/...

{ 266}
14

2014 } {
{}
:
()

CHEMISTRY
TIME: 3 HOURS
Write all the equations balanced with the conditions
(
)
:
.
ANSWER ONLY FOUR QUESTIONS:
QUESTION ONE: (15 MARKS)
First: Choose the correct answer for each of the following:
1- Ionic equilibrium occurs in weak electrolytic solutions between......
a) molecules of reactants and molecules of products
b) molecules of reactants and ions of products
c) ions of reactants and molecules of products
d) ions of reactants and ions of products
2- From the general properties of basic aqueous solution..
a) Has pH less than 7
b) Makes litmus solution red
c) Has a bitter taste.
d) Makes methyl orange turn
yellow
3- The concentration of sodium hydroxide solution which results from
dissolving 40gm of it in water is..
(Na = 23, O=16 , H =1)
a) 1 mole/L
b) 0.5 mole/L
c) 0.25 mole/L
d) 2 moles/L
4- Chemical equilibrium for any balanced reaction is affected by the
following factors except.
a) Pressure
b) Heat
c) Concentration
d) Catalyst
5- Number of litres of oxygen resulted from dissolving 36gm of water at
stp is
(H = 1, O = 16)
a) 22.4 litres
b) 44.8 litres
c) 11.2 litres
d) 5.6 litres
6- In the dry cell reaction, reduction occurs to

a) Zn
c) MnO2

b) MnO(OH)
d) NH4+
()
-2 /...{ 266}
14

Second: 1- What is the chemical structure and IUPAC name for each of
the following?
a) Formic acid.
b) Pyrogallol
2- Mention Faradays first law and how it can be determined
experimentally.
3- Show by balanced chemical equations how to obtain the
following:
a) Dihydroxy alcohol from a monohydroxy alcohol.
b) Picric acid from benzene.
QUESTION TWO: (15 MARKS)
First: Write the scientific term for each of the following:
1- The only alkene that gives a primary alcohol by catalytic hydration.
2- The arrangement of elements in a descending order according to the
standard oxidation potential, and in an ascending order according to the
standard reduction potential.
3- The product of multiplying the concentration of hydrogen ions and
hydroxyl ions that result from the ionization of water.
4- A solution whose one litre contains one mole of solute.
5- Saturated hydrocarbons with the general formula (C nH2n).
Second: 1- Arrange the following aqueous solution in an ascending
order from the acidic to the basic:
(potassium nitrate ammonium chloride sodium hydroxide)
2- Which of the following compounds can be oxidized with
acidified potassium dichromate solution? (Write the
equation)
(Methane gas Ethyl alcohol Acetic acid Tertiary alcohol)
3- What is the scientific basis of the precipitation method in
analytical chemistry? Show its steps.

4- Compare between:
a) Electrolytic cells and Galvanic cells
b) Complete ionization and Weak ionization
()
-3-

/...{ 266}
14

QUESTION THREE: (15 MARKS)

First:
1- Show by a chemical equation how to obtain industrial detergents from
aromatic sulphonic acid compounds. Mention the components of the
detergents and method of operation.
2- Write the chemical equation for the preparation of methane gas in the
lab with drawing a labelled diagram of the apparatus used.
Second:
1- Scientists have agreed to use the standard hