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A Method for Assessing Thermodynamically the Depletion of Nonrenewables

Mark Lindley

Antonio and Alicia Valero, a father-and-daughter pair of professors at the University of Zaragozas
Centre of Research for Energy Resources and Consumption, have published recently (2014) a magnum
opus more than 650 pages long, and with 81 tables and 132 figures1 about the ongoing decline in
worldwide availability of non-renewable, abiotic (i.e. not living) natural resources vital to modern societies: the fossil fuels and various kinds of minerals.2 The book has a poetic title, Thanatia: The Destiny of
the Earths Mineral Resources: A Thermodynamic Cradle-to-Cradle Assessment (yes, cradle-to-cradle!),
and contains a fascinating and sometimes daunting array of explanations and technical information,
much of which is based on a new theoretical concept (grave-to-cradle) which is described thoroughly
and complemented with practical suggestions for addressing the economic problem.
A quick way to get the drift of the theory is via an analogy between the well known concept in physics of an isolated system in a dead state and a salient aspect of the new concept for which the book
is named. Thanatia is an imaginary geological condition in which (along with some other features specified by the authors) the Earths various minerals, though not absent they have, after all, nowhere
else to go as long as the planet remains coherent would be distributed quite evenly (no longer concentrated in ores or recycling repositories) throughout the land and water. On the other hand, in an
isolated physical system in a dead state, all the energy in the system would be distributed evenly
throughout it with for instance the heat (haphazard zigzag stirrings and reboundings of molecules)
at uniform temperature throughout and there would thus be a physical equilibrium whereby no work
in the physicists sense of the term 3 could take place.
(The Earth is, thank heavens, not isolated, as plenty of energy is radiated here from the Sun.4 But
no minerals are radiated to the Earth.)
Exergy is a term in physics, and important in this book, for energy which in a system with disequilibrium yields work if it is kinetic or can do so if it is potential and is then released. The apple
fell on Newton that was an historic kinetic event when the potential mechanical energy of its high
position on the tree was released by the stem breaking; he could then, by eating it, use some of the
potential chemical energy in it. The difference between exergy and the energy that would be present
throughout an isolated system at uniform temperature,5 pressure and chemical composition is qualita-

1. The publisher is the World Publishing Company (in Singapore). The ISBN is 978-9814273930.
2. See for instance Michael T. Klare, The Race for Whats Left (Henry Holt, 2012). This is one of several kinds
of currently notable environmental degradation. The other kinds include: overshoot in the use of renewable resources; pollution; unduly fast climate change; troublesome changes in the locations of certain kinds of material
(e.g. of H2 O which has, on the one hand, melted from the polar caps and is, on the other hand, flooding Bangladesh); mass extinction of biological species, and yet also new super bacteria and more virulent viruses capable of
causing epidemics.
3. In order, for instance, for a force to qualify as having done mechanical work on a physical object, the force must
have caused a displacement of the object. The amount of the displacement is measured in terms of distance. The
amount of the work is equal to the distance times the amount of resistance that the object poses to being displaced.
With the same amount of work you can either lift one cup of tea 20 cm straight up or else two such cups 10 cm.
4. The flow of energy radiated here from the Sun in a week is more than the total stock of terrestrial energy (thermal energy, fossil fuels etc.).
5. How much energy is there in the aimless molecular stirrings and reboundings which we perceive as heat? The

tively just as notable as, say, the difference in our emotional life between love and boredom, or the
difference in a market economy between legal tender with and without galloping inflation. (Inflation
isnt a lack of money, but it affects the quality of money.)
A basic law of physics says that the exergy in an isolated physical system with disequilibrium would
expend itself in the course of time, and the system would thereby approach equilibrium. A well known
term for such self-expenditure of exergy is increase of entropy. The authors explain that the fundamental idea underlying the concept of entropy is that in an isolated system everything degrades or
becomes dispersed by and by as the systems exergy is gradually expended: sooner or later fluids will
stop flowing, [relatively] warm bodies will get colder, [and] pure substances will become impure.... This
is an experimental fact and constitutes the Second Law of Thermodynamics. The reason why it is called
a law of thermo- dynamics is that the earliest formulations (in the 19th century) of the principle were
just about the fact that heat is spontaneously transferred from warmer to cooler parts of the system,
and did not say anything about, for instance, substances becoming dispersed and thereby immersed in
impurities. In the 1970s, Nicholas Georgescu-Roegen (who was a sharp economist but not a thermodynamicist) proposed an additional theoretical law in regard to dispersion of substances. The Valeros
derive it from the Second Law, and Georgescu-Roegens most accomplished former student, Herman
Daly, has likewise held that the Second Law covers the fact that things left to themselves ... tend to get
mixed up and scattered.6
According to the Valeros, dispersion of raw materials has not been sufficiently considered in economic analyses. It has been ignored as a materials availability loss[,] and it is viewed [instead] as a pollution problem, more than anything else. The purpose of the book is to show, without belittling the pollution problems, how to analyze correctly the materials-availability losses. The Valeros note that nowadays,
technology is employing all [the] elements of the periodic table and their use is growing exponentially.
Yet this fact is barely discussed in conventional ecological discourse that preferably focuses on climate
change, loss of biodiversity, deforestation or ecosystems destruction. Instead, the problem of a future
lack of abiotic resources is readily solved [in the writers imaginations] with the ideas that the Earths
crust is almost unexplored (oceans, the poles, deep underground mines, etc) and that technology will
overcome any potential market disruption. The truth however is quite different, with mining companies
telling another story.
Thanatia is defined as a theoretical, quantitatively formulated model of an economically dead
condition of the Earths atmosphere, hydrosphere and upper crust, whereby all the fossil fuels would
have been burned, leading to an increase in atmospheric CO2 concentration (the authors reckon it
would be some 70% higher than now) and hence in mean global surface and atmospheric temperature
due to the greenhouse effect, and, all commercially exploitable [mineral] resources [would] have been
consumed and dispersed (my italics) throughout the upper crust and hydrosphere. This model provides
a theoretical baseline against which the authors venture quantitative assessments of what would be
required theoretically to restore the minerals from thanatia to useful conditions of concentration (like,
for instance, in economically feasible ores).

authors mention that Whilst a calorie is a really small amount of heat, namely that [which is] needed to warm a
gram of water by one degree centigrade, it is also the kinetic energy of that same mass at 327 km/h! Hence, small
fluctuations in system temperatures result in considerable energy expenditures. (They mean exergy expenditures.)
6. Herman Daly and Joshua Farley, Ecological Economics: Principles and Applications (Island Press; 1st edition,
2004; revised 2nd edition, 2011), Glossary.

The assessments are in terms of physical exergy costs (although data for monetary costs etc. are
also amply cited). Prices depend on psychology,7 whereas physical exergy cost in regard to minerals
depends only on the techniques of mining, processing, using, recovering and/or disposing of them.
Monetary sums are at least latently akin to microeconomic thinking, partly because the quality of social
power in the money in the employers pocket depends on the employee wanting to have some of it in
his. The Valeros are making macroeconomic assessments of Humankinds mutual relation with the abiotic content of the outer layers of the planet, which doesnt care about social power.
They use the noun grave to refer metaphorically to thanatia, and they use cradle to refer to (1)
the corresponding, not economically dead condition nowadays (as there is still nowadays a modicum of naturally concentrated mineral deposits) and (2) an economically equivalent condition after a
recuperation from a dangerous (and perhaps disaster-laden) historical approach to the theoretical
thanatia. Hence the books subtitles, The Destiny of the Earths Mineral Resources: A Thermodynamic Cradle-to-Cradle Assessment.
The following schematic chart (slightly simplified from one in Chapter 4) represents flows of exergy
(except that its dissipation, represented by the lowest arrow, is loss of exergy and hence growth of
entropy) in the global economy:

Use includes all the uses by consumers. The Stock in Landfills block overlaps with Thanatia because in some of that stuff in the landfills, the minerals which had previously been economically useful
are so utterly dispersed that to restore them, by urban mining, to a feasible degree of purity and/or
concentration would be unfeasible. The Valeros envisage estimating (a) the exergy costs nowadays of
extracting and processing fuels and minerals, and also (b) the potentially smaller such costs if there

7. The Valeros tactfully refrain from mentioning price fluctuations due to mob psychology rather than to rational
assessments of value. Instead, they say (p.xii) that if Economics is used to explain value creation, Thermodynamics can describe and quantify the resource destruction [in regard to mineral resources] that comes about
in the creation of that value. Some relevant but woefully mistaken modern laissez-faire precepts are that the
eventual unavailability of any one kind resource can always be dealt with by paying more money for a substitute
and that the price system thus communicates to the scientifically ignorant man on the spot all the information
beyond the limited but intimate knowledge of the facts of his immediate surroundings that is needed in order
for society to make wise decisions. (These phrases are from Friedrich Hayek, The Use of Knowledge in Society,
American Economic Review, XXXV (1945), p.525.)

were wiser and more expert uses of technology (as well as wiser patterns of consumption and recycling). These exergy-cost estimates would presumably be helpful for figuring out the best ways of
slowing down the dissipation and conserving more of the valuable stuff.
The book has 16 main chapters, as follows.
1: The Depletion of Non-Renewable Abiotic Resources. This is mainly about how the currently
increasing demand for certain minerals may hinder the development of a green economy as proposed
by the U.N. The discussion is rich in geological data and engineering savvy, and contains the equivalent
of a two-hour graduate-level seminar in environmental economics for people who expect windmills,
solar photovoltaics and bioenergy to supply consumable energy as plentifully in the 21st century
as fossil fuels did in the 20th. Three facts which leap off the page are that (a) in order for half of the
worlds electric power in 2030 to be generated by windmills of the types that we now have, an amount
of copper equal of that which could be obtained by mining two-fifths of the worlds current economically exploitable reserves of copper ore would have to be mined just to supply the copper for the motors
in those windmills and the transmission lines from them (Would you call this green?); (b) the dependency of new-fangled solar photovoltaics on critical chemical elements is just as drastic; and, apropos
bioenergy, (c) the global supply of phosphates will not meet future demand without drastic changes
within the recycling sector [and] in the application of fertiliser, improvements in food chain production[,] and alterations to the Western diet. The authors point out that Plants and other biota require
phosphorus to live[,] with no possibility of replacing it with an alternative.... [T]he amount of biomass
that can be produced is absolutely limited by the phosphorous resources of the planet and mankinds
capacity to recycle it [i.e. the phosphorus]. Any solution will almost certainly sharply raise future food
This can be understood without the Valeros theoretical innovation. (Toward the end of the chapter they say a little about why they think the innovation will be useful.) The next two chapters provide
some historical and intellectual background against which they will, in some of the subsequent chapters, survey more thoroughly and in a more long-term context the material facts that have been
sampled in this prologue.
2: Economic versus Thermodynamic Accounting. Economics professors who are familiar with
the modern history of their discipline can readily understand a good deal of this chapter. It describes
various concepts which (a) economists, (b) accountants (in a broad sense of the word) and (c) scientists have devised for assessing environmental degradation in general and mineral-resource depletion in particular. At the outset the Valeros mention the well-known distinction between economic
capital measured in terms of money, social capital and material natural capital, and describe this
latter idea as a useful conceptual bridge that can help economists and thermodynamicists to understand each other ... especially in [regard to] quasi-static geological systems as opposed to the more
dynamic biological ones.8 Later in the book they will suggest that natural endowment would be a
more valid concept than natural capital.

8. What is said here about geological (vs biological and sociological) realities reminds me of what Kenneth Boulding said in 1981 (in his book, Evolutionary Economics, p.44) about the solar system: The only reason why prediction is so successful in celestial mechanics is that the evolution of the solar system has ground to a halt in what
is essentially a dynamic equilibrium with stable parameters. Evolutionary systems, however, by their very nature
have unstable parameters.... If, of course, it were possible to predict the change in the parameters, then [this would
mean that] there would be other parameters [structurally deeper] which were unchanged; but the search for ultimately stable parameters in evolutionary systems is futile, for they probably do not exist.

