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The inclusions in molten aluminum were removed using the deep filtration of ceramic foam filters and
ceramic particles with active coatings. The results of tensile tests showed that the elongation of the
filtered tensile specimen S6 increases by 17.93 pct, but the tensile strength does not. The scanning electron microscope (SEM) examination showed that the secondary cracks and dimples in the filtered tensile
specimen S6 were finer and more homogeneous than those in the unfiltered tensile specimen S0. In addition, metallographic examination showed that there were only a few inclusions of approximately
6 mm in diameter in the filtered specimen S6, but more inclusions of approximately 40 mm in diameter were found in the unfiltered specimen S0. The filtration efficiency of the coated ceramic particles
was higher than that of the coated ceramic foam filters. The active coating could effectively capture
the inclusions and dissolve Al2O3 in them during filtration.
I. INTRODUCTION
MOLTEN aluminum is so active that it can easily chemically react with O2 and H2O to form Al2O3 inclusions and
H during melting practice. However, some other inclusions,
such as TiB2, Al4C3, MgAl2O4, etc., form by the electrolytic
process. Under turbulent flow conditions, the inclusions are
distributed unevenly in the molten aluminum. They may
associate with cracks or be the locations of crack initiation
in solidified casting. Aluminum products containing these
inclusions will probably exhibit poor ductility or toughness.
Therefore, the purification of the molten aluminum is one
of the most important processes for improving the quality
of aluminum products.[1,2]
The inclusions of 30 mm in diameter are hardly removed
from the molten aluminum using glass fibrous webs or foam
ceramic filters. Fu et al.[37] purified industrial, commercial
pure aluminum using a mixture of KCl-NaCl and small
quantities of fluoride, carbonate, sulfate, and a fusing agent.
During casting, this mixture forms a layer of molten flux.
When the melted aluminum droplets pass through this
molten flux layer, the inclusions on the surface of the large
aluminum droplets can be removed, but the inclusions inside the large aluminum droplets may not be in contact with
the molten fluxes. Besides, a thin film of liquid aluminum on
the surface of the inclusions hinders chemical reaction
between the inclusions and the molten fluxes, as is confirmed
by the chemical-reaction kinetics, which predicts a low
efficiency of inclusion removal in this case.
For the deep filtration, the inclusions are hardly removed
from the molten aluminum by using uncoated ceramic
particles of large sizes, and uncoated fine ceramic particles
are easily washed away by molten aluminum and may form
new inclusions. However, the cake mode is the mechanism
of capturing the inclusions by micropores of the ceramic
M. ZHOU, D. SHU, K. LI, W.Y. ZHANG, H.J. NI, B.D. SUN, and
J. WANG are with the School of Materials Science and Engineering, Shanghai University, Shanghai 200030, Peoples Republic of China. Contact email: jdzhm@sina.com or jdzhm@sohu.com
Manuscript submitted August 6, 2002.
METALLURGICAL AND MATERIALS TRANSACTIONS A
(NH4)2
HPO4
Na2B4O7
10H2O
Na3A1F6
CaCO3
Li2CO3
K2CO3
Na2CO3
Mg2(OH)2CO3
H3BO3
40
60
2
0
11
20
2
2
2
2
3
3
5
9
1
1
34
0
X1
X2
X1
X2
700
700
710
710
5
5
Table III. The Process of Suspension Enamel Coated on the Surface of Ceramic Foam Filters
Specimen
S3
S4
Filter Quantities
Powder Enamel/g
Water Volume/mL
1
1
16
32
250
500
Ceramic
Particle
(Wt/g)
Powder
Enamel
(Wt/g)
Water/mL
Particle
Diameter
240
240
22
20
260
260
1.2 mm
0.7 mm
Fig. 6SEM BEI photograph of used ceramic foam filter S2 with active
enamel coating.
Table V. SEM Interface and Energy Spectrum of Used Ceramic Foam Filters with Active Coating
Content (Wt Pct)
Locations
Si
Na
Al
Ca
Mg
1
2
3
4
5.49
0
31.15
11.31
11.21
11.99
4.90
0
13.15
43.02
53.95
32.54
21.03
39.50
0
44.39
14.31
5.12
0
6.91
30.49
0
5.21
3.79
4.32
0.37
4.79
1.06
Na
Al
Ca
Mg
1
2
3
4
5
6
7
3.58
5.53
0.94
0.07
4.38
1.24
0.46
52.51
69.63
98.33
98.75
77.66
97.11
99.19
11.93
10.89
0.28
0.38
12.72
0.36
0.15
9.86
7.70
0.00
0.00
4.13
0.11
0.00
7.38
3.22
0.39
0.03
1.10
1.04
0.19
14.74
3.02
0.07
0.14
0.00
0.15
0.00
Na
Al
Ca
Mg
1
2
3
4
0
0
0
8.29
100
100
100
42.82
0
0
0
27.60
0
0
0
16.22
0
0
0
3.30
0
0
0
1.06
Fig. 9SEM photograph of unfiltered tensile sample S0.
