Академический Документы
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R. Chandramouli
Associate Dean-Research
SASTRA University, Thanjavur-613 401
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Table of Contents
2. Materials and their structures ..................................................................................................... 3
2.1 Introduction:.......................................................................................................................... 3
2.2 Crystalline arrangement: ....................................................................................................... 3
2.3 Planar and direction indices .................................................................................................. 5
2.4 Crystal imperfections:............................................................................................................ 6
2.5 Deformation of crystalline solids:.......................................................................................... 8
2.5.1 Single crystals: ................................................................................................................ 8
2.5.2 Polycrystalline materials................................................................................................. 9
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2.1 Introduction:
The ability of materials to undergo forming by different techniques is dependent on
their structure and properties. Behavior of materials depends on their structure-atomic
structure, crystal structure and grain structure.
Materials are generally classified into metals/alloys and non-metals such as plastics,
ceramics, composites. Metals are further classified into ferrous and nonferrous metals.
Further, materials can be classified into crystalline and amorphous materials.
Materials
Metals/Alloys
Iron
Alumina
Titanium
Silica
Steel
Glass
Duralumin
Porcelain
Brass
Concrete
Composites
Polymers
GFRC
Nylon
CFRC
Polyester
MMC
Polyethylene
Carboncarbon
Bakelite
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BCC: Metals like alpha iron, chromium, molybdenum, tungsten, vanadium exhibit BCC
structure. The packing efficiency which is the ration of the volume of effective number
of atoms per unit cell to the volume of the unit cell for BCC is found to be 58%.
Number of neighboring atoms in a BCC unit cell is 8 called coordination number.
FCC: Metals like nickel, copper, aluminium, silver, gold, platinum have fcc structure with
a packing efficiency of 74%. And coordination number of 12.
HCP: For hcp metals such as zinc, magnesium, alpha titanium, cobalt, cadmium the
packing efficiency is 74% and coordination number is 12.
FCC and HCP have more densely arrangement of atoms within, than BCC.
1,1,0 plane
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Miller indices of atomic directions are obtained as the difference between the intercepts
of the end point of the direction and origin of the direction with the respective
reference axes.
Difference in crystal structures of metals is due to the difference in energy required for
the formation of the structures among different atoms. Some metals can exist in
different crystal structures under different conditions of temperature. Iron exists as BCC
at room temperature, but when heated to 1185 K it becomes FCC. This property is called
polymorphism or allotropism.
Adding another element to a pure metal forms an alloy. For example carbon added to
iron forms steel which has different properties compared to iron.
Alloying generally improvesstrength and hardness of pure metals. Pure metals as such
have limited engineering applications in view of their limited strength, hardness, wear
resistance, fatigue and creep resistance.
101
101
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Edge dislocation extra plane of atoms present within the crystal giving raise to
distortion of the structure.
Screw dislocation It is a kind of distortion in the arrangement of atoms produced by a
shear between two halves of a crystal the upper front part moved by one atomic
distance with reference to lower front.
Unit displacement of atoms in dislocations is represented by the Burgers vector.
Dislocations play active role during plastic deformation of crystalline solids.
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= G/2
where G is shear yield strength of the material.
Similarly, it can be shown that the maximum theoretical tensile strength of a perfect
crystalline solid is given by:
= E/10
where E is elastic modulus. Theoretical strength is of the order of GPa.
However, actual shear strength and tensile strength of crystals is much less than that
predicted by the above expressions because of crystal defects discussed in sections
above.
2.5.2 Polycrystalline materials
Polycrystalline materials have defects in the crystal structure, which considerably reduce
their strength.
Basic mechanisms causing plastic deformation in crystalline solids are slip and twinning.
Slip is sliding of one plane of atoms over another plane due to application of forceshear force. It is similar to the sliding of playing cards. A minimum shear stress called
critical resolved shear stress is required to cause slip in single crystals. Slip specifically
happens only along specific planes called slip planes and along specific directions called
slip directions. Family of slip planes and slip directions together form slip systems.
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Normal
Slip direction
Slip Plane
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Finer grains prevent easy motion of dislocations thereby increasing the strength of
crystalline materials.
Single crystal has anisotropic properties, whereas polycrystalline materials have
isotropic properties. Isotropy refers to uniform properties along all directions in the
crystal.
Grain size has profound effect on strength and hardness of metals. Large grains produce
smaller strength. Yield strength dependence on grain size is given by Hall-Petch relation:
Y = Y i + kd-1/2
where Y i is resistance to dislocation motion, d is grain size, k is a constant indicating
dislocation pileup.
Grain size is given by ASTM grain size number, n.
N = 2n-1, where N is number of grains per square inch at a magnification of 100X and n is
grain size number-varies between 0 and 10.
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