(a) Economists. After noting the radical views of Ludwig von Mises (It is vain to provide for the
needs of [future] ages the technical abilities of which we cannot even dream) and Friedrich Hayek
([T]he conservationist who urges us to make greater provision for the future is [thereby always] in
fact urging a lesser provision for posterity), and Harold Hotellings less radical precept (1931) that
mining companies would inevitably extract non-renewable resources at a rate which would maximize
social well-being indefinitely, the Valeros outline some subsequent opinions of market economists
(from Barnett and Morse 19639 to Krautkraemer 2005) and mention that fluctuation in the price of oil
in the last fifty years has often been due more to political manipulation than to a new objective finding
as to how much is left in the bucket. They then distinguish between the ideas of environmental economists (such as the polluter-pays precept and the application of cost/benefit analysis to economicenvironmental tradeoffs)10 and those of ecological economists such as Georgescu-Roegen (who is
discussed at some length), Daly, Kenneth Boulding and Kozo Mayumi. These ecological economists are
found to have deeper transdisciplinary inspirations and a larger time-horizon in mind (i.e. deeper and
larger than has been characteristic of the environmental economists), but even they have lacked, the
Valeros maintain, the quantitative instruments to convert economic statements into global vision and
policy for a sound management of planetary resources. (The work of certain other ecological economists is treated under the Accountants and Scientists headings.)
(b) Accountants. Some of the concepts described here are the SNA (System of National Accounts);
GNP (Gross National Product); EW-MFA (Economy-Wide Material Flow Accounts); NPV (Net Present
Value, i.e. with discounting11 from supposed future monetary values); the SEEA (System of Environmental-Economic Accounts; the Valeros praise this for the way in which the statistics are universally
organised permitting well established procedures for their analysis, but they also criticize it, partly
because its recommended method of valuation is in terms of imaginary market prices (estimated NPVwise) for non-market assets an accounting technique which harbors implicitly the absurd notion that
if one could extract and use all present environmental capital and convert it into money it would be
better than having [any] physical assets yet to be exploited); the Net Price Method, User Cost
Method and Hartwick Rule (all of which fail, in the Valeros opinion, to seriously look at the consequences of production and [indicate] whether it is sustainable on the long term); Wouter van Dierens precept of Environmental Defense Expenditures; and Roefie Heutings concepts of Prevention
Costs, Avoidance Cost, and indefinitely extending [non-renewable] reserves. The Valeros discuss
strong-sustainability thinking (i.e. thinking about each kind of natural resource in its own right, without assuming a priori that if it is used up, a substitute can replace it), and this prompts them to examine critically the common-sense notion of natural capital and to list some misconceptions hidden in

9. According to Harold Barnett and Chandler Morse, Scarcity and Growth: The Economics of Natural Resource
Availability (Johns Hopkins University Press, 1963; p.11), Advances in fundamental science have made it possible to take advantage of the uniformity of matter/energy a uniformity that makes it feasible, without preassignable limit, to escape the quantitative constraints of the earths crust. Daly has perspicaciously detected here
the alchemists dream of converting lead into gold. (See Dalys brief essay, Georgescu-Roegen versus Solow/
Stiglitz, in the journal Ecological Economics, 22 (1997), p.263.) V. Kerry Smith has correctly remarked (in
Scarcity and Growth Reconsidered, Johns Hopkins University Press, 1979; p.69) that it is not the uniformity
of matter-energy that makes for usefulness, but precisely the opposite.
10. Such precepts are not mainly what business schools teach as environmental economics. Some of the lessons
in those schools are, for instance, about how to pollute without paying.
11. The idea of discounting when assessing the present negative monetary value of a future cost is that if you
know that the cost at a certain future time will be a certain amount, you could put a smaller amount now in, say,
a savings account with a guaranteed annual interest rate, such that the account would yield the full amount by the
time you have to pay.

the analogy with industrial capital. (Natural endowment would be, they say, a more suitable term. I
agree.) They warn against supposing that substituting one mineral for another is going to be routinely
feasible in a high-tech era of clever uses for this and that specific mineral resource. They mention that
recycling often requires a lot of exergy (a fact which Chapter 14 will explain in detail). And they point
out the paradoxical fact that since the overriding mentality [nowadays] is that ecosystems are subject
to irrevocable death whilst minerals are not, modern society likes to use up, in order to restore local
ecosystems, the non-renewable kind of natural endowment which is the subject of their book, without
trying to use inherently renewable (though evolving) ecosystems to help recover certain non-renewable
mineral resources from degeneration into useless waste.
(c) Scientists. This part of the chapter is a bridge between its earlier parts and the next chapter.
The Valeros say that ecological footprint (Wackernagel and Rees, 1996; this concept is based on
reckoning in terms of surface areas of economically and environmentally valuable parts of the globe)
explains well the demand for the regenerative capacity of biotic systems but provides insufficient
information when dealing with abiotic resources. (Indeed. How could you guess at the value of an
abiotic resource on the basis of square meters? Its not like a field of wheat.) They are ambivalent about
H.T. Odums emergy analysis. It is, they find, too inexact (and I agree), even though it does address
eco-centric problems that other methodologies are unable to, and is based on the resources [own]
physical characteristics, and measures all resources ... with a single unit, and is therefore useful
(notwithstanding the inexactness) for ecosystem analysis. They find that Friedrich Schmidt-Bleeks
proposed method (1993, 1994) of assessing by weight the material input per unit of [economic]
service is a sustainability-indicator which is easy to understand but takes no account of irreversibilities like material dispersion and depletion, nor of the costs of dealing with contamination through
heavy metals, radioactive materials and persistent [noxious] organic compounds, and thus yields insufficient clues for prioritizing among possible remedial measures. They are likewise ambivalent about
embodied-energy analysis (with estimates of how much consumable energy has been consumed in
the course of creating various commodities and delivering them to customers), which Bruce Hannon
in the 1970s had used in drawing up input-output matrices for the U.S. economy (with the numbers
representing amounts of consumed energy rather than dollars).12 They say that this kind of analysis
often provides valuable insights but is to some extent methodologically weak because it lacks thermodynamic fundamentals and therefore lacks good rules for allocating [the supposed] energy inputs [i.e.
exergy costs] among [the resulting] co-products, by-products and wastes common in many mines.
Georgescu-Roegen had, on the basis of his own regard for thermodynamic fundamentals, criticized
the concept of embodied energy more sharply than the Valeros do.13 I see two interesting analogies
here. One of them is with W. S. Jevonss famous rejection (1871) of the classical economists labour
theory of economic value. Labour and embodied energy are, alike, aspects of the history of the commodity up to the moment when it is ready for sale to consumers, whereas (a) Jevons pointed out that
its market value routinely depends on how much people are thereupon willing to pay for it (regardless

12. See Bruce Hannon, The role of inputoutput analysis of energy and ecologic systems in the early development of ecological economics a personal perspective, Annals of the New York Academy of Sciences, 1185
(2010) pp.30-38. The account begins as follows: The idea of combining economics and ecology into a single
discipline has it roots in the ideas of Robert Costanza in the mid-1970s when he was completing his PhD thesis
with the Energy Research Group ... at the University of Illinois in Urbana....
13. See Mauro Bonaiuti, ed., From Bioeconomics to Degrowth: Georgescu-Roegens New Economics in eight
essays (Routledge, 2011), p.237.

