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SAFETY DATA SHEET

Section 1. Identification
Product identifier

: BAYFERROX 110 M

Material Number

: 00006122

Chemical family

: Inorganic Metal oxide.

Identified uses

: Inorganic pigment
: LANXESS Corporation
Product Safety & Regulatory Affairs
111 RIDC Park West Drive
Pittsburgh, PA 15275-1112
USA

Supplier/Manufacturer

In case of emergency

For information: US/Canada (800) LANXESS


International +1 412 809 1000
: Chemtrec (800) 424-9300
International (703) 527-3887
Lanxess Emergency Phone (800) 410-3063.

Section 2. Hazards identification


HAZCOM Standard Status
Physical state

: This material is considered hazardous by the OSHA Hazard Communication Standard


(29 CFR 1910.1200).
: Powder.

Color

: Red.

Classification of the
substance or mixture

: SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (lungs) (inhalation) Category 2

Hazard pictograms

Signal word
Hazard statements
Hazard Not Otherwise
Classified (HNOC)
Precautionary statements

: Warning
: May cause damage to organs through prolonged or repeated exposure if inhaled. (lungs)
: None known.

Prevention

: Do not breathe dust or mist.

Response

: Get medical attention if you feel unwell.

Storage

: Not applicable.

Disposal

: Dispose of contents and container in accordance with all local, regional, national and
international regulations.
: Store in original container protected from direct sunlight in a dry, cool and well-ventilated
area, away from incompatible materials and food and drink.

Supplemental label
elements

BAYFERROX 110 M

00006122

Version

1/10

Section 3. Composition/information on ingredients


Substance/mixture

: Mixture

Ingredient name

CAS number

Barium Sulfate
Titanium dioxide (Rutile)

<2%
<2%

7727-43-7
13463-67-7

Any concentration shown as a range is to protect confidentiality or is due to batch variation.


There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures


Description of first aid measures
Eye contact

Inhalation

Skin contact

Ingestion

: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Get medical attention if irritation
occurs.
: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get
medical attention following exposure or if feeling unwell. If unconscious, place in
recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband. If not breathing, if breathing
is irregulor or respiratory arrest occurs, provide artifical respiration, or oxygen by a
trained professional, using a pocket type respirator.
: Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes.
Continue to rinse for at least 10 minutes. Get medical attention following exposure or if
feeling unwell. Wash clothing before reuse. Clean shoes thoroughly before reuse.
: Wash out mouth with water. Remove victim to fresh air and keep at rest in a position
comfortable for breathing. If material has been swallowed and the exposed person is
conscious, give small quantities of water to drink. Do not induce vomiting unless
directed to do so by medical personnel. If vomiting occurs, the head should be kept low
so that vomit does not enter the lungs. Get medical attention following exposure or if
feeling unwell. Never give anything by mouth to an unconscious person. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Potential acute health effects


Eye contact

: May cause mechanical irritation (abrasion).

Inhalation

: No known significant effects or critical hazards.

Skin contact

: May cause mechanical irritation (abrasion).

Ingestion

: No known significant effects or critical hazards.

Over-exposure signs/symptoms
Eye contact

: No specific data.

Inhalation

: No specific data.

Skin contact

: No specific data.

Ingestion
: No specific data.
Potential chronic health effects
May cause damage to organs through prolonged or repeated exposure if inhaled. Long-term exposure to high
concentrations of dust containing iron oxide can cause a benign condition termed pulmonary siderosis. This condition is
not associated with any physical impairment of lung function. Repeated or prolonged inhalation of dust may lead to
chronic respiratory irritation.
Notes to physician
Protection of first-aiders
BAYFERROX 110 M

: Treat symptomatically. No specific treatment.


: No special measures required.
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Section 4. First aid measures


See toxicological information (Section 11)

Section 5. Fire-fighting measures


Extinguishing media
Suitable extinguishing
media

: Use an extinguishing agent suitable for the surrounding fire. In case of fire, use water
spray (fog), foam or dry chemical.

