SKOR A KIMIA 2014

TAJUK: KADAR TINDAKBALAS

SET 1
(a) Food can be cooked faster when smaller pieces of charcoal are used compare to
bigger pieces of charcoal. Explain why.
Makanan akan lebih cepat masak apabila menggunakan arang yang bersaiz kecil berbanding
arang bersaiz besar. Terangkan mengapa.
[4 marks]
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(b) A group of students carried out three experiments to investigate the factors affaecting
the rate of reaction between sulphuric acid and zinc.
Sekumpulan pelajar menjalankan tiga eksperimen untuk mengkaji faktor-faktor yang
mempengaruhi kadar tindak balas di antara asid sulfurik dan zink.
Table 7 shows the results of the experiments.
Jadual 7 menunjukkan keputusan bagi eksperimen itu.
Experiment

II

Hydrogen gas
Gas hidrogen

Hydrogen gas
Gas hidrogen

Eksperimen

Set-up of
apparatus

III

Hydrogen gas
Gas hidrogen

Zinc powder

Zinc granule

Zinc granule

Serbuk zink

Ketulan zink

Ketulan zink

Susunan
radas

50 cm3 of 1.0 mol dm-3 sulphuric acid

50 cm3 of 1.0 mol dm-3 sulphuric acid
50 cm3 of 0.5 mol dm-3 sulphuric acid
50 cm3asid sulfurik1.0 mol dm-3
50 cm3asid sulfurik1.0 mol dm-3
50 cm3asid sulfuric 0.5 mol dm-3

Time taken to
collect 40cm3
of hydrogen
gas/s
Masa yang
diambil untuk
mengumpulkan
40 cm3 gas
hydrogen/s

80

160

240

Table 7
Jadual 7

(i) Calculate the average rate of reaction for experiment II.

Hitungkan kadar tindak balas purata bagi eksperimen II.

[1 mark]

(ii) Write the chemical equation for the reaction between zinc and sulphuric acid.
Calculate the maximum volume of hydrogen gas produced in Experiment III.
[ 1 mol of gas occupies the volume of 24 dm3 at room temperature and pressure]
Tuliskan persamaan kimia bagi tindak balas antara zink dengan asid sulfurik.
Hitungkan isipadu maksimum gas hidrogen yang terhasil dalam Eksperimen III.
[ 1 mol gas menempati isipadu sebanyak 24 dm3 pada suhu dan tekanan bilik]
[5 marks]
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(iii) Based on Table 7, compare the rate of reaction between

Berdasarkan Jadual 7 bandingkan kadar tindak balas antara

Experiment I and experiment II

Experiment II and experimen III

Eksperimen I and experiment II

Eksperimen II dan eksperimen III

In each case, explain the difference in the rate of reaction with reference to the
Collision Theory.
Bagi setiap kes, terangkan perbezaan kadar tindak balas dengan merujuk kepada
Teori Perlanggaran.

[10 marks]
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SKOR A KIMIA 2014

TAJUK: KADAR TINDAKBALAS
SET 2
Two experiments were carried out to investigate factors that affect the rate of reaction. Table 4
shows the description of each experiment.
Dua eksperimen telah dijalankan untuk menentukan faktor yang mempengaruhi kadar suatu
tindak balas. Jadual 4 menunjukkan perincian setiap eksperimen.

Experiment
Eksperimen

Reactant
Bahan tindak balas

Temperature,
o

C
Suhu,
0
C

Total volume of gas

collected at 2
minutes
3
(cm )
Jumlah isi padu gas yang
dikumpulkan dalam
3
2 minit (cm )

Excess zinc powder + 20 cm

-3
of 0.1 mol dm sulphuric acid
Serbuk zink berlebihan +
3
-3
20 cm of 0.1 mol dm asid
sulfurik

30

20.0

30

32.0

Excess zinc powder + 20 cm

-3
of 0.1 mol dm sulphuric acid +
copper(II) sulphate
solution
II

Serbuk zink berlebihan + 20 cm of

-3
0.1 mol dm asid sulfurik+ larutan
kuprum(II) sulfat
Table 4
Jadual 4
(a)

Draw a diagram of the set-up of apparatus to carry out this experiment.

