CHEMISTRY

CREST

EAMCET
2008(MEDICINE)

Maximum Marks: 40

Question paper format and Marking scheme:

1. This question paper has 40 questions of equal weight age. Each question is allotted 1 mark for each correct
response.
2. No deduction from the total score will be made if no response is indicated for an item in the answer sheet.
3. There is only one correct response for each question. Filling up more than one response in each question
will be treated as wrong response

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Page
1

121.

The wavelength in A 0 of an emission line obtained for Li 2+ during an electronic transition from
n 2 to n 1 (R = Rydberg constant)
2

(1)
Sol.

3R
4

(2)

(3)

4
3R

For Li

1
2
n1

2
,v

4
27 R

4
27 R

1
2
n2

2 1
R.3
12

1
2
2

27 R
4

Match the following:

List I
mvr

nh
2

(i)

Paschen series

(B)

Infra-red

(ii)

Electron total energy

(iii)

De Broglie equation

(iv)

Schodinger equation

(v)

Bohrs equation

(D)

h/ p
e 2 / 2r

The correct answer is

A
B
C
(1)
v
ii
iii
(2)
iii
ii
v
(3)
v
i
iii
(4)
iv
i
ii

D
i
iv
ii
iii

(3)

nh
-Bohrs equation
2
(B) Infrared paschen series
(A) mvr

(C)

List II (at STP)

(A)

(C)

Sol.

(4)

(4)
= R H .Z

122.

27 R
4

h de-Broglies equation
p

(D) e 2 / 2r - Total energy of electron

123.

particle
particle
particle
A
B
C
D
In the conversion, which one of the following is not true?
(1) A and D are isotope
(2) B and C are isodiaphers
(3) C and D are isobars
(4) A and B are isotopes

Sol.

(4)
A and B are isobars but not isotopes.
When a particle is emitted, isobar is formed
When particle is emitted, isodiapher is formed
When 1 and
particles are emitted, isotope is formed

124.

The elements X, Y and Z form oxides which are acidic, basic and amphoteric respectively.
The correct order of their electro-negativity is
(1) x > y > z
(2) z > y > x
(3) x > z > y
(4) y > x > z

Sol.

(3)
X forms acidic oxide. E.N of X is high
Y forms basic oxide E.N of Y is low
Z forms amphoteric oxide. Moderate E.N.
Order of E.N. X > Z > Y

125.

Match the following:

List I

(A)

BCl

(B)
(C)

2
PdBr4
F

(D)

The correct answer is

A
B
C
(1)
ii
iii
iv
(2)
v
iii
ii
(3)
ii
v
iv
(4)
v
iv
iii
Sol.

List II

(3)

(i)

Linear

(ii)

Planar Triangular

(iii)

Tetrahedral

(iv)

Octahedral

(v)

Square planar

D
i
i
i
ii

(A) BCl3 Planar triangular

2 -square planar
(B) PdBr 4

(C) SF6 Octahedral

(D) I

-linear
3

126.

Sol.

The correct order of dipole moments for NH3, H2O and CO2 molecules is
O
(2) CO2 NH 3 H 2O
CO
O
NH
(4) H O NH
2
3
2
(4)
H2O has dipole moment = 1.84 D
NH3 has dipole moment = 1.46 D
CO2has dipole moment = 0 D
CO
The correct order is H O NH
2
3
2

127.

40 grams of a sample of carbon on combustion left 10% of it unreacted. The volume of oxygen
required at STP for this combustion reaction is
(1) 22.4 I
(2) 67.2 I
(3) 11.2 I
(4) 44.8 I

Sol.

(2)

40 10
4 g.
100
Carbon burnt = 40-4 = 36 g. = 3 moles
CO
2
C + O
2
Unreacted carbon =

3 22.4
= 67.2 lit at STP.

3 moles
128.

In a flask of V litres, 0.2 moles of O2, 0.4 moles of N2, 0.1 moles of NH3 and 0.3 moles of He
0
gases are present at 27 C. If total pressure exerted by these non-reacting gases is 1 atm, the
partial pressure exerted by N2 gas is
(1) 0.4 atm
(2) 0.3 atm
(3) 0.2 atm
(4) 0.1 atm

Sol.

129.

(1)
Total no. of moles
= 0.2 + 0.4 + 0.1 + 0.3 = 1
Moles fraction of N2 = 0.4
Partial pressure = Mole fraction x Total pressure
PN
0.4 1 0.4 Atm.
2
The volumes of two HCl solutions A 0.5N and B(0.1N) to be mixed for preparing 2l of 0.2M HCl

Sol.

solution
(1) 0.5 l of A + 1.5 l of B
(3) 1 l of A + 1 l of B
(1)
Conc. of final solution =
0.25 0.15
2

0.4
2

0.2 N

(2) 1.5 l of A + 0.5 l of B

(4) 0.75 l of A + 1.25 l of B
0.5 0.5

1.5 0.1
2

130.