Unsuitable extinguishing
media

: None known.

Specific hazards arising


from the chemical

: No specific fire or explosion hazard.

Hazardous thermal
decomposition products

: No specific data.

Special protective actions


for fire-fighters

: Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
: Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective
equipment for fire-fighters

Section 6. Accidental release measures


Personal precautions,
protective equipment and
emergency procedures
Environmental precautions

: No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing dust. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on
appropriate personal protective equipment.
: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Methods and materials for


: Move containers from spill area. Approach release from upwind. Avoid dust generation.
Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a
containment and cleaning up
closed, labeled waste container. Avoid creating dusty conditions and prevent wind
dispersal. Dispose of via a licensed waste disposal contractor. Note: see Section 1 for
emergency contact information and Section 13 for waste disposal. Prevent entry into
sewers, water courses, basements or confined areas.

Section 7. Handling and storage


Precautions for safe handling
Protective measures
: Do not breathe dust. Do not ingest. Avoid contact with eyes, skin and clothing. Use only
with adequate ventilation. Keep in the original container or an approved alternative
made from a compatible material, kept tightly closed when not in use. Empty containers
retain product residue and can be hazardous. Do not reuse container. Remove
contaminated clothing and protective equipment before entering eating areas. Workers
should wash hands and face before eating, drinking and smoking. Put on appropriate
personal protection equipment. Eating, drinking and smoking should be prohibited in
areas where this material is handled, stored and processed.
Conditions for safe storage : Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10) and food and drink. Keep container tightly closed and sealed until
ready for use. Containers that have been opened must be carefully resealed and kept
upright to prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination. Empty containers retain product
residue and can be hazardous. Do not reuse container.

BAYFERROX 110 M

00006122

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3/10

Section 8. Exposure controls/personal protection


Occupational exposure limits
Ingredient name

Exposure limits

Barium Sulfate

ACGIH TLV (United States, 4/2014).


TWA: 5 mg/m 8 hours. Form: Inhalable
fraction
OSHA PEL (United States, 2/2013).
TWA: 5 mg/m 8 hours. Form: Respirable
fraction
TWA: 15 mg/m 8 hours. Form: Total dust
ACGIH TLV (United States, 4/2014).
TWA: 10 mg/m 8 hours.
OSHA PEL (United States, 2/2013).
TWA: 15 mg/m 8 hours. Form: Total dust

Titanium dioxide (Rutile)

If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be
required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use
respiratory protective equipment.
Appropriate engineering
controls

: Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor
or mist, use process enclosures, local exhaust ventilation or other engineering controls
to keep worker exposure to airborne contaminants below any recommended or statutory
limits.

Personal protection
Hygiene measures

Respiratory protection

Skin protection
Eye/face protection
Medical Surveillance

: Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period. Appropriate
techniques should be used to remove potentially contaminated clothing. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety showers
are close to the workstation location.
: The following respirator is recommended if airborne concentrations exceed the
appropriate standard/guideline. NIOSH approved, air-purifying particulate respirator with
N-95 filters.
: Gloves
: safety glasses with side-shields
: Not available.

Section 9. Physical and chemical properties


Physical state

: Solid. [Powder.]

Color

: Red.

Odor
Odor threshold

: Odorless.
: Not available.

pH
Boiling point
Melting point
Flash point

:
:
:
:

4 to 8 [Conc. (% w/w): 5%]


Not available.
>1000C (>1832F)
Not available.

Evaporation rate
Explosion limits
Vapor pressure
Density
Specific gravity (Relative
density)

:
:
:
:
:

Not available.
Not available.
Not available.
5 g/cm
4 to 5

Bulk density
Solubility

: 300 to 1000 kg/m


: Insoluble in the following materials: cold water

BAYFERROX 110 M

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Section 9. Physical and chemical properties


Partition coefficient: noctanol/water
Vapor density
Viscosity

: Not available.

