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(GwINNETr and BUONOCORE, Br Dent J 119: 7780, 1965) that concentrated HSPO4 solutions
resulted in less etching of enamel than did less
concentrated solutions. It would seem, however,
that the same effect could be achieved by a
more dilute solution of H3PO4 containing added
calcium phosphate (for example, composition
F). Such a solution might be safer from a
clinical point of view because of its lower acidity
and the lesser capacity to dissolve Ca5 (PO4) 2OH
in step 2. Finally, if teeth were treated with
solutions containing less than -27% H3PO4, dicalcium phosphate dehydrate would probably
form (line A), but this salt would not be
washed away completely in a clinical situation.
100
_a(H2P04)2* H20
D
0 o
a-
-'
40
CaHPO4
1158
ISOTHERM
_-
ISOTHERM
~HCaHP04 2H20
ISOTHERM
IIlII
Ca(OH)2, %
Solubility phase diagram for system Ca (OH) 2at 25 C. Lines A through E are hydroxyapatite dissolution lines.
HaPO-HaO