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197
ABSTRACT
Camus, F., 1990. The geology of hydrothermal gold deposits in Chile. In: J.W. Hedenquist, N.C.
White and G. Siddeley (Editors), Epithermal Gold Mineralization of the Circum-Pacific: Geology, Geochemistry, Origin and Exploration, I. J. Geochem. Explor., 36: 197-232.
A detailed geologic study has been undertaken of the characteristics of 20 of the best known
hydrothermal gold deposits in Chile. Characteristics include production and reserve data, metal
grades, geotectonic setting, morphology, mineralogy, zonation, alteration assemblages and fluidinclusion studies. Based on this geologic data base, two broad categories of gold deposits have been
recognized: volcanic-hosted epithermal deposits of the adularia-sericite and acid-sulphate types
and porphyry-related deposits.
Volcanic-hosted epithermal deposits of the adularia-sericite type appear to be more abundant
than the acid-sulphate type. Very few examples of porphyry-related deposits have been recognized.
The majority of the acid-sulphate type deposits were formed during the Oligocene-Quaternary
time-span and no adularia-sericite type examples are yet known from this period. This latter
epithermal type was formed exclusively during the Mesozoic and Early Tertiary.
Presently accepted ore-deposit models have been applied to the Chilean epithermal gold deposits, and an empirical model for adularia-sericite epithermal system is presented.
INTRODUCTION
Background
The surge in precious-metals exploration worldwide in the past 15 years has
resulted in a greater interest in the study of hydrothermal deposits, especially
of gold. These studies are aimed at defining the geological characteristics, depositional environments, and origin of these deposits in order to develop better
tools for exploration. The works of Buchanan (1981), Henley and Ellis (1983),
Berger and Bethke (1985), and Heald et al. (1987), among others, are examples of general studies of this type.
The marked increase in gold-silver exploration in Chile during the past 10
years has resulted in the discovery of the E1 Indio ore deposit, east ofLa Serena
0375-6742/90/$03.50
198
F. CAMUS
in the high Andes - presently the largest gold producer in Chile - and the recent
discoveries at La Coipa and Marte.
Chile's total recorded gold production between 1545 and 1987 was 688,000
kg. Almost 50% of this gold (341,000 kg) has been mined since 1932. Since
1980 there has been a strong revival of exploration and mining. At present the
official average annual Chilean gold production is 16,000 kg.
Geological studies of Chilean gold and silver deposits have not been developing at the same rate as exploration. A review of the literature shows a scarcity of published detailed geological work even for the principal gold camps of
the country. The only published compilations are papers by Flores (1942) and
Ruiz et al. (1965). Recently, Camus (1985) and Cabello (1986) described the
principal geological features of a number of these deposits using updated
concepts.
This paper represents an updated version of Camus' (1985) review of new
research results and describes the geological characteristics of the best known
gold deposits in Chile. A major aim is the understanding of the genesis and
evolution of the deposits within the geological context of the country. A possible classification is established, based on conceptual models that may be useful in exploration.
Available data of the 20 best known gold districts or their most important
TABLE 1
List of 20 epithermal gold deposits/districts with selected references considered in this study
Deposit/district
References
Choquelimpie
Faride
San Cristobal
E1 Guanaco
La Coipa
Marte
E1 Hueso
Inca de Oro
Cachiyuyo de Oro
E1 Capote
E1 Indio
Andacollo
Los Mantos de Punitaqui
Las Vacas
E1 Bronce
Alhu~
Chanc6n
El Tigre
E! Chivato
Minas del Prado
Thomas (1973)
Camus (1987)
Lowell and Aspillaga (1987), Rivera (1984)
Llaumett {1979)
Cabello (1986)
Mining Journal (1988)
Minerfa Chilena (1987)
Flores and Ruiz (1946), Villarroel (1972)
Salinas (1975)
Flores (1943), Frank et al. {1985)
Siddeley and Araneda (1986)
Llaumett (1980)
Lepeltier (1964), Galay (1974)
Swayne (1949), Camus and Reichhard (1987)
Camus (1982), Camus et al. (1986)
Flores (1948)
Camus and Duhalde ( 1981 ), Dfaz (1986)
Camus (1981)
Camus and Drummond (1979)
Ambrus and Araya (1981)
199
deposits have been compiled and summarized in Tables 1 to 14. This information was used to group the deposits into certain deposit types. In addition,
an empirical model for vein deposits is presented in an attempt to establish a
point of reference for Chilean vein gold deposits.
F. CAMUS
200
TABLE 2
Time distribution of gold districts
Magmatic Arc Upper
Jurassic-Lower Cretaceous
Magmatic Arc
Miocene-Recent
Inca de Oro
El Capote
Las Vacas
Los Mantos de Punitaqui
E1 Chivato
Cachiyuyo de Oro
Andacollo
Faride
San Cristobal
E1 Guanaco
E1 Bronce
Alhud
Chancdn
E1 Tigre
Choquelimpie
El Indio
Minas del Prado
La Coipa
Marte
El Hueso
The 20 districts reported in this paper all formed during the Andean Cycle
and can be grouped chronologically as follows (Table 2):
(1) deposits associated with the Upper Jurassic-Lower Cretaceous magmatic arc;
(2) deposits associated with subvolcanic systems developed during the Upper Cretaceous-Lower Tertiary; and
(3) deposits associated with subvolcanic systems developed during the Miocene to Recent.
Most of the gold was introduced during this latter time span (Fig. 3). The
geographical location of these groups are shown in Figure 1.
Gold deposits formed during the Late Jurassic-Early Tertiary time span are
mainly volcanic-hosted epithermal veins of the adularia-sericite type, associated in most cases with volcanic centers. Towards the Late Oligocene-Early
Miocene period, changes in the geological setting (and different erosion levels? ) are reflected in the predominance of the acid-sulphate epithermal deposits of the stockwork/disseminated type associated with large hydrothermal
alteration zones. Finally, during the Miocene-Pleistocene, gold hydrothermal
systems appear to be more related to an increased geothermal activity, so all
the existing epithermal systems are of the acid-sulphate type.
From the above discussion we could presume an evolution of the Chilean
gold deposits from more deep-seated deposits of the adularia-sericite bonanza
type, with a relatively simple mineralogy, occurring in the early stages of the
Andean cycle to morphologically, mineralogically and structurally more complex, shallow acid-sulphate epithermal deposits, associated with volcanic centers, during the later stages of this cycle.
Nevertheless, since the acid-sulphate deposits are generally associated with
shallow hydrothermal systems, erosion might well account for the fact that no
known deposits of this type has yet been found in the older Mesozoic rocks.
201
71
T
6-~,
69 o
~.....:-
lJ~ ""'"~t~il~
- -
Gold deposit
250
I
500Km
I
(~achiyuyodeOro
OF G
01
~)~
OEI Chivato
VEIN DEPOSITS
DEPOSITS
10
PRODUCTION PLUS RESERVES
STOCKWORK /DfSSEMINATED
1
GOLD ORE IN METRIC TONNES OF PAST
.,..~OC,,..~o'n
Lal VaCllO
100 6
(Tonnes)X 10
Fig. 2. Size and grade characteristics of the 20 selected hydrothermal gold deposits. 1986 Chilean gold production is shown for reference.
~"
OJ
100
t~
b~
203
The lack of data on grade and tonnage for most of the deposits allows only
a rough estimate of their metal content. Figure 2 was constructed using the
published information, for the better known deposits and tonnage and grade
estimate based on personal evaluations of the author for deposits without published data. For the majority of the vein orebodies, reserve figures are based on
the length, width and depth of the mineralized structure and assuming that
only 25-30% of the vein volume carries economic grades. The grade-tonnage
distributions for the 20 districts are shown graphically on log-log scales in Figure 2. Forty-five percent of the deposits, by size, fall in the range of 200,000500,000 tonnes of contained ore; 25% in the 1,500,000-7,500,000 tonnes range
and the remaining 30% fall in the 10,000,000-40,000,000 tonnes range. This
last group represents the great majority of the stockwork/disseminated deposits, while the smaller groups are mainly vein-type deposits. The smaller and
medium-sized deposit groups have grades between 2.8 and 14 g/t Au. The larger
deposits contain between 1.6 and 2.1 g / t Au. The richest deposit is El Indio
204
F. CAMUS
TONN S
(Au~
400-
UPPER JURASSIC-LOWERCRETACEOUS
[~
IOCENE-QUATERNARY
[ ~ 1 No OF DEPOSITS
300 -
200-
100-
41
TIME
Fig. 3. Relative gold deposition during Mesozoic and Cenozoic time-span for the 20 selected deposits.
with 106 tonnes of contained gold; the smallest deposit considered is Minas del
Prado with 0.5 tonnes of gold, according to current information (Fig. 2 ).
Most of the smaller deposits are located in the Coastal Range; their smaller
size probably reflect the deeper erosion level of this morphological unit. The
larger deposits occur at elevations greater than 3500 m in the High Andes, with
the exception of the San Cristobal deposit.
Associated metals
Most of the gold-bearing vein deposits also contain metals such as Ag, Cu,
Pb, Zn, As and Hg. However, with the exception of silver, these minor metals
are generally not recovered.
Silver: Silver grades typically range from < 5 to 10 g/tonne. Silver is of economic significance in the Choquelimpie, Faride, La Coipa and E1 Indio deposits. Au/Ag ratios are generally less than one for most of these ore deposits
(Table 3 ).
Copper: The copper content rarely exceeds 0.50% Cu, and as a result is rarely
recovered. However, San Cristobal, Faride, E1 Guanaco, and E1 Indio have av-
GEOLOGYOFHYDROTHERMALGOLDDEPOSITSIN CHILE
205
TABLE3
Production data for 20 selected hydrothermal gold deposits
Deposit or district
Ton ( 10e)
(ProdRes)
Au
(g/t)
Ag
(g/t)
Au/Ag
Base metals
(%Cu+Pb+Zn)
Choquelimpie
Faride
San Cristobal:
(Diss)
(Vein)
El Guanaco
La Coipa
Marte
El Hueso
Inca de Oro
Cachiyuyo de Oro
El Capote
El Indio:
(Bonanza)
(Plant-Grade)
Andacollo
Los Mantos de Punitaqui
Las Vacas
E1 Bronce
Alhu~
ChancSn
E1Tigre
E1 Chivato
Minas del Prado
11.75
1.50
2.11
2.80
60
240
0.035
0.012
15.90
0.15
5.40
33.80
36.00
16.00
0.20
0.30
0.50
1.58
4.00
3.70
1.70
1.26
1.68
4.00
12.00
9.00
NP
50
17
88
NP
NP
NP
NP
NP
>1
0.080
0.22
0.019
>1
>1
>1
>1
>1
NP
2.0%Cu
2.0% Cu
Traces
NP
NP
Traces
NP
NP
0.18
7.40
10.00
2.50
0.25
4.30
0.50
0.55
0.25
0.20
0.20
218.00
9.10
1.50
9.00
12.50
5.00
5.00
5.00
8.00
7.50
2.30
109
91
NP
NP
NP
20
20
10
50
NP
NP
2.0
0.10
>1
>1
>1
0.25
0.25
0.50
0.16
>1
>1
2.87% Cu
4.33%Cu
NP
0.5% Cu
NP
2.20
0.10%Cu
1.50
1.50
NP
NP
Traces
2.50
206
F. CAMUS
order of 0.25-0.30% Hg and the mercury distribution within the orebody shows
a horizontal zonation.
