1012 Purification, Classification and Nomenclature of Organic compounds

1.

IUPAC name for the compound

Cl

6.

CH 2 CH 3
CC

(a) Spectrophotometer

[CBSE PMT 1998]

H3C

(b) Mass spectrometer

(a) trans 3 iodo, 4-chloro, 3-pentene

(c) Atomic absorption spectrometer

(b) cis 3 chloro, 3-iodo, 2-pentene

(d) Calorimeter

(c) trans 2 chloro, 3-iodo, 2-pentene

7.

(d) cis 3 iodo, 4-chloro, 3-pentene

2.

The IUPAC name of

CH 3 C CH 2 COOH
||
O

the

following

structure

is

[RPMT 1997]

8.

(a) 3-ketobutanoic acid

(b) 2-ketobutanoic acid
(c) 4-ketobutanoic acid
(d) 3-oxopropanoic acid
3.

IUPAC name of the following compound

O
/ \
CH 3 CH 2 CH CH 2 is

9.
[UPSEAT 2001]

(a) C2 H6 N 2

(b) C3 H 4 N

(c)

(d) C9 H12 N 3

C6 H8 N 2

An alkane has a C/H-ratio (by mass) of 5.1428. Its

molecular formula is
[KCET (Engg./Med.) 1999]
(a) C5 H12

(b) C6 H14

(c)

(d) C7 H10

C8 H18

N
H 2 SO4 are used to neutralize ammonia given
5
by 1 g of organic compound. Percentage of nitrogen in the
compound is

58 ml of

(a) 34.3

(b) 82.7

(b) Ethyl methyl ether

(c) 16.2

(d) 21.6

(c) Keto pentanone

CH 3
|
The IUPAC name for CH 3 CHOHCH 2 C OH is
|
CH 3

10.

The IUPAC name of

CH 2CH 3 CH 3
|

CH 3 CH 2 C
|

[AIIMS 1992; MNR 1992; JIPMER 1997]

CH CH 2 (CH 2 )2 CH 3 is

(a) 1, 1-dimethyl-1, 3-butanediol

CH 2CH 3

(b) 2-methyl-2, 4-pentanediol

[CPMT 2000]

(c) 4-methyl-2, 4-pentanediol

(a) 2, 2-diethyl-5-methyldecane
(b) 3, 3-ethyl-5-methyldecane
(c) 3, 3-diethyl-5-methylhexane
(d) 3,3-diethyl-4-methyl octane
5.

In a compound C, H and N atoms are present in 9 : 1 : 35 by

weight. Molecular weight of compound is 108. Molecular
formula of compound is
[AIEEE 2002]

(a) 1, 2-epoxy butane

(d) None of these

4.

Accurate determination of atomic masses is done with the

instrument called as
[Kerala (Med.) 2002]

The emperical formula of compound is CH 2 O . If its

molecular weight is 180. The molecular formula of the
compound is
[AIIMS 1999; CPMT 1999; AFMC 1999; BHU 1999]

(a) C3 H6 O3

(b) C4 H8 O4

(c)

(d) C5 H10 O5

C6 H12 O6

(d) 1, 3, 3-trimethyl-1, 3-propanediol

11.

Choose the correct IUPAC name of the compound

CH 3 CH 3
|
|
CH 3 CH CH C C CH 3
(a) 2, 3-dimethyl-4-hexyne
(b) 4,5-dimethyl-2-hexyne
(c) 5-propyl-2-pentyne
(d) 2-propyl-3-pentyne

Purification, Classification and Nomenclature of Organic compounds

1013

(SET -22)
4

Cl

1.

8.

CH 2 CH 3

Alkanes have General formula Cn H 2n 2

CC

(c)
H3 C

(b) The ratio of C/H in an alkane is 5.1428.

The mass ratio of

Trans 2-chloro, 3-iodo, 2-pentene

2.

6n
5.1428
n1

(a) CH 3 C CH 2 COOH
||

6n = 5.1428n + 5.1428 = 0.8572n + 5.1428

3-keto butanoic acid

3.

(a) CH 3 CH 2 CH CH 2
4

5.1428
6
0.8572

molecular formula C6 H 2n2 C6 H14 .

1, 2 epoxy butane

9.

(c) % of N

CH 2 CH 3
4.

(d) CH 3 CH 2 C
1

3|

CH CH 2 (CH 2 )2 CH 3
4|

CH 2 CH 3 CH 3

3, 3 di ethyl 4-methyl octane.

5.

C
12n
6n
is
or
2n 2
n1
H

(c) Molecular formula = (Emperical formula)n

7.

(c) Molecular weight of compound = 108

CH 3

10.

(b) CH 3 CH CH 2 C OH
5

2|
1CH 3

2-methyl 2, 4 pentane diol

CH 3 CH 3

(CH 2O)6 C6 H12 O6

(b) Atomic masses, determined by the mass spectrometer.

1.4 1 58
16.2 .
1 5

OH

Molecular weight
180
n

6
Emperical formula wt .
30

6.

1.4 Normality of acid Volume of acid

Mass of substance

11.

(b) CH 3 CH CH C C CH 3
6

4, 5-di methyl 2-hexyne

C12 12 6 72
H1 1 8 8

N 14 14 2 28

Total molecular weight = 108

Molecualr formula C6 H8 N 2

***