PERC G3 (GEAS: CHEM/THERMO)

1. Which of the following cannot

separate a homogeneous mixture?
Filtration
2. The amount of energy needed to
change a given mass of ice to water
at constant temperature is called
heat of FUSION.
3. Which of the following is a binary
compound? Hydrochloric acid
4. What is the charge of a Hydrogen
atom? ZERO
5. If the volume of 1 mole of gas is
constant, lowering the temperature
will make the pressure increase.
6. When 200 mL of a gas at constant
pressure is heated from 0 degree
Celsius to 100 degree Celsius, the
volume must be multiplied by
373/273.
7. How many moles of O2 are present in
44.8 L of O2 at STP? 2
8. At 5 atm and 70 degree Celsius, how
many moles are present in 1.5 L of
O2 gas? 0.267
9. If 40 g of ice melts at 0 degree
Celsius, total heat absorbed is ____.
10.The properties of a solution include
all of the following except: dissolved
particles will settle out upon
stirring.
11.The transfer of energy from the more
energetic to the adjacent less
energetic as a result of interaction
between
particles
is
called
conduction.
12.The molarity of a solution made by
placing 98 gram of H2SO4 in
sufficient water to make 500 mL of
solution is 2.
13.It indicates the rate of heat
conduction
in
the
direction
proportional to the temperature
gradient in that direction. Fouriers
law of heat conduction.

14.If the change in enthalphy of a

reaction is negative, the reaction is
definitely endothermic.
15.The pH concentration of solution with
hydrogen concentration of 1x10^-6
mole/liter is 6.
16.The pH concentration of a solution
that
has
a
hydrogen
ion
concentration of 1x10^-6 mole/Liter
is 8.
17.What is the best conductor of heat?
Diamond
18.The volume of a definite quantity of
dry gas is inversely proportional to
the
pressure
provided
the
temperature
remains
constant.
Boyles law
19.Point at which titration is complete.
Endpoint
20.It is the enthalpy change associated
with the condensation of gaseous
positive and negative ion into a
crystal. Lattice energy
21.Hunds rule indicates that electrons
occupy all orbitals of given subshell
singly before pairing.
22.What are the particles that include
proton and neutron? Baryons
23.What is the quantum number which
defines the direction of electrons
angular
momentum
vector?
Magnetic quantum number
24.What is the process in which
hydrogen is changed to helium inside
the sun and makes the sun shinier?
Fusion
25.What thermodynamic cycle describes
functions of typical reciprocating
piston engines? Otto cycle
26.It is the mode of energy transfer
between a solid surface and the
adjacent liquid or gas that is in
motion, and it involves the combined
effect of conduction and fluid motion.
Convection

27.What is the resulting compound

when oxygen combines with an
element? oxide
28.According to the Bronsted-Lowry
theory, an acid is proton donor.
29.The second law of thermodynamics
states that no engine can have a
thermal efficiency of 100 % or as far
as power plant to operate, the
working fluid must exchange heat
with the environment. Kelvin-planck
statement
30.It is defined as the amount of light
output in lumens per watt of
electricity. Light efficacy
31.Lead in pencil is made up of
graphite and clay.
32.It states that the thermal efficiencies
of all reversible heat engines
operating between two reservoirs are
the same and that no heat engine is
more efficient than a reversible one
operating between the same two
reservoirs. Carnot principle.
33.The process where heat is absorbed
from the surroundings is called
endothermic process.
34.It states that the change in the
enthalpy of a reaction is the sum of
the enthalpies of reactions from
which the reaction can be built.
Hess law
35.Constant of proportionality between
energy of photon and frequency is
called plancks constant.
36.States that every substance has
finite position entropy except the
entropy of pure, perfect crystalline
structure which is zero at 0 K. Third
law of thermodynamics.
37.Number of intensive variables that
can be changed independently in
system
without
disturbing
the
number of phases in equilibrium.
Degree of freedom
38.It states that the vapor pressure in a
solution is the sum of the vapor