Geotectonic setting
In the better known deposits, such as El Indio and El Bronce, a close association of the veins with nearby caldera structures or volcanic centers is recognized (Camus et al., 1986 ). At least 11 deposits are closely related to margins
of calderas or stratovolcanoes. These include deposits at Choquelimpie, E1
Guanaco, La Coipa, Marte, E1 Indio, E1 Bronce and Minas del Prado (Table
4). As noted by Heald et al. (1987), caldera settings represent excellent plumbing systems for the development of hydrothermal convection cells. Volcanic
centers commonly are capable of generating the necessary zones of structural
weakness along which the hydrothermal fluids were channeled.
Deposits like Los Mantos de Punitaqui, E1 Tigre, E1 Capote or Las Vacas,
are associated with structurally complex fault zones.Other deposits like E1
Hueso or Andacollo, are marginal to porphyry copper systems, which may also
be related to volcanic centers.
Present evidence, for all these deposits, suggests that hydrothermal mineralization occurred at the end of a phase of active volcanism, in what Smith and
Bailey (1968) define as "the terminal stage of waning volcanic activity".
Geological characteristics
Host-rock lithology
The main host rocks for Chilean gold deposits are andesites, volcanic breccias, ignimbrites, tufts, rhyolites and dacites. As a rule these rocks are intruded
by dioritic to granodioritic stocks. Only in two cases do sedimentary rocks act
as host rocks. Andesite is the most common wall rock in the deposits assigned
to the Upper Jurassic-Lower Tertiary time span. Some of these deposits in
part occur in diorite to granodiorite intrusives. Rhyolites and dacites become
more important in deposits associated with the Upper Cretaceous-Recent period. If we consider all reported gold deposits in Chile, including the 20 deposits
listed in Table 1, the distribution of host rocks is as follows: andesites-dacites:
44%; granitic intrusives: 47%; and sedimentary rocks: 9% (Ruiz et al., 1965;
Fuenzalida, 1974; Salinas, 1975; Sandoval, 1975; and Munoz, 1975).
In some deposits, especially in those hosted by andesites and granitic rocks,
basic to intermediate dikes occur along the mineralized structures. Examples
are E1 Capote, Inca de Oro and E1 Bronce districts. Barren diorite or diabase
stocks are also spatially related to some of these districts.
GEOLOGY OF H Y D R O T H E R M A L
207
G O L D DEPOSITS IN CHILE
TABLE 4
Geotectonic setting,age and host rock
Deposit/district
Geotectonic setting
Age
Host rock
Choquelimpie
Faride
San Cristobal
El Guanaco
La Coipa
Stratovolcano
Marginal to porphyry system
Volcaniccomplex
Caldera complex
Volcanic complex (caldera?)
Miocene
Upper Cretaceous
Upper Cretaceous
Lower Tertiary
Late Miocene
Andesite
Granodiorite
Marte
El Hueso
Inca de Oro
Marginal to stratovolcano
Marginal to porphyry Cu system
N-S to N45. E-trending structure
within magmatic island arc.
Magrnatic arc. Mineralization along
N-S to NE-trending structures
Magmatic arc. Mineralization along
N15-40W-trending structures
Subvolcanic system associated with
magrnatic arc. Mineralization in
structures marginal to volcanic
center
Radial fractures marginal to
porphyry Cu system
N-S to NE-trending shear zone
Miocene
Miocene
Lower Cretaceous
Upper Cretaceous
Granodiorite
Granodiorite, tonalite
Upper Cretaceous
Rhyolite, dacite
Lower Cretaceous
Lower Cretaceous
Meta-andesite
Granodiorite
Andesite, breccia
Upper Cretaceous
Andesite, breccia
Lower Cretaceous
Granodiorite, monzonite
Mid-Tertiary
Andesite, hydrothermal
breccia
Cachiyuyo de Oro
El Capote
El Indio
Andacollo
Los Mantos de
Punitaqui
Las Vacas
El Bronce
Alhud
Chancdn
El Tigre
E1 Chivato
Minas del Prado
Quartz porphyry
Andesite, dacite,rhyolite
Andesite, breccia,
granodiorite, tuff
Morphology
As already mentioned, in all deposits the control of mineralization is primarily structural and related to volcanic centers. Usually, the vein ore deposits
in these volcanic related environments are contained in complex structures in
which several generations of faults or fractures are present. Common types of
208
F. CAMUS
(a)
A'
GEND
IEINS, QUARTZ--SOLD
"MASSIVE SULPHIDE
~AULTS
~ R S l L L I C / S E RICITIC
..............~ ILTERATION
PROPYLITIC
ALTERATION
. ~f~.!
(b)
SECTION
B--B
, ~!
t!
HZ\
il~! V \
I
.....
,,===
LEGEND
g/
Or#
f'
VEIN
ANCESfTE
DIKE
" - ~ FAUL T
,o~.
I
Fig. 4. (a) Plan and section of El Indio vein system. Plan corresponds to level 4050. After Siddeley
and Araneda, 1986. (b) Plan and section showing distribution of veins at the El Bronce epithermal
system.
