Академический Документы
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Культура Документы
Version 1
0601
Not Regulated
Mixture of glycol ethers, Glycols, Polyglycols.
Brake Fluid
Not applicable
Restricted to professional users.
Consumer use
2. HAZARDS IDENTIFICATION
Classification
Acute toxicity - Oral
Serious eye damage/eye irritation
Category 4
Category 1
Label elements
Emergency Overview
Danger
Hazard statements
Harmful if swallowed
Causes serious eye damage/eye irritation
Odor Mild
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Page 1 of 10
3. COMPOSITION/INFORMATION ON INGREDIENTS
Mixture of glycol ethers, Glycols, Polyglycols.
Synonyms
Components
Triethylene Glycol Monomethyl Borate
Ester
Triethylene Glycol Monoethyl Ether
Diethylene Glycol Monoethyl Ether
Diethylene Glycol Monobutyl Ether
Triethylene Glycol Monomethyl Ether
Borate Ester
Triethylene Glycol Monomethyl Ether
Polyethylene Glycol Monomethyl Ether
Triethylene Glycol
Tetraethylene Glycol
Diethylene Glycol
Triethylene Glycol Monobutyl Ether
Tetraethylene Glycol Monobutyl Ether
CAS Number
68441-44-1
Weight %
0-50
Trade Secret
*
112-50-5
111-90-0
112-34-5
71243-41-9
0-50
0-50
0-50
0-40
*
*
*
*
112-35-6
9004-74-4
112-27-6
112-60-7
111-46-6
143-22-6
1559-34-8
0-31
0-28
0-25
0-25
5-10
0-4
0-1.5
*
*
*
*
*
*
*
* The exact percentage (concentration) of composition has been withheld as a trade secret.
Take proper precautions to ensure your own health and safety before attempting rescue
and providing first aid. In case of accident or unwellness, seek medical advice immediately
(show directions for use or safety data sheet if possible).
Skin contact:
Remove contaminated clothing. Wash exposed skin with soap and water. If irritation occurs,
seek medical attention. Launder contaminated clothing before reuse. (Discard
contaminated shoes).
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If affected remove individual to fresh air. If breathing is difficult, give oxygen. If not
breathing, give artificial respiration. Call a physician immediately.
Eye contact:
Rinse cautiously with water for several minutes. Remove contact lenses if present and easy
to do. Continue rinsing for 15 minutes. Seek immediate medical attention/advice.
Ingestion:
If swallowed, rinse mouth with water (only if the person is conscious). Call a physician or
Poison Control Center immediately.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media:
Use dry chemical, CO2, water spray (fog) or alcohol resistant foam.
Small Fire
Large Fire
Explosive properties:
Explosive when mixed with oxidizing substances. Containers may rupture if exposed to
extreme heat.
Contaminated surfaces will be extremely slippery. Do not walk through spilled material. Use
spark-proof tools and explosion-proof equipment. Do not touch damaged containers or
spilled material unless wearing appropriate protective clothing. Avoid contact with skin and
eyes. Use personal protective equipment. For personal protective equipment see Section 8.
Use personal protection recommended in Section 8. Ventilate the area. Remove all sources
of ignition.
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Environmental precautions:
Prevent further leakage or spillage if safe to do so. Prevent from spreading or entering
drains, ditches, or rivers by using sand, earth, or other appropriate barriers.
Extremely slippery when spilled. Avoid accidents, clean up immediately. Reclaim liquid
directly or in an absorbent. Soak up residue with absorbent such as clay, and or other
suitable material and place in chemical waste container for proper disposal.
Handling:
Use local exhaust ventilation if there is a risk of inhalation of vapors, mists or aerosols. Eye
wash should be easily accessible.
Materials to avoid:
Oxidising agents: Acids, Strong bases, Light and/or alkaline metals; Zinc.
.
ACGIH TLV
-
NIOSH IDLH
-
Not established
Not established
Not established
Not established
Not established
Not established
Not established
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Other information
Not established
Not established
Not established
Not established
Use local exhaust ventilation if there is a risk of inhalation of vapors, mists or aerosols. Eye
wash and safety shower should be easily accessible.
Wear safety glasses with side shields (or goggles). If splashes are likely to occur, wear:
Face protection shield.