pressure at the pure component

multiplied by the mole fraction of
that component. Raoults law
39.Temperature at which water density
is maximum. 4 degree celsius
40.Isothermal
process
is
a
thermodynamic
process
with
constant temperature. It is known as
a hyperbolic process.
41.Thermodynamic measurement of
strength
of
bonding
between
molecules. affinity
42.A substance that increases the rate
of reaction without itself being
consumed. Catalyst
43.A carnot engine receives 500 kJ per
cycle from a high temperature source
at 600 degree Celsius and rejects
heat at temperature sink at 40
degree Celsius. Determine thermal
efficiency. 64.15%
44.What is added to a weak monoprotic
acid to produce a buffer solution? Its
conjugate base
45.In an engine, work is defined as the
difference between heat input and
heat discharge.
46.It is the customary to indicate
accuracy by using a certain number
of figure or digits. Significant
figures
47.It states that if a stress is placed on a
system on equilibrium whereby the
equilibrium is altered, the change will
take palce which tends to relieve or
neutralize the effect of applied stress.
Le Chateliers principle
48.Considered
as
derivatives
of
ammonia in which one or more of the
hydrogen have been replaced by the
alkyl or aryl group. It is characterized
by unpleasant odor. Amine
49.a piston cylinder device contains a
liquid-vapor mixture of water at 400
K. during constant pressure process,
700 kJ of heat is transferred to the
water. As a result, part of the liquid in

the cylinder vaporizes. Determine the

entropy change of the water during
this process. 1.75 kJ/K
50.Which of the following equation has
two constants?
a. Van der waals equation (2)
b. Strobridge equation (16)
c. Benedict-webb-rubin equation
(8)
51.Calculate the molar concentration of
a solution that contains 15 grams of
potassium hydroxide in 225 mL of
solution
(K=39amu,
O=16amu,
H=1amu). 1.2 M
52.A piston cylinder device initially has
0.8 cubic meter of air at 110 kPa and
at 80 degree Celsius. The air is now
compressed to 0.2 cubic meter in
such a way that the temperature
inside the cylinder remains constant.
Determine the work done during the
process. -122 kJ
Solution:

W =P V i ln

Vf
Vi

53.It states that if two bodies are in

thermal equilibrium with a third body,
they are also in thermal equilibrium
with each other. Zeroth law of
thermodynamics
54.It is the borosilicate glass with a very
low coefficient of thermal expansion;
hence it is widely used as cooking
and serving utensils. Pyrex
55.It is a colorless solid capable of being
cut into brilliant crystals. It is the
hardest and most abrasive mineral
known. Diamond
56.It is the set of nuclide having equal
mass number but of different atomic
numbers. Isobars
57.It is the first antimatter particle
discovered, and it has the same mass
as the positive particles but with
opposite charge. It can survive by
moving rapidly but once at rest,

these are quickly annihilated and

converted totally and directly to
energy. Positron
58.It is the calculation of both energy
balances and material balances in a
chemical system. Stoichiometry
59.It involves the replacement of one of
the atoms or groups of atoms
attached to the carbon backbone of
the organic material.
60.Heat is transferred to a heat engine
from a furnace at a rate of 92 MW. If
the rate of waste heat rejection to a
nearby river is 45 MW, determine the
efficiency for the heat engine.
51.08%
61.Calculate the volume in liters
occupied by 7.40 gram of ammonia
at STP (use N=14amu, H=1amu).
9.75 liters
62.Ten grams of sodium hydroxide is
dissolved in enough water to make 1
L of solution. What is the molarity of
the solution? 0.25 M
63.The
food
compartment
of
a
refrigerator is maintained at 4 degree
Celsius by removing heat from it at a
rate of 300 kJ/min. if the required
power input to the refrigerator is 3
kW, determine the coefficient of
performance. 1.67
64.What is true about the polytropic
exponent n for a perfect gas
undergoing an isobaric process. n=0
65.Sulfur hexafluoride is a colorless,
odorless and very unreactive gas.
Calculate the pressure in atm exerted
by 1.82 moles of gas in a steel vessel
of volume 5.43 L at 45 degree
Celsius.
66.The ratio in absolute units of the
actual gas temperature to the critical
temperature
of
gas.
Specific
gravity
67.Ratio in absolute units of the actual
gas temperature to the critical

