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Second PUC Chemistry July, 2015 Question Paper

(Ensrishversion)

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caper has v;ffiffiF{i,

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compulsory.

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ii) Part - A carries 1 0 marks. Each question canies one mark.

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C c a rri es 1 5 m arks. Ea c h qu estion canies th

re m arl<s.

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Pa

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Part- B carries 1 A marks. Each question carriestwo ma*s.

Part - D carries 35 marks. Each guestion carriesfive marks,

iv)

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iii) Write balanced chemical equations and-Qqw diagrams

wherevernecessary.
Use log tables and the simple

(06n4t

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7"1)uL

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fllse of scientific calculator is ilot allowed.l

PARr-A

lf
aiN-fu
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Answer all the questions. Each question carries one mark. (Answer each question
(10x1 =10)

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in one word or one sentence).

1) On what factorthe value of colligative property depends ?

2) Give an example for liquid solution in which solute is gas.

3) How many Coulombs of electricity required to oxidise one mole of Alto

4) ln azeroorder reaction, the time taken to reduce

from 50 % to 25

o/o

Al3+ ?

the concentration of reactant

is 30 minutes. What is the time required to reduce the

concentration f rom 25

o/o

5) Name the enzyme used

lo 12.5 "/" ?
in the inversion of cane sllgar.

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34 (NS)

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6) V\fhich nietal is refined by Van-4rkel method ?

7) Name the noble gas which does not have general noble gas

R-X+l'rlal

^."%,

R-t+NaX

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B)

g.

configuration ns2 np6.

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What is the name of reaction ?

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e) Which oxldising agent used in Etard-reaction ?

10) Write the generalstructure o{ Zwitter ion.

of the following. Each question carries two marks.

(5x2=10)

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ll. Answeranyfive

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PART- B

11) Give anytwo differences between Frenketand Schottky defects.

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12') State:

i) Kohlrausch's law

ii)

Faraday first law of electrolysis

13) Calculate the half-life period of a first order reaction, if the rate constant of
the reaction is 6.g3 x 10-3 S-1.

14) Give reasons:

'

i) Actinoids showvariable oxidation states.

ii) Cerium (Ce) exhibits +4 oxidation state.

:.

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34 (NS)

-1 1-

reaction

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b) Complete the

a) Write the,luPAC narne of rnajor product formed in FriedelCrafts acylation

of anisole.
l

t.

g.

ocH3

,l
Lj

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-LU +Hl ---->

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16) How are carlcoxytic acid prepared from Grignard reagent ?

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17) What are antibiotics ? Give an example.

18) What is Saponification ? Give the equation to form sodium stearate by this

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method.

PART.C

Answer any,tive of the fotlowing. Each question carriesthree

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marks. (5x3=15)

19) Explain the reducing behaviour cif carbon in the extraction of iron using

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20) a) Name the'gas liberated when zinc reactswith dil. HNog

b) Give !.eason
:i)

PHB has lower boiling

pointthan NH,

ii) Nitrogen is less reactive at roorn temperature.

(1+2)

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34 (NS)

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21\ Give the principles involved in the manutacture of sulphuric

acid by contact
process with equations.

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i) Which halogen

has highestelectron affinityqelectron gain enthalpy?

Give the structure of perchtoric acid.

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ii)

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Cl, + 2H2O + SO,

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b)

g.

2\ a) Complete the reaction

'(1+2;

23) a) 3d-series etements exhibitvariable oxidation states.

why ?

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b) Calculate the magnetic moment

of Mn2+ ion.

[Atomic number of Mn = 25].

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(1+2)

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24) Describe the manufacture of potassium dichromate from

chromite ore.

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aS

25) with the help of Valence Bond Theory

UBT) explain hybridisation, geometry
and magnetic properv of
[coFu]r-, hexafruoridocobartate (ilr) ion.

[Atomic number of Co _ Zt]

26) a) What is the tupAC name ot

[cr1Nn.). (Hro).]

ct, r

b) Give the facial (fac) and meridional (mer) isomeric structures

of

[co6n.;.

(Nor).]

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(1+2)

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-13-

PART- D

(3xS=1S)

a) Calculate the packing efficiency in Body Centred Cubic (BCC)

b) An element having atomic mass

lattice.

g.

27)

marks.

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lV. Answer any three of the following. Each question carriesf ive

34 (r\rs)

107.9 gmoFt has fcc unit cell. The edge

cell.

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[Given NA = 6.022x 1023 mol-l].

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length of unit cell is 408.6 pm. Catculate the density of the unit

z\f)
/

.:

(3+2)

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The boiling point of benzene is 353.23 K when 1.80 g of a non-volatite,

non-ionising solute was dissolved in 90 g of benzene, the boiling point is

raised to 354.1 1 K. calculate the motar mass of the solute.

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[Given Ko for benzene = 2.53 K kg mol-t]

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b) Write two differences between idealand non-idealsolutions. (3+z)

29/ a) Draw the neat labelled diagram of Standard Hydrogen Electrode (St-lE)
and write its symbolic representation.

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//-

b) Calculate the emf

Ni(r) + ZAglo.oorrur
i

[Given

F3",, =

1.05

of the cell in which the following reaction takes place

+Nito1,uo,+ ?-Ag1s1

V]

(2+3]

30) a) Derive integrated rate equation for rate constant of zero order reaction.
b) Showthatthe rate of first order reaction is doubled when concentration
of

the reactant is

doubled.

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(B+2)

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a) i) Give any two characteristics of chemisorption.

ii) What is meant by selectivity of a catalyst

31)

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34

g.

b) Define:

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i) Brownian movement
ii) Tyndatteffect.

a) i) Exptain the SNz mechanism.

ii) What

(4x5 = 20)

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32)

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Answer any four of the following. Each question carries f ive marks.

is the reagent used in the conversion of alkyl halide into alkene ?

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b) Comptete the reaction

V'

(3+2)

c)

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CH.-CHr-Br+AgCN--TWhat are enantiomers ?

(3+1+1)

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33) a) Explain the Kolbe,s reaction.

,

b) Complete the reactions :

i) R-cH2-oH-#il

ii) @

ton'f*o.,

c) write the general equation of wiiliamson's ether synthesis.

(2+2+11

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34 (NS)

-15-

a) How would you prepare acetaldehyde from acetyl chloride. Name the
b)

co

reaction.

Name the reagent used in the conversion of ketone to hydrocarbon. Name

c) Acetaldehyde

does not undergo Cannizzaro's reacJion. Why

Explain the Hoffmann's bromamide reaction.

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b)

at low temperature.

is treated with

ib

methylamine

ii) aniline

(2+2+1\

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35) a) Name the major product formed when nitrous acid

i)

g.

the reaction.

CH2

CHs

(2+2+1)

c) Write the IUPAC name of (CH3)2 N -

36) a) Givethe Haworth structure of lactose.

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b) What are hormones ? Give an example.

base present in DNA but not in RNA ?

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c) Which nitrogenous

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37) a) How is neoprene prepared

b) What are bio-degradable polymers

? Give exampte.

c) What is vulcanisation

(2+2+11

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(2+2+11