a UN exploration reconnaissance program for Archean metavolcanics hoste
d
massive sulfide (i.e. VMS) mineralization in the West African nation of Burkina Fa
so.
Follow-up soil sampling on a 25 m grid spacing of small weak anomalies detected in t
he
reconnaissance phase (Fig. 12.10
) confirmed the existence of a dist
inct 550 by 250 m 2n
***'
)
anomaly (I.e. >200 ppm) (Fig.
* *
*/*
**
Heavy-metal content
of colluvium (ppm)
>2000
.500-2000
< 500
)*
1
2 kilometers
500 meters
FIG
12.6
Lemieux
fraction.
100
District, Q u e b e c . Data on - 1c m
(Rose, Haw kes & Webb, 1979)
Af.s**
o*i.S
Ol.o-I.s
*0T
xo.s
t.M
1100
f. .
<
1000
FIG
12.7
1100
3k~A
0>5f
e it>5e
X
X S.
+ 1.5-3 . ** ,
Example of b a s e1000
- o f -s l op e sampling pattern,
,,.0
1000-
llOO
TI.AA
-B 1.3-1.7
o I.UI.2
X .*-1.0
X .1-
1100
1000-
I,
FIG 12.8
1000-
Spatial variation of anomalous soil samples. Symbols represent the histogram groups.
Outlined samples are those that have element concentrations in the upper two histogram
groups and are considered anomalous for this sample population. Deep ore = : shallow
ore \\\\ and ////. (Bagby et al., 1984)
101
FIG 12.9
102
FIG 12.10
FIG 12.11
103
exploration method b a s e d on the heavy mineral concentrate fraction of soils (i.e. "loam"
concentrates).
Transported soils present especially difficult sampling problems, but meaningful
surveys are possible in many areas once the genetic origins of the transported cover are
jnderstood. in glaciated areas, for example, soils derived from glacial dispersion trains
can present far larger targets than the suboutcropping source mineralization. At Buchans,
Newfoundland, extensive soil anomalies, overlying tills, reflect glacial dispersion trains
which extend for s o m e miles "down-ice" (i.e. southwestward) from suboutcropping
volcanogenic massive sulfide mineralizations (Fig. 12.15). Anomalous "hot-spots" reflect
ocally enriched (or better exposed) portions of the dispersion train which are often far
104
FIG 12.13
105
LAGS
4000E
6000E
4000E
SOILS
6000E
1 km
50000N
+
-+
< 5 ppb Au
49000N
\ I < 5 ppb Au
m 5 -40
iU
5-30
30-85
40-70
>85
> 70
FIG 12.14
2INC IN
> 100
Il~c
100 p p i i
SCO
\j
SOILS
BftCKSfiOUNC
an o malo us
Q
MODERATE-STflONGk-l"
p pm
kOTg:
DITA RELATE TO MIHUS
106
from their bedrock source. In this type of situation, unless the nature of the surficial
environment is fully appreciated, time and effort could be wasted in fruitless searches for
mineralized bedrock sources in the immediate vicinity of many of the anomaiy "peaks".
In some areas with barren exotic overburden the soi l humus horizon (alternatively
known as mull. Ao, or Ah material) constitutes an effective geochemical sampling medium.
As discussed below in the section dealing with geochemical surveys based on vegetation
sampling, the root penetration of plants sometimes exceeds the thickness of barren cover
and obtains nutrients from underlying mineralized bedrock and/or anomalous ground
water. In glaciated areas, deep rooted plants can sometimes obtain nutrients from
anomalous till dispersion trains (related to nearby suboutcropping mineralization) which
are obscured by barren oveburden. The seasonal fall of leaves and needles transfers
some of the accumulated metals to the surface soil where they are incorporated in the
humus. An early demonstration of the potential effectiveness of mull sampling in gold
exploration was provided by Curtin et al. (1971) in a research study of the Empire mining
district, Colorado. Au distribution patterns in mull (Fig. 12.16) were found to more dearly
reflect glacial sediment covered gold bearing quartz/sulfide veins than the Au distribution
patterns for the C horizon soils (Fig. 12.17). More recently, considerable attention has
been given to the use of humus as a geochemical sample medium in the Canadian
Shield. Gleeson and Sheehan (1987) report an absence of humus response around the
Doyon gold deposit in Quebec Province, presumably due to the presence of 1 m of
relatively impermeable glaciolacustrine clay and silt that overlies the 1 m to 2 m of
anomalous, locally derived till. At the Williams property, in the Hemlo district, generally
poor response is reported for "B" horizon soils due to the presence of several meters of
exotic calcareous till. However, humus samples show well defined gold anomalies (Fig.
12.18) over gold occurrences and associated anomalous glacial dispersion trains (Fig.
12.19).
They conclude that in the Hemlo district humus sampling is an effective
geochemical exploration medium over terrain underlain by up to 5 m of permeable
overburden (exotic or otherwise), whilst "B" horizon sampling should be confined to areas
where the till cover is thin or absent (i.e. <1 m).
Attention is drawn to a useful check list for the organization of soil surveys (Table
which
also has some relevance to other types of sample media.
12-2)
12.2.3.
Stream Sediments
Stream
CO
ra
c
"S
a
Q. -c
'3
>
.E
.E t:
oras
"
c <
.
o
"
o
M
W
\
r oT ffl
j=
.5
- i:
n
ffl
a
Q.
a, tn
ffl
-J
_c
(Q n
0)
ffl
2
d
o
C) o
o>
I|
E
a
Q.
Oi
Q.
cn
1/5
iSd
w
03 r
cn
AOKHnOSUd J.K|33H3d
l
T
O
O .=
a
\\
\
.
c
g
.
=5
n
E E
Q. Q.
Q Q.
T"
CO
cn d 2
'S ?
to
"
w ffl
o
ffl
c
o
a u
c
03
o
O CO
to
o
oT CO
Q.
a.
M
o) a
i
c -1
<]> (A
.i:
"q. =
CQ
i?
Q.
Q.
CO
(0
ffl
2
o
12
o
G)
-JZ
ffl
O)
)
i
a
s
A3M3n03U4 1M33MU
;o
rg
rCJ
108
7+oost:
TroasCanada
Ou tline
~
malers
I 50
BHBi 500
FIG 12.18
gold
Highway
zones
MetasedimentsMetovolcanics
-25
400
of
coniact
ppb
ppb
ppb
7+OOSt
Tra n s C a n o d o
Ou t lin e
-
400
meters
of
go ld
Hghwoy
zones
MetosedimenfsMetavolcanics
25
ppb
-50
ppb
500
ppb
contact
109
Check
Item
numbers, composition, experience, leader
when, where, by whom
appropriate scale, topography, etc.