When 0.1 moles of an acid is added to 2 litres of a buffer solution, the pH of the buffer decreases
by 0.5. The buffer capacity of the solution is
(1) 0.6
(2) 0.4
(3) 0.2
(4) 0.1

Sol.

(4)
Buffer capacity
=

0.05
0.5

No. of moles of acid or base added to 1 lit. of the solution

Change in pH

0.1

131.

Identify Bronsted-Lowry acids in the reaction given

2
OAl H O
HC
Al H O
OH
H2 CO3
2
2
3

5
B
A
C
The correct answer is
(1) (A), (C)
(2) (B), (D)
(3) (A), (D)
(4) (B), (C)

Sol.

(3)
Al H O
2 6
Acid
H
HCO
3

132.

Sol.

Al H O OH
2 5

H CO
2 3
Acid

The cell potential of the following cell at 250 C (in volts) is

+
0

Cu 2+ Cu
Pt H H
0.337V
E
2 0.01M 0.1M

Cu 2+ / Cu
1atm
(1) 0.308
(2) 0.427
(3) 0.308
(2)
2+
+
Net reaction : H2 + Cu 2H + Cu
0.059
[ pds]
0
E E
log
n
[rea]
E

(0.337 0.00)

0.337 0.03(3)

0.427V

0.06
(0.01)
log
2
(0.1)

(4) 0.337

133.

Which one of the following reactions occur at the cathode?

2e
(2) Ag
Ag 1 e
(1) 2OH
H O 1O/ 2
2
2
(3) Fe 2

3
Fe

(4) Cu

2e

Cu

Sol.

(4)
Reduction occurs at cathode. Gain of electrons is reduction.

134.

AB is an ionic solid. If the ratio of ionic radii of A and B is 0.52. What is the coordination

Sol.

number of B ?
(1) 2
(3)

(2) 3

If the Limiting radius ratio

(3) 6
r

(4) 8

0.414 0.732 , then coordination no. is 6.

r
1

135.

The rate constant of a first order reaction is 0.0693 min . What is the time (in minutes) required
for reducing an initial concentration of 20 mol 1 to 2.5 mol 1 ?
(1) 40
(2) 30
(3) 20
(4) 10

Sol.

(2)
First order rate constant expression,
2.303
a
K
log
t
(a x)
2.303
20
0.0693
log
t
2.5
log 8
3 log 2
t
0.0301 0.0301
3 x0.301
30
0.0301
1 1
A
B
g
g is a first order reaction. The initial concentration of A is 0.2 mol l . After 10

136.

Sol.

minutes, the concentration of B is found to be 0.18 mol 1 l 1 . The rate constant (in min ) for the
reaction is
(1) 0.2303
(2) 2.303
(3) 0.693
(4) 0.01
(1)
2.303
0.2
log
K
t
0.2 0.18
2.303
log10 0.2303 min 1
t

137.

100 cm3 of 0.1M HCl and 100 cm3, a 0.1 M NaOH solutions are mixed in a calorimeter. If the heat
liberate is Q kcal, the heat of neutralization H (in Kcal) of HCl
aq and NaOH aq is
(1) 10 Q
(2) -100 Q
(3) -1000 Q
(4) Q

Sol.

(2)

100
0.1 = 0.01 moles
1000
0.01 mole reacts with 0.01 moles to liberate ----------- Q kcal
1 mole reacts with 1 mole to liberate ..?
=100 Q kcal
Therefore , heat of neutralization = - 100 Q
No. of moles of HCl and NaO H =

138.

Which one of the following reactions is an example of auto-catalysis?

(1) 2 AsH
2 As
3H
3 s
s
2 g
Fe
3H
2 NH
s
2 s
3 g
(2) N
2 g
NO
(3) 2SO
2 g
(4)

g
2SO
3 g

O2
g

12 22 11 l

6 22 6 l

6 12 6 l

Sol.

(1)
As is auto-catalyst in the decomposition of AsH3
2 AsH
2 As
3H
3 s
s
2 g

139.

If 11.1 mg of CaCl2 and 12 mg of MgSO4 are present in 2 litres of water, what is its hardness (in
grams CaCO3/ppm)?
(1) 5
(2) 10
(3) 15
(4) 20

Sol.

(2)
11.1 mg MgCl2
= 10 mg CaCO3
12 mg. MgSO4
= 10 mg CaCO3
11.1 mg MgCl2 + 12 mg. MgSO4 = 20 mg. CaCO3
20
2000g. of water contain
g. of CaCO3
1000
106 g. of water contain?
20 106
Degree of hardness of water = 1000 2000 10 ppm.

140.