209
Morphology
Choquelimpie
Faride
San Cristobal
Deposit/district
TABLE 5
L: 80-100 m
W:
L: 60-550 m
W:
L: 20-30 m
W:
L: 50-100 m
W:
L:100-150 m
W:
50-60 m d i a m e t e r
W:
W:
W:
W:
W:
W:
800 m
7 km
200-300 m
600 m
1.2 k m
0.5-1 k m
200-300 m
50-250 m
250-400m
140-200 m
100-200 m
1-1.2 k m
300 m
L:
L:
L:
L:
L:
L:
1.2 m
1-20 m
1.5-7 m
1-4 m
0.5-3 m
0.50 m
0.80 m
1-2 m
0.5-12 m
100-300 m
4-23 m
W: 100 m
100-1000 m
250-2000m
1-2 k m
1.5 k m
1-3 k m
3.4 k m
L: 2 0 0 - 5 0 0 m
W: 0.5-1.5 m
L: 50 m
?
4.0 k m
9
250-300 m by 150 m
L: 100-400 m W: 1-3.5 m
L: 800 m
W: 80 m
Size of orebodies
1.5 k m
2.5 k m
2.0 k m
Length of
mineralized
structure
D:
D:
D:
D:
D:
D:
D:
D:
D:
D:
D:
D:
350 m
200-400 m
100 m
50-200 m
300 m
200 m
350 m
200 m
350-400 m
270 m
20-50 m
350 m
D: 10-40 m
D: 290 m
D: 200 m
D: 100 m
C)
bO
211
#3@"
..tC ~
/~
LEGEND
~,
~ BBarctceiaAlunite
~ s , . ..... Br.0i.
F~
l ~ O L e v ~
-~l
'.
Dacitic Tuff
Limit Over
A~ L t L~
I- ~
-B
~.:\v
~ ~o.
300m
I
LEGEND
I'
- ~
I
KIMBERLY BRECCIA
ORE BODY
PLAN AND SECTION
Porphyritic Andesites
'~]
~
(a~
OEOLO~Y A F T E R
" SIODELEY AND ARANEDA
Fault
(b)
OEOLOQY.00iF'SO
AFTER
AMBRUSAND ARAYA1981
198~
E
SECTION
~'t
~ , X ~ _ ~, 3
xF.././/../., ~ / ~
v/
7.069.475 N
..
~.~'.-t-..J~
::
............
. o o ........
:::::"i
~SEO''ENTS
I"~'~
(c)
VOLCA NICS
~;~-I FAULT
SOURCE :MINERIA CHILENA 1 9 8 7 . -
Fig. 5. (a) Plan and section of Kimberly breccia, E1 Tambo. {Taken from Siddeley and Araneda,
1986 ). (b) Plan and section of Minas del Prado gold deposits. (c). Longitudinal section of Pajonales orebody, El Hueso stockwork/disseminated deposit.
(b) quartz-barite-alunite-pyrite-enargite with minor amounts of chalcopyrite, galena, sphalerite, sulphosalts and silver sulphides.
Gold occurs as native gold, associated with silver (electrum) or copper (cuproauride ) or with sulphides such as pyrite or arsenopyrite. In some cases gold
is found in cracks or fractures in chalcopyrite, sphalerite or tetrahedrite. Silver
212
F. C A M U S
TABLE 6
Mineralogy of the hydrothermal vein districts
District/deposit
Major
Minor
Rare
Faride
Ag-Au-gal
bar-qtz-hem
Mn-oxides
Ag sulfides
sph-cpy-py
calc-sid-rho-Mn-silicates-bol
Tet/tenn
El Guanaco
Au-Ag
qtz-bar
py-cpy-en
Ag sulphides
sph-gal
alun
Inca de Oro
qtz-py-Au
Au tellurides-calc-cpy
Cachiyuyo de Oro
qtz-py-Au
hem-cpy
El Capote
Au-qtz
arsenopy
cpy-py
calc-hem-bar
bn-gal
cov-po
E1 Indio-Tambo
Au-Ag
en-py
bar-qtz
tet/tenn
cpy
arsenopy
anh-gyp
alun-nat S
Au tellurides
stib-Ag-sulphides
sph-gal
cov-bn-po
qtz-spec
py-cpy
calc-Au
schw-cinn
mgtt
Las Vacas
qtz-py-Au
calc-hem
E1 Bronce
qtz-py-Au
sph-cpy
calc-sid
ank
Ag-gal-tet/tenn
hem-bn
Alhud
qtz-py-Au
cpy-sph
Chanc6n
qtz-py-Au
cpy-sph
E1 Tigre
qtz-py-Au
arsenopy
gal-sph
cpy-stib
po-arsenopy
bn-mgtt
-
213
District/deposit
Major
Minor
Rare
Choquelimpie
qtz-bar-py-gal
Au-Ag-acan
orp-real-arg
alun-calc
Hg-Sn
sulphosalts
qtz-py-Au
qtz-py-Au
cpy-calc-bar
gal-sph
hem-anh
La Coipa
Ag
qtz-py
Ag chlorides
Au-sph-gal
arg-sulphosalts
cinn
El Hueso
Au-py
cpy
po-bn-cc
Andacollo
Au-py
El Chivato
qtz-py-Au
gal-sph
qtz-py-Au
San Cristobal
Diss:
Veins:
KEY: same as Table 6 except for: orp = orpiment; real = realgar; arg = argentite; acan = acanthite.
TABLE 8
Vertical zonation of primary mineralization along vein deposits
Zone
Mineral associations
I: Upper precious
metals zone
Gold (g/t)
2 4 6 8 10
15
20
quartz-pyrite-arsenopyrite
metal-bearing zone; and a lower or root zone. Note that the location of both
mineral associations distinguished above are shown in Table 8 together with
the gold distribution. In contrast, stockwork/disseminated deposits do not show
such well defined vertical zonation.
Lateral zonation has been described for some vein oreb0dies, but available
214
F. CAMUS
data are insufficient to define a generalized zonal pattern. Based on our present
information, gold tends to be located in the central part of the system with
lateral increase of, first Ag-Cu and then Pb-Zn minerals. At Los Mantos de
Punitaqui, the lateral zonation is unusual with a gold zone grading into copper
zone and finally into a peripheral mercury zone.
Most deposits show several mineralization stages, each of which probably
represent structural reactivation accompanied by a respective pulse of mineralization. Each deposit is the result of a unique tectonic and depositional continuum, involving changes in both precious- and base-metal-bearing mineral
stabilities, thereby explaining the differences observed in the mineralogy of
the 20 deposits. However, the basic assemblages are always present. Gold-silver deposits invariably are the result of more than one pulse of mineralization.
Thus after a silver mineralization stage may follow a gold or base-metal pulse,
provided permeability requirements were met. La Coipa and Faride are good
examples of this style of mineralization.
Hydrothermal alteration
The major alteration types recognized in the 20 districts or individual deposits are:
{a) Quartz-sericitic,
(b) Silicification or silicic,
(c) Argillic of the intermediate and advanced types,
(d) Chloritic and/or propylitic, and
(e) K-feldspar in the form of adularia.
In addition tourmalinization (El Chivato, Faride), albitization (Andacollo)
and carbonatization (El Bronce) may also be present. In all cases there is
evidence of multiple alteration stages.
The determination of alteration types in some of the vein deposits is difficult
because underground workings are usually driven along orebodies. The alteration descriptions and personal observations were interpreted on the basis of
Meyer and Hemley's (1967) classification.
The alteration most commonly found includes the quartz-sericitic and argillic assemblages (Tables 9 and 10). These assemblages occur in all vein and
stockwork/disseminated districts. However, at the El Guanaco and E1 Indio
vein districts advanced argillic assemblages prevail. In the stockwork/disseminated deposits silicic and argillic alteration types predominate, with the advanced argillic assemblage prevailing at La Coipa and possibly Marte. Adularia
has been recognized locally only at Faride in association with quartz veinlets.
No adularia has yet been reported in other well-studied vein deposits.
The majority of the individual vein deposits are characterized by quartzsericite halos or by argillization bordering the vein. Occasionally, argillic alteration predominates intermixed with quartz-sericite. The argiUic alteration
consists mainly of kaolinite with minor proportions of montmorillonite. Chlor-
215
TABLE 9
Alteration assemblages in vein districts
District/deposit
Type
Description
Faride
Quartz-sericite, argillic,
propylitic, tourmaline
El Guanaco
Silicic, quartz-sericite,
advanced argillic.
Propylitic halos
Inca de Oro
Argillic
Cachiyuyo de
Oro
Argillic
El Capote
Quartz-sericite, argillic
El Indio
Advanced argillic,
silicic, weak chloritic
Los Mantos de
Punitaqui
Argillic
Las Vacas
Quartz-sericite,
chloritic
E1 Bronce
Quartz-sericite, argillic,
propylitic
Alhud
Quartz-sericite
Chancdn
Quartz-sericite,
chloritic
E1 Tigre
Argillic, quartz-sericite
216
F. CAMUS
TABLE 10
Alteration assemblages in stockwork/disseminated breccia-hosted and shear zones-related deposits
District/deposit
Type
Description notes
Choquelimpie
Argillic, silicic,
propylitic
San Cristobal
Quartz-sericite,
argillic
La Coipa
Advanced argillic,
argillic,silicic,
propylitic halo
Matte
Advanced argillic,
silicic
E1 Hueso
Silicic, argillic
Andacollo
Propylitic zone
E1 Chivato
Quartz-sericite,
argillic (supergene)
Silicic, chloritic
217
nite. The presence of zunyite has also been reported locally. Propylitization
occurs farther outward in the form of a weak chlorite envelope.
The alteration types associated with vein deposits also appear in stockwork/
disseminated orebodies. However, both types of ore deposits show significant
differences in the extent and distribution of the alteration assemblages. Widespread silicification and argillization seem to be typical of the stockwork/disseminated deposits. Silicification occurs as quartz veinlets or silica flooding,
in some cases accompanied by sericite. Argillization, characterized by the occurrence of kaolinite with lesser montmorillonite and halloysite, is the most
frequent of the feldspar destructive type of alteration. At La Coipa, advanced
argillic alteration occurs as a major phase of alteration together with silicification. The advanced argillic assemblages in these deposits include alunite,
pyrophyllite, native sulphur and traces of zunyite. A propylitic outer zone has
been reported for at least four of the deposits listed in Table 10. So far, no
propylitization has been found in the other deposits. Vertical zoning patterns
have not been well documented. At E1 Hueso and La Coipa silica caps with
sinter development are preserved on the surface, grading into argillic (El Hueso)
to advanced argillic (La Coipa, Marte? ) assemblages with depth.
