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EVALUATION
Faculty: Dr. P.N. Kapoor
GT Lecture 18.08.2008
Source Rock
The sediments that have
been able to generate or may
have the potential to generate
hydrocarbons
Petroleum System
An integrated geological syst em
that:
-- Generates hydrocarbons (gas & oil)
-- Concentrates and traps them
-- Produces economic deposits
Four Main Steps
-- Source: Rich in Organic Matter
-- Maturation & Generation: Burial Heating
-- Migration: Movement thru permeable beds
-- Trap (Reservoir & Seal): Structural & Stratigraphic
Cross Secti on of a Petrol eum System
(Foreland Basin Example)
Sedimentary
Basin Fill
Elements Seal Rock
of Reservoir Rock
Petroleum
Pod of Active System Source Rock
Source Rock
Underburden Rock
Petroleum Reservoir (O)
Basement Rock
Fold-and-Thrust Belt Top Oil Window
(arrows indicate relative fault motion)
Top Gas Window
SAPROPELIC
Algal Amorphous Alginite
REACTIVE KEROGEN
GAS KEROGEN
REFRACTORY
C1-C5 Type III Brown Wood Vitrinite
KEROGEN
HUMIC
compounds (Hydrogen Poor)
INERT KEROGEN
INERT KEROGEN Black Wood Inertinite
CARBON Type IV
Kerogen Classification
Source Component Structure
Organic Matter components
Sediment Profile
Evolution of Organic
Matter
ØDIAGENESIS
ØCATAGENESIS
ØMETAGENESIS
DIAGENESIS
ØTYPE I
ØTYPE II
ØTYPE III
TYPE I
ü Highest H & Lipid content
ü High potential for HC
ü Derived from Algal/ Microbial
Lipids
TYPE II
ü Hig H & Lipid content
ü High potential for HC
ü Derived from Phyto & Zoo
Planktons Lipids
TYPE III
ü Less H & more Oxygen
ü Low potential for HC
adequate for Gas
ü Derived from Terrestrial
Higher Plants
Types of Kerogen
• Type I : algal kerogen
– “best” oil source
– Lipid-rich
• Type II: herbaceous kerogen
– Good oil source
– Includes zooplankton (sapropelic)
• Type III: woody kerogen (coaly)
– Good gas source
– Rich in humic components
• Type IV: amorphous kerogen
Rock Eval Pyrolysis
4 Parameters
ü S1
ü S2
ü S3
ü Tmax
S1
Measures HC liberated by
heating at Moderate
Temperature
S2
Measures Petroleum
Constituents generated by
heating Kerogen at Higher
Temperature
S3
Temperature recorded at
max. of peak S2
Used to measure Maturation
Stage
S2/S3
Signifies type of HC to be
generated from the Kerogen
Tmax
ØImmature Biogenic Gas < 435 0 C Tmax
ØMature Oil Generation > 435 0 C - < 450 0 C Tmax
ØMature Gas Generati on > 450 0 C - < 470 0 C Tmax
ØPost Mature Thermal Gas > 470 0 C Tmax
Prospect
Evaluation
Source Rock Evaluation
The main source materials for
hydrocarbon are the vegetal
debris, including those of
phytoplankton, marine and
terrestrial algae as well as
lipid rich land plant remains.
Application of Organic Matter
Phytoplankton
Thalloid algal matter
Filamentous algae
Phytoplankton
Structured Aqueous
Amorphous organic matter
a. HUMIC – WOOD (H–W) Wood + BDT > Charcoal Very good (gas)
b. HUMIC – CHARCOAL (H–C) Wood + BDT < Charcoal Poor
II. SAPROPELIC (S) S > 75% (PC) Very good (oil)
a. HUMIC SAPROPELI C – WOOD (HS–W) Wood + BDT > Charcoal Good (oil)
b. HUMIC SAPROPELI C–CHARCOA L(HS–C) Wood + BDT< Charcoal Marginal (oil)
Wood = Structured Terrestrial OM, BDT = Biodegraded Terrestrial OM, PC = Pre Condition
Richness of Organic Matter
• Productivity
• Grain size
• Sedimentation rate
• Oxidation/Reduction
Organic matter: 1%
• Kerogen 90%
• Bitumen 10%
Post burial chemical
evolution of natural
combinations of
preserved organic debris
conversion into
KEROGEN
Hydrogen: Carbon and Oxygen: Carbon contents of
common organic and palynological types .