of how much labour may have gone into producing and delivering it),14 and (b) the Valeros will estimate
losses of the thermodynamic rarity of mineral resources on the basis of assessing how much exergy
would theoretically thereafter have to be spent to recover them from thanatia. The other analogy that
I have in mind is between the concepts of embodied energy and virtual water (i.e., water used to
produce a commodity which may or may not then actually contain it):15 In each case a qualitative qualifier should be recognized as being crucial to the argument, since the energy is really exergy and the
water is practically always freshwater.
(Given that the Valeros see, just as clearly as Georgescu-Roegen had seen it, a lack of thermodynamic fundamentals in the concept of embodied energy, why do they say that it often provides
valuable insights? The answer has to do, I think, with the fact that retail consumers shouldnt have to
study exergy etc. in order to make environment-friendly microeconomic choices. For that kind of purpose a thermodynamically inexact concept such as embodied energy will suffice. What the Valeros
are trying to provide, however, is a more exact kind of guide for engineers and the like. They dont go
into political science, but I imagine that if they did, they would mention Pigouvian taxes.16)
After discussing in this chapter several additional ways of assessing environmental impact, the
Valeros prepare the reader for the next chapter by introducing the concept of thermoeconomics,
the basic precept of which is that the role of exergy in our material activities ought to be understood
not only by means of the Second Law but also in terms of such criteria as the efficiency and benefits
(health-wise, for instance) of the various mechanisms for capturing and utilizing exergy to make commodities and perform other services.
(If this basic precept of thermoeconomics is worth applying to all our material activities, why should
it be especially pertinent to our uses of abiotic natural resources? The answer lies in Alfred Lotkas distinction (1945) between endosomatic and exosomatic instruments. Endosomatic is a tag for things
inside the body of a given creature; exosomatic refers to things outside it. A birds wings, beak and
feet are endosomatic; a beavers dam and a [wo]mans gun are exosomatic. We humans have, however,
far more exosomatic instruments than other creatures do. Whereas all creatures with skeletons need
calcium phosphate endosomatically for their bones, we humans also need calcium carbonate (limestone) exosomatically for building stones and cement; we need calcium sulfate (gypsum) for plaster;
etc. Whereas all red-blooded animals need iron endosomatically in order not to become anemic, we
modern humans also need it exosomatically for steel. And so on; the examples are legion.)
The latter part of this chapter and the entire next one are philosophically the most interesting parts
of the book. In order to serve up a taste of the philosophy (and, in particular, the concept of quality
as a characteristic which can be found in our lives and in the inanimate world) let me mention first that
in physics, the word system is a term (i.e. a word with a standard technical meaning) for any given or
imagined portion of the universe that has been chosen for studying the physical changes which take
place within the system in response to varying conditions (that is, it doesnt have to be something

14. William Stanley Jevons, Theory of Political Economy (1871 and several later editions; my reference here is to
the 1931 edition), p.164: [L]abour once spent has no influence on the future value of any article.
15. Different writers have offered somewhat different definitions of virtual water. The definition best suited to
my point here is in A.Y. Hoekstra and A.K. Chapagain, Water Footprints of Nations: Water Use by People as a
Function of their Consumption Pattern, Water Resources Management, vol.21 (2007), pp.35-48): the volume
of freshwater used to produce the product, measured at the place where the product was actually produced.
16. The concept of Pigouvian taxes was first set out in 1920 in A.C. Pigous The Economics of Welfare. The
Organization for Economic Co-operation and Development defines them as tax[es levied on an agent causing
an environmental externality (environmental damage) as an incentive to avert or mitigate such damage.

which would be described in common-sense talk as systematic; it can be anything physical, big or
small, that a physicist wants to study); the properties of a given system are said to be either extensive or intensive; and, its extensive properties include its total energy as well as its mass and volume, whereas the intensive properties (i.e. properties which can be estimated quantitatively without
having first got estimates of the extensive ones) include the systems temperature(s), level(s) of pressure, and chemical composition. The Valeros theory depends on the fact that the systems intensive
properties can each be converted into exergy; but they appreciate also the fact that the qualitative
aspect of a systems energy which determines what proportion of it is exergy (i.e. to what extent the
energy can perform work) is hardly the systems only quality that is likely to be important to us. They
point out that a certain morsel of food could to some appear repugnant, whilst to others [it might be
of] extraordinary [value,] but regardless of opinion it will always maintain the same exergy value, and
that a work of art will have aesthetic as well as physical qualities, and the former will of course have a
lot to do with its value. They decline, therefore, to put forward exergy as a physical measure of the
value of things as an alternative to their market price.
In regard to Humankinds uses of minerals and fuels the Valeros are seeking to define and identify
(and here I will italicize some of their words that imply quality) the true efficiency [exergy-wise, and
therefore macroeconomically in the long term] of processes in a given system, once the desired flows
[of goods] to be produced are identified. They want to show how to increase the true efficiency.
3: From Thermodynamics to Economics and Ecology. This chapter is about some aspects of
thermodynamics which are relevant to macroeconomic assessments of all kinds of environmental
degradation. It starts out with detailed accounts of the laws of thermodynamics, of the concepts of
exergy and irreversibility, and of thermoeconomics. Then it gives, in preparation for the next chapter,
an introductory account of physical geonomics, which is an application of thermodynamics that the
Valeros have devised in order to be able to make their quantitative evaluation[s] of mineral resources
from a Second Law perspective. Exactly how they would do this for each kind of mineral is explained
later in the book; Chapters 5 and 6 will meanwhile provide an introductory account of all the valuable
abiotic stuff that is currently accessible to mining companies etc., or which may become accessible in
future if inventors devise new ways to get and use it (and if civilization is not meanwhile destroyed).
4: Physical Geonomics: A Cradle-Grave-Cradle Approach for Mineral Depletion Assessment. The
key idea here is to consider, in assessing quantitatively Humankinds current and likely future relation to
minerals, not just how much pollution etc. is caused by mining and by industrial uses of minerals, and
how much exergy will sooner or later have to be expended to prevent the pollution from rendering us
very sickly or even extinct, but also how much exergy would theoretically be needed to return each economically valuable kind of mineral from an utterly dispersed, crepuscular condition of thanatia to a
condition of a certain degree of rarity thermodynamically equivalent to what it was when the stuff
was in the mines where Humankind found or will have found it. This latter amount of exergy is equal
to the natural bonus of having minerals concentrated in the ores in the mines rather than being dispersed evenly throughout the Earths crust.
This chapter culminates in a set of three graphs in each of which the curve looks as though it were
plotting commodity price (on the vertical axis) against market demand (on the horizontal axis), but
actually the difference in height between any two points on the curve represents an amount of exergy
which has somehow been expended on work (in the physicists sense of the term) causing a certain
batch of a certain mineral to have a certain degree of thermodynamic rarity, while the resulting economic quality of the ore the ore grade is plotted horizontally in the graph. Of particular interest
are the situations (a) in the dire crepuscular conditions of thanatia (xC), which are, however, infinitely
better than before the cosmic Big Bang (we would need an infinitely tall graph to chart the situation

