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Example :
Zn + 2Ag+ Zn2+ + 2Ag
Oxidation Half-equation : Zn Zn2+ + 2eReduction Half-equation : 2Ag+ + 2e- 2Ag
Oxidised substance : Zinc (Zn)
Reduced substance : Silver ion (Ag+)
Oxidising agent
: Silver ion (Ag+)
Reducing agent
: Zinc (Zn)
a)
Cl2 + 2I 2Cl + I2
Oxidation Half-equation:
Oxidised Substance:
Reduction Half-equation:
Reduced Substance:
Oxidising Agent:
Reducing Agent:
Oxidation Half-equation:
Oxidised
Substance:
Reduction Half-equation:
Reduced
Substance:
Oxidising Agent:
Reducing Agent:
c)
Pb + Br2 PbBr2
Oxidation Half-equation:
Oxidised
Substance:
Reduction Half-equation:
Reduced
Substance:
Oxidising Agent:
Reducing Agent:
d)
4Na + O2 2Na2O
Oxidation Half-equation:
Oxidised
Substance:
Reduction Half-equation:
Reduced
Substance:
Oxidising Agent:
Reducing Agent:
Procedure :
1.
2.
Add .................................. drop by drop into the test tube and heat the mixture.
3.
4.
Observation :
The colour of iron(II) sulphate solution change from ....................... to ................. The
bromine water change from ....................... to ........................ In order to detect
iron(III) ion in the solution, add ...................................................................................in
excess. .................................... precipitate of iron(III) hydroxide is formed.
5.
Concept :
a)
b)
Half equation
Fe2+ ............. + ............
Br2 + ............ .....................
c)
d)
e)
Procedure :
1. The test tube contains 2.0 cm3 of ............................................. solution.
2. Add ......................................... into the test tube and heat the mixture.
3. Record the .............................................................
4. Observation :
a. The colour of iron(III) chloride solution change from (i) .......................
to (ii) .................
b. In order to detect iron(II) ion in the solution, add (i)........................................
in excess. A (ii).................................... precipitate of iron(II) hydroxide is
formed.
5. Concept :
a. Iron(III) ion is (i)..................... to iron(II) ion by (ii)................................... At the
same time, zinc is (iii)......................... to (iv)............................... ion.
b. Half equations :
Fe3+ +
.................... ..............
Zn .................. + ..................
c. Iron(III) ions (i) .............. electrons to become iron(II) ions. Iron(III) ions
are (ii) .......................
d. Zinc atom (i).................. electrons to form (ii)................ ions. Zinc atoms
are (iii)........................
e. Reducing agent : (i) .................................
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Mn+
ne
2.
The element that is located higher in the electrochemical series can displace other
elements that are (i) .. in the electrochemical series from its salt
solution.
Example :
Zn
Zn
Cu2+
CuSO4
ZnSO4
Zn2+
2e
[ Oxidation ]
2e
Cu
[ Reduction ]
Cu
Activity 8
Displacement of halogens from their halide solutions by other halogens.
less
receive
halide
seventeen
decreases
oxidising agent
more
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2)
3)
4)
The
electronegativity
of
halogens
or
their
tendency
to
accept
electrons
6)
Activity 9
Transfer of electrons at a distance
1.
Carbon
Electrode
Bromine
Water
to
potassium
Xiodide
Solution
.
3. The colour of bromine water changes
from to
Dilute
Sulphuric acid
4. Oxidation half-equation :
.
Reduction half-equation :
.
5.
6. Oxidising
agent :
7. Reducing
agent :
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Carbon rod
Acidified Potassium
Manganate (VII)
solution, 1.0 mol dm-3
Potassium Iodide
Solution, 1.0 mol dm-3
Dilute Sulphuric acid,
1.0 mol dm-3
2.
The half equation for the reaction that occurs around the carbon rod on the left is as
follow.
MnO4- +
a)
8H + +
5e
Mn 2+
4H2O
b)
A brown vapour was observed around the carbon rod on the right. Name the
brown vapour formed.
..
c)
d)
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B.
Learning Outcomes :
You should be able to,
state the conditions for the rusting of iron
.state what corrosion of metal is.
Activity 10
1. Fill in the blanks with suitable terms
a) (i).. is the oxidation of a metal while (ii)
is the oxidation of iron when the metal or iron interact with the environment by losing
electron.
b) The presence of
g) Zinc is used to protect iron or steel by coating a thin layer of zinc onto it, this process
is called (i).. In industry, zinc is chosen to serve the
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2.
Activity 11
Answer the questions below.
1.
2.
Galvanising
involves
coating
an
iron
of..
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or
steel
sheet
with
thin
layer
Name three metals that can be used in sacrificial protection for an underground pipe.
4.
Name a reagent that is usually used to detect the presence of iron (II) ion in an
experiment to investigate the rusting of iron.
..
Activity 12
1
Diagram below shows the apparatus set-up for the experiment to study the effect
of metals P and Q on the rusting of iron nail. The results are recorded after one
day.
Experiment
A
(a)
After 1 day
Observation
Some
dark
precipitate.
blue
No dark blue
precipitate. Solution
turns pink.
Write the half-equation for the formation of iron(II) ion from iron.
..............................................................................................................................
(b)
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Which test tube shows the highest rate of rusting of iron? Explain your answer.
..............................................................................................................................
..............................................................................................................................
(d)
(e)
(i)
(ii)
(f)
State the ion that causes the solution in test tube C to turn pink.
..............................................................................................................................
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