Post depositional
alteration of
KEROGEN
into
BITUMEN
What happens when we subject
kerogen to subsurface conditions?
KEROGEN
Shallow subsurface
Normal pressure and temperature
Diagenesis Released: CH4, CO2, H2O
• Overall decrease in O
• Overall increase in H and C
Deeper subsurface
Catagenesis Increased pressure and temperature
Released: oil & gas
• Overall decrease in H and C
Metamorphism
Metagenesis High temperature and pressure
Only C remains: becomes graphite
THERMAL STAGES OF BITUMEN GENERATION :
DIAGENESIS l ow-temperature/bac terial alteration
CATAGENESIS intermedi ate-temperature alteration
METAGENESIS high-temperature/pre metamorphi c alteration
PALYNOFOSSILS
• SPORES
• POLLEN (Gymnosperms &
Angiosperms)
• DINOFLAGELLATES
• ACRITARCHS
• FUNGI
• CHITINOZOA
(contd.)
PALYNOFOSSILS
• SCOLECODONTS
• SILICOFLAGELLATES
• DIATOMS
• CALCAREOUS ALGAE
• CALC. NANNOFOSSILS
• ORGANIC MATTER
PROCESSING
TECHNIQUES
• Rock Samples -
(cores/cuttings)
• Powdering
• Treatment with Acids
• Obtain Organic Residue
• Slide Preparation
FLOW CHART FOR PROCESSING OF SAMPLES FOR
ORGANIC MATTER
.......
.....
depth
CENTRIFUGE
1200-
1205m
.........................................................................
SLIDE READY
FOR STUDY
SLIDE MOUNTING
O
ON HOTPLATE
AT 100 C
DRYING OF
RESIDUE BY SPREADING
ON COVERSLIP CENTRIFUGE
.........................................................................
RESIDUE MIXED WITH HEAVY LIQUID
POLYVINYL ALCOHOL SEPARATION
Commonly Used
Maturation Parameters:
Vitrinite Reflectance
Liptinite Fluorescence
Thermal Alteration Index
Spore Coloration Index
Tmax
Time Temp Index (TTI)
Oil Window
based on
various
Maturation
indicators
Indicators of
HC
Maturation:
Vitrinite
Reflectance
&
Liptinite
Fluorescence
Fluorescent organic matter
POTENTIAL
OM FACIES
PALEO-
TOTAL OM
CRETACEOUS CENE EOCENE OLIGO MIOCENE REC
POOR SOURCE
LR UP L UP L M U L U L M U
100
2.25 TAI
120
110
FM
Ma
90
80
60
70
20
10
30
50
40
0
30oC SAPROPELIC
TITTACHERI HUMIC-
PORTONOVO SH.
400m FM. CHARCOAL
2.50
RICH
oC
40
GOOD
MOD -
MADANAM LST. HUMIC
VANJIYUR SST. .
50
oC 800 SHIYALI CL ST. SAPROPELIC -
CHARCOAL
oC
60 1200 SH-C MOD
POOR-
NIRAVI FM.
MOD
POOR
NNLM
FM.
oC HUMIC-
70 1600 CHARCOAL
2.75
KARAIKAL SH. KDV
MOD MOD
BVG
oC
FM.
80
2000
KAMALAPURAM
STP
SH.
oC FM.
90
2400
MOD - GOOD
SAPROPELIC
oC RNL TTI=15 HUMIC-
ANDIMADAM FM.
100
RICH
PORTONOVO
2800 SH. CHARCOAL
oC
110 NNLM FM.
BVG FM.
TTI=61 3200 STP SH.
