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Sec:
PTM-16
Dt: 27-12-
IMPORTANT INSTRUCTIONS:
1.
Immediately fill in the particulars on this page of the Test Booklet with Blue/Black Ball
Point Pen. Use of
pencil is strictly prohibited.
2.
3.
The Test Booklet consists of 90 questions. The maximum marks are 360.
4.
There are three parts in the question paper A, B, C consisting of Chemistry, Physics and
Mathematics having 30 questions in each part of equal weightage. Each question is
allotted 4 (four) marks for correct response.
5.
Candidates will be awarded marks as stated above in instruction No. 4 for correct
response of each question. (1/4) (one fourth) marks will be deducted for indicating
incorrect response of each question. No
There is only one correct response for each question. Filling up more than one response
in any question
16
will be treated as wrong response and marks for wrong response will be deducted
accordingly as per
instruction 5 above.
Sr.IIT-Z (IZ)_JEE-MAIN
Page 2
16
CHEMISTRY
1.
1)
2.
2)
3)
4)
How many oxime(s) formed if the smallest ketone and its homologues ketone are
reacted with NH2OH.HCl
1) 1
2) 2
3) 3
4) 4
OH
O
H
2)H3O
OH
OH
3.
CH3
One mole
Sr.IIT-Z (IZ)_JEE-MAIN
2) 2
3) 3
4) 4
Page 3
16
4.
O
CH3 CH C CH3
1) CF3 C CF3
5.
Hydrolysis product of
1) HO
3) HO
6.
CH3 C CH3
2)
3)
CI
4)
H O H
C6H5CC6H5
is:
OH
OH
2) O
4) HO
CH3 OH
O
O
1)
Sr.IIT-Z (IZ)_JEE-MAIN
2)
3)
4)
C6H5CC6H5
Page 4
16
7.
H3C
OH
1) H3C
O
HO
OH
OH
2) H3C
OH
CH3
8.
3)
4)
End product in the following sequence of reaction is
1)
Sr.IIT-Z (IZ)_JEE-MAIN
2)
3)
4)
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16
9.
1) CH3 CCH2CH2CH2CH2CH
O
3)
10.
CHCH2CH2CH2CH2CH2CH
2)
CHCH2CH2CH2CH2CH
CH3CCH2CH2CH2CCH3
4)
CH 3CH 2CHO
1) dil2). NaOH
1)
CH3CH2CH
CHCH2CHO
2)
CH3CH2CH=CCHO
CH3
CH3CH2CHCH2CH2CHO
3)
OH
Sr.IIT-Z (IZ)_JEE-MAIN
CH3CH2CHCHCHO
4)
OH
Page 6
16
11.
X and Y are respectively
D
O
D
O-
, D
1)
C
O-
, D
2)
O-
, D
OH
O-
, D
4)
OH
3)
OH
13.
12.
OH
OH
|
CH
C
CN
A.
3
|
CH 3
OH
|
CH
C
CN
B.
3
|
H
H
|
2) R C O
|
O
3) RCOOH
K1
O
||
CH 3 C CH 3 HCN
K2
O
||
CH 3 C H HCN
RC O
|
4)
H
Page 7
16
1) K1 K 2
2) K1 K 2
3) K 2 K1
CH 3 C C CH 3
14.
, the sum, x + y is
1) 2
15.
16.
17.
18.
19.
4) unpredictable
2) 3
3) 4
4) 5
Sr.IIT-Z (IZ)_JEE-MAIN
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16
CN
COCH3
COOH
COCH3
1)
20.
21.
22.
2)
3)
4)
3) sodium stearate
OH
in all cases
1)
in all cases
2)
OH
in all cases
3)
A;
4)
23.
OH
OH
B;
C;
Which of the following reagents is best reagent used for the conversion shown below?
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16
24.
1) 1.NaBH 4 / 2. D3O
2) 1.NaBD4 / 2. H 3O
3) 1.LiAlH 4 / 2. D3O
4) 1.LiAlH 4 / 2. H 3O
CH 3 C CH
HgSO4
dil . H 2 SO4
CH 3 C CH
1 BH 3 .THF
2 H 2O2 / HO
A
B
2) NaOI
1) CH3OCCH2CH2CH2CH2OH
O
26.
27.
28.
29.