before that), and then (b) in an ore which is more or less feasible for mining (xM), and then (c) postbeneficiation (xB), which is economically better than before the beneficiation17 but is still prior to the
refined minerals use in manufacturing to make commodities such as houses, airplanes, hair dryers,
diet-supplement pills etc. The first
of the three graphs, which can be
taken as being about a momentary
situation in regard to a certain mine
and a certain mineral taken from it,
includes a note to the effect that
while the difference in thermodynamic rarity between the stuff
theoretically in thanatia and actually
in the mine is a natural bonus
(since our heritage from Nature includes the existence of this batch of
ore suitable for mining), the subsequent difference between the ore (a)
in the mine and (b) after extraction,
beneficiation, etc. is the mine-tomarket cost (reckoned here in
terms of exergy):
The second graph indicates that
the mining process itself diminishes
the natural bonus, since more exergy
has to be expended to dig deeper (or
whatever). In this graph, xM1 and xM2
represent earlier and subsequent conditions, given a certain mine and a
certain set of techniques for mining
it and processing the stuff:18
But what if better techniques could
be devised and applied, such that (a)
the mine would yield more from the
same Human-administered amount of
exergy, and (b) the processing became
likewise more efficient exergy-wise? In
that case, we would have a new curve,
in which each distance rightwards would be at a lower height:

Ore grade

17. The mining consists of extracting ore from the deposit and transporting it (inside and outside of the mine).
The ensuing beneficiation would characteristically consist of crushing and grinding the ore and then separating
the sought-after stuff (by such techniques as flotation, magnetization, sieving, washing etc.) from other stuff in the
ground-up ore. (That other stuff is called "gangue".) The resulting valuable stuff then transported to a treatment
plant, where metallurgical treatment would consist of "smelting" (chemical reduction of metallic oxide to obtain
(unpurified) metal(s) and then "refining" the metal(s), e.g. by electrochemistry or carbochemistry, to whatever
degree of chemical purity the manufacturer requires.
18. There is no arrow of time from left to right in these graphs. Instead, the points further to the right represent
higher grades of economic quality in the stuff at a certain stage (indicated by the subscript to x) of the process.

(And yet there would be, of course, a steadily increasing mine-to-market cost to be charted on this
new curve as time goes by; and the mine would eventually be exhausted, and the natural bonus
thereby lost.)

The next four chapters make up a section of the book which is entitled Over the Rainbow: From
Cradle to Grave. It goes into detail about the chemical and mineral makeup of the Earths abiotic stuff,
about the global distribution of the various substances, and about how they are taken from the natural
endowment to Industry en route to their consumption and toward the theoretical thanatia. These chapters are like handbooks inasmuch as they include 29 tables (as well as 30 figures), some of them several
pages long; but virtually all the data is in one way or another needed to help provide a reasonably solid
basis for the important (though somewhat speculative) assessments set out in Chapter 13.
5: The Geochemistry of the Earth and 6: The Resources of the Earth. These chapters review
the planets geological and geochemical characteristics, focusing especially on the quantity and quality
of the useful mineral resources. Chapter 5 is equivalent to a graduate-level lecture19 on geology and
account of the make-up of our abiotic natural endowments20 in terms of all the important kinds of minerals and of 77 chemical elements which are potentially available for extraction and use. It describes
the composition of the various layers of the atmosphere, of the hydrosphere (i.e. the various forms of
H2O, including the atmospheric water vapour, the renewable freshwater resources,15 the ice caps, ice

19. Appendix B in the book provides, for economists and other readers who may not have had college-level education in chemistry or geology, the equivalent of undergrad-level lectures on the minerals and the chemical elements
and their characteristic economic uses.
20. Topsoil is not included in this survey, as it is teeming with worms, insects, plant roots and microorganisms
hardly abiotic; and, the moisture in the topsoil (which amounts to a tiny portion of the hydrosphere, but is of
course vital for the plants on the land) is not included in the hydrospheric reckoning.

sheets and glaciers, and the 97% of the hydrosphere which is salt water) and of the continental crust,
with detailed attention to the chemical and particularly the mineralogical composition of the upper
part of the crust. (99% of this upper part can be accounted for in terms of eight chemical elements. The
other elements are rare.) The history of the methods of making such estimates is described in some
detail. The Valeros regard the findings of N.A. Grigorev (2007)21 as being a significant improvement
upon those available in the compilations published by Wedepohl (1995), McLennan (2001) and Rudnick
and Gao (2004).
Chapter 6 is mostly about the various possible resources of consumable energy: nuclear, geothermal (i.e. from heat radiating ultimately from the innermost parts of the Earth to the surface), tidal,
hydroelectric, from windmills, and more or less directly from solar radiation, as well as from burning
various kinds fossil fuels and of biomass. Remarkably detailed data are set out, for instance in regard
to ores, petroleum etc. of various different qualities. The reason why is perfectly obvious when it comes
to fuels: the higher the quality, the less is needed to provide this or that amount of consumable energy.
An excellent recent textbook by Nancy Carpenter22 describes in detail the theoretical chemical aspects of various industrial methods of producing consumable energy, and she is clearly attentive to the
fact that even if a certain method may appear to be inherently sustainable, the materials needed to use
the method may be too readily exhaustible. The Valeros go into far more detail about this latter point.
7: An Introduction to Mining and Metallurgy and 8: Metallurgy of Key Minerals. Chapter 7
describes the main physical processes, costs exergy-wise, and environmental impacts of the mining and
metallurgical industries (exploration, extraction, smelting, refining), and also the reclamation, rehabilitation and post-closure treatment of mines. This serves as an introduction to a set of more specific and
detailed analytical descriptions, in Chapter 8, of the processes in regard to each of a dozen different
demetallurgical categories (iron and steel; aluminium; copper; copper-related metals; nickel and cobalt;
etc.) and to each of several subcategories within some of these categories.

Having thus discussed taking stuff from Nature23 to Industry en route to the theoretical grave
of thanatia, the Valeros devote Chapters 9-12 to a theoretical reversion from grave to cradle, a
reversion which they also tag metaphorically as down the rainbow, i.e. back to a useful degree of
concentration. Their quantitative study of such theoretical reversions will provide data for a comprehensive set of provisional assessments, in Chapter 13, of how fast the natural endowments of the nonfuel minerals their economically feasible natural concentrations in the Earths upper crust could well
be exhausted in the next ten or twenty decades.
(Chapters 14-16 will then suggest how to develop and adopt more efficient ways of extracting, processing, using and recycling nonrenewable abiotic resources. To cultivate a rational management
rational for Humankind of mineral resources would be, the Valeros say, like tying the rainbows: rerouting the stuff away from the last part of its journey to thanatia. These Spanish-style poetic touches
carry messages of admonition and of hope.)

21. N.A. Grigorev, Average composition of the upper continental crust and dimensions of the maximum concentration of chemical elements... (in Russian), Uralian Geological Journal, III (2007), pp.3-21.
22. Nancy E. Carpenter, Chemistry of Sustainable Energy (Boca Raton (Florida, USA), CRC Press; 2014).
23. I put this word in quotation marks in order to avoid implying that Humankind is not part of Nature.

9: Thermodynamics of Mineral Resources. This is about which particular thermodynamic concepts are useful for exergy-cost assessments of mineral formation, separation, scarcity and mining,
and for exergy-calculations in regard to the resulting fuel and non-fuel minerals.
10: Thanatia and the Crepuscular Earth Model. This is about how to assess quantitatively the
theoretical baseline for exergy-assessments of mineral resources. It includes accounts of how much of
each kind of the various mineral resources (defined in terms of their differing chemical compositions,
which are described in detail) would exist in thanatia.
11: The Exergy of the Earth and its Mineral Resources. This chapter provides definitions and discussions of enthalpy and of Gibbs free energy. These mathematically formulated concepts of physics
closely related to, but not the same as, exergy are of use in the next chapter.
12: The Exergy Replacement Costs of Mineral Wealth. This is about how the replacement costs of
depleted mineral resources compare, exergy-wise, with the current consumable-energy costs of mining
and metallurgical processing. Replacement here means recovery, not substitution.24 (You may recall
my having mentioned that Chapter 1 includes a remark to the effect that plants and other biota require phosphorus to live and that there is no possibility of replacing it with an alternative, i.e. of
substituting something else for it.) Phosphorous is not the only such indispensable stuff.
A notable fact brought out in this chapter is that while more than 60% of the physical exergy costs
attributable to the total worldwide production (as of 2008) of the main non-fuel mineral commodities
had been in the form of fossil fuels being burnt up in order to get the stuff, some 33% of the exergy
costs was in the form of a resulting loss of the bonus of having the minerals concentrated in feasible
ores instead of being spread thin in a crepuscular worldwide landfill. (The Valeros havent used this
phrase, but it seems to me suitable.) No wonder recycling will be discussed at length in Chapter 14.
13: The Exergy Evolution of Mineral Wealth. This is to my mind an especially impressive chapter.
Back in Chapter 2 the difference between quasi-static i.e. non-renewable resources and the more
dynamic biological systems has been mentioned. A well-established way of making predictions in regard to the rates of extraction and (hence) exhaustion of the non-renewables is by means of Hubbert
curves. Hubbert was a geophysicist in Texas who devised the following kind of graph and used it to
make a remarkably accurate prediction that peak production (i.e. the historically fastest overall
annual rate of production) from oil wells within the USA would occur in 1970:25

24. See apropos Kozo Mayumi, The_Notion_of_Substitution..., at www.academia.edu/12516509/The_Notion_of_Substitution_Reconsidered_Economical_Biophysical_Epistemological (downloaded 27 May 2015).
25. M. King Hubbert, Nuclear Energy and the Fossil Fuels (Houston 1956), p.10 (and p.22), and Energy Resources: A Report to the Committee on Natural Resources of the National Academy of Sciences National
Research Council (Washington 1962), p.73.

The area under the curve represents the stock. The height of the curve at any given moment (time is
plotted from left to right) represents the rate of its extraction at that moment. The left half of the curve
represents an historical progression from a gradual start-up to a kind of feeding frenzy as the curve approaches the peak production phase, some halfway through its historical course. For any given real
stock, data must be available (if this method of prediction is to work) for a fair amount of the left half of
the curve (which will therefore be less smooth than in the idealized version); the method entails using
on the one hand an estimate of the total natural stock and on the other hand a presumption, based on
some historical observations which Hubbert had made, that after half of it has been used, the rate of
extraction will slow down pretty much in reverse to the way it had sped up.
Chapter 13 includes more than 70 Hubbert curves (as well as dozens of other graphic figures) providing easy-to-read assessments of when the peak-production years for each of the various kinds of
useful minerals are likely to have occurred.
Some words of caution are called for. If the estimate of the feasibly available natural stock is too
hopeful, then the peak-production moment will come sooner, and vice versa if feasible ores prove to be
more bountiful than expected. If the estimate is to be made in terms of exergy costs, then good data in
regard to the history of the ore grades is also very desirable; and yet only patchy data are at hand for
the assessments in regard to some of the minerals; and so, many of the Valeros Hubbert curves represent merely provisional assessments. (They acknowledge this and discuss various ramifications of the
uncertainties.) But the method is informative even so, because if the stock that is feasibly available
from natural endowment is really twice as big as estimated, then the rightward shift of the peakproduction moment is a matter of only some 35 years.
The chapter culminates in a set of five graphs, on each of which several Hubbert curves are placed.
The first and last of this set are shown below. (Note that the amounts represented by the heights of the
curves in the first graph are far greater than in the second one. All the stuff for which data are plotted
in the second graph is merely part of what is covered by the hardly perceptible curve labeled Rest of
minerals in the first graph.)