2.75+
120
oC
TTI=108 ANDIMADAM -.-.-.-
3400 FM. .-.-
Burial History Curve, TTI, OM Facies, TOM, TAI and source potential in w ell RNL
TP-A NG-A NR-A
TITTACHERI FM
MADANAM LST.
KARAIKAL
TIRUPPUNDI
FORMATION NR-A
NAGAPATTINAM
NG-A
KAMALAPURAM FORMATION
TP-A
+
KOMARAKSHI SH
+
+ SATTAPADI
SATTAPADI SHALE
STP SH SH ALE
+ 0 10Km
+
SOURCE ANDIMADAM FM + wells studied
POTENTIAL +
POOR
+
MOD-GOOD
+
Depth (m)
Formation
Geochemical Parameters
Position
Organic
Sample
Total (Rao et al., 1988)
Matter Source
Dep.
Age
Env.
Organic
Potential
TAI
Facies Matter TOC T Max. S2
Eoc. BMP Lst.
M.
2000 2.00
Pasarlapudi Formation Rich 430
0.63 – 2.99
1.00
2.25
2100
Moderate- Poor
Humic-
Rich 1.50
Wood
2200
2.50
443
2.50
Rich Good for Gas 3.50
2400
2500 0.50
2600 Poor
Mainly Sand
Poor Organic Matter
2700 0.30
2800
Palakollu
0.76 – 10.6
2900 3.00 446
Humic Sapro Marginal for
Shale
Charcoal 3.50
2.75
position
Sample
(Philip et al., 1986
Depth OM Depo. TMax
Age Formation Facies TAI Source Potential
(m) TOM Env. TOC & vRo
2.00
Inner Neritic
Early-Middle
Poor-Moderate
Eocene
2200 SH-W
436-308
0.75
Middle –
Pasarlapudi
Humic Sapro- Poor
2.25
2300 0.90
pelic - Wood Rich
2400 1.00
2500 1.00
Sapropelic
Marginal
Paleocene
Neritic
1.50
436-
Outer
275
2600 Humic-
for Gas
Late
2.50
Palakollu 0.90 445-
2900 Charcoal 318
Shale Poor 0.75
Early 3000
Palocene Poor 0.80
Razole 3100 Poor
1.50
3200
2.50
3300
4.00
(Maastrichtian)
Sapropelic 0.76
3400 Marginal
Chintalapalli Shale)
Humic- 3.50
Moderate for Gas
Upper Bathyal
3500
Charcoal 2.50
3600
2.75
Late Cretaceous
468-237
3700 2.00
(Maastrichtian)
3800
Late Cretaceous
1.00
3900 Poor-
Humic- 0.75
4000
Charcoal
Moderate Poor
4100
1.50
4200 Moderate Marginal
SH-C for Gas 2.00
4300
0.80
4400 Humic-
Charcoal Rich Poor 0.90
4500
Palynofacies, TOM, maturation and source potential of Chintalapalli Shale, Palakollu Shale and
Pasarlapudi Formation in well MTP
NE SW
BMP PSP CTP RZL NSP GS8 GS5
B B’
0
Rajahmundry Sandstone
Narasapur Claystone
Narasapur Claystone
1000
Matsyapuri Sandstone
2000
Depth in meters
Pasarlapudi Formation
3000
Palakollu Shale
Razole Formation
4000
Chintalapalli Shale
5000
0 25 50 75 km
B B’
0
Rajahmundry Sst
Narasapur Cl
Narasapur Claystone
1000
Matsyapuri Sst
2000
Depth in meters
Pasarlapudi Fm
3000
4000 Razole Fm
Good for oil & gas
Chintalapalli Sh
Moderate for oil & gas
FLUVIAL
KMG-A MDP-A
END-A
DKR-A
FLUVIAL-PARALIC INNER NERITIC
0m
LOWER DELTA INNER-MIDDLE NERITIC
Bay of Bengal
1000m MARGINAL MARINE MIDDLE-OUTER NERITIC
0 10km
TANUKU HORST MANDAPETA
DRAKSHARAMA RIDGE
SUBBASIN
MDP-A
HUMIC-CHARCOAL HUMIC KMG-A END-A
0m (H-C) SAPROPELIC- DKR-A
CHARCOAL
SAPROPELIC HUMIC HUMIC
-CHARCOAL (SH-C) SAPROPELIC-
WOOD
SAPROPELIC
1000m HUMIC- WOOD (SH-
SAPROPELIC Bay of Bengal
0 10km W)
TANUKU HORST MANDAPETA
DRAKSHARAMA RIDGE
SUBBASIN
KMG-A MDP-A
END-A
DKR-A
1000m MANDAPETA
0 10km TANUKU HORST DRAKSHARAMA RIDGE
SUBBASIN
MID-LATE
TRIASSIC
MID. TRIASSIC
- PERMIAN
GAS PROD.