Auto-ignition temperature

: Not available.

Decomposition temperature

: Not available.

: Not available.
: Not available.

Section 10. Stability and reactivity


Reactivity
Chemical stability
Possibility of hazardous
reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition
products

: No specific test data related to reactivity available for this product or its ingredients.
: The product is stable.
: Under normal conditions of storage and use, hazardous reactions will not occur.
: No specific data.
: No specific data.
: Under normal conditions of storage and use, hazardous decomposition products should
not be produced.

Section 11. Toxicological information


Information on the likely
routes of exposure

: Dermal contact. Eye contact. Inhalation. Ingestion.

Potential acute health effects


Eye contact
: May cause mechanical irritation (abrasion).
Inhalation

: No known significant effects or critical hazards.

Skin contact

: May cause mechanical irritation (abrasion).

Ingestion
: No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Eye contact
: No specific data.
Inhalation

: No specific data.

Skin contact

: No specific data.

Ingestion

: No specific data.

Potential chronic health effects


Short term exposure
Potential immediate
: Not available.
effects
Long term exposure
Potential delayed effects
General

: Not available.

Carcinogenicity

: May cause damage to organs through prolonged or repeated exposure if inhaled. Longterm exposure to high concentrations of dust containing iron oxide can cause a benign
condition termed pulmonary siderosis. This condition is not associated with any
physical impairment of lung function. Repeated or prolonged inhalation of dust may
lead to chronic respiratory irritation.
: No known significant effects or critical hazards.

Mutagenicity

: No known significant effects or critical hazards.

Teratogenicity

: No known significant effects or critical hazards.

Developmental effects

: No known significant effects or critical hazards.

Fertility effects

: No known significant effects or critical hazards.

Information on toxicological effects


Acute toxicity

BAYFERROX 110 M

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Section 11. Toxicological information


Product/ingredient name

Result

Species

Dose

Exposure

Test

COLORTHERM RED 110M

LD50 Oral

Rat

>5000 mg/kg

Titanium dioxide (Rutile)

LC50
Inhalation
Dusts and
mists

Rat

>6.82 g/m

4 hours

Score

Exposure

ObservationReversibility

72 hours

72 hours

72 hours

72 hours

Fully
reversible
Fully
reversible
Fully
reversible
Fully
reversible

Irritation/Corrosion
Product/ingredient
name
Barium Sulfate

Titanium dioxide (Rutile)

Conclusion/Summary
Skin
Eyes

Result

Species

Eyes - Cornea opacity

Rabbit

Eyes - Iris lesion

Rabbit

Eyes - Redness of the


conjunctivae
Eyes - Edema of the
conjunctivae
Skin - Erythema/Eschar

Rabbit

Rabbit

Rabbit

0.28

1 hours
100mg
1 hours
100mg
1 hours
100mg
1 hours
100mg
-

Skin - Edema

Rabbit

Eyes - Edema of the


conjunctivae
Eyes - Redness of the
conjunctivae

Rabbit

Rabbit

0.1

: Non-irritating *Test results on an analogous product


: Non-irritating *Test results on an analogous product

Sensitization
Product/ingredient name

Route of
exposure

Species

Result

Barium Sulfate
Titanium dioxide (Rutile)

skin
skin
skin

Mouse
Guinea pig
Mouse

Not sensitizing
Not sensitizing
Not sensitizing

Chronic toxicity
Product/ingredient name

Result

Species

Dose

Exposure

Barium Sulfate

Chronic NOAEL Inhalation


Dusts and mists
Sub-chronic NOEL Oral

Rat

<40 mg/m

60 days; daily

Rat - Male

24000 mg/kg

Chronic NOEL Inhalation


Dusts and mists

Rat - Male,
Female

10 mg/m

29 days; 7 days
per week
2 years; 6 hours
per day

Titanium dioxide (Rutile)