The surface distribution and extent of the various alteration types reflect
the intensity and extent of the hydrothermal activity. Vein deposits associated
with quartz-sericite/argillic assemblages tend to have very narrow alteration
envelopes, while vein deposits, with important development of advanced argillic alteration, are associated with altered areas covering several square kilometers. At E1 Indio, the alteration zone directly associated with the mineralization occupies a surface area of 3 by 10 km, which occurs within a 200-kmlong and 1 to 10-km-wide belt of alteration (Siddeley and Araneda, 1986). In
contrast, at E1 B ronce (Camus et al., 1986), the structural system that hosts
the ore deposits extends for more than 8 km, with only weakly developed surface alteration.
In the stockwork/disseminated deposits the mineralization covers large areas
and the alteration is equally widespread. This gives rise to strong colour anomalies. For example, at La Coipa the hydrothermal alteration zone covers an
area of approximately 20 by 3 km.
Differences in level of erosion and in the intensity of the hydrothermal alteration-mineralization process may explain the variability of surface expression between deposits.
Oxidation zone
218
F. C A M U S
T A B L E 11
Disseminated:
E1Guanaco
La Coipa
E1Hueso
I n c a d e Oro
C a c h i y u y o de Oro
E1Capote
E1 I n d i o
Andacollo
L o s M a n t o s de Punitaqui
LasVacas
E1Bronce
Alhud
Chancdn
E1Tigre
E1Chivato
Depth of
oxidation zone ( m )
Grade
(g/t Au)
(g/t Au)
80-200
200
1- 2
2- 3
0.5- 1
1 - 2
100
100
5 0 - 70
100-150
100-150
4 0 - 80
200
100-150
20
1 0 - 20
4 5 - 60
2 0 - 30
2 0 - 30
1 5 - 20
50
3 0 - 40
2 0 - 70
-
50
2
50-60
1.80
1- 2
20-40
12-30
10-15
30
2
8-10
13-30
20
10-20
30
10-15
10-15
4
< 1.0
4 - 5
< 1.0
< 1.0
5 -10
5 -10
5 - 6
10 - 1 5
0 . 5 - 1.0
3 - 4
8 -10
5 - 6
5
3 - 4
2 - 3
3 - 4
2 - 3
thin blanket of secondary sulphides before entering the primary zone. The
depth and gold grades of the oxidation and primary zones for each of the selected deposits are summarized in Table 11.
The oxidation zone is characterized by the presence of complex oxides, carbonates, sulphates and chlorides, products of oxidation and supergene leaching
of pre-existing Cu, Fe, Pb, Zn, Ag sulphides and sulphosalts. Coexisting with
those minerals, pervasive clayey minerals of secondary origin are also present.
The principal minerals present in the oxidation zone are listed in Table 12.
The degree of oxidation and supergene enrichment in each of these deposits
is controlled by the primary mineralogy and permeability of the host rocks. As
previously mentioned, the majority of the gold deposits contain iron as well as
copper sulphides which carry precious metals. Oxidation and leaching of these
sulphides liberates the gold content, which is then transported and fixed within
the oxidation zone. As a result, a zone of high gold or silver concentration is
formed in the upper part of the oxidation zone of most of these deposits, which
gradually diminishes in grade with depth. The importance of this zone will
depend on the primary gold-bearing sulphide content and host-rock permeability and reactiveness. If the permeability of the rock is sufficient, gold may
GEOLOGYOFHYDROTHERMALGOLDDEPOSITSINCHILE
219
TABLE 12
Principal mineralspresent in the oxidationzoneof Chileangolddeposits
Major minerals
Minor minerals
Goethite
Jarosite
Hematite
Alunite
Anglesite
Cerussite
Atacamite
Brochantite
Malachite
Native sulphur
Gypsum
Scorodite
Osarizawaite
Mackayite
Boleite
Emmonsite
Beudantite
Rodalquilarite
Native gold
Native silver
220
F. CAMUS
Surface geochemistry
Quantitative studies about the Chilean gold deposits with regards to primary
metal dispersion are scarce. Of the 20 deposits considered in this study, only
the detailed surface geochemical study undertaken at E1 Indio is available
(Siddeley and Araneda, 1986). In this study 2000 rock samples derived from
fine colluvium and weathered subcrop were analyzed for Au, Ag, As, Cu, Pb
and Zn. With the exception of Cu and Zn, all elements were highly anomalous.
Arsenic proved to be a very good pathfinder, showing a positive correlation
with gold and silver (Siddeley and Araneda, 1986). Gold and silver anomalies
defined the approximate location of the orebodies.
Studies elsewhere remain confidential at the time of writing this paper.
Fluid-inclusion studies
Preliminary or detailed studies on fluid inclusions, tied to mineral paragenetic sequences, were undertaken at Faride (Skewes, 1986), E1 Bronce (Skewes
and Camus, 1988), E1 Indio (Jannas and Araneda, 1985; Jannas et al., 1990,
this volume) and E1 Guanaco (Cuitino et al., 1988). According to these authors, precious metal deposition occurred between 190 and 330 C (Table 13 ).
The Faride, E1 Guanaco and E1 Indio deposits show relatively low temperatures and low salinities. In these deposits there exists evidence for boiling during the precious-metal deposition stage; Skewes (1986), Cuitino et al. (1988)
and Jannas and Araneda (1985) considered boiling the main depositional
mechanism. Salinities, determined from freezing point depression measurements, range in value between 0.1 and 3.5 eq. wt.% NaC1 at El Indio, E1 Guanaco and Faride (Table 13). These values suggest a significant influx of dilute
meteoric water into the hydrothermal system, which perhaps also contained a
minor magmatic component.
The E1 Bronce deposit, on the other hand, shows relatively higher temperatures and salinities. A boiling event is also documented but in this case took
place during barren late-stage mineral deposition. At E1 Bronce, the deposition
of precious metals and gold-rich zones occurred below the boiling zone. A mix-
221
T A B L E 13
Measured
T
( C )
Selected
Salinityequiv.
T
( C )
(wt.%)
Faride
ElIndio
E1Bronce
EI Guanaco
180-270
(90)
190-280
1.5- 7.6
(75)
0.1-40
150-358
(256)
130-290
(60)
0.5-10
(205)
0.8-3.6
(14)
Salinityequiv.
Evidence
of
boiling b
Paleodepth
estimation
(m )
Reference
(wt.%)
190-250
3.5
Yes
150- 200
Skewes (1986)
220-280
0.1-1.4
Yes
250
230-330
5.1
No
400-1200
240
3.0
Yes
160
Jannas and
Araneda (1985)
Jannas et al. (1990)
Skewes and Camus
(1988)
Cuitifio et al.
(1988)
Isotopic studies
Of the 20 deposits considered in this work the only isotope data come from
:El Bronce. Sulphur isotope compositions with ~4S ranging from 0.5 to 2.3 %o
(Camus et al., 1986) suggest a magmatic source for sulphur in the sulphide
:minerals of this deposit (Ohmoto and Rye, 1979).
GENETIC MODELS AND TYPES OF HYDROTHERMAL
GOLD DEPOSITS
Based on the reported morphological, structural and mineralogical characteristics, the Chilean hydrothermal gold deposits can be grouped into two broad
genetic categories: volcanic-hosted epithermal deposits and porphyry-related
deposits.
F. CAMUS
222
TABLE 14
Faride
San Cristobal
Inca de Oro
Cachiyuyo de Oro
E1 Capote
Los Mantos de Punitaqui
Las Vacas
E1 Bronce
Acid-sulphate
Choquelimpie
E1 Guanaco
La Coipa
Marte
E1 Indio
Alhu~
ChancSn
El Tigre
E1 Chivato
Minas del Prado
Porphyry-related deposits
Andacollo
E1 Hueso
GEOLOGYOFHYDROTHERMALGOLDDEPOSITSIN CHILE
223
~-~P~MFTEOfflWATER
C
":',~;'o":'~:z~ ~OL'AT::V:__,
1 ~1
I:o'~::E
o[~,,om..;~
(a)
METEORIWATER
C
-i.o;;
I I
WATER A
o
o____o
~
l
(b)
Fig. 6. Models for the two types of Chilean volcanic-hosted epithermal gold deposits. Modified
from models of geothermal systems of Henley and Ellis (1983). (a) Acid-sulphate type. (b) Adularia-sericite type. Examples of Chilean gold deposits are shown.
224
F. CAMUS
o.L,
VEIN
IN
ACID
(eUANACO
L
Acid
VOLCANICS
DISTRICT~
D
Veins
Volconics
Foul1
Gronodlorite
Siliclc/orgillic
Porphyry
Propylitic
O. 3
V
&
f
v
a.
o. x
x
:r: i
x
v/'x
ix
VEIN
I N VOLCANICS A N O
IN TRUSlVES
IINCA DE ORO OISTRICTsEL TIORE')
VEIN
IN VOLCANIC$
(INCA
OE ORO O/STRICT)
VEIN IN I N T R U S I V E
(PICH/~EOgA #I~rTRICT)
Fig. 7. Geologic sketches of different vein type deposits. Subgroups a.1, a.2 a n d a.3 are shown m
the bottom part of the figure.
shear zones and fracture-related types have one example each. Since veins are
the more common type of deposits they are referred to in more detail below.
225
other is a breccia-hosted deposit (Minas del Prado) (group c), and the last
one being related to a shear zone (group b).
a. Vein deposits
This group includes all districts where mineralization is hosted by pre-existing structures. The resultant orebodies are lense-shaped and they are more
persistent laterally than vertically. Within some of these veins stockwork zones
are developed.
Based on host-rock types, mineralogy and alteration, three subgroups of veins
have been distinguished. These three subgroups, according to their geomorphological setting, are interpreted to represent different erosion levels of an
original vein orebody. The three subgroups are the following (Fig. 7).
a. 1. Veins in intrusive. They generally correspond to the root zones of adulariasericite type vein deposits, hosted by intrusives of dioritic to granodioritic composition. Veins are narrow, generally less than one meter in width, decreasing
in width with depth. Mineralogy is simple, consisting of quartz, pyrite, arsenopyrite and associated gold. Locally, galena, sphalerite and chalcopyrite occur in the upper portions of the veins. Gold grade in the primary zone of these
veins is frequently low (less than 4 g/t Au), so oxidation and supergene processes would be required in order to make these veins economically feasible.
No other valuable metals are present. Alteration is weakly developed and is
represented by a narrow silicified envelope 20-30 cm wide.
Generally, this subgroup of vein deposits is found to be emplaced in Upper
Jurassic-Upper Cretaceous rocks. Examples are the Las Vacas, Cachiyuyo de
Oro and E1 Capote districts (Fig. 1 ).
a.2. Veins associated with volcanic rocks of intermediate composition. These veins
are morphologically similar to the veins described in (a.1). However, these
veins tend to be wider ( > 1 m) and mineralogically more complex, containing
quartz, pyrite, chalcopyrite, sphalerite, tetrahedrite-tennantite, calcite, barite
and, locally, bornite and anhydrite. These minerals display lateral and vertical
zonations with chalcopyrite-pyrite-sphalerite-tetrahedrite/tennantite assemblages located in the central part of the deposit, grading laterally and with
depth into pyrite. Gold occurs associated with pyrite and to a lesser extent with
chalcopyrite and sphalerite.