4) NaHSO3
3) Lucas reagent
2) CH3CCH2CH2CH2CH2OH
O
3) HCCH2CH2CH2CH2OH
4) HCCH2CH2CH2CH
The substance used in the birth control pills is
1) Tetracycline
2) Sulphadiazine 3)Novestrol
4) Penicillin
Acetylation of the two -OH groups of morphine with acetic anhydride gives
1) codeine
2) heroin
3) cocaine
4) quinine
The drug used as an anti depressant is
1) luminal
2) phenalzine
3) mescaline
4) sulphadiazine
The IUPAC name of the insectiside lindane is
1) dichlorodiphenyltrichloroethane 2) benzene hexachloride
3) hexachloran
4) 1,2,3,4,5,6-hexachlorocyclohexane
Sr.IIT-Z (IZ)_JEE-MAIN
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30.
Penicillin G contains
1) phenyl group 2) Benzyl group
3) Benzo group
4) Benzal group
PHYSICS
31.
32.
What is the ratio of de Broglie wave lengths of electron in the second & third Bohrs
orbits in a hydrogen atom?
1) 2/3
2) 3/2
3) 4/3
4) 3/4
The energy of a hydrogen like atom (or ion) in its ground state is -122.4 eV. It may be
1) Hydrogen atom 2) He
3) Li
4) Be3
Maximum kinetic energy of a photoelectron is E when the wavelength of incident light
is . If energy becomes four times when wavelength is reduced to one-third, then
work function of the metal is
2
33.
1)
34.
36.
37.
2)
5f
3
2)
hc
3
3)
51 f
31
3)
hc
4)
9f
25
4)
hc
2
If the frequency of k X-ray emitted from the element with atomic number 31 is f ,
then the frequency of k X-ray emitted from the element with atomic number 51
would be (According to Moosleys law)
1)
35.
3hc
25 f
9
A potential of 10,000 V is applied across an X-ray tube. Find the ratio of de-Broglie
wavelength associated with incident electrons to the minimum wavelength associated
with X-rays
(Given e/m= 1.8 X 1011 C/kg for electrons)
1)10
2) 20
3) 1/10
4) 1/20
Photoelectric work function of a metal is 1 eV. Light of wavelength 3000A0 falls on
it. The photoelectron comes out with a maximum velocity of (Approximately)
1) 10m/s
2) 103 m/s
3) 104 m/s
4) 106 m/s
An electron revolves round a nucleus of atomic number Z. If 32.4eV of energy is
required to excite an electron from n=3 state to n=4state, then the value of Z is
1) 5
2) 6
3) 4
4)7
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38.
An orbital electron in the ground state of hydrogen has magnetic moment 1 . This
orbital electron is excited to 3rd excited state by some energy transfer to the hydrogen
atom. The new magnetic moment of the electron is 2 , then
1) 1 42
2) 21 2
3) 161 2
4) 41 2
39.
40.
2) 1/8
42.
4) 8/1
A radioactive isotope is being produced at a constant rate A. The isotope has a half-life
T. Initially there are no nuclei, after a time t>>T, the number of nuclei becomes
constant. The value of this constant is
1) AT
41.
3) 4/1
2)
A
ln 2
T
AT
3) AT ln 2
4) ln 2
A bone containing 200g carbon -14 has a decay rate of 375 decay/min. calculate
the time that has elapsed since the death of the living one. Given the rate of decay for
the living organism is equal to 15 decay per min per gram of carbon and half-life
carbon -14 = 5730 years.
1) 27190 years
2) 1190 years
3) 17190 years
4) none of these
Two radioactive samples of different elements (half-lives t1 and t2 respectively) have
same number of nuclei at t=0. The time after which their activities are same is
t1t2
t2
1) 0.693 t t ln t
2
1
1
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t1t2
t2
2) 0.693 ln t
1
t1t2
t2
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16
43.
A
X 90
Y .What fraction of the total energy released in the decay will be the
90
92
2)
228
232
3)
228
232
4)
1
2
45.
2 A1
A1
A2
A2
1) ln 2 ln A
2) T ln A
3) ln 2 ln 2 A
4) T ln 2 A
2
2
1
1
In a nucleus if F1 is the net force between two protons, F2 is the net force between
two neutrons and F3 is the net force between a proton and a neutron at a separation of
46.
B C 2 then
47.
1
e
Sr.IIT-Z (IZ)_JEE-MAIN
2) 1
1
e
3)
0.693
e
4) 0.693 1
e
Page 13
16
48.
49.
1
e
2)
1
1 e
3) 1
1
e
4)
1
1
e
A proton has kinetic energy E=100 keV which is equal to that of a photon. The
wavelength of photon is 2 and the De-broglie wave length of proton is 1 . The ratio of
2 / 1 is proportional to
1) E 2
2) E 1/ 2
50.