The general take-away message is that all the peaks will probably have occurred before the next
century and that a great number of shortages will become drastic before the end of it.26
However, the Valeros purpose is not just to sound an alarm about looming shortages of nonrenewable abiotic resources but also to outline a well-designed basis for mitigating the effect of the shortages. The next three chapters are about that. The following graph shows what percentages of the
estimated original natural endowments (i.e. as of the birth of modern industry) of ores for 42 economically important non-fuel mineral commodities had been exhausted as of 2008:

26. Let us recall here that radical shortages of nonrenewable abiotic resources comprise only one aspect of looming environmental degradation, and that some of the other aspects may be of more urgent significance. The effects
of climate change are likely, IMHO, to cause agricultural havoc already in this century. Newfangled epidemics
due to superbacteria etc. will meanwhile draw immediate attention. The timescale of the effects, dangerous to
Humankind, of diminishing biological diversity may be comparable to that of the diminishing natural endowment
of mineral resources: a well-qualified Canadian ecologist has estimated (Peter F. Sale, Our Dying Planet: An Ecologist's View of the Crisis We Face (University of California Press, 2011; p.233) that by the end of this century,
Most larger species (coyote size and up), other than those directly cultivated by humans, are likely to be extinct
or to exist only as threatened populations.... Environmental goods and services [needed by humankind] will be
much reduced simply because of the loss of diversity of organisms. With the increased homogeneity and overall
reduced diversity, there will be a much greater risk of pandemics that severely impact particular species and create
massive change in ecosystem composition as a result. The risk of a species extinction that has major ramifications
through the ecosystem will become ever greater as diversity falls, and our own population will be precariously
dependent on just a few species to sustain its vast size.... [Probably] it could be a sustainable world for a time,
as long as we engaged in a fair amount of environmental engineering to help it along until it neared the point
of final collapse.

14: Recycling Solutions. Some of the points covered in this chapter are that the only way to eliminate extraction from natural endowment would be to increase recycling and reduce demand until the
latter no longer exceeds the former; that this is not going to happen very soon in regard to strategic
metals (the recycling of which has seldom amounted to as much as half of the fast-increasing demand
in modern times); that even so, to recover economically valuable chemicals from tailings,27 slags and
post-consumption waste is beginning already to gain importance as the ore-grades of natural deposits
continue to decline and as extraction from this or that kind of waste tends therefore to become costeffective; that dispersion should therefore be assessed as the replacement cost from thanatia not just
to traditional mines (as described in Chapter 12) but also to potentially useful technospheric waste;
that while we cannot improve the levels of concentration of valuable minerals in natural-endowment
sources, we can by means not only of technology but also of lifestyle-alteration improve the levels
of concentration in various kinds of anthropogenic mines, while also improving the techniques of
anthropogenic-mine as well as natural-mine beneficiation and metallurgy; that all forms of recovery
from technospheric waste are subject, however, to the Second Law, and the waste from a consumed
recyclate is likely to contain more entropy than the recyclate had contained; and yet that there is nonetheless a huge potential for material and energy savings and for reducing pollutant emissions. The
Valeros call for a holistic view of life-cycles [of consumable minerals] and recycling chains, for further
research in process and in end-of-life recovery, eco-efficient design [and] disassembly, for systematic
account of [exergy] losses[,] ... a new way of promoting and managing material streams[,] ... and an economic paradigm shift.
15: The Challenge of Resource Depletion. This chapter discusses (in a somewhat rambling way, it
seems to me) why mineral resources are being poorly managed. It identifies accurately (in my opinion)
some big defects in the neo-classical economic theory which has focused so much on material social
exchanges that it has neglected environmental externalities and has incorrectly taken as for granted
that everything in our natural exosomatic28 endowments can be substituted for. The Valeros call for a
paradigm shift whereby (a) since money is not an absolute and universal magnitude, as it is subject to
both inflation and monetary revaluation..., the unit of measure employed for [natural-]resource use
[would] be physically [rather than monetarily] based[,] and in this respect Thermodynamics must play
a prime role, (b) economists and the politicians whom they guide would realize that the substitution
of materials, unlike that of money or [sources of consumable] energy[,] is limited and case-specific, and
(c) long-term thinking would become embedded in economic theory.
16: The Principles of Resource Efficiency. This chapter is rich in engineer-type professional chat
and sets out 12 basic principles, together with an ample number of corollaries to them, which the
Valeros propose that businessmen as well as engineers adopt in striving toward sustainable resource
management. The text includes many references to other authors similar proposals. The references in
Chapter 2 to writings by other authors were part and parcel of an historical narrative (complemented by
criticisms and critical appreciations) and I therefore mentioned some of them; but here I will just give a
prcis of some of the ideas:
To take seriously the Second Law (i.e. that even though energy is, as the First Law tells us, never lost,
every expenditure of exergy entails some irreversible loss of exergy). Since the various processes for
obtaining purified materials from mixtures of materials cost gobs of exergy, two of the corollaries for

27. Tailings are ground-up waste from mineral processing operations. Slags are waste from metal smelting.
28. The term exosomatic means outside the body of the organism (in this case human). See p.@.

industrial engineers are do not mix, purify, clean, heat, cool, pressurise or depressurise more than
strictly necessary and segregate polluting flows; do not mix them.
To think about replacement costs and to reckon that the greater the cost of replacing a resource, i.e.
the greater its rarity (exergy-wise), the more it should be preserved.
To attend to the difference between efficacy (getting things done) and efficiency (getting them done
without wasting resources). One of the corollaries is that getting things done faster in industry means
more heat, more chemicals, more water, more effluents, more solid waste and special hardware requirements. Consider time as a resource that ultimately saves more resources.
To design products to last and to be easily repaired, and then extend their viability through upgrades
and careful maintenance. Two of the corollaries are to upgrade [factory] systems through replacing
obsolete components, instead of replacing the system in its entirety and to personalise possessions
as this may augment their endurance.
To repair things efficiently and to reuse them with due revisions when appropriate.
To exercise intelligent control for maintaining, in the economy, the required quality of purified minerals with as little expense of exergy as possible. Two of the corollaries are: know your process and
invest in appropriate equipment in order to know it all the better and predict the accident, dont just
react to it.
Since the storing and transmitting of electricity as well as of heat (i.e. of a temperature higher than
that of the surroundings], costs a lot of exergy, to instantaneously couple supply and demand of
consumable energy, and avoid unnecessary distances of transmission. One of the corollaries is:
Undertake intensive research in [better methods of] energy storage.
To be alert to the fact that since each physical system on Earth is part of a greater system, all the
systems are somehow connected. One of the corollaries is: The industry and urban system must be
[regarded as] part of the natural system. The [deliberate] connections must be multiple and ongoing,
not discrete, aggressive and/or ill-considered."
To be aware that the malfunctioning of a subsystem is likely to render the broader system inefficient
(but also that the proper functioning of a subsystem doesnt ensure proper functioning of the broader
system!). One of the corollaries is to design flexible and resilient systems.
To feel that all waste symbolises defeat in the design of some system in the economy and/or in its
connection with other systems. Here the Valeros mention that in the biological world, one organisms
waste is another ones feedstock. Two of the corollaries are: Embrace Biomimicry in product design
and Energy must come from renewable sources (as should the materials used to generate it).
For society at large, to evolve toward paying a larger share of money for goods and services that cost,
directly or indirectly, a lot of exergy, and hence toward paying relatively less for those that cost less
exergy. (The Valeros mention, as a notable example of imbalance between monetary and exergy costs,
the fact that in the entire process of creating a residence, the deed-signing entails the highest financial
expenditure per unit of energy effort.)
17: Epilogue. Some of the theoretical points restated in this chapter are that exergy can serve as
a universal measure for resource accounting, that the concept of decreasing degrees of thermodynamic rarity (reckoned in terms of exergy) can be used to indicate the hidden but eventually real
depletion-costs of producing industrially useful minerals, that cradle-to-grave technologies constitute
only half of the theoretical material cycle for each industrially useful chemical element, and that the
concept of thanatia provides a baseline for calculating the other half, i.e. for assessing depletion in

terms of grave-to-cradle exergy costs. It would be sane to use up the fossil fuels sparingly (as they cannot be recycled) and to recycle efficiently the other ingredients of the Earths natural endowment of
mineral resources, realizing that for them as well, an actual grave-to-cradle process would take too long
millions of years to be of use to Humankind.

There are five appendices (labeled A, B, etc.):

A: Discussion of which kinds of materials, and how much of each, are used up in green technologies (electric and hybrid vehicles; flourescent and LED lighting; newfangled information and
communication technologies).
B: Descriptions of seven main groups of minerals in our natural endowment (the silica minerals, the
feldspars, the pyroxenes, and the amphibole, olivine, mica and chlorite groups) and of the geochemistry
and various industrial uses 77 of commonly produced minerals (from Aluminium to Zirconium).
C: Detailed description and discussion of the parts of the U.N.'s internationally accepted System of
Environmental-Economic Accounting (SEEA) that are directly relevant to the subject of the book: i.e. the
asset accounts for mineral and energy resources.
D: Additional Data and Calculation Procedures. The topics of the data and/or calculation procedures are: standard redox potentials (i.e. how much voltage is needed to cause certain industrially
desirable chemical reactions with minerals to take place); how much exergy is needed (it is a lot) for
communition (i.e. to reduce chunks of various kinds of ore to small particles by cutting, grinding, vibrating etc.); the estimates published by (a) Rudnick and Gao in 2004 and (b) Grigorev (2007) of how much
of this and that chemical element is in the Earths upper crust; Australian fossil-fuel production; and
worldwide fuel production.
E: An account of a philosophical interview in November 1991 with Nicholas Georgescu-Roegen. His
reason for advocating conservation was that with conservation we gain time, and in gaining time
we make it more probable for a [new] Prometheus to arrive if it is to arrive; we dont know what is
to come next.
* * *

I can see two main problems in regard to the reception and usefulness of this book. (1) It is full of
data which will soon be outdated. An occasionally renewed online version should be published for a
decent subscription price. An ancillary advantage of this other way of publishing would be to allow for
refinements (as well as updatings) in the presentation. (2) Meanwhile, however, it is clear to me that
nearly all economics professors are, alas, too ignorant about science and technology to understand the
theory and reckoning which the book offers. Perhaps some of them would, even if they could understand the argument, belittle the Valeros projections somewhat as Robert Solow in the 1970s belittled
the projections prepared at MIT for the Club of Rome. Many of those dismissive professors would be
implicitly content with von Misess and Hayeks precept (let me cite here Milton Friedmans description
of it) to base economics on propositions that are self-evident ... because they are about human beings,
and were human beings. So we have an internal source of final knowledge....29 Their intellectual level
would match that of Solows famous declaration that The world has been exhausting its exhaustible
resources since the first cave-man chipped a flint, and I imagine the process will go on for a long, long
time.30 (So why worry?)
The ecological economists do worry, but even they, by and large, dont know enough about the
relevant aspects of chemistry, engineering and industrial production to understand a great deal of what
the book says. An abridged and simplified edition for them might be worthwhile. It might help their successors who will have studied scientific topics at graduate-school level (which 21st-century ecological
economists ought anyway, IMHO, to do) upgrade the level of discourse in the field and bring it well beyond rudimentary concepts like throughput, social metabolism31 and happy planet. It could also,
with luck, prompt attentive welfare economists to deconstruct the tragically misleading postulate of
sustainable human development endorsed by Amartya Sen and promoted by the United Nations in
the 1990s that The fact of substitutability (in both production and consumption) implies that what
we are [morally] obligated to leave behind [for children and future humans] is a generalized capacity to
create well-being, not any particular thing or any particular resource.32

29. Cited in Alan O. Ebenstein, Friedrich Hayek: A Biography (2001), p.273. Friedman went on to say, If youre
always going back to your internal, self-evident truths, how do people [i.e. economic theorists] stand on one anothers shoulders? And the fact is that fifty, sixty years after von Mises issued his capital theory which is whats
involved in Hayeks capital theory so-called Austrian economists still stick by it. There hasnt been an iota of
progress.... If you and I disagree about whether some proposition or statement is correct, how do we resolve that
disagree ment?... We [would] have [on the basis of allegedly self-evident truths] no way to resolve it except by
fighting, by saying youre wrong and Im right.
30. Robert Solow, The Economics of Resources or the Resources of Economics, The American Economic
Review, LXIV/2 (1974), p.1.
31. The term social metabolism came into use in the late 19th century as a translation of the German term Stoffwechsel. It is a misleading translation, since (a) only organisms have metabolisms and (b) societies are not really
organisms. A phrase conveying correctly the meaning of Stoffwechsel is transformative exchanges of matter.
32. Sudhir Anand and Amartya Sen, Sustainable Human Development: Concepts and Priorities (U.N. Human
Development Report Office, 1994; 2nd edition, 1996), p.11.

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