Wear normal work clothing including long pants, long-sleeved shirts and foot covering to
prevent direct contact of the product with the skin. Launder clothing before reuse. If skin
irritation develops, contact your facility health and safety professional or your local safety
equipment supplier to determine the proper personal protective equipment for your use.
Wear chemical resistant gloves (consult your safety equipment supplier). PVC, neoprene,
or nitrile rubber gloves are recommended.
Respiratory protection
Handle in accordance with good industrial hygiene and safety practice. When using do not
eat, drink or smoke. Wear suitable gloves and eye/face protection. Avoid contact with eyes,
skin and clothing. Avoid breathing vapors or mists. Wash face, hands and any exposed skin
thoroughly after handling. Take off all contaminated clothing and wash it before reuse.
Liquid
Glycol Ether based solution
Light yellow to Yellow
Property
pH
Melting point/freezing point
Boiling point/boiling range
Flash point
Evaporation rate
Flammability (solid, gas)
Flammability Limits in Air
Upper flammability limits
Values
8.0-8.6
<= -47.22 C / -53.00 F
> 230 C / 446 F
> 95 C / 203 F
Remar
ks:Met
hod
(25%) Aqueous Solution
No information is available
Odor
Odor threshold
Mild
No information is
available
@760 mm Hg
Pensky-Martens Closed Cup (PMCC)
No data available
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No data available
> 0.013 kPa
Heavier than air
1.05 -1.06
Soluble in water
No data available
No data available
>300 C / 572 F
No data available
No information is available
No data available
No data available
No data available
Other information
No data available
No data available
No data available
1.05 - 1.06 g/cc
No data available
Softening point
Molecular weight
VOC Content (%)
Density
Bulk density
Hygroscopic.
Chemical stability
Possibility of Hazardous Reactions
May form peroxides of unknown stability.
Hazardous polymerization
Conditions to avoid
Heat, flames and sparks.
Incompatible materials
Oxidising agents: Acids, Strong bases, Light and/or alkaline metals; Zinc.
Materials to avoid:
Hazardous Decomposition Products
May be harmful if swallowed. Causes serious eye damage/eye irritation. May be absorbed
through skin in toxic amounts.
Inhalation
Eye contact
Causes serious eye damage/eye irritation. Not expected to cause permanent damage. May
cause pain, redness, stinging and tearing.
Skin Contact
Repeated or prolonged contact may cause slight skin irritation. May be absorbed through
skin in toxic amounts.
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Ingestion
Components
Triethylene Glycol Monomethyl Borate Ester
68441-44-1
Triethylene Glycol Monoethyl Ether
112-50-5
Diethylene Glycol Monoethyl Ether
111-90-0
Diethylene Glycol Monobutyl Ether
112-34-5
Triethylene Glycol Monomethyl Ether Borate Ester
71243-41-9
Triethylene Glycol Monomethyl Ether
112-35-6
Polyethylene Glycol Monomethyl Ether
9004-74-4
Triethylene Glycol
112-27-6
Tetraethylene Glycol
112-60-7
Diethylene Glycol
111-46-6
Triethylene Glycol Monobutyl Ether
143-22-6
Tetraethylene Glycol Monobutyl Ether
1559-34-8
Oral LD50
-
Dermal LD50
-
Inhalation LC50
-
Aspiration hazard
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Fish
Crustacea
Algae/aquatic plants
Fish
Crustacea
Algae/aquatic plants
Fish
Crustacea
Fish
Crustacea
Algae/aquatic plants
Fish
Crustacea
Fish
Crustacea
Algae/aquatic plants
Fish
Crustacea
Algae/aquatic plants
Fish
Crustacea
_____________________________________________________________________________________________
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Partition coefficient
1
-1.12
0.51
Contaminated packaging
Do not reuse container. Dispose of in accordance with federal, state and local regulations.
Not regulated
IATA
Not regulated
IMDG
Not regulated
Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA) - This product contains a chemical
or chemicals which is/are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part
372:
Components
Triethylene Glycol Monoethyl Ether
Diethylene Glycol Monoethyl Ether
Diethylene Glycol Monobutyl Ether
CAS Number
Weight %
112-50-5
111-90-0
112-34-5
0-50
0-50
0-50
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112-35-6
143-22-6
0-31
0-4
Yes
Yes
Yes
No
No
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Page 10 of 10