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INDIA
Jr. IIT-IZ3-SPARK
Time : 3:00
JEE MAIN
2013 model
Dt:10-01-15
Marks : 360
IMPORTANT INSTRUCTIONS:
1.
2.
3.
4.
The test Booklet consists of 90 questions. The maximum marks are 360.
There are three parts in the question paper A, B, C consisting of Physics, Chemistry and Mathematics having
30 questions in each part of equal weightage. Each question is allotted 4 (four) marks for each correct
response.
Candidates will be awarded marks as stated above in instruction No. 5 for correct response of each question
1/4 (one fourth) marks will be deducted for indicating incorrect response of each question. No deduction from
the total score will be made if no response is indicated for an item in the answer sheet.
There is only one correct response for each question. Filling up more than one response in each question will
be treated as wrong response and marks for wrong response will be deducted accordingly as per instruction 6
above.
PHYSICS
1)
2)
3)
k 1 3k 2
4
3k 1 k 2
4
C)
8k 1 k 2
9
D)
k 1 8k 2
9
An experiment measures quantities x,y,z and then t is calculated from the data as
t
xy 2
. If percentage errors in x, y and z are respectively 1%, 3%, 2%, then percentage
z3
error in t is:
A) 10%
4)
B)
B) 4%
C) 7%
D) 13%
10-01-15_Jr.IIT-IZ3-SPARK_JEE-Main 2013
5)
6)
oscillations with the stop watch of least count T and he commits a human error of 0.1
sec. For which of the following data, the measurement of g will be most accurate?
A) L 0.5m, T 0.1s, n 20
B) L 0.5s, T 0.1m, n 50
C) L 0.5m, T 0.01s, n 20
D) L 0.1m, T 0.05s, n 50
7)
To estimate g (from g 42
L
), error in measurement of L is 2% and error in
T2
The dimensions of a rectangular block measured with a vernier calipers having least
count of 0.1 mm is 5 mm 10 mm 5 mm. The maximum percentage error in
measurement of volume of the block is
A) 5%
B) 10%
C) 15%
D) 20%
9)
Four rods of the same material with different lengths (L), radii (r) and temperature
difference across their ends () are shown below:
a) L = 50 cm, r = 2 cm, = 100oC
b) L = 100 cm, r = 3 cm, = 60oC
c) L = 80 cm, r = 4 cm, = 50oC
d) L = 75 cm, r = 5 cm, = 80oC
The decreasing order of the rates of heat conducted is
A) d, c, a, b
B) a, b, c, d
C) d, c, b, a
D) b, a, c, d
10)
Two resistor R 1 24 0.5 and R 2 8 0.3 are joined in series. The equivalent
resistance is (use equivalent resistance R R1 R2 ).
A) 32 0.33
B) 32 0.8
C) 32 0.2
D) 32 0.5
11)
A wire has a mass (0.3 0.003)g, radius (0.5 0.005) mm and length (6 0.06) cm.
The maximum percentage error in the measurement of its density is
A) 1%
B) 2 %
C) 3%
D) 4%
12)
A Carnot engine whose efficiency is 40% receives heat at 500K. If the efficiency is to
be 50%, the source temperature for the same sink temperature is
A) 900K
B) 600K
C) 700K
D) 800K
10-01-15_Jr.IIT-IZ3-SPARK_JEE-Main 2013
13)
Using screw gauge, the observation of the diameter of a wire are 1.324, 1.326, 1.334,
1.336 cm respectively. The percentage of error is.
A) 0.1%
B) 0.2%
C) 0.3%
D) 0.4%
14)
A body of surface area 5 cm2 and temperature 727oC emits 300 J of energy per minute.
Then its emissivity will be ( = 5.5510-8 Wm-2K-4)
A) 1
B) 0.81
C) 0.18
D) 0.48
15)
16)
During severe winter at the low temperature zones of the world, the superficial parts of
the lakes are frozen, leaving water below. The freezing at the bottom is prevented
because
A) the conductivity of ice is low
B) the water has large latent heat of fusion
C) the water has large specific heat
D) both options 1 and 2 are correct
17)
The cooling curves 1 and 2 of two liquids of same mass, specific heats S 1 and S2, same
initial temperatures are cooled under identical conditions are as shown in the graph.