S0
S3
S4
S5
S6
S7
71.46
43.00
71.46
47.12
9.58
71.48
48.53
12.86
71.44
48.90
13.70
71.38
50.71
17.93
71.46
44.12
Table IX. Impurity Elements of Unfiltered and Filtered Tensile Specimen Examined with ICP-AES
Content of Impurity Elements (Pct)
Specimen
S0
S6
Pb
Ca
Cr
Fe
Mg
Na
Si
0.0008
0.0009
0.0412
0.0400
0.028
0.030
0.0051
0.0050
0.0034
0.0036
0.0890
0.0884
0.0027
0.0029
0.0032
0.0034
0.0454
0.0450
IV. DISCUSSION
A. Corrosion Properties
M. Zhou et al.[12] examined the corrosion resistance of an
enamel coating with a high B2O3-P2O5 content to molten
aluminum. B2O3 and P2O5 form a kind of BPO4[13,14,15]
network structure, and the conversion of the boron crystalline structure from trigonal to tetrahedral can increase the
VOLUME 34A, MAY 20031187
B. Thermodynamic Theory
The molten enamels exhibit slight spreadability on the
surface of molten aluminum because the enamel is a kind
METALLURGICAL AND MATERIALS TRANSACTIONS A
of noncrystalline solid,[11] which can improve the wettability between ceramic particles and molten aluminum to
some extent. Moreover, the molten enamels can spread
on the surface of ceramic filters.
As a result, the inclusions tend to move out from the
molten aluminum into the molten enamel. Thermodynamic
expressions of inclusion removal with the molten enamel
are as follows:[1621]
G gIE gME gIM
[1]
gIG gEG cos uIS gIE, gIG gMG cos uIM gIM [2]
G gEG cos uIE gMG cos uMI gME
[3]
[4]
where l is the filter coefficient (m1), t is the time of filtration (seconds), c is the concentration of inclusions in the
liquid phase (volume fraction pct), Vsf is the superficial
velocity (m/s), and a is the specific deposit (the inclusions
captured by the active coating, in volume fraction pct).
From Eq. [4], it can be seen that the specific deposit also
increases when the superficial velocity of the molten aluminum increases. At the same superficial velocity of the
molten aluminum, the distance of the inclusions transferring
from the inside to the surface in fine molten aluminum
streams is shorter than that for large molten aluminum
streams. Figure 21 show random movement and distribution
of the inclusions in molten streams. The probability of
METALLURGICAL AND MATERIALS TRANSACTIONS A
3
a
a
b a1
b [5]
(1 0)(1 a)
0 (1 a)
the mesopore of ceramic particles by its own weight to overcome the capillary force induced by the nonwettability
between the micropore ceramic tube and the molten aluminum. At the same time, contact areas between the molten
aluminum and the coated ceramic filters increase. The
inclusions in the fine molten streams move to the surface
of the fine molten streams more easily, which can be
captured by the active coating on the surface of ceramic
filter pores. Although the remaining air in the ceramic foam
filters can oxidize some molten aluminum at the beginning,
1. The active enamel coating, with good corrosion resistance to the molten aluminum, adheres on the surface of
ceramic filters and is not consumed by the molten
aluminum.
2. The SEM examination indicates that the secondary cracks
and dimples are fine and homogeneous in the filtered
tensile specimen, but large and inhomogeneous in the
unfiltered tensile specimen.
3. The elongation of the filtered tensile specimens increases,
but their tensile strength does not show meaningful
change.
4. The contents of trace impurity elements in the filtered
specimen S6 show no obvious change compared with the
unfiltered specimen S0.
5. The inclusions can be removed by a simple and inexpensive deep filtration using the ceramic foam filters and
ceramic particles with an active coating. The filtered
material of specimen S6 shows better properties and very
few inclusions of 6 mm in diameter.
6. The efficiency of removing inclusions from molten
aluminum is very low for uncoated ceramic foam filters.
METALLURGICAL AND MATERIALS TRANSACTIONS A
ACKNOWLEDGMENTS
This work was supported by the National Key Fundamental
Research Project (973) (Project No. G1999064900).
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