Вы находитесь на странице: 1из 4


Which of the following statements regarding the rate constant in the rate law expression
is incorrect?
-Its value is independent of initial concentration at a given temperature.
2. Which of the following will result to successful use of catalyst?
-Stable product is formed.
3. Which of the following shows a picosecond regime for catalysis?
-Activation and Breaking of chemical bond
4. This quantifies the activity of the catalyst.
-turnover frequency
5. If one of the reactant is in gaseous state reacts with an adsorbed reactant then it follows
-Eley Riedel
6. It is a high molecular weight protein like substance that acts on a substrate to transform it
chemically at a greatly accelerated rate.
7. Which of the following reactors will maximize the desired product when its reaction
order is less than that of the undesired product?
8. When the concentrations of reactant molecules are increased, the rate of reaction
increases. The best explanation for this phenomenon is that as the reactant concentration
-the frequency of molecular collisions increases.
9. The measured reaction order and activation energy are not true values due to which of the
following limitations?
-Internal diffusion
10. If the activation energy of the desired product is greater than that of the undesired then
reaction system should
-be at highest possible temperature
11. Which of the following reactors can be used for highly exothermic gas phase reactions to
maximize the desired product?
12. Which of the following falsely describes enzymes?
- Enzymes match the shape of the substrate they bind to
13. If the adsorbed reactant interacts with another site such as the dehydration of butanol then
it follows
-Langmuir Hinshelwood
14. Which of the following will increase the overall rate for an internal diffusion limited
-Increase temperature
15. It represents the amount of gas adsorbed on a solid at different P and T
16. Which of the given reactions show homogeneous catalysis?
-Ozone reaction with chlorine atoms
17. An increase in the temperature of the reactants causes an increase in the rate of reaction.
The best explanation for this behavior is that as the temperature increases,
-the fraction of collisions with total kinetic energy is greater than Ea increases
18. Diffusion through internal boundary layer is rate limiting if and only if

-Reactant is consumed only near the exterior of the surface of the pellet
19. Which of the following is a microscopic scale in catalysis?
20. Catalysts that are sufficiently active which are used if pressure drop and heat removal are
major considerations.
-monolithic catalyst
21. The smaller is the particle size
-The greater is the pressure drop in a PBR
22. For reaction orders greater than 1, internal effectiveness factor
-Decreases as concentration increases at the external pellet surface
23. Which of the following pH values would enzymes work at its optimum?
24. Which of the following reactors is often used to determine reaction orders, activation
energies and specific reaction rates of exothermic reactions?
25. If the system is surface reaction limited then Thiele modulus
-decreases while internal effectiveness factor approaches 1
26. Which of the following is a microscopic regime in catalysis?
-complexation between reactant and catalyst
27. For a rapid reaction, the rate per unit surface area can be increased if
-Kc is increased
28. This is a reaction where the reactant is consumed by two different reaction pathways to
form different products.
-independent reactions
29. If the enzyme is exposed to extreme conditions, then
-it is said to be denatured
30. Which of the following statements is true?
-The reaction of the catalyst is more complex but energetically more favourable.
31. Which of the following is true for an active intermediate?
-formed by interaction with other molecules
32. Which of the following interprets the result for Weisz Prater Parameter?
-If Cwp much greater than 1 then internal diffusion limits the reaction
33. This factor indicates relative importance of diffusion and reaction limitations.
-Internal Effectiveness Factor
34. If very high feed temperature is used for a reaction that is reversible and exothermic, then
equilibrium conversion is
-minimum (or close to zero, slide 31 steady state nonisothermal ppt)
35. This diffusion system occurs when mean free path of molecule is greater than the catalyst
pore diameter.
-Knudsen diffusion
36. Catalyst deactivation may be caused by:
37. This gives insights in choosing reactors and reaction schemes that will help maximize
-Reaction Yield? (instantaneous selectivity dapat)

38. Sum of the net internal energy carried into or out of the system by mass flow and flow
39. Effectiveness factor can be greater than 1 if
-Reaction is exothermic and non-isothermal
40. Internal diffusion is rate limiting if Thiele modulus is
41. For gas phase external mass transfer limited reactions, the overall reaction rate
-Increases approximately linearly with temperature
42. If diffusivity is finite, the only way the flux can be zero is when
-No mass transfer at the boundary
43. If molecular diffusion is small relative to bulk flow then
-Only molar flowrate is considered relative to the axial direction
44. It is the spontaneous mixing of atoms or molecules by random thermal motion.
45. Which of the following is not part of the sequence of steps for catalysis?
-chemical adsorption
46. Which enzyme substrate interaction models results to distortion of bonds to
accommodate attachment?
-induced fit
47. This material increases the activity of the catalysts even in small amounts.
48. Which of the following describes molecular adsorption?
-two adjacent vacant sites are required
49. The pores in the pellet can be represented as a function of
50. This is a measure of the attraction of the enzymes for its substrate.
51. The overall effectiveness factor helps in
-Designing packed beds in terms of diffusion, flow and reactions
52. Enthalpies in a given system volume are evaluated at the temperature of the
53. For dilute concentrations, bulk motion flux is negligible because
-Both mole fraction of solute and convective motion is small
54. Diffusion through external boundary layer is rate limiting if and only if
-The reactant diffuses to the surface slowly due to low velocity.
55. Which of the following is true for Michaelis constant?
-The larger its value, the higher is the substrate concentration necessary to reach half the
maximum rate
56. Which of the following shows a mesoscopic scale of catalysis?
57. Which of the following will maximize the desired product if its reaction order is greater
than that of the undesired product and reaction is carried out in gas phase?
-Run without inerts and high pressure
58. Which of the following is exothermic in a catalytic reaction?

59. Which of the following shows an important point of the energy diagram between
catalytic and non-catalytic reactions?
-The activation energy of catalytic reaction is significantly smaller
60. The diffusivity always increases with
-Increasing Temperature for both gas and liquid systems