Then the most appropriate option is
A) S1 = S2
B) S1 < S2
C) S1 > S2
D) S1 S2
18)
The temperature of a black body corresponding to which it emits energy at the rate of 1
W/cm2 will be nearly ( = 5.710-8 Wm-2K-4)
A) 350 K
B) 1000 K
C) 250 K
D) 650 K
19)
A tungsten filament lamp of power 625 W is at 2227oC. The emissivity of the filament
10-01-15_Jr.IIT-IZ3-SPARK_JEE-Main 2013
A body cools from 60oC to 50oC in 12 minutes and from 50oC to 40oC in 24 minutes.
What further time it would take to cool from 40oC to 38oC?
A) 9.6 min
B) 4.8 min
C) 2.4 min
D) 12 min
21)
A 2 cm thick brass plate (K = 105 W/Km) is sealed to a glass sheet (K = 0.8 W/Km)
and both have the same area. The exposed face of the brass plate is at 80 oC, while
exposed face of the glass is at 20oC. If the interface is at 65oC, the thickness of glass
sheet is
A) 0.46 mm
B) 0.23 mm
C) 0.92 mm
D) 1.84 mm
22)
23)
If rate of loss of heat (dQ/dt) of the two bodies of different masses are same, then the
A) their rates of fall of temperature (dT/dt) will be same
B) rate of fall of temperature of the body having large thermal capacity will be large
C) rate of fall of temperature of the body having large thermal capacity will be small
D) The rate of fall of temperature depends only on ratio of masses of the bodies.
24) A black body radiates power P and maximum energy is radiated by it around a
wavelengtho. The temperature of the black body is now changed such that it radiates
maximum energy around the wavelength 3o/4. The power radiated by it now is
A) 256P/81
B) 16P/9
C) 64P/27
D) 4P/3
25)
26)
27)
An ideal gas heat engine operates in carnot cycle between 2270 C and 1270 C. It absorbs
6.0 x 104 cal at higher temperature. The amount of heat converted into work is equal to
A) 4.8 x 104 cal B) 3.5 x 104 cal
C) 1.5 x 104 cal
D) 1.2 x 104 cal
A Carnot engine operating between temperatures T1 and T2 has efficiency 1 /6. When
28)
10-01-15_Jr.IIT-IZ3-SPARK_JEE-Main 2013
the sink temperature (T2) is lowered by 62 K, its efficiency increases to 1 /3. Then T1
and T2 are respectively
A) 372K and 310 K
B) 372K and 330 K
C) 330K and 268 K
D) 310K and 248 K
29)
Two cubes of sides 2 cm and 3 cm made of same material are at same temperature. The
ratio of amounts of heat radiated per second by them is
A) 9 : 4
B) 8 : 27
C) 4 : 9
D) 27 : 8
30)
Three metal rods of same length and same cross-sectional area are connected in
parallel. If their conductivities are 30 Wm-1K-1, 90 Wm-1K-1 and 180 Wm-1K-1
respectively, the effective conductivity of the combination is
A) 150 Wm-1K-1 B) 100 Wm-1K-1
C) 300 Wm-1K-1 D) 20/3 Wm-1K-1
CHEMISTRY
31.
d[A]
d[B]
d[C]
xA + yB zC. If
=
= 1.5
= then x,y and z are :
dt
(A) 1,1,1
32.
dt
dt
(B) 3,2,3
(C) 3,3,2
(D) 2,2,3
A reaction follows the given concentration (M)time graph. The rate for this reaction at
20 seconds will be:
0 .5
0 .4
0 .3
0 .2
0 .1
0
20
40
60 80 100
T im e /s e c o n d
(A) 4 103 M s1
(C) 2 102 M s1
33.
(B) 8 102 M s1
(D) 7 103 M s1
aA + bB
Product, dx/dt = k [A]a [B]b . If concentration of A is doubled, rate
becomes four times. If concentration of B is made four times, rate is doubled. What is
the relation between rate of disappearance of A and that of B ?
10-01-15_Jr.IIT-IZ3-SPARK_JEE-Main 2013
34.
For a first order reaction, the plot of log C against t (logC vs 't') gives a straight line
with slope equal to :
(A) (k / 2.303)
(B) ( k / 2.303) (C) (ln k / 2.303)
(D) k.
35.
In presence of HCl, sucrose gets hydrolysed into glucose and fructose. The
concentration of sucrose was found to reduce from 0.4 M to 0.2 M in 1 hour and to 0.1
M in a total of 2 hours. The order of the reaction is :
(A) zero
(B) one
(C) two
(D) None of these
36.
K1
K2
In the first order reactions (A)
Product, (B)
Product, the ratio k1 /k2 if
90% of (A) has been reacted in time 't' while 99% of (B) has been reacted in time 2t is :
(A) 1
(B) 2
(C) 1/2
(D) None of these
37.
In the reaction,
P QR S
The time taken for 75% reaction of P is twice the time taken for 50% reaction of P. The
concentration of Q varies with reaction time as shown in the figure. The overall order of
the reaction is
(A)2
(B) 3
(C) 0
(D) 1
A + B C is
[B]0
initial rate
0.035
0.10
0.035
0.80
0.070
0.10
0.070
0.80
(B) r = k [A]3
(C) r = k [A] [B]4 (D) r = k [A]2 [B]2
38.
39.
10-01-15_Jr.IIT-IZ3-SPARK_JEE-Main 2013
40.
In the reaction NH4NO2 (aq.) N2 (g) + 2 H2O (l), the volume of N2 after 20 min
and after a long time are 40 ml and 70 ml respectively. The value of rate constant is :
(A) (1/20) In (7/4) min1
(B) (2.303 /1200) log (7/3) sec1
(C) (1/20) log (7/3) min1
(D) (2.303 / 20) log (11/7) min1
41.
42.
The first order rate constant k is related to temp. as log k = 15.0 (10 6 /T) Which of the
following pair of value is correct ?
(A) A = 1015 and E = 1.9 104 KJ
(B) A = 1015 and E = 40 KJ
(C) A = 1015 and E = 40 KJ
(D) A = 1015 and E = 1.9 104 KJ
43.
(a x )
( a x ) 1
(A)
44.
(B)
p
( a x ) 1
p
(C)
( a x ) 1
(D)
45.
(A)
(C)
46.
10-01-15_Jr.IIT-IZ3-SPARK_JEE-Main 2013
dx
dt
C + D.
= k1 [A] [B] k2[C] [D] in which set of the concentration reaction ceases?
(B)
(D)
[A] [B]
[C] [D]
0.4 M 0.25 M 0.2 M
0.5 M
0.2 M 0.2 M 0.4 M
0.2 M
The rate constant for two parallel reactions were found to be 1.0 102dm3 mol-1 s1
and 3.0 102 dm3 mol1 s1. If the corresponding energies of activation of the parallel
reactions are 60.0 kJ mol1 and 70.0 kJ mol1 respectively, what is the apparent
overall energy of activation ?
(A) 130.0 kJ mol1
(B) 67.5 kJ mol1
(C) 100.0 kJ mol1
(D) 65.0 kJ mol1
48.
At the point of intersection of two curves as shown, the concentration of B is given for
the reaction A nB as
(A)
nA0
2
(B)
10-01-15_Jr.IIT-IZ3-SPARK_JEE-Main 2013
A0
n 1
(C)
nA0
n 1
(D)
n 1
. A0
n 1
49.
The inversion of cane sugar proceeds with half life of 50 minute at pH = 5 for any
concentration of sugar. However if pH = 6, the half life changes to 500 minute of any
concentration of sugar . The rate law expression for sugar inversion can be written as :
(A) r = K [sugar]2 [H+]0
(B) r = K [sugar]1 [H+]0
(C) r = K [sugar]1 [H+]1
(D) r = K [sugar]0 [H+]0
50.
Two I-order reactions have half-lives in the ratio 3 : 2. Calculate the ratio of time
intervals t1 : t2. Where t1 is the time period for 25% completion of the first reaction and
t2, for 75% completion of the second reaction.
(A) 0.311 : 1
(B) 0.420 : 1
(C) 0.273 : 1
(D) 0.199 : 1
51.
(A) 3.3
52.
(B) 6.3
(C) 3.6
[B]t 16
[C]t 9
(D) None
10-01-15_Jr.IIT-IZ3-SPARK_JEE-Main 2013
If initially, total pressure was 800 mm of Hg and after 10 minutes it is found to be 650
mm of Hg. What is half-life of A ? (Assume only A is present initially)
(A) 10 mins
(B) 5 mins
(C) 7.5 mins
(D) 15 mins
53.
54.
55.
(D)
1
6
A reaction takes place in three steps ; the rate constants are k 1, k2 and k3.The overall
k1 k 3
rate constant k = k . If energies of activation are 40 , 30 and 20 kJ, the overall energy
2
of activation is (assuming A to be constant for all )
(A) 10
(B) 15
(C) 30
(D) 60
56.
dA
=
dt
(D) 13/12
57.
In a certain reaction, 10% of the reactant decomposes in one hour, 20 % in two hours,
30% in three hours and so on the dimensions of the rate constant is :
(A) hour1
(B) mole litre1 sec1 (C) litre mole1 sec1 (D) mole sec1
58.
The rate of a chemical reaction doubles for every 10 C rise of temperature. If the
temperature is raised by 50 C, the rate of the reaction increases by about :
(A) 10 times
(B) 24 times
(C) 32 times
(D) 64 times
59.
1.0
0.75
0.40
0.10
0.0
0.05
0.12
0.18
60.
10-01-15_Jr.IIT-IZ3-SPARK_JEE-Main 2013
(C) 0
(D) 1
time (min) :
0
30
angle (degree) :
30
20
15
Identify the incorrect statement (log 2 = 0.3, log 3 = 0.48, log 7 = 0.84)
(A) The half life of the reaction is 82.7 min
(B) The solution is optically inactive at 131 min.
(C) The equimolar mixture of the products is dextrorotatory
(D)
The angle would be 7.5 at half time
MATHEMATICS
61.
An investigator interviewed 100 students to determine their preferences for the three
drinks milk(M), coffee(c), and tea(T). He reported the following : 10 students had all
the three drinks M,C,T ; 20 had M and C only ; 30 had C and T ; 25 had M and T ;
12 had M only ;
5 had C only ; 8 had T only . Find how many did not take any of the three drinks
A) 20
B) 3
C) 36
D) 42
62.
63.
Let W denotes the words in the English dictionary .Define the relation R by R ={(x,y)
W x W:the words x and y have at least one letter in common }, then R is
A) reflexive, symmetric and transitive
B) reflexive, not symmetric and transitive
C) not reflexive, symmetric and transitive D) reflexive, symmetric and not transitive
64.
Let N denote the set of all natural numbers and R be the relation on N x N defined by
(a,b) R (c,d) if ad (b+c)=bc(a+d), then R is
A) symmetric only
B) reflexive only
10-01-15_Jr.IIT-IZ3-SPARK_JEE-Main 2013
C) transitive only
65.
D) an equivalence relation
Let R be the real line . Consider the following subsets of the plane R x R :
S={(x,y) : y=x+1 and 0<x<2} ; T={(x,y) : x-y is an integer }. Which one of the
following is true?
A) Both S and T are equivalence relations on R
B) S is an equivalence relation on R
but T is not
68.
Given p( x) x 4 ax3 bx 2 cx d such that x=0 is the only real root of p '( x) 0
If p(-1)<p(1), then in the interval [ -1,1]
A) P(-1) is not minimum but p(1) is the maximum of p
B) P(-1) ) is minimum but p(1) is not the maximum of p
C) neither P(-1) is minimum nor p(1) is the maximum of p
D) p(-1) is minimum and p(1) is the maximum of p
69.
70.
2 3
8
B)
3 2
5
C)
3
4
D)
p2
2
B)
p2
2(2 2) 2
C) P 2
D) 2 p 2
3 2
8
71.
10-01-15_Jr.IIT-IZ3-SPARK_JEE-Main 2013
A Triangular park is enclosed on two sides by a fence and on the third side by a straight
river Bank. The two sides having fence are of same length x. The maximum area
enclosed by the
Park is
A)
1 2
x
2
B) x 2
C)
3 2
x
2
D)
x3
8
72.
A cylindrical gas container is closed at the top and open at the bottom . If the Iron plate
of the top is 5/4 times as thick as the plate forming the cylindrical sides, the ratio of the
radius to the height of the cylinder using minimum material for the same capacity is
A) 4
B) 5
C) 4/5
D) 20
73.