FIELD PARTY
TRAINING
BASE MAPS
NUMBERING SCHEMES
FIELD NOTES
QUALITY CONTROL
COMMUNICATIONS
W ITH LABORATORY
SHIPPING LISTS
INSTRUCTIONS
RETURN OF DATA
DATA H A N D L IN G
INTERPRETATION MAPS
INTEGRATION OF FIELD
NOTES
STORAGE OF DATA
ARCHIVE OF SAMPLES
INTEGRATION WITH
OTHER EXPLORATION
PROCEDURES
REPORTING
TABLE 12.2
(Thomson, 1987)
As has been recently pointed out (Plant, et al., 1989) stream sediment samples fall
into two broad categories:
(i)
(ii)
representative samples;
samples designed to enhance patterns or anomalies related to specific
mineral deposit types.
110
RIVER
RIVERPLAIN
FIG. 12.20a
FIG 12.20b
Overbani<
FIG. 12.21
A d i a g r a m m a t i c de pic ti on of h o w g e o c h e m i c a l dispersa
patterns f or active stream s ed i m e n t and o v e r b a n k
se d i m e n t m a y be influenced b y mineralization and
se d i m e n t sources. In tine stream on the right ha nd side,
th e active stream sed im en t is d o m i n a t e d b y sed im en t
so u rc e No. 1, a reason why the anomaly can be det ec te d
onl y in th e o v e r b a n k sediment, in the m id dl e river, wh e r e
no active sed im en t sources exist in t he u p p er part, a
str ea m-se di men t a n o m a l y has d e ve l o p e d wh e r e th e
s tre am crosses th e mineralization du e to influence f r o m
pa ie o-so urces and a presentl y small, diffuse se d i m e n t
p r o d u c t i o n o c c u r r i n g along the stream bed. This anomaly
Is diluted b y sed im en ts f r o m so u rc e 3. (Otteson et al.,
1989)
112
t
- >
''
"t-
:%/
T.r\
y " -
t'
-W,-
'
./
..'"iC, il
ay-i
w
~i> ,
"S-.*""- -;
..w
.-A " p p m
.
' . *. '
'.'
-1.6
>:';
ft Q
?i6-o
-.
'X
*. f.y
FIG 12.22
200km
Hot nitric acid soluble Mo in overbank sediment, Norway. An anomalous sample down
stream from the Nordli deposit is indicated witli an arrow. (Otteson et al, 1989)
113
Towsey, 1989). Large (often 5-10 kg) samples of active stream sediment (minus the
coarser fractions) are exposed to a weak cyanide solution which leaches out accessible
gold. The gold content of the leachate can then be analyzed. The method is extremely
sensitive and helps minimize "nugget effects". Obviously it can only be used where gold
is freely accessible (i.e. in fine particulate form, exposed on mineral surfaces, etc.) io the
leachate, and is most effective in deeply weathered areas and in samples which are free
of refractory materials and the gold is not occluded.
Geochemicai exploration efficiency can in many cases be increased by collection
and analysis of specific fractions of active stream sediments or even alternative drainage
sediment components which, in certain circumstances, display more distinct and more
consistent Indications of the presence of target mineral deposits than do representative
samples of active stream sediments. Probably one of the better examples of this type of
approach is provided by heavy mineral concentrates. These improve contrast for
elements such as tungsten (e.g. Turiel, et al, 1987), barium (Coats, et al., 1981) and gold
(Fletcher, 1985 and Mauhce, 1991) when they are held in resstate mineral phases. They
are sometimes also useful in lateritic terrain where elements of interest are held in iron
oxides.
In some areas (e.g. southeastern U.S.A.) selective analysis of manoanese and iron
hydroxide coatings on stream sediment particles (boulders down to fines) is an effective
method of detecting hydromorphically dispersed ore and pathfinder elements (Figs.
12.24a and 12.24b) which have been adsorbed and concentrated by these coatings
(Chao and Theobald, 1976; Carpenter, et al., 1975; Nowlan, 1976; Whitney, 1981; Hale
et al., 1984). However, interpretation of the resultant data can sometimes be difficult.
The ultra fine sieved fractions (e.g. minus 200 mesh - minus 75 microns) of stream
sediments have been shown to be effective geochemicai exploration sample medium in
some arid and semi-arid environments. Observed advantages in both base metal
exploration in Australia (Mazzuchelli, 1980; Beeson, 1984), and gold exploration in Nevada
(Mehrtens, pers. comm. 1986) include more extensive and consistent anomalous
dispersion trains than those provided by other sample media such as heavy mineral
concentrates and the coarser sieved sediment fractions. In contrast Moeskops and White
(1980) found the +35 to -18 mesh (+0.5 to -1.0 mm) sieved coarse fraction to be
especially effective in a base metal exploration program in South Australia, whilst Zeegers114
Geoce/Tllcol Re$us
in
p p m
- 20
HCIO4 digestion
A AS Anolysts
Kilometres
Geochemical results for the 1970-71
Tasmania. (Webster and Skey, 1979)
FIG 12.23
scale
survey.
mile
V.
N
.*-
76
5>i
f'
V
/ 'm aG R U D E R
>
A_
>/
!
yi
l DRAINAGE
ffroni
stream sediment
p
V
MAP
mine area
Sompte s<t
Magruder mme
Mmeraliid zone
.r
FIG 12.24a
FIG
116
12.24b
area,
Pajala
has
been
discussed
previously,
in
all
surveys
in
new
areas,
the
critic
al
parameters of sample interval, sediment size fraction, appropriate analytical procedures,
significant anomaly contrasts, and background levels are determined through orientation
surveys. In areas where no previous experience exists, a short interval of 150 ft. (50 m)
over an initial downstream distance of 1050 ft. (350 m) is recommended. This interval
should then be progressively expanded with distance from the metal source to the limits
of the known or anticipated dispersion pattern. Samples must also be collected from nonreconnais but also within the Fennoscandian Shi
eld
sance
mineralized areas to establisii the
technique, and the Cordilleran and
and
sufficient
material
background range
particularl
Appalachian
should be collected at each site to allow
y
regions of North America. The ide
for the determination of optimum size
within th al
e Canadi terrain for this
fractions, analytical techniques, and other
technique is where l
factors listed in Tables 11.1, and 11.4).
an Preca akes
mbrian S are
common, conditions are swa
12.2.4. Lake Sediments
hield,
mpy,
and/or where stream drainages
Lake sediment sampling has been
are
developed into an effective geochemical
117
10-3cm
Eye f o r attaching
line
5 m
FIG 12.26
.V Q,.~
O'
;0
> O
o-
Vv,
S'Q.'.
. 'OI
': '
rj
r'
0_
--
. r-- -'
( -!.
9
' t '
' - "-r,
'
'I
f ) I
. -
(\\{
Vjp..;
a'~
.,
>-/
"~J
>-
Qv
FIG 12.27
FIG 12.28
application
massive
sulfide
Agrcola
deposit, Northwest Territories
(Fig, 12.29), and in fact assisted
in its original discovery (Coker,
1979). More recently a number
of authors have reported on the
of
lake
sediment
119
by anomalous Au concentra
tions in nearby take sediments
12.30
and
(Figs.