HYDROCARBON SOURCE POTENTI AL
0m MARGINAL FOR
MDP-A
GAS/OIL KMG-A END-A
DKR-A
MODERATE FOR MODERATE-GOOD
GAS FOR OIL & GAS
1000m MODERATE FOR
GOOD FOR GAS
0 10km OIL & GAS
MODERATE-GOOD
GOOD FOR OIL & Bay of Bengal
FOR GAS
GAS
Cenomanian
Late Albian -
3200 Moderate 0 VIII s s m
for gas :s:s ss VIII
:s:s s s
:s:s ss Poor ss
:s:s VIII s
ss ss ss 1220
VII 1500 s s
Late Aptian -
ss ss ss
Albian
s s s
VIII 1300 s s ss VII 1300
3400 s s s
ss ss ss
VI s s
ss ss ss 1405
s s s
A p t I a n
ss ss VII VI
s 1700 s s
V ss ss
s s s
ss ss ss 1500
3600 s s s
s s Mod.for oil ss ss
IV & gas s s
VII ss ss ss
s s
Moderate 1600 ss ss
for gas VI
-
1900 s
ss ss
s V
s
ss ss 1700
B a r r e m i a n
3800 s
ss ss
s s
ss ss
s s
VI ss ss
2100 V s
BKD 2120 ss ss
ANNAVARAM
2140 s s
2160 :s:s Mod.-Good ss 1900
2180 :s:s for gas
4020 PITHAPURAM 2200 :s:s
BKA 2220 :s:s
2240 :s:s
KAKINADA 2260 :s:s IV
SBKA 2280 IV
2300 :s:s
0 20 Km :s:s
GSZ :s:s
YANAM
:s:s 2100
Orissa
SME-A
SWL 560-570nm
0 20 40 60 Km
Oligocene Bihar
Karimpur-A
SWL 580-585mm
Immature phase
ØImmature phase Abhay-A
B, C, Mainagar-A, Mainagar-A
Early phase of maturation
Ichapur-B
Abhay-A Chandkuri-A
wells SME-A, 0 20 40 60 Km
Chandkuri-A,
Ichapur-A, B and
Karimpur-A Maturation profile on the basis of Spectral
wavelength in Bengal Basin during Oligocene
Maturation during N
Eocene Bihar
Ichapur-A
SWL<570nm
ØEarly phase of Mainagar-A SWL>600nm
Ichapur-B
Initiation of generation
maturation in the wells of hydrocarbons
Mainagar-A, Palashi-A Chandkuri-A
ØInitiation of SWL>600nm
Orissa
generation of
SME-A
hydrocarbons in the SWL590-600nm
wells SME-A, 0 20 40 60 Km
Chandkuri-A, Ichapur-
A, B, Abhay-A and
Karimpur-A Maturation profile on the basis of Spectral
wavelength in Bengal Basin during Eocene
Maturation N
Karimpur-A 0 20 40 60 Km
Ø Mature phase in
Chandkuri-A
Maturation profile on the basis of Spectral
wavelength in Bengal Basin during
Paleocene
N
Maturation Bihar
Orissa
ØMature phase in SME-A
Chandkuri-A
0 20 40 60 Km