3) E 1
4) E1/ 2
In a photoelectric experiment, anode potential with respect to cathode is plotted
against plate current. Select the correct statement from the following (Assuming
intensity of incident radiation is varied at constant frequency)
1) A and B will have different intensities while B and C will have different frequencies
2) B and C will have different intensities While A and C will have Different
frequencies
3) A and B will have different intensities while A and C will have equal frequencies
4) A and B will have equal intensities while B and C will have different frequencies
Sr.IIT-Z (IZ)_JEE-MAIN
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51.
52.
2) 1.0 X 1017 kg ms 1
3) 0.3 X 1017 kg ms 1
4) 9.0 X 1017 kg ms 1
k Wavelength emitted by an atom, of atomic number Z=11 is . Find the atomic
number for an atom that emits k radiation with wavelength 4 (According to
53.
Moosleys law)
1) Z=6
2) Z=4
3) Z=11
4) Z=44
The largest wavelength in the ultraviolet region of the hydrogen spectrum is 122 nm.
The smallest wavelength in the infrared region of the hydrogen spectrum (to the
54.
nearest integer) is
1) 802 nm
2) 823 nm
3) 1882 nm
4) 1648 nm
Electrons with de Broglie wavelength fall on the target in an X-ray tube. The cut-0ff
wavelength of the emitted X-rays is
2mc 2
1) 0
h
55.
2h
2) 0
mc
2m 2c 2 3
3) 0
h2
4) 0
Which one of the following statement is wrong in the context of x-rays generated from
X-ray tube?
1) Wavelength of characteristic X-rays decreases when the atomic number of the target
increases.
Sr.IIT-Z (IZ)_JEE-MAIN
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16
2) Cut-off wavelength of the continuous X-rays depends on the atomic number of the
target.
3) Intensity of the characteristic X-rays depends on the electric power given to the Xray tube.
4) Cut-off wavelength of the continuous X-rays depends on the energy of the electrons
56.
57.
Ra
2)
3
4
2) E
92
3) E
236
4) E
60.
3)
4)
1
4
In the options given below, let E denote the rest mass energy of a nucleus and n a
59.
1
2
92
53
140
56
U E
Ba
E
39
94 Kr
36
2E n
236
92
236
92
137
53
U E
140
56
U E
97
39
94
36
Ba
E
2E n
Kr
2E n
Sr.IIT-Z (IZ)_JEE-MAIN
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16
nuclei as a function of time which of the following figures best represents the form of
this plot?
1)
2)
3)
4)
MATHEMATICS
61.
Box A contains 3 red and 2 black balls. Box B contains 2 red and 3 black balls. One
ball is drawn at random from Box A and placed in Box b. Then one ball is drawn at
random from the Box B and placed in A. The probability that the composition of balls
in the two boxes remain unaltered is
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16
9
4
17
16
2)
3)
4)
30
15
30
30
B
A
If p p B , the relationship between p and p A (is)
A
B
1
A
A
1) p p A
2) p p A
2
B
B
A
3) p p A
4) Cannot be decided
B
1)
62.
63.
64.
1
5
2)
2
5
3)
3
5
4)
4
5
A letter is taken out at random from the word ASSISTANT and another from
STATISTICS. The probability that they are the same letters is
1)
65.
13
90
2)
17
90
3)
19
90
4)
15
90
A has 3 tickets of lottery containing 3 prizes and 9 blanks. B has 2 tickets of another
lottery containing 2 prizes and 6 blanks. The ratio of their chances of success is
32 15
32 13
34 13
34 15
:
2) :
3) :
4) :
55 28
55 28
55 28
55 28
Out of 2n 1 tickets consecutively numbered, three are drawn at random. The chance
1)
66.
n2 1
Sr.IIT-Z (IZ)_JEE-MAIN
2)
3n
n2 1
3)
3n
4n 2 1
4)
3n
4n 2n 1
2
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16
67.
If A, B and C are three events of a random experiment such that P(A) = 0.3, P(B) =
0.4, P(C) = 0.8,
P A B 0.12, P A C 0.28,
68.
1) [0.32,0.52]
2) [0.23,0.48]
3) [0.19,0.44]
4) [0.21,0.19]
A and B alternatively throw a pair of symmetrical dice. A wins if he throws 6 before B
throws 7 and B wins if he throws 7 before A throws 6. If A begins, The probability of
his winning is
1)
69.
11
36
2)
30
61
3)
31
61
4)
1
36
A bag contains 2n 1 coins. It is known that n of these have a head on both the
sides, whereas the remaining n 1 coins are fair. A coin is picked up at random from
the bag and tossed. If the probability that the toss result is a head is 31/42, then value
70.
of n is
1) 10
2) 8
3) 6
4) 25
The chance that doctor A will diagonise disease X correctly is 60%. The chance that a
patient will die by his treatment after correct diagnosis is 40% and the chance of death
after wrong diagnosis is 70%. A patient of doctor A who had disease X died. The
probability that his disease was diagonised correctly is
1)5/3
2) 6/13
3) 2/13
Sr.IIT-Z (IZ)_JEE-MAIN
4) 7/13
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16
71.