12.31).
Pathfinder elements (Sb, As, Pb,
Cu and Zn) display inconsistent FIG
relationships to gold mineraliza
tion and it was concluded that
108-"0
7 n N es r s ho r e
l8i:e
METASEDIMENTS .
sediments
\ .90
GRANITES
Geological boundar y
12.29
Au is the only
universal
indicator. They suggest that for detailed exploration a sampling density of at leas
t 1
sample per 4-5 km is necessary.
Useful
reviews
of the
application
of
lake
sediment
geochemistry
in
mi
neral
exploration in Canad
riske (1991).
12.2.5.
Glacial Sediments
Extensive Quat
ernary glacial deposits occurring over mos
/
t of Canada and th
e
northern United States, northern Europe, northern Asia, Geenland, and a number of hi
gh
elevation areas in the southern hemisphere have presented major challenge
s to
exploration. As a better understanding of the origin and formation of these gl
acial
sediments has grown, their blanketing presence has become progressively
less
formidable and effective exploration techniques have been developed.
>'
"J*
miL
iOfit
1.
6 59.0,
'
flAM.Aq.Cu.Pttl
/
./
'
o
CAnoowFenous
A
154* d u i Morlfi Brook a4nta
7
StrAMOcrfy MH< Qfarulc
OeVONiAN
6
uVin<lCHNylA&s 4Hilf Gnnie:
5
MVnOSor P<ni S f A i p tntfn; ftff /ffste
>
S'LURI-AN
a<4D0VJCfi*iM
4
Cap
Gr*piie
tuttS
-15
-S.O-,
-A S-
Minfrgifiea
JOflt
...
G-eaJftjjr<:rr bounOfft..
g}RPOVK:iAN
3
fo J /0 a rwtaftte m ffrwntfota r oc *f
2
otitic se/tfft df*o msfhttufinr
C?#C4//Snr OrecfVfT
fA. fOCf. A
Ca,m6 A0 OIOOviCian
1
long sngt ntM/rc - UttrnmsfK Compf
FIG 12.30
i O" OO >1
Fault
Newfoundland.
area.
1 &&
[-4
7.0-
1-4.4-
OOUCERS
system
fault
-1.6
valley"//
iacv
4+',
.,# "
,i / orfL
./*
20 3040506070 80
90 9
CAfaONIFEftOUS
Dr Lak Coup.- eistitc & e m t n i A y rocki
"f
I
to
DE V O N IA N
2 1
10 ?o ao d( >s a 07 0 ac h
99
7 SII LM Ininjfthv SuKO: grtntt.
fonaui. jaJfirffl
SILUR IA N
6 Soos A r m Croup- seifTi9rftr<f foc*& ie3,ic a n a
tiiifict miic vo'cvi'c rociks
CAMeRO' OfDOViCIAN
5 SOMlf>*rn Whtiv
Bay
Atlochlhon ion*ht9
/9 s cft ist . mtagr>fwctm. minq*
A Ci,>nv Arm Croui t4i*tbor\4tt *<i<t c<4iti4
roc ki
P R EC A MB R IA N
3 0V* &n(Ie
S 2i . Frer>cn-CiiKl3 grdrtodO'ii*. 20. Qtwnn
1 jnvnjbo'Kp.. p4iro
|c5
FIG 12.31
ci09ca
r
'f
'<l
tmjna f}f
Ptvit
A./" S.<
; K
Gtaci&i-tion <9<recrro/i
(A. emriy. 6
'ar|
//v>\
'I
Bay
area.
Newfoundland.
121
FIG 12.32
Simplified
circulation
1979)
sketch
drilling
of
the
reverse
system (Thompson,
sampling tills in the 1950's, and this technique is n o w the preferred sampling method
in
iiiost Finnish geochemical exploration programs. Esker sampling and till sampling for
distinctive heavy mineral suites have been used for kimberlite and diamond prospectin
g
ir the Canadian Shield.
Approximately
70% of l od g em e n t till
is
locally
derived,
and
most
of the
arly
mjccess with till sampling was in areas of shallow till cover (less than 30 ft or 10 m) wh
ere
iTe sample medium is reasonably accessible. In the 1960's, lightweight percussion drill
s
K j c h as the Pionjar and Cobra models, were adapted to collect small samples of till fro
m
i r m e d i a t e i y above the subou tcro ppin g bedrock to geochemicall y categorize anomaJous
geophysical features at depths of up to 70 to 80 ft (23 to 25 m) (Gleeson et al., 1
971).
Overburden drilling technology, particularly reverse circulation (Fig. 12.32) and son
ic
Tifing, advanced rapidly with the utilization of larger drills in pro grams for uranium, ba
so
metal and gold deposits in glaciated areas.
Because most types of
I
geophysical methods, lodgement
ft
has been routinely used
poo m)
he
te il y 1980's. In these programs
are
122
LONGITUDINAL
SECTION
A
FIG 12.33
generally recovered and the heavy mineral fraction is separated and examined both
visually and chemically for gold and other metals. It Is essential that the whole of the
lodgement till section is routinely sampled as indicator trains tend to rise down-Ice along
smear or thrust planes within individual till formations as shown in Figure 12.33. Even in
this simple example, significant parts of the dispersion train will not necessarily b
e
detected if attention is restricted to till immediately adjacent to bedrock. Adequate
sampling becomes even more critical when there are several lodgement tills related to
distinct glacial episodes in an area with pronounced bedrock topography (Fig. 12.34).
In the hypothetical example shown in the figure three mineral deposits suboutcrop
beneath lodgement tills which have been sampled by six vertical drill holes. Samples of
till from hole 01 will not contain anomalous indications because the site is up-ice
of
mineralization. Hole 02 will contain anomalous material related to Mineralization A in
"basal" till (2). Hole 03 will contain a strong anomaly in "basal" till (1) related
to
Mineralization B and a weaker, distal anomaly in an "upper" till (2) related to Mineralization
A. Hole 04, because of the effect of bedrock topography and the constriction of till
deposition and possibly accelerated erosion of earlier till over the bedrock escarpment,
will contain no anomalous material related to either Mineralizations A or B. Hole 05 will
contain anomalous material related to Mineralization C in its "basal" till (4) but hole 06 with
ICE
MOVEMENT
02
03
04
05
REWORKED TILLS.
HORIZONS ETC.
01,02-.
i t2.34
124
OVERBURDEN
rLUVIOClAC'JM.
DRILL
HOLE
STES
Ontario.