The correct order of stability for the following superoxides is

(1) KO2 RbO
(2) RbO2 CsO2 KO2
2 CsO2
(3) CsO2 RbO
(4) KO2 CsO2 RbO2
2 KO2

Sol.

(3)
As the size of the alkali metal ion increases, the stability of the superxoide increases due to the increase
in lattice energy.
The correct order is CsO2 RbO
2 KO2

141.

A mixture of boron trichloride and hydrogen is subjected to silent electric discharge to form A
0
and HCl. A is mixed with NH3 and heated to 200 C to form B. The formula of B is
(1) H3BO3
(2) B2O3
(3) B3N3H6
(4) B2H6
(3)
silent electric discharge
6HCl
B H
2BCl 6H
3
2
2 6
1200 C
2000 C
2
.2
B H
NH
B H NH
B N H
2 6
3
2 6
3
3 3 6

Sol.

142.
Sol.

Hydrolysis of SiCl4 gives compound X and HCl. On heating to 1000 C X loses water and forms Y.
Identify X and Y, respectively
(1) SiO2 and Si
(2) H4SiO4 and SiO2
(3) SiO2 and SiC
(4) H4SiO4 and SiC
(2)
l
H O
H SiO
HCl
SiC
4
4
4
2
4
4
Orthosilicic acid
0
1000 C
H SiO
2H O
SiO
4
4
2
2

143.

The number of P-O bonds and lose pairs of electrons present in P4O6 molecule, respectively
(1) 12, 16
(2) 12, 12
(3) 8, 8
(4) 12, 4

Sol.

(1)

No. of P O bonds = 12
No. of lone pairs of electrons = 16

144.

Sol.

145.

X, Y are anhydrides of sulphurous acid and Sulphuric acid, respectively. The hybridization state
and the shape of X and Y are
X
Y
2
(1) sp , angular
sp3 , tetrahedral
(2) sp 2 , angular
(3) sp 2 , angular

sp 2 , angular
sp 2 , planar triangular

3
(4) sp , planar

3
sp , planar

(3)
2
Anhydride of sulphurous acid, H2SO3 (X) is SO2. Hybridization of S in X is sp . Shape angular.
2
Anhydride of Sulphuric acid, H2SO4 (Y) is SO3. Hybridization of S in Y is sp . Shape is plane triangular.
Ca OH
B
auto-oxidation CaCl
Cl
2
2
2
A
dry
H O
2
Identify B in the above reaction.
(1) CaOCl
2
(3) Ca OH

Sol.

(2)
Ca OH

(2) Ca ClO
3 2
2 2
(4) Ca CIO

Cl
2

dry
6Ca OCl Cl

CaOCl

H O
2

A
5CaCl Ca ClO
2
3 2
B

146.

Which of the following statements about Noble gases are correct?

I.
XeO3 is an explosive tetrahedral molecule.
II
In Fisher Ringe Method, a mixture of CaCl2 and CaC2 is used to remove N2 and O2.
III.
He and Ne are chemically inert due to lack of d-orbitals and high ionization potential.
IV.
At 173 K He and Ne are absorbed on activated charcoal.
The correct answer is
(1) I and II
(2) II and III
(3) II, III and IV
(4) I, II, III and IV

Sol.

(2)
II and III are correct statements. I and IV are wrong statements.

147.

Which one of the following pairs of complexes has the effective atomic number equal to 36 for the
transition element?

(2) Co NH Cl ; Cr H 2O Cl3
Cl ; K Fe CN
(1) Co NH3
6

3 6 3
3
3
6

4
(3) Fe CO ; K Fe CN
5
6

Sol.

(4) Fe CO ; K Fe CN

5
6
3

(3)
EAN = Z oxidation state of metal + 2 x C. No
Fe CO ; EAN = 26 0 + 2x5 = 36

5
4
K Fe CN ; EAN= 26 2 + 2 x 6= 36
6

148.

5 l aqueous solution is kept in the presence of oxygen and suitable micro-organism for five days at
2000 C . If the O2 consumed is 0.2 g. the BOD value of the sample is
(1) 4 ppm
(2) 0.4 mg l 1
(3) 40 ppm
(4) 20 mg l 1

Sol.

(3)

No. of mg. of O 2 required

No. of litres of water sample
200
BOD =
40 ppm.
5
BOD

149.

Which one of the following graphs represent the correct order of boiling points (B.P) of ethane
(I), ethyl alcohol (2) and acetic acid (3)?

(1)

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1010

Sol.

(3)
Ethane has no H bonds. Ther remaining two have hydrogen bonds. Possibility of H bonding is more in
acetic acid
(1) ethane gas lowest B.P.
0
(2) ethyl alcohol B.P. 78.1 C
0
(3) Acetic acid B.P. 118 C

150.

