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rA
k1 k2 k3
k4
1 2
CA
1 2
k1 k2 k3
* then the overall rate constant is k
k4
* if the temperature dependence of this rate constant is found, then we can write the pre-exponential and the activation
energy k1 k2 k3
E1 E2 E3 E4
E
1
ln k
ln k0
RT
2 ln
k4
RT
* or the overall pre-exponential is k
* the overall activation energy is E 1 2
E E E
0
1 2
E4
* note that this activation energy may turn out to be negative.
1