Diagrammatic overburden profiies in tlie Abitibi clay belt,
no lodgement till will not provide material suitable for sampling. The correct interpretaticr
of till data is obviously dependent on a thorough understanding of local glacial sedimen
stratigraphy and provenance. The technique is expensive, with combined drilling, samp
treatment, and analytical costs ranging from $20 to $30 per foot ($66-$99 per m), but :
is cost effective in deep overburden covered environments where other exploratior
methods have not been as successful, especially in gold exploration.
Up to now the majority of the glacial overburden drilling programs in North America
have primarily relied on geochemical analysis of the heavy mineral concentrate fraction
of overburden samples. Several significant gold deposits have been discovered in Canada
by this method. For example, in the Casa Berardi area of Quebec the technique was
successfully used in follow-up of favorable stratigraphic zones delineated by geophysica
methods (Sauerbrei, et al.. 1987).Initially, orientation studies of glacial overburder
overlying a portion of this stratigraphic sequence known to contain pyrite-arsenopyritenative Au bearing quartz-carbonate vein mineralization (Golden Pond deposit) had
enabled determination of optimum geochemical procedures for the district. Targets were
first tested with overburden drill holes located 25-100 m down-ice at 300-400 m intervals
along strike (Fig. 12.35a). Closer spaced overburden drilling was used to further define
anomalous dispersion trains prior to diamond drilling of bedrock (Fig. 12.35b) which
resulted in the discovery of the Golden Pond East zone. The gold content of heavy
mineral concentrate samples from the overburden were determined both visually and by
analysis. The samples were also analyzed for As and Sb. It should be noted that in this
particular area glacial dispersion of gold is only of the order of 200 to 400 m.
The degree of complexity sometimes observed in till stratigraphy and glacial
dispersion, which was previously alluded too, is clearly shown by the work of Bird and
Coker (1987) in the vicinity of the Owl Creek gold mine, Timmins, Ontario. They defined
four distinct glacial episodes each with different ice movement directions. In the lowest
(older) till, which directly overlies bedrock, gold dispersal (as determined by analysis of
heavy mineral concentrates) is very limited, as it is truncated against a bedrock ridge (Fig.
12.36). The highest gold concentrations are located adjacent to the subcropping gold
occurrence. The overlying till has not been in contact with the mineralization and has
derived it's gold from the lower till. This disperal train is longer (approximately 600 m, and
maximum gold values in heavy mineral concentrates are displaced 300 m down-ice from
the mineralization (Fig. 12.37).
A successful gold exploration program using both geophysical and geochemical
techniques is described by Harron, et al. (1987). Around 90 overburden sampling drill
holes were completed to test specific geophysically defined targets in an area virtually
devoid of outcrop. On the first pass, sampling of overburden drill holes at 800 to 1200
ft intervals perpendicular to the ice transport direction yielded anomalous gold values in
the heavy mineral concentrate fraction of till and carbonatized quartz pyrite-rich bedrock
chips. Subsequent induced polarization-resistivity surveys defined the areal extent of a
pyritic carbonate alteration zone. A second pass till sampling and shallow bedrock
125
E.M.
w
GOLD
HE AVY
Km
MINERAL
C ONC E NT R ATE S
Anomalous > 2.0 ppm
o We a k l y Anomalous 0.5 - 2.0 ppm
lU
o
FIG 12.35a
IN
Conductor
Not
Anomalous
<0.5
ppm
100
10300 N
714S5
71432
Gold in Heavy
Mineral Concentrates
FIG 12.35b
Discovery
Phase I
Phase II
Plan showing the results of the initial and follow-up phases of reversecirculation drilling at Golden Pond East, Quebec. (Sauerbrei, et al 1987)
127
the
LggEHO
* MINCIULjUTK)H
o DVERfiURDeH
-EH COHOUCTOfi
cHMSEiaiuTT log'
C7r> HESISTIVITT
-Z. "100'
S 500 PMJ [N LOH TILL'iig;
CS eSKEH
DIABASe
[T] SEDIHEKTS
MAfIC
I VOtCAHICS
MURPHY-HOYLE J.V.
1320' !6<W
SCALE IN FEET
exploration
Murphy-Hoyle
J.
V.,
Timmlns
area,
Ontario,
use
of
mineral
Canada. Gold in tni anomaly plotted in relation to
heavy
concentrates
fromresulting
is the FIG 12.38 induced polarization/resistivltyand horizontal loop
successes
from
till, caution
electromagnetic survey results. (Harron, et al,,
recommended. In view of the
variable
nature
of target
m ineralizations
and the
weathering history of the glacial overburden, heavy mineral concentrates will not
necessarily always constitute the optimum sample medium for geochemical analysis.
There have in fact been a number of reports of the successful use of the ultra fine sieved
fractions (e.g. <2 microns) of glacial overburden samples in Canada and Scandinavia
(Coker and DiLabio, 1989, Shilts, 1984, Nikkarinen, et al., 1984). It is thought probable
that in weathering tills the fine grain size phyllosilicate and secondary minerals act as
scavengers, and adsorb trace metals released during the breakdown of sulfide and other
minerals. However, in view of the practical problems associated with the preparation of
sufficient <2 micron material for analysis, the <63 micron (<250 mesh) is more
commonly used. Shelp and Nichol (1987) demonstrate, using data from the Hemlo Au
district and the area containing the Owl Creek Au deposit, Ontario Canada, that the <63
micron fraction can be a more effective geochemical sample medium than heavy mineral
concentrates, at least when target mineralizations contain ultrafine gold. At Hemlo the
HMC gold anomaly decays far more rapidly than that associated with the sieved fines
(Fig. 12.39). At Owl Creek they are broadly comparable in extent (Fig. 12.40). It should
be noted that Scandinavian explorers place a greater routine reliance on the minus 63
micron (minus 240 mesh) fraction of till than do the Canadians. This fraction has
successfully indicated the presence of several types of mineralization, including gold, in
Scandinavia.
heavy-mineral
mineralization
Nicliol. 1987)
129
In view of the general complexity of glacial sediments and the need for correc t
identification of the materiaf being sampled, effective aeochemical exploration in glaciated
terrain requires the particioation of Quaternary geologists or at least geologists with some
training in Quaternary aeoloov fCoker. 1991).
Probably the best recent reviews of geochemical exploration in glacial terrain are
provided by Coker and DiLablo (1989), Coker (1991) and Shilts (1991).
12.2.6.
Vegetation
Early scientific observers dating from the eighth and ninth centuries recorded that
the morphology and distribution of certain plants were affected by the presence of metals
in the soils. Such visible variations in a plant species are referred to as oeobotanical
indicators. Many other plants, while not showing any visible variations, are capable of
concentrating metals in their tissues and the presence of anomalous metals in the soils
or ground waters is often reflected in the metal content of leaves, twigs, or other plant
organs. These invisible metal concentrations are known as biooeochemica l indicators
(Brooks, 1972).