Lukis gambar rajah untuk menunjukkan susunan radas yang digunakan
dalam eksperimen ini.

(b)

Write the chemical equation for the reaction between zinc and sulphuric acid.
Tuliskan persamaan kimia bagi tindak balas zink dan asid sulfurik.
................................................................................................................................
[ 1 mark]

(c)

Calculate the average rate of the reaction for the first two minutes of experiment I
3 -1
and experiment II in cm s .
Hitung kadar tindak balas purata bagi dua minit pertama untuk eksperimen I
3 -1
dan eksperimen II dalam cm s .
Experiment I
Eksperimen I

Experiment II
Eksperimen II

(d)

[ 2 marks]
Calculate the maximum volume of gas produced in experiment II.
Hitungkan isipadu maksimum gas yang dibebaskan dalam eksperimen II.
3
[1 mol of gas occupies 24 dm at room condition]
3
[1 mol gas menempati 24 dm pada keadaan bilik]

[ 2 marks]
(e)

Compare the rate of reaction between experiment I and experiment II, explain
why there is a difference in the rate of reaction based on the collision theory.
Bandingkan kadar tindak balas antara eksperimen I dan II, terangkan
perbezaan dalam kadar tindak balas menggunakan teori perlanggaran.
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[ 3 marks]

SKOR A KIMIA 2014

TAJUK: KADAR TINDAKBALAS
SET 3

An experiment is carried out to determine the rate of reaction between excess calcium carbonate and
3
-3
50.0 cm of 0.2 mol dm hydrochloric acid. The volume of carbon dioxide gas produced is recorded
at 30 seconds intervals. The result obtained is recorded in Table 4.
Satu eksperimen telah dijalankan untuk menentukan kadar tindak balas antara
3
-3
50.0 cm asid hidroklorik 0.2 mol dm dengan kalsium karbonat berlebihan. Isipadi gas karbon
dioksida yang terbebas direkodkan pada setiap 30 saat dalam Jadual 4.
Time/s
3
Volume/cm

0
0

30
17

60
29

90
34

120
36

150
36

180
36

210
36

240
36

Table 4

a. Based on Table 4, draw a graph of volume of carbon dioxide gas against time.
Berdasarkan Jadual 4, lukis graf isipadu gas karbon dioksida melawan masa.
4mrk

b. Calculate the average rate of reaction for this experiment.

Hitungkan kadar tindak balas purata bagi tindak balas ini
2mrk

-3

c. If the experiment is repeated by using 50.0 cm of 0.1 mol dm hydrochloric acid, sketch
the expected curve in graph (b) .
3
-3
Jika eksperimen diulangi menggunakan 50.0 cm asid hidroklorik 0.1 mol dm , lakarkan
lengkung yang dijangkakan dalam graf (b).
2mrk
d. The factor that affects the rate of reaction in this experiment is concentration.

State two other factors that can affect the rate of reaction in this experiment.
Faktor yang mempengaruhi kadar tindak balas dalam eksperimen ini ialah
kepekatan. Nyatakan dua lagi faktor yang dapat mempengaruhi kadar tindak
balas eksperimen ini.