Mutagenicity
Product/ingredient name

Test

Experiment

Result

Barium Sulfate

OECD 471 Bacterial


Reverse Mutation Test

Experiment: In vitro

Negative

Subject: Bacteria
Metabolic activation: with/without S9
mix
Experiment: In vitro

Negative

OECD 473 In vitro


Mammalian
Chromosomal
Aberration Test
BAYFERROX 110 M

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Section 11. Toxicological information

OECD 476 In vitro


Mammalian Cell Gene
Mutation Test

Titanium dioxide (Rutile)

OECD 471 Bacterial


Reverse Mutation Test
OECD 473 In vitro
Mammalian
Chromosomal
Aberration Test
OECD 476 In vitro
Mammalian Cell Gene
Mutation Test
OECD 474 Mammalian
Erythrocyte
Micronucleus Test
OECD 487 In vitro
Micronucleus Test

Subject: Mammalian-Animal
Cell: Somatic
Metabolic activation: with/without S9
mix
Experiment: In vitro

Negative

Subject: Mammalian-Animal
Cell: Somatic
Metabolic activation: with/without S9
mix
Experiment: In vitro

Negative

Subject: Bacteria
Metabolic activation: +/Experiment: In vitro

Negative

Subject: Mammalian-Animal
Cell: Germ
Experiment: In vitro

Negative

Subject: Mammalian-Animal
Cell: Somatic
Experiment: In vitro

Negative

Subject: Mammalian-Animal
Cell: Germ
Experiment: In vitro

Negative

Subject: Mammalian-Human
Cell: Somatic
Conclusion/Summary
Carcinogenicity
Conclusion/Summary

Product/ingredient name
Barium Sulfate
Titanium dioxide (Rutile)

: Titanium dioxide (Rutile):Not mutagenic in a standard battery of genetic toxicological


tests.
: In a lifetime inhalation study rats were exposed for 2 years to respirable TiO2.
Microscopic lung tumors were observed in some rats which caused overloading and
impairment of rat lung clearance mechanisms. Mice and hamsters did not develop lung
tumors under similar testing conditions.
Detailed epidemiology studies have also shown no causative link between titanium
dioxide exposure and cancer risk in human and no lung cancer hazard workplace
exposure concentration. In February 2006 IARC concluded, There is inadequate
evidence in humans for the carcinogenicity of titanium dioxide.
CAS #
IARC
NTP
OSHA
7727-43-7
13463-67-7

Not classified.
2B Possibly
carcinogenic to
humans

Not classified.
Not classified.

Not classified.
Not classified.

Name

Category

Route of
exposure

Target organs

Titanium dioxide (Rutile)

Category 3

Not applicable.

Respiratory tract
irritation

Specific target organ toxicity (single exposure)

BAYFERROX 110 M

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Section 11. Toxicological information


Specific target organ toxicity (repeated exposure)
Name

Category

Route of
exposure

Target organs

Barium Sulfate

Category 2

Inhalation

lungs

Acute toxicity estimates


Route

ATE value (Acute Toxicity Estimates)

Not available.

Section 12. Ecological information


Toxicity
Product/ingredient name
COLORTHERM RED 110M

Test

Result

Acute EC50 >10000 mg/l

Acute LC50 >1000 mg/l

Conclusion/Summary

Species

Exposure

Daphnia - Daphnia
magna
Fish - Leuciscus
idus

48 hours
48 hours

: Not available.

Persistence and degradability


Conclusion/Summary

: Not available.

Product/ingredient name

Aquatic half-life

Photolysis

Biodegradability

Barium Sulfate

Readily

Bioaccumulative potential
Product/ingredient name

LogPow

Titanium dioxide (Rutile)

BCF

Potential

<400

low

Mobility in soil
Soil/water partition
coefficient (KOC)
Other adverse effects

: Not available.
: No known significant effects or critical hazards.