Which one of the following reactions yields 2E-butane as the major product?
(1) CH C C CH
Na / NH liq.
3
3
3
(2) CH CH CH CH
Li / NH liq.
3
3
3
(3) CH C C CH
Na / NH OH
3
3
4
3
3
4
(4) CH C C CH
Pd / BaSO

Sol.

(1)

151.

Identify C in the following reaction:

NH
Chromic acid
3 B
C H
A
2 2
(1) CH

(3) CH
Sol.

CH

CH

NH

(4)
HC

CH

CH COOH
3

H O
2

NH 3

(2) CH

NH

H 2O

CH

Chromic acid

(4) CH

C NH

CH COOH
3

CH 3COONH 4

CN

H O
2

CH 3CONH 2
C

152.

Pyridine
C H OH SOCl
2 5
2
(1) C H Cl , O , HCl
2 4 2 2
S

(2) C H Cl , SO ,HCl
2 5
2

(3) C H Cl , SOCl , HCl

2 5
Sol.

Z , in this reaction X, Y and Z respectively, are

(4) C2 H 4 ,SO 2 , Cl2

(2)
C2 H 5OH

SOCl2

C2 H5Cl SO2 HCl

Z
X
Y

153.

The compound that reacts with CH MgBr to yield methane as one of the products is
3
(1) CH3CHO
(2) CH3COCH3
(3) CH3COOCH3
(4) CH3CH2OH

Sol.

(4)
C H OH
2 5

154.

CH MgBr
3

CH

M g OC H
2 5

The organic compound which gives peroxy compound on exposure to atmospheric air in the
presence of sunlight is
(1) C H OC H
(2) CHCl3
2 5 2 5
3

(3) CH CH OH
Sol.

(1)

C H
2 5

C H
2 5

(4) CH CHO

C H
2 5

C H
2 5

O
155.

Sol.

When 1, 1-dichloro propane and 2, 2-dichloro propane are reacted separately with aqueous
potassium hydroxide solution, compounds A and B are formed. Both A and B gave the same
product C on reduction using amalgamated zinc and HCl. Idenfity C
(1) Propyl alcohol
(2) Isopropyl alcohol
(3) Propyl chloride
(4) Propane
(4)
KOH CH CH CH OH
CH CH CHO
CH CH CHCl
2
3 2
3 2
2
3 2
H O
2
A
O

KOH CH C OH
CH
CH C CH
CH CCl CH
2
3
3
3
3
2
3
3
H O
2

CH

C
CH

Sol.

HCl

CH

CH
3

2
CH

CH CH CHO
3 2

156.

Zn Hg

3
propane

Zn Hg HCl

CH . CH 2CH 3
3
Propane
H+

excess Cl
2
CH CN+H O
A
B
3
2
red P
In the above reaction, A and B are respectively
(1) CH COOH, CCl COOH
(2) CH CH OH, CH CH Cl
3
3
3 2
3 2
(3) CH CHO, CCl CHO
(4) CH COCH , CCl COCH
3
3
3
3
3
3
(1)
CH CN
3

H O
2

CH COOH
3

excess Cl

CCl COOH
3

Red P

157.

Nitrobenzene undergoes reduction with Zn/alcoholic KOH to form a compound A. The number of
Sigma and Pi bonds in A, respectively are
(1) 17, 6
(2) 27, 6
(3) 27, 8
(4) 17, 8

Sol.

(2)
Nitrobenzene undergoes reduction with Zn/alcoholic KOH to form Azo Benzene.
It contains 27 and 6 bonds
NO
2
2

Zn KOH
10 H

alc

4H O
2

158.

Which of the following compounds helps in achieving equilibrium between O2 and CO2 is
atmosphere?
(1) Chlorophyll
(2) Vitamin-B12
(3) Porphyrin
(4) Acetyl salicylic acid

Sol.

(1)
Chlorophyll helps in maintaining O2, CO2 equilibrium in the nature.

159.

Natural rubber is a polymer of

CH
CH

(1) CH

CH CH
CH

(3)

Sol.

CH

CH
C

CH
3
CH

(2)

(4) CH

CH C

CH CH
2

3
CH

CH

(2)
Natural rubber is a polymer of isoprene . It is cis 1, 4 - poly isoprene.
CH
3
CH

2 CH C
isoprene

CH

160.

Match the following:

List I
(A)

B1

(i)

Riboflavin

(B)

B2

(ii)

Pentothenic acid

(C)

B3

(iii)

Niacin

(D)

B5

(iv)

Thiamine

The correct match is

A
B
C
(1)
iv
i
iii
(2)
iv
iii
i
(3)
iii
iv
ii
(4)
iv
i
ii
Sol.

List II (at STP)

(4)
(A) B1 Thiamin
(C) B3 Pentothenic acid

D
ii
ii
i
iii
(B) B2 Riboflavin
(D) B5 Niacin