.
..
.
[2 marks]

SKOR A KIMIA 2014

TAJUK: KADAR TINDAKBALAS
SET 4
A student carried out three experiments to investigate the factors affecting the rate of reaction.
Table 10 shows the results of the experiments. The reaction between sodium thiosulphate and
hydrochloric acid produced sodium chloride, sulphur, sulphur dioxide and water.
Seorang pelajar menjalankan tiga eksperimen untuk mengkaji faktor yang mempengaruhi kadar tindak
balas. Jadual 10 menunjukkan keputusan bagi eksperimen itu.Tindak balas antara natrium tiosulfat dan
asid hidroklorik menghasilkan natrium klorida, sulfur, sulfur dioksida dan air
Time taken for mark X
0
disappears from sight/s
Temperature/ C
Experiment
Reactants
0
Masa
untuk pangkah X
Suhu / C
Eksperimen
Bahan tindak balas
hilang dari penglihatan/s
3

50 cm larutan natrium tiosulfat

-3
3
0.2 mol dm + 5 cm asid
-3
hidroklorik 1 mol dm
3

II

50 cm larutan natrium tiosulfat

-3
3
0.2 mol dm + 5 cm asid
-3
hidroklorik 1 mol dm

18.0

40.0

11.0

40.0

2.0

-3

50 cm of 0.2 mol dm sodium

3
thiosulphate solution + 5 cm of
-3
2 mol dm hydrochloric acid
3

30.0

-3

50 cm of 0.2 moldm sodium

3
thiosulphate solution + 5 cm of 1
-3
moldm hydrochloric acid

III

-3

50 cm of 0.2 mol dm sodium

3
thiosulphate solution + 5 cm of
-3
1 mol dm hydrochloric acid

50 cm larutan natrium tiosulfat

-3
3
0.2 mol dm + 5 cm asid
-3
hidroklorik 2 mol dm

(a) (i) Based on Table 10, arrange the rate of reaction for experiments I,II and III in
ascending order. state the factor that affect the rate of reaction between
- Experiment I and Experiment III
- Experiment II and Experiment III
write the chemical reaction for Experiment III
Berdasarkan Jadual 10, susunkan kadar tindak balas bagi eksperimen I,II dan III dalam tertib
menaik. nyatakan faktor yang mempengaruhi kadar tindak balas di antara
- Eksperimen I dan Eksperimen III
- Eksperimen II dan Eksperimen III, dan
tuliskan persamaan kimia untuk Eksperimen III
[5 marks]
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(i)

b.

Explain using collision theory the difference in the rate of reaction between
Experiment II and Experiment III.
Terangkan dengan menggunakan teori perlanggaran perbezaan kadar tindak balas antara
Eksperimen II dan Eksperimen III.
[5 marks]
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Referring to Table 10, describe a laboratory experiment using one of the factor that affecting the
rate of reaction between sodium thiosulphate solution and hydrochloric acid. In your description,
include an experiment procedure, observation and an ionic equation.
Merujuk kepada Jadual 10, huraikan satu eksperimen yang menggunakan salah satu faktor yang
mempengaruhi kadar tindak balas di antara larutan natrium thiosulfat dengan larutan asid
hidroklorik. Dalam huraian anda, sertakan kaedah eksperimen, pemerhatian dan persamaan ion.
[10 marks]
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SKOR A KIMIA 2014

TAJUK: KADAR TINDAKBALAS
SET 5

An experiment is carried out to study the effect of concentration on rate of reaction.

3
-3
50.0 cm of 0.5 mol dm hydrochloric acid and excess granulated calcium carbonate is put into a
conical flask and is placed on an electronic balance as shown in Diagram 4.
The mass of the conical flask and its contents is recorded at 60 seconds intervals.
Satu eksperimen telah dijalankan untuk mengkaji kesan kepekatan ke atas kadar tindak balas.
50.0 cm3 asid hidroklorik 0.5 mol dm-3 dan ketulan kalsium karbonat berlebihan dimasukkan
ke dalam kelalang kun diletakkan di atas neraca elektronik seperti dalam Rajah 4.
Jisim kelalang kun dan kandungannya direkodkan pada sela masa 60 saat.

Table 4 shows the results.

Jadual 4 menunjukkan keputusan

Time/sec.
[Masa/saat]

Balance readings /g
[Bacaan neraca/g]

60

120

180

240

300

360

420

480

140.64 140.48 140.37 140.31 140.26 140.22 140.20 140.20 140.20

JADUAL 4

(a)

Give the definition of rate of reaction.

[Berikan maksud kadar tindak balas]

(b)

....................................................................................................................................
[1 mark]
Explain why the mass of the conical flask and its content decreases with time.
[Terangkan mengapa jisim kelalang kun dan kandungannya berkurang dengan masa]

........................................................................................................................................
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[1 mark]
(c)

Based on Table 4, plot a graph of the mass of the conical flask and its content
versus time on the graph paper below.
[Berdasarkan Jadual 4, plotkan graf jisim kelalang kun dan kandungannya melawan masa
pada kertas graf di bawah].

d)

Based on the graph, calculate the instantaneous rate of reaction at 120 seconds.
[Berdasarkan graf, hitungkan kadar tindak balas pada saat ke 120]

(e)

(i)

Calculate the mass of carbon dioxide gas produced.

[Hitungkan jisim gas karbon dioksida yang dihasilkan]

(ii)

Calculate the expected volume of gas produced at room condition.

3
[1 mol of gas occupies 24 dm at room condition; relative molecular mass of
CO2 is 44 ]

[Hitungkan isipadu gas yang dijangka akan terhasil pada keadaan bilik.
3
1 mol gas menempati 24 dm pada suhu bilik ; jisim molekul relatif CO2 ialah 44]

SKOR A KIMIA 2014

TAJUK: KADAR TINDAKBALAS

SET 6

Two experiments were carried out to compare the effect of catalyst on the decomposition of
hydrogen peroxide. For each experiment, 50 cm3 of 0.1 mol dm-3 aqueous hydrogen peroxide
was used. The volume of oxygen gas produced was measured at regular time intervals.
Table 8 shows the results of the experiments.
Dua eksperimen telah dijalankan untuk membandingkan kesan mangkin terhadap
penguraian hydrogen peroksida. Dalam setiap eksperimen,50 cm3 0.1 mol dm-3 larutan
hidrogen peroksida akueus digunakan. Isipadu gas yang terbebas diukur pada sela masa
tertentu.
Jadual 8 menunjukkan keputusan eksperimen tersebut.
Experiment

II

Reacting mixture
Campuran bahan
tindak balas
Hydrogen
peroxide, H2O2
Hidrogen
peroksida, H2O2
Hydrogen
peroxide, H2O2 +
catalyst
Hidrogen
peroksida, H2O2 +
mangkin

Time/s
Masa/s
Volume of
oxygen gas
(cm3)
Isipadu gas
oksigen/cm3
Volume of
oxygen gas
(cm3)
Isipadu gas
oksigen/cm3

10

15

20

25

30

35

10

18

24

30

34

38

40

24

40

50

57

60

60

60

TABLE 8
JADUAL 8
(i) On the same axis, plot graphs for the volume of oxygen gas against time for
experiments I and II. Use the graph paper provided in page 22.
Pada paksi yang sama, plot graf isipadu gas oksigen melawan masa bagi
ekperimen I dan II. Gunakan kertas graf yang dibekalkan di muka surat 22.
[4
marks]
(ii) Based on the graphs in b(i),determine the instantaneous rates of reaction for
experiments I and II at 15 seconds.
Berdasarkan pada graf b(i),tentukan kadar tindak balas bagi eksperimen I dan II
pada saat ke 15.
[6 marks]

iii)

Based on the values obtained in b(ii), which experiment has a higher rate of
reaction? Explain your answer.
Berdasarkan nilai yang didapati di b(ii),eksperimen manakah mempunyai kadar
tindak balas yang lebih tinggi? Terangkan jawapan anda.
[3 marks]
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iv)

Based on the collision theory, explain the effect of the catalyst on the rate of
decomposition of hydrogen peroxide.
Berdasarkan teori perlanggaran, terangkan kesan mangkin ke atas kadar
penguraian hidrogen peroksida.

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