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COURSE OUTLINE:
1. Theory of Atomic Structure
2. Thomson, Rutherford, and Neils Bohrs theories
3. The Hydrogen atom
4. Properties of the atom, Ions, Protons Neutrons and Electrons
5. Millikans oil-drop experiment
6. Properties of the Atomic nucleus
7. Natural Radioactivity
8. Wave Particle duality of Light
9. X-Rays
10.Photo electricity
11.Thermionic Emission
12.Diode Valve etc.
atoms of identical size and mass. These particles were indivisible and remained
unchanged during a chemical reaction. Dalton and other Scientists discovered that the
atom was not indivisible, but consisted of subatomic particles such as electrons,
protons, and neutrons.
J.J. Thomson was the first scientist to identify electrons through his work on Cathode
rays. Cathode rays consisted of streams of negatively charged particles called Electrons.
He was able to determine the charge-to-mass ratio (e/m) of these electrons. In all his
experiments the value of e/m was the same. He therefore concluded that all atoms
contained electrons.
In 1909 Millikan, through his oil-drop experiment determined the charge (e) of an
electron. When combined with Thomsons value for e/m, the mass of an electron can
be calculated to be:
e = 1.602 x 10 -19C
m = 9.110 x 10-29gm
The Proton: The Proton was the second sub-atomic particle to be discovered in 1886 by
Goldstein. These particles are known as positive rays.
Rutherford in 1899 discovered alpha (a) and Beta (b) radiation. Hence by all of these
experiments there is evidence that the atom consists of very small positively charged
nucleus surrounded by a large space containing light negatively charged electrons.
Rutherford then went on to propose the existence of the Proton and showed that its
mass was 1800 times that of an electron.
The Neutron: The neutron was predicted by Rutherford I 1920 to account for the
difference between atomic mass and atomic number. This was later proven
experimentally in 1932 by J. Chadwick. He showed that these neutron particles were
electrically neutral and called them neutrons.
Models of the Atom: In 1913 Neils Bohr described the model of an atom. He viewed the
atom as a positive nucleus surrounded by electrons, and suggested that the electrons
travelled in circular orbits around the nucleus. These orbits had different energies,
hence an electron could gain or lose energy by jumping from one orbit to another.
Quanta: In 1900, Max Planck suggested that energy could be only be absorbed or
emitted in discrete quantities called QUANTA. The magnitude of E of these bundles of
energy were related to the frequency ( v ) of the energy by a constant ( h), known as
Plancks constant. Thus: E = hv
Hence, the higher the energy of a quantum, the higher its frequency.
Einstein, in 1905 postulated that light was composed of particles called photons. He
used this theory to explain why metal surfaces emitted electrons when light was shown
on them. This phenomenon was known as the Photoelectric Effect. Hence Light was
seen to have a dual nature. It could behave as waves by forming interference and
diffraction pattern or it could behave as a beam of particles as is the case in
photoelectric effect.
Mass of an Atom: The Atomic mass number is the number of protons and neutrons in a
nucleus. It is given a symbol (A). A nucleus is often called a nuclide and the nuclear
particles protons, and neutrons sometimes called Nucleons.
The Atomic Number: The atomic number of an element is the number of Protons in the
nucleus. It is represented by letter (z). Atomic number is related to the mass number as
follows:
A=z+N
Where N is the number of neutrons in the nucleus. Each element has its own atomic
number. No two elements can have the same atomic number. The atomic number is
not only the number of protons in a nucleus, but is also equal to the number of
electrons surrounding the nucleus. This is because there is no net charge on an atom.
The number of protons thus equals the number of electrons. This does not apply to
ions which are charged particles.
radius of the particles, the nucleic attraction between two protons far exceeds the
repulsion due to their electric charges.