Alteration envelopes up to 50 cm wide around the veins consist of quartz,
sericite and clay minerals, grading marginally into weak propylitization.
Primary gold grade in these group of vein deposits may exceed 10 g/t Au.
Generally, recoverable quantities of silver and copper are also present. The
majority of these deposits belong to the Upper Cretaceous-Early Tertiary time
span. Examples of these subgroup are E1 Bronce, E1 Tigre, ChancSn and Alhud
(Fig. 1 ).
'
v(
slo....
c
STOCKWORK
St
u ~
t-.
z
ZONE
INTRUSIVES
(PICHIDEGUA )
LOWER
RE,
MASSIVE VEIN
LEGEND
DIKEB
ANDESITE
STOCKWORK
VEFNING .
DIKE
STOCKWORK
QUARTZ.
AND/OR
DEFINED
LOCALLY
WELL
STOCKWOR K
FI L L I N G .
OF OPEN-SPACE
VEIN
PYRITE ,
Ag
VEIN
CLEAR EVIDENCE
TRUE
FRACTURING
WORK
ONLY STOCK--
NO TRUE VEIN
CHLORITE.
WEAK
HALOS.
SILICIC
NARROW
HALO.
PROPYLITIC
ARGIL L IC
SERICITIC ,
SILICIC,
CHLORITE
WEAK
STRUCTURE ALTERATION
ARSENOPYRITE.
TO
Au-
L A T E TENNANTITE
SPHALERITE.
PYRITE, G A L E N A ,
CHALCOPYRITE ,
CARBONATES.
QUARTZ-- B A R I T E
_+CARBONATES
QUARTZ + B A R I T E
MINERALOGY
GRANODIORITE
DIORITE
VOLCANICS
INTERMEDIATE
VOLCANICS
BRONC E,TIG
METALS
INCA DE ORO )
(EL
BASE
BRONCE)
VOLCANICS
GEOTHERMAL ACTIVITY
(EL
ACID TO
iNTERMEDIATE
L ITHOLOGY
Fig. 8. Empirical model for an adularia-sericite epithermal vein system. Modified from Camus, 1985.
1500m"
1000
500,
Om
:>
b.3
t~
227
228
F. CAMUS
c. Breccia-hosted deposits
Such deposits are irregular or pipe-like concentrations of pyrite and free gold
together with quartz veining, which appear within as well as on the margins of
hydrothermal breccias bodies.
The hydrothermal alteration coexisting with these ore bodies consists of
silicification and chloritization, as well as abundant pyrite and minor sericite.
Primary gold grades are between 1 and 2 g / t Au, but locally, along individual
quartz veins, grades as high as 10-20 g / t Au are found. No other metals of
economic interest exist.
Deposits of this type, as for example the deposits at Minas del Prado (Fig.
5b ), are apparently genetically related to volcanic activity of Tertiary age.
Volcanic-hosted acid-sulphate epithermal deposits
Five deposits of this type are recognized: E1 Guanaco, La Coipa, Choquelimpie, E1 Indio-Tambo and possibly Marte. They are Early Tertiary to Recent in
age. Morphologically, they form vein deposits (group a) or low-grade stockwork/disseminated orebodies (group e) showing a close association with volcanic centers of acid to intermediate affiliation.
a. Vein deposits
These vein type deposits are hosted by dacitic to rhyolitic domes or stocks.
The orebodies are lense-shaped and occur along pre-existing faults or fractures, locally forming stockworks a n d / o r breccia zones. Mineralogy consists of
quartz, alunite, barite, rhodochrosite, enargite, pyrite, chalcopyrite and gold,
free as native gold or associated with sulphides.
Gold grades in the primary sulphide zone of these deposits are high ( > 10
g/t Au), with bonanza zones reaching grades of 50 to 100 g / t Au. Copper and
silver are significant metals and are economically recoverable.
Alteration is widespread, covering areas of 200 m wide by 500-1000 m long,
within which the veins are situated. A very distinct alteration zonation is generally recognized, with a central zone of sericite-quartz and clay minerals grading gradually into a marginal propylitic zone. Toward the top of the deposits,
extensive advanced argillic alteration zones are present. This alteration pattern can be recognized both locally and district-wide.
229
b. Low-grade deposits
The low-grade deposit type (group e) was recognized only very recently in
Chile. Consequently, published information regarding its geological characteristics is scarce.
These type of deposits contain low-grade stratabound mineralization hosted
by favorable volcanic horizons, usually slightly or strongly silicified. These
horizons tend to overlie acid leached argillized zones. Mineralization occurs as
fine-grained disseminations and as quartz vein stockworks. Some of these deposits developed silica sinters at the surface. In others the presence of silicified
breccias is conspicuous. Quartz is generally of the chalcedonic type.
Most of these deposits are hosted by Oligocene to Miocene volcanics, being
spatially and possibly temporally associated with deeply eroded stratovolcanoes. Considering its geological setting, the mineralization may have occurred
in very shallow epithermal systems associated with hot-spring environments
of the High Andes. Erosion at these elevations has been minor, leaving the
deposits of this type almost untouched. Normally, these orebodies contain gold
and silver, and are large in size and bulk mineable.
This paper has benefited from the critical comments of R.H. Sillitoe, G.
Westra, E. Reichhard and J. Davidson, to whom I am very grateful. I wish to
thank also to M.A. Duhalde who helped me in the preparation and was my
coauthor of an earlier version of this work. I am also grateful for the excellent
drafting of G. Alarcon.
230
F. CAMUS
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