1
cubic meters which is open at the top is to be
7
manufactured from a sheet of metal . The dimensions of the vessel so that the amount of
sheet used in manufacturing it is least are
A) radius = height = 4 mts
B) radius = height = 5 mts
C) radius = height = 2 mts
D) radius = height = 3 mts
a2 4 3
x 3 x sin 3 . Then for f ( x) to be a decreasing function in R, possible
a2 2
74.
Let f ( x)
75.
76.
c3
2ab
c3
A)
2ab
77.
A) 1
78.
79.
B) 2
n
2
C) 1 2
D) none of these
A)
B)
C)
D)
6
4
3
2
80.
c3
D)
ab
c3
B)
C)
ab
1
1
B) a7 or a8
n
is
n 100
C) a4
2
27 cos 2 x.81sin 2 x
B) -5
C) 1/5
D) a10
is
D) none of these
10-01-15_Jr.IIT-IZ3-SPARK_JEE-Main 2013
81.
A bird is sitting on the top of a vertical pole 20m high and its elevation from a point O
on the ground is 450 . It flies horizontally straight away from the point O . After one
second , the elevation of the bird from O is reduced to 300 . Then the speed (in m/s) of
the bird is
A) 20 2
B) 20( 3 1)
C) 40( 2 1)
D) 40( 3 2)
82.
In a triangular plot ABC with BC = 7m, CA = 8m and AB = 9m. A lamp post is situated
at the middle point E of the side AC and subtends as angle Tan 1 3 at the point B, the
height of the lamp post is
A) 21m
B) 24m
C) 27m
D) Cant be determine
83.
A tower AB leans towards west making an angle with the vertical . The angular
elevation of B, the top most point of the tower , is , as observed from a point C
due east of A at a distance d from A. If the angular elevation of B from a point due east
of C is at a distance 2d from C is , then
A) 2 tan 2 cot cot
B) 2 tan 3cot cot
C) 2 tan cot cot
D) None
Three poles of heights h1 , h2 and h3 at the vertices A,B and C of a ABC subtend angles
, and respectively at the circumcentre of the triangle . If cot , cot and cot
are in A.P. then h1 , h2 , h3 are in
A) A.P.
B) G.P.
C)H.P.
D)none of these
84.
85.
The angle of elevation of the top of a tower from a point A due south of it , is Tan 1 6
and that from B due west of it, is Tan 1 7.5 . If h is the height of the tower , then AB h ,
where 2
A)
21
700
B)
42
1300
C)
41
900
D) none of these
86.
A ladder leans against a wall at an angle to the horizontal . Its foot is pulled away
through a distance a1 so that it slides a distance b1 down the wall and rests inclined at
an angle with the horizontal. Its foot is further pulled away through a2 , so that it
slides a further distance b2 , down the wall and is now inclined at an angle . If
a1a2 b1b2 , then
A) is greater than
B) is equal to
C) is less than
D) nothing can be said about the sum
87.
AB is a vertical pole with B at the ground level and A at the top .A man finds that the
angle of elevation of the point A from a certain point C on the ground is 600 . He moves
away from the pole along the line BC to a point D such that CD = 7m. From D the
angle of elevation of the point A is 450 . Then the height of the pole is
A)
88.
7 3
2
3 1 m
B)
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7 3
2
3 1 m
7 3
C) 2 3 1 m
7 3
D) 2 3 1 m
1 1
A vertical pole subtends an angle Tan at a point P on the ground . If the angles
2
subtended by the upper half and the lower half of the pole at P are respectively and ,
then (tan , tan )
1 1
A) ,
4 5
1 2
B) ,
5 9
2 1
C) ,
9 4
1 2
D) ,
4 9
89.
A tower stands at the center of a circular park . A and B are two points on the boundary
of the park such that AB(=a) subtends an angle of 600 at the foot of the tower , and
the angle of elevation of the top of the tower from A or B is 300 . The height of the
tower is
A) 2a / 3
B) 2a 3
C) a / 3
D) a 3
90.
( p 2 q 2 )sin
B)
( p cos q sin ) 2
( p 2 q 2 ) sin
C)
p cos q sin
p 2 q 2 cos
D)
p cos q sin
Paper Setters
Mobile No.
MATHS
V SRINIVASA RAO
7731031500
PHYSICS
V N M PRASAD
9440263456
CHEMISTRY
J MAHESH KUMAR
9393707007