Geobotanical and biooeochemica l indicators are of greatest potential interest as
mineral exoloration tools ]n areas where soil sampling Is ineffective (e.g. jn areas with
barren transported overburdenV Deep penetrating root systems can sometimes provide
surface evidence of bedrock and ground water geochemistry (i.e. they allow the
prospector to "see through" the overburden). Consequently, these techniques, in
particular biogeochemistry, have been applied with varying degrees of success in
glaciated regions of North America (Boyle et al., 1969), Europe and Asia, and in arid and
semi-arid areas, like the Southwestern United States, where pediment, colluvial, and
alluvial cover is extensive (Chaffee, 1977).
Although a number of papers and books on geobotany have been published over
:he years, there is little evidence of extensive direct surface application in mineral
exploration field surveys. The bulk of the published studies are of an academic nature
(e.g. Cannon, 1979) rather than case histories of successful exploration programs. This
presumably, at least to some degree, reflects the fact that effective application of
geobotany requires highly developed botanical skills which are unlikely to be found in the
majority of exploration groups. In addition, effective programs for large areas are difficult
r) design as the results of orientation studies are often likely to have only restricted
acpticability due to the wide variety of environmental factors which can influence plant
growth. Probably the greatest potential value geobotanical features have in mineral
' exploration is indirect. Suitably enhanced satellite imagery may sometimes detect
listinctive spectral responses related to vegetational associations, together with other
iaace features, whose distribution patterns disclose significant (i.e from a mineral
tetploration point of view) regional structural and lithological features (Cole, 1980). In
130
detected in the course of regional geochemical mapping based on till and drainage
sampling.
Althouch bioaeochemistry has found wider acceptance than geobotany in mineral
exploration, it is still generally far less popular than the techniques described in the
preceding sections (i.e geochemical methods based on rock, soil, stream sediment, etc.,
sampling), mainly due to the difficulties associated with program design and data
interpretation. Plants are complex organisms and so is their metabolism. Different
species respond differently to the same conditions and consequently some species are
more effective biogeochemical indicators than others. For example, deep-rooted plants
(e.g., the mesquite) are much more effective prospectors of the deeper ground waters
than the shallow-rooted flora of the southwestern U.S. deserts and are, therefore,
generally preferred species in biogeochemical work in this particular region.
Nevertheless, shallow rooted plants growing in transported cover may reveal meaningful
patterns in some desert regions. Evapotranspiration has been suggested as a
mechanism for movement of metals into the nutrient depth of these plants.
131
1000
900
-700
-600
UOO
1300
1200
HOC
1000
900
800
700
600
SOO
tOO
congesto ,
ens
Assaciotion of Aristido
Eragrostis denudata
and Anthephoro pubesc
300 ZOO
shrub co*er
'0
o .- .
-..*
FIG. 12.42
n
5
N>
O
O
(D
to
CD
O
to
ro
;
" S,
c B * e
.
S*
=>
'
|ea
6 D
100 200 m
'
49 *
Q
.D
bO
V;>-.*ws:
0 D qO
' P 0
0
1 OA
o . 8.1 a
V
O e
. "
0
%2 , 0 0
. . v,V*s*'i w" Is
0 .
n.*.
D
*#&
*
D
D
.
.
o' O
Helicbrysum leptolepis (DC) occurrences over one area ne
D O
0
* , % o
., ; ooWWS
bia. (Cole, 1980)
e> q
*
o Q D
Da U
D
"
D, "< e
*
!?6-'.'
qViV*""?
D
i'iy.'s';-! :'vX ao
*i " o5*i
o
o" Se A ti*
1. .*:. *?*,* t *
.*
t.
/ a * o D
4
*1 #
e*
n
o !
*
.Via
p ,\
I i "i*,* *
<".
*. *>* "* * f
V.VJf-*
, e S- >
tie-1 4
, **
* 4
.w**
0 * 0
4!r"fc V
cT*
4
O*
* * "J" *.tfi
4
4 D
4
. ,
*
#
V . .*;/.*
t* 4
t
t9o
I '
E1 5a
iijifnilfi,
iJUIIdiWfrsHl
i f ni i
CO
CO
"
5'
I' I til
'I s
Usi I
11
'l
i
I
i M I i5Sallii lit
i
'
IIM
in
f
l|33|t
I
HIilll
11
11
v>
0)
u
c
o
u
w
3
u
0
a
.2
a
<t)
o
a
a>
Ihii
IIS3
a
en
>
L.
Ml
I I
<M
X
0
tfl
s
c
o
N
15
b
d)
>
<0
(0
CO
CO
o
u
u
m
u
0)
vt
c
n
w
n
O)
c
O
ra
>
O) O
o (
o en
0)
ra
c a>
0 o
'5 o
3
"u n
2
I>
'B
en
o
"
I
a
V3
IMd
(0
Z
C
a>
k.
re
o4 0 asD
T-
CM
2
134
Alder Twigs
Gold (ppb) in ash
1985
1984
Site
l
.
Alder Leaves
Gold (ppb) in ash
Early
June
Early
August
Mid
Mid
September
April
32
23
250
53
17
47
58
20
34
29
1984
June
August
September
130
43
19
15
166
48
15
10
37
27
18
11
35
34
21
12
23
13
57
25
13
25
13
41
21
13
13
25
11
20
27
21
11
16
10
20
14
20
<5
11
11
29
20
23
75
11
22
12
35
10
22
58
13
23
14
51
FIG 12.43
Copper values in surface soi
in area shown in Fig. 12.42
(Cole, 1980)
12
17
18
33
10
135
Ash yield of dry twigs is about 2 percent; Ash yeield of dry leaves is 5 - 6 percent.
TABLE 12.3
Seasonal changes in the gold content of ashed aider twigs and leaves.
(Dunn,
19 91 )
136
(i)
(ii)
(iii)
(iv)
(v)
Dunn (1991) also provides a useful summary of the procedures to be used and the
precautions to be observed when conducting a biogeochemical survey (Table 12.4).
Dunn (1987) has pointed out that with some species, sampling of bark (a dead
tissue) can be an effective technique that is not subject to seasonal metabolic variations.
The potential value of humus as a geochemical sampling medium has already been
discussed in the section on soil surveys. This again avoids the effects of seasonal
variations as the accumulated material constitutes an integrated sample. Weathering,
leaching, and bacterial decomposition will work to diminish the metal contents, but
signatures in mull are generally preserved.
In
view
137
Basic Rules
Reasons
1.
has
a different
Every
species
chemical composition, and trace
element
a nd
requirements
tolerances.
2.
Each
3.
4.
This
is
the
basic
inter-site
that
is
for
consistency
required
any
geochemical sample medium.
5.
There
tissue
[Dead
can
be
bark)
any time
6.
(e.g, outer
collected at
Do
not
return
to
previously sampled tree and
expect to obtain exactly the
same analyses.
biogeochemical survey.