Section 13. Disposal considerations


Disposal methods

: The generation of waste should be avoided or minimized wherever possible. This


material and its container must be disposed of in a safe way. Care should be taken
when handling emptied containers that have not been cleaned or rinsed out. Empty
containers or liners may retain some product residues. Avoid dispersal of spilled
material and runoff and contact with soil, waterways, drains and sewers. Waste disposal
should be in accordance with existing federal state, provincial and or local
environmental controls laws.

RCRA classification

: If discarded in its purchased form, this product would not be a hazardous waste either
by listing or by characteristic. However, under RCRA, it is the responsibility of the
product user to determine at the time of disposal, whether a material containing the
product or derived from the product should be classified as a hazardous waste. (40
CFR 261.20-24)

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Section 14. Transport information


Regulatory
information

UN number

Proper shipping
name

Classes

PG* Label

Additional
information

DOT Classification

Not regulated.

IMDG Class

Not regulated.

IATA-DGR Class

Not regulated.

PG* : Packing group


RQ

: 0 lbs

Section 15. Regulatory information


SARA 311/312

: Delayed (chronic) health hazard

SARA Title III Section 302


Extremely Hazardous
Substances

: None

SARA Title III Section 313


Toxic Chemicals

: None

US EPA CERCLA
: None
Hazardous Subtances (40
CFR 302)
State regulations
The following chemicals are specifically listed by individual states; other product specific health and safety data in other
sections on the SDS may also be applicable for state requirements. For details on your regulatory requirements you
should contact the appropraite agency in your state.
Ingredient name
CAS number
State Code
Concentration
(%)
Iron (III) Oxide
1309-37-1
MA - S, NJ - HS, PA - RTK HS
91 - 97%
Barium Sulfate
7727-43-7
MA - S, NJ - HS, PA - RTK HS
<2%
Titanium dioxide (Rutile)
13463-67-7
MA - S, NJ - HS, PA - RTK HS
<2%
Massachusetts Substances: MA - S
Massachusetts Extraordinary Hazardous Substances: MA - Extra HS
New Jersey Hazardous Substances: NJ - HS
Pennsylvania RTK Hazardous Substances: PA - RTK HS
Pennsylvania Special Hazardous Substances: PA - Special HS
California Prop. 65
WARNING: This product contains a chemical known to the State of California to cause cancer.
Potential exposure to some or all of the California Proposition 65 chemicals in this product have been determined to be
below the No Significant Risk Level (NSRL)
Ingredient name
Titanium dioxide (Rutile)
U.S. Toxic Substances
Control Act

BAYFERROX 110 M

CAS #
Concentration (%)
13463-67-7
<2%
: Listed on the TSCA Inventory.

00006122

Cancer
Yes

Version

Reproductive

9/10

Section 16. Other information


Hazardous Material
Information System

Health

Flammability

Physical hazards

0=Insignificant 1=Slight 2=Moderate 3=High 4=Extreme


*=Chronic
The customer is responsible for determining the PPE code for this material. HMIS ratings are to be used with a
fully implemented HMIS program. HMIS is a registered mark of the National Paint & Coatings Association
(NPCA). HMIS materials may be purchased exclusively from J. J. Keller (800) 327-6868.
No
National Fire Protection
:
Association (U.S.A.)
Flammability

0
Health

Instability/Reactivity
Special

0= Minimal 1=Slight 2=Moderate 3=Serious 4=Severe


LANXESS' method of hazard communication is comprised of Product Labels and Safety Data Sheets. HMIS and
NFPA ratings are provided by LANXESS as a customer service.
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not
the complete and official position of the National Fire Protection Association, on the referenced subject which is
represented only by the standard in its entirety.
No
Date of issue
Date of previous issue
Version

: 12-19-2014
: 12-19-2014

: 2
Product Safety and Regulatory Affairs
Indicates information that has changed from previously issued version.
No
Notice to reader
This information is furnished without warranty, express or implied. This information is believed to be accurate to
the best knowledge of LANXESS Corporation. The information in this SDS relates only to the specific material
designated herein. LANXESS Corporation assumes no legal responsibility for use of or reliance upon the
information in this SDS.