temperature
of
gas.
Reduced
temperature
68.A bottle of ceramic tile cleanser
which essentially a solution of
hydrochloric acid contains 130g of
HCl and 750g of water. What is the
percent mass of hydrochloric acid in
cleanser? 14.88%
69.An enthalpy entropy chart is?
Mollier diagram
70.Covalent bond between 2 atoms with
different electronegativities so that
the
electron
density
is
asymmetrically distributed. Polar
71.Rigid tank contains hot fluid that is
cooled while being stirred by a
paddle wheel. Initially the internal
energy of the fluid is 850kJ. During
the cooling process, the fluid losses
550kJ of heat and the paddle wheel
does 200kJ of work on the fluid.
Neglect energy in the paddle wheel.
500 kJ
72.Lowest approximate temperature at
which water can be liquid? -18
degree celsius
73.Energy which a substance possesses
because of motion and configuration
of
its
atoms,
molecules
and
subatomic
particles.
Internal
energy
74.Percent change in volume as liquid
water freezes? 9.1 % increase
75.Three moles of an ideal gas are
compressed slowly and isothermally
from a volume of 5 to 1.5 ft^3 at a
temperature of 320K. How much
work is done? -9.61 kJ
76.How much heat is needed to raise
the temperature of 0.80 kg of ethyl
alcohol from 59degF of its boiling
point 172.94degF? (c = 0.6 cal/g
degC) 30 kcal
77.Temperature at which the vapor will
start to condense? Dew point
78.Element with highest ionization
potential of its atom? helium
79.Minimum amount of radioactive
material needed to sustain a nuclear
chain reaction. Critical mass
80.Which of the following is the weakest
attractive force?

a. Van der Waals force

b. b. Coordination covalent bond?
c. Covalent bond
d. Polar Covalent bond
81.What chemical bond is formed in
binary
compounds
where
the
electronegativity difference between
atoms is greater than 0.2? covalent
bond
82.Compute the maximum possible
efficiency of a heat engine operating
between
temperature
limits,
100degC and 340degC. 39.15%
83.Efficiency of an Otto cycle with a
compression ratio of 7:1? The gas
used is air. 0.541
84.Air in an automobile tire is initially at
-10degC and 190kPa. After the
automobile is driven awhile, the
temperature rises to 10degC. What is
the new pressure? 204.448 kPa
85.A 30-m vertical column of fluid
(density = 1878 kg/m^3) is located
where
g=9.65mps^2.
Find
the
pressure at the base of the column.
543.68 kPa
86.A vertical column of water will be
supported to what height by standard
atmospheric pressure? 33.9 ft
87.A substance which can act as an acid
and a base. Amphoteric
88.How much water in L must be added
to 0.5L of 6M HCl to make it 2M? 1.5
L (?)
89.The First law of Thermodynamics
maybe expressed in the following
equivalent:
a. net transfer is equal to the
network
b. sum of total energy forms
leaving the system boundary is
equal to the energy input
c. c. energy can neither be
created nor destroyed, can be
converted from one form to
another
d. d. all of the above
90.A unit of pressure used in high
vacuum technology and is equal to 1
mmHg. Torr
91.Heat engine deriving its power from
the energy liberated by the explosion

of a mixture of some hydrocarbon, in

a gaseous or vaporized form.
Internal combustion engine
92.A steady-flow process at total
constant pressure through a control
volume for which there is no heat.
Adiabatic saturation process
93.The Pauli exclusion principle: limits
the number of electron that can
occupy an orbital to 2
94.The Carnot cycle is composed of how
many reversible processes? 4
95.Assumes that the concentration of a
reaction intermediates is constant
during the main part of the reaction.
Steady-state approximation
96.It is a thermodynamic cycle that
converts heat into work. Water is
usually the working fluid of the cycle
and heat is supplied externally in a
closed system. Rankine cycle

97.The impossibility of knowing both the

precise location and the velocity of
subatomic particles at the same time
is known as: uncertainty principle
98.What pressure must be applied to
225mL of gas at 1atm to reduce its
volume to 100mL? 2.25 atm
99.The property of a substance which
remains constant if no heat enters or
leaves the system while it does work
or alter its volume but which
increases or diminishes should a
small amount of heat enter or leave.
entropy
100.
Calculate the energy change
associated with the third line of the
Balmer Series for Hydrogen gas, that
is, the line that results when an
electron moves from n=6 to n=2
(Rhc
=
-1313kJ/mole).
301.45
kJ/mol