138
TABLE 12.4
Basic
rules
are
seasonal
significant
in
changes
plant chemistry.
to be
(Dunn, 1991)
applied at
each sampling
station
when
conducting
.4
'
STANOARO HILL
BtOCEOCHEMICAL SURVEY
AU
0 UMEMIEEO mU HOU
. PLANT SAMPLE
D *OIT
AflA Of IS U SAMPLE
SPACMQ
IlllllltllllU
OrSPPSAU
}-CPPtAU
FIG 12.44
139
Cre4k
Roc'
a
'
C/i,
, Adelaide C/own
Mines
- O*-'!i.-i
25-ra21
19 1 4*IS 1311 9 *'*
-32 1 A '
3629>7
*
.
28-26 24 22 10 10 J6 M 12 10 8 ' rXf
Adelaide
*
-.
/"
<f/
Mapf
Mine
XtLOMfTERS
RG. 12,46
140
30
S'
10
8
linit aT detrnMna.twn
A.
1/
14
backup in the event of undetected problems with the gold analysis. The data suggest
that in this district biogeoc
POORLY DRAINED
hemistry would be more e
ffective than geochemical s
SPRUCE
3 ,
oil
2 [
sampling in poorly drained are
----- needJes
1
as. In well drained areas geo
bail*
0
chemical soil sampling would
/A
probably be preferable as biog
BALSAM FIR
/
V 1
/
A
/\
eochemistry appears to offer n
ppb
/
Ai
/
\
o clear technical advantages
4
'
and is certainly more expensi
J >
''
2
ve.
i 1
1
needles
/I
bark
1
B HORIZON SOILS
1
1 1
HUMUS
// M
I' H /\
150
225
200
3QG
melfes
FIG 12.48
contents of needles and bark of Balsam Fir (Abiles balamea) and Spruce (Picea
glauca, P. mariana) and B horizon soils and humus. ("M" represents location o
mineralization), (Cohen, et al., 1987)
POORLY DRAINED
BIRCH
Au
ppb
300 rnslrea
FIG 12.49
142
Hemlo District. Ontario. Comparison for poorly drained ground between the Au
contents of Aider leaves, first year twigs and bark, White Birch (Betula papyrifera)
leaves and bark and B horizon soils and humus. ("M" represents location of
mineralization). (Cohen, et al., 1987)
FREELY DRAINED
SPRUCE
FIG 12.50
Hemlo District, Ontario. Comparison for freely drained ground between tfie Au
contents of needles and tjarl< of Balsam Fir (Abies balamea) and Spruce (Picea
glauca, P. mariana) and B horizon soils. ("M" represents location of mineralization.).
(Cohen, et al., 1987)
FREELY DRAINE D
ALDE R
FIG 12.51
of Alder (AInus rugosa, A. crispa) leaves, first year twigs and bark and B horizon soils.
("M" represents location of mineralization). (Cohen, et al., 1987)
143
62-30
6'30'
TT T"
6r
45*15
/
iftmiwnjrti, E*
/
45'15
10
45
GOLD
44''JS'
W)
44" as'
sam ph Site
es"'
62
62" 30
62'
5130
61"
61"
45" 15
45 15
45'
45"
44i5'
44 45
52*mFIG 12.52a&b
62
ei-aa-
61
Elements in ash of outer scales of spruce bark, Nova Scotia: (a) (above) gold, (b) (above)
arsenic, (c) (next page) antimony, (d) (next page) selenium (Dunn, 1989)
145
a5)fl
44ii5
62 30
FIG
45-I5'
45* 15'
44J!
- 44 45
12.52c&d
{Dunn,
1989)
146
Excellent reviews of recent developments in exploration
biogeochemistry are
provided by Dunn (1989 and 1991). Although it is now a little dated, a useful bibliography
on the use of plants in prospecting for gold was compiled by Erdman and Olson (1985).
12.2.7.
Water
in particular:
(i)
(ii)
(iii)
(iv)
environmental factors,
some
3* S
seasonal in nature and not all of
T3 0)- -t of which might be
= ?-sl 1
C o u -g >. n e
which will be necessarily
e (0
U J=
fl "O ? M 55
"X (Jrecognized.
Qk
SS3 co
n a
0
>o.ti
y
.
& >
1 -S
Water samples are generally
in clean acid rinsed 500 ml or 1000 ml
collected
i
?
M
=
3
2
k.
fti
1
5?
0
lU cj g
as these are"5more
than glass bottles under
% a s ?practical
E s B
polyethylene or polypropylene bottles
aCT" 0 u
field conditions. However, several Important trace metals are incorporated in plastics
during the manufacturing process and are often present in teachable form. This applies
(Q
particularly to zinc. 5Therefore
u
thorough cleaning prior to use iiisc arequired.
Prolonged
is. W
i 9
a. M nitric acids followed
in
50%
or
with
distilled or
soaking
hydrochloric
by repeated rinses
deionized water is recommended. Prior to sampling in the field the
bottles
should
be
3 O ffl E
rinsed seve P", r. nic ral times with the water to be sampled. Samples that are to be analyzed for
0
F G acidified to
trace eleme 3y viT 0)5 nts should
I
be
a> Enitric
u 41 or hydrochloric acid to
pH <2 with metal free
0) cl
Q
0
J3
Q i to
I uthe
S O from precipitating or adhering
walls. Turbid water
Q. 1; bottle
O. O
keep the di <0 IS V ssolved metals
3n g cu
should be
filtered using a 0.45 micron membrane before addition of the acid, otherwise
t V
0
When both trace and
leaching o
0* T f elements from the suspended sediment might occur.
major elements are to be determined, at least two samples must be collected so that
material without introduced cations and anions is available for the major element analysis.
In order to minimize growth of algae (Miller, 1979) in samples prior to analysis they should
be stored in a cool place away from sun light. If this is not possible, chloroform should
be added. pH, conductivity and certain other measurements are commonly made at the
sample site.
N.
'
S 2 S
5 "3 "w Hi
01 _w "Eo
i2 _iii_ 0u t, u
o XJ j;o"
0 s9
S
?e
f
R Q C
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i l = i
i e =" 2 s
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C
U -Q 41
- 3
2 o*
c-S S
trl
o
.5:
XQ.
Oi T5 .2 *J3
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->
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g u a o
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; o
"
5
c3 1 n B
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t,
-
11 CT
1. oC -tE isS
S 2
? g'l l
3 --
-S ,s i
.=: =
i 6<0 -
2r
S-"2
>> o ii -g 1.
B ,t 5 2 c>
ju S j
0 C J <- O*
c C
w
l|.C&S
=C5 " S "a i a
-n
w
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s Q A M
o>
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c 0
5 5 S
t: = p'-
to
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=2111
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c
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is w
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= "S - T g y g
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.9 - o S 5? 2
2 u f C U b " W
s-?! 2
5* !
11 =
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pi
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ill
<e V
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->
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_ =51 IB Cl|
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Sir = I
19 as- > j:
49 4i $
3 -I
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e
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5
.jj
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=
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<0> gE a>. 2
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J .2 .2 .E
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oID -Ow fl e
fe E
S s
o Q. M
u JS
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(T S =
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j:
#2
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a. o
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Jii OJ
tD .- (0
gat
{J O. <A
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. w cQ >S
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"
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75
CC S G.
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tq
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a
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u
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3
in
a
O
in
<v
a
9
148
Regional reconnaissance for selected metals can also be achieved by sampling the
waters f actively flowing streams where metal is dispersing in solution. A prospecting
approach similar to the sampling of stream sediments is necessary. Sampling of ground
water seepage sites is an integral part of stream water surveys. In view of the paucity of
recently published examples of stream water sampling, it is again necessary to refer to
fairly old studies. For example Dyck et al. (1971) sampled stream water in addition to take
water (see above) in their experimental uranium exploration program in the
BeaverlodgeDistrict of Saskatchewan. Stream water (and stream sediment) samples were
collected at an average density of 1 sample/square mile. Sample temperature was
recorded at the sample site, whilst radon, pH and alkalinity were determined in a field
laboratory. The samples were then acidified and transported to a central laboratory for
uranium and other trace element analyses. Although the regional uranium distribution
patterns (Figs. 12.54a and 12.54b) were found to be broadly similar to those displayed
by the lake waters, it was concluded on economic grounds (i.e. ease of sample
collection) that the latter were the preferred sample medium.
Groundwater can also play a useful role in mineral exploration, especially when the
targets and large potential target hosts are obscured by post mineral overburden or
unmineralized bedrock, and target and/or associated pathfinder elements are mobile in
the prevailing groundwater environment. Interesting examples of the attempted
application of groundwater geochemistry in mineral exploration are provided by work
carried out by the U.S.G.S. (Huff, 1970), and various companies in the southwestern
U.S.A. in the 1960's and 1970's. Here the primary interest was in locating porphyry
copper deposits under pediment and alluvial sediment cover. The exploration technique
BEAVERiODGE.
5ASK.
CONGLOMERATE
CfAlWTE.
dRAw ite
GNEISS
AMPrt ieOLlT C
HiiiTAseDmEJjrs
RADIOACTIVE
mn. occ, , ..
FIG 12.53a
GRANJTE.
0EAVERLODG,
S AS K.
t:>-|BASAU
C ONG LOME RAT E
GRAMlTE,
granitegneiss
AMfhiaOLITE
METASEPmEMTS
radioactive
MIN- pCC,
FIG 12.53b
150
beaverlooce,
SAS+.
Ibasal
VjCONOLOMERATe
GAANITEGMCiSS
AWPHIBOLTe
MCTASgCjMENTS
loUARTZtTC
j WIGMATITC
(li me stone
RAOiOAC
MN. OCC.T(VE
FIG 12,54a
beaverlodge.
SASK,
BASAt
CONLOMCRATC
GRAhTE.
QRANire
iSNESS
AMHISOLITC
MgTASEQJMCMTS
OUAfiTZfTE
M(CMATITE
Ilimstonc
AOOACTIVE
UIN CC
FIG 12.54b
151
vas based on the known mobility of molybdenum, a significant component of most
zorphyt7 copper deposits, in the neutral to alkaline conditions prevalent in local
groundwater. Samples were generally collected from domestic and irrigation wells, and
atural springs. Early results, as for example in the Pima Mining District, showed
anomalous molybdenum was indeed present in the groundwaters around known deposits
e.g. Fig. 12.55) and elsewhere, but the anomalies were so large (i.e. tens or even
~;-uiiftf<jbi3i"si:|uarfeTrtiej*1[rTi source location in routine surveys was not apparently
economically feasible. In addition, anomalous contrast appeared to often correlate with
total dissolved solids, a feature presumably unrelated to mineralization. Later studies by
~'OSt and Trautwein (1975) indeed found molybdenum concentration in groundwater to
correlate strongly with conductivity (an indirect measure of total dissolved solids), weakly
vrth pH and not at a!! with Eh (Fig. 12.56). On theoretical grounds they concluded that
ris reflected a relationship between the solubility of molybdate salts, such as CaMoO,
zje to an increase in ionic strength and corresponding decrease of the activity
3cefficients. They suggested utilizing the ratio of log [Mo/K] in conjunction with a plot of
og [Mo/K] vs. log [Mo] to determine the proximity of a buried oxidizing porphyry copper
zeposit. The possibility of applying sophisticated hydrogeochemlcal models to mineral
fxploration purposes was discussed by Runnells and Lindberg (1981). They determined
Tat the saturation index is a reliable indicator of the presence of uranium mineralization,
'2.2.8.
Eh
measurements
could
present
certain
practical
Gases
Under certain conditions, mineral deposits produce gaseous emanations which can
ze detected by specialized measurements. There are two broad categories of soil gas
sampling technique:
(i) instantaneous;
(ii) integrated.
//h the instantaneous method, specific volumes of soil gas are extracted through a
3nDbe, from some predetermined optimal depth which is normally somewhere in the range
zr 20 to 40 inches (50 to 100 cm). These can then be either:
(i)
(ii)
153
20oH
set A
U ; i tI'M '
"
t.
Eh
0-
(b)
log K
OB
12
1.6
RG 12.56
Correlation
154
(iii)
and transported to
The main potential problem with the instantaneous methods is that they are subject to a"
'
short term gas flux variability which might occur. This could prove particularly serious
large surveys during periods of climatic instability. Instantaneous methods are als:
inappropriate when dealing with gases occurring in concentrations at or near \lr
detection limits of the available analytical equipment. The main advantage of th'S
instantaneous methods is that they only entail one visit to the sample site.
With the integrated method of soil gas sampling, special adsorbent or reactive
material, including molecular sieves or porous polymer sorbents (e.g. Clifton, 1984a ar:
1984b, etc.), or activated carbon (e.g. "Petrex" system), is buried in the soil at eac
sampling site for specific periods of time (generally for several weeks). At the end of th;=
time the collectors are recovered and sent to the laboratory for analysis. Alternatively, us
can be made of natural soil gas collectors, including specific soil fractions (e.g. clays
"Advol" system). The main potential advantage of the integration methods of soil gas
sampling is that results are unlikely to be influenced by short term fluctuations in the so
gas flux. However, two visits to each sample site are required, except in the case of ti-re
natural soil collectors. A problem with some of the collector systems (i.e. molcula*
sieves) is that gas desorption in the laboratory requires heating to very high temperatures
which will likely modify the nature of some of the volatile species.
Much of the published information on the application of gas geochemistry '
mineral exploration relates to research and orientation studies. However, numerous
geochemical gas surveys were carried out some years ago during the last uraniu"
"boom". These were mainly concerned with measurement of radon produced during t
radioactive decay of uranium and radium. Although some radon in stream and lake watestudies were undertaken (e.g. Dyck et al., 1971), most of the programs were based or
integrated measurements of radon in soil gases. Some of the better known procedures
(e.g. "Track Etch") use detectors which respond to alpha particles emitted during rado
decay (e.g. Gingrich, 1984). The "Track Etch" procedure utilizes small pieces of radiatio'
sensitive film. These are processed in an etching solution to provide visible track-like
images of the alpha particles which can then be counted to provide an indication of the
average amount of radon present during the exposure time (Fig. 12.57). Later versiorts
include plastic filters to prevent exposure of the detectors to thoron. In "Track Etcf
surveys the integrative detectors are buried at shallow depth (i.e. normally around 0.5 r
in inverted plastic cups (Fig. 12.58) and left for a specific period of time. In the BakeLake area in Northern Canada (Fuchs et al., 1982) cups were buried for the full winteseason at 100 ft intervals along traverses with 200 ft separation. The unusually lone
exposure produced improved results over those obtained with detectors left in place fo'
shorter periods during the summer. Follow-up of several high contrast anomalies
resulted in the discovery of the Lone Gull Uranium Deposits (Fig. 12.59).
A LP H A
TRACKS RETAINED
PARTtCLE
FIG 12.57
FIG 12.58
156
FIG 12.59
(Gingrich, t984)
The oxidation of moist sulfides leads to the generation of CS and COS (Taylor, et
al., 1982). Oakes and Hale (1987) describe an experimental exploration technique basec
on the selective thermal desorption of COS from the <150 micron fraction of overburden
materials and quantitative determination by a rapid gas chromatographic method. At
Johnson Camp, Arizona the surface microlayer of the soil was sampled on 30x60 m grid.
Analysis disclosed distinct COS anomalies over suboutcropping sediment hostec
replacement sphalerite/chalcopyrite mineralization despite the presence of considerable
thicknesses of pediment gravel and alluvium (Fig. 12.62). Elsewhere comparable
-ADHESIVE
PLASTIC
PLASTIC
Q L A$S VIAL
( r em o ved during
H g- va oou r collection)
FIG 1 2. 6 0.
TAB
CUP
of the Aurex
C o mpo ne n t s
integrative detector.
(Feciikow
1990)
CAP
DETECTOR
(silver wire)
Hg-vapour
and Amor,
STfilP
FIG
1 2. 6 1 .
158
Schematic
of Hg-vapour
representation
me a su r e me n t utilizing the Aurex detector
(Fedikow and Amor, 1990)
FIG 12.62
;c
the
of
buried
accumulations
was
sulfide
by gas chromatography. Although
presence
found to be reflected by strong CO2 anomalies {Fig. 12.63). these anomalies were
extremely sensitive to climatic change (e.g. rainfall). In recent years COg and Og in so?
gas surveys have also been applied in a number of exploration programs for sedimert
hosted gold deposits in the western U.S.A. These surveys have reportedly resulted in the
determination of lithology changes, location of faults and the presence of alteration
beneath transported overburden (Jaacks, 1989).
Recent studies in Sweden (Malmqvistet al., 1986) have identified an upward fluxinc
of GEOGAS in the near-surface sections of the earth. This GEOGAS enters the grounc
waters as dissolved air. The circulating meteoric waters and changing pressure
conditions in the subsurface cause the GEOGAS to rise as small streaming bubbles. The
bubbles contain other gases and can also collect metallic ions and particles that can be
trapped in collectors set out in the surface soil. Anomalous patterns in GEOGAS have
FIG 12.63
Particulates
Solid particles down to the size range of large molecules are present in the
atmosphere. Weiss (1971) developed an airborne geochemicai prospecting technique
for arid terrain based on the collection of dust particles suspended in the atmosphere.
The AIRTRACE and SURTRACE techniques of Barringer Research Ltd. were designed to
sample a variety of particulates in the lower atmosphere including spores, pollen, dust,
microorganisms, organometallics, and hydrocarbon complexes. The collected particulates
*6re analyzed using a laser pulse/inductively coupled plasma spectrometry (ICP)
p-ocedure in the laboratory. The same airborne platform could be equipped with a
-mercury sensor for real-time measurements. According to the Barringer organization
AIRTRACE was successful in sensing gas and oil resources and produced positive results
ever mineral deposits. Reproducibility of the technique in the search for mineral deposits
hampered by variable weather conditions and temperature inversions. The
SURTRACE method was designed to overcome these climatic problems by sampling
160
<s
k.
5-
01 horizon
o
a
}\ A1 horizon
4-
a
o
3-
glacial tllf
_60
meters
FIG 12.64
old vein
cranlttc host rock
gold voin
20
particulate matter from the ground surface (i.e. microlayer) using a helicopter-based or
manually transported system. Despite the fact they have been available for a numtjer
ofyears neither method has yet been used extensively in routine metallic minera
exploration programs. AIRTRACE was used in some large scale hydrocarbon surveys
in the 1980's.
12.2.10.
Microorganisms
Parduhn and Watterson (1984) and Parduhn et al. (1985) have demonstrated tha
the population of the common microorganism, Bacillus cereus, increases with natura
increases in the base and precious metal content of soils in the vicinity of known minera
deposits. It has also been noted that the increased antibiotic resistance of these bactera
correlates with increased metal concentrations in soils (Watterson et al., 1986). On the
basis of very limited sampling Parduhn and Watterson (1984) reported anomalous Bacillus
cereus populations over quartz/gold/sulfide veins, overlain by 15-20 feet of glada
overburden, near Empire, Colorado (Fig. 12.64). However, earlier work by Curtin, et a.
161
f1971), determined that although the B horizon soils were not particularly effective sam
ple
"ledia in this district, the Au, Cu and Bi content of the forest humus layer (mull) dear
ly
efine the mineralized veins. Ttius no particular advantage appears to be provided by
the
Bacillus cereus data in this example. The same appears to be true in certain other t
est
ireas (e.g. Vista Pit area, Mesquite Deposit, Imperial County, California) studied by
=arduhn (1987).
An interesting alternative approach to the possible application of microbiology to
mineral exploration is discussed by Michaels and Riese (1986), They sug
gest
determination of the metal tolerance of bacteria by the addition of suitable met
al
ancentrations to culture media prepared from stream sediment, stream vi/ater, and
organisms on stream water surfaces. Peliminary data indicate bacteria populations are
more metal tolerant in mineralized areas.
IVIineral exploration methods based on microbiological features are still in their
rfancy and should be approached with extreme caution.
12.2.11. Animal Tissues
Animal tissues have not been used extensively as a geochemical medium. Warr
en
St
al. (1971) analyzed 96 trout livers from locations in British Columbia and identified
a
general correlation between the zinc and copper contents of these livers and known