If the integers m and n are chosen at random from 1 to 100 then the probability that
a number of the from 7m +7n is divisible by 5 is
1)
1
5
2)
1
7
1
4
3)
4)
1
49
72.
A natural number x is chosen at random from the first 1000 natural numbers. If [.]
73.
x x
74.
If P B
3
1
,P A BC
4
3
1) 1/12
75.
If
1 3p
3
2) 1/6
,
1 p
4
and
1 2p
2
and
P A BC
1
,
3
31x
4) 1
10n
then P B C is
3) 1/15
4) 1/9
1
1
1 1
2) 0,
3) , 1
4) 3 , 2
2
3
In a test, an examinee either guesses or copies or knows the answer to a multiple
1) [0,1]
76.
choice question with four choices. The probability that he makes a guess is
1
and the
6
1
8
probability of his answer is correct given that he copied it is . The probability that he
knows the answer to the question given that correctly answered it is
Sr.IIT-Z (IZ)_JEE-MAIN
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16
1)
77.
24
2)
24
29
3)
23
4)
49
11
24
2)
7
20
3)
9
20
y 16 x 8 a 5 x 7 a 5
2
11
20
y
R
x
Two numbers
are selected such that x 0, 4 and y 0, 4 . Find the probability
,
1)
78.
23
4)
2)
1
3
3)
6
7
4)
4
5
A lot contains 20 articles. The probability that the lot contains exactly 2 defective
articles is 0.4 and the probability that it contains exactly 3 defective articles is 0.6.
Articles are drawn from the lot at random one by one, without replacement and tested
till all defective are found. The probability that the testing procedure ends at the 12th
testing is
1)
80.
1
2
11
1900
2)
44
1900
3)
66
4)
1900
99
1900
n 1
2
m 1
2)
n2
2m 1
3)
n
2
4)
m 1
n3
2m 1
81.
If a and b are chosen randomly from the set consisting of numbers 1, 2, 3,4,5,6 with
82.
a x b x / 2
6 is
replacement. Then the probability that xlit
0
1)1/3
2)1/4
3) 1/9
4) 2/9
Two persons A and B agree to meet at a place between 11 to 12 noon. The first one to
2/ x
arrive waits for 20 minutes and then leave. If the time of their arrival be independent
and at random, the probability that A and B meet
Sr.IIT-Z (IZ)_JEE-MAIN
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16
1)
83.
4
9
2)
5
9
3)
2
9
4)
1
9
100 boys are randomly divided into two groups containing 50 boys each. The
probability that the two tallest boys are in different groups is
1) 50/99
84.
2) 49/99
3) 25/99
4)
1
2
3 white balls 5 black balls are placed in a bag and three men draw a ball in succession
(the balls drawn not being replaced), until a white ball is drawn, the ratio of their
85.
respective chances is
1) 27:18:11
2) 11:18:27
3) 18:11:27
4)18:27:11
A three figure number is formed by the digits 4,5,6,7,8 (no digit being repeated in any
number). The probability that the number formed is divisible by 9 is
1)
86.
1
5
2)
1
10
3)
1
15
4)
1
6
10 pairs of shoes are there in a closet. Four shoes are selected at random. The
probability that there will be at least one pair is
1)
87.
343
2)
10
10
c4
3)
99
323
4)
89
323
88.
224
4
11
2)
7
11
3)
1
22
4)
21
22
A box contains 24 identical balls of which 12 are white and 12 are black. The balls are
drawn at random from the box one at a time with replacement. The probability that a
white ball is drawn for the 4th time on the 7th draw is
Sr.IIT-Z (IZ)_JEE-MAIN
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16
1)
89.
5
64
2)
27
32
3)
5
32
4)
1
2
There are four machines and it is known that exactly two of them are faulty. They are
tested one by one in a random order till both the faculty machines are identified. Then
the probability that only two tests are needed is
1)
90.
1
3
2)
1
6
3)
1
2
4)
1
4
In a shooting test, the probabilities for 3 persons A, B, C to hit the target are
1 2
, and
2 3
3
. If all if them simultaneously aim at the target, The probability for exactly two
4
1
384
Sr.IIT-Z (IZ)_JEE-MAIN
2)
1
12
3)
11
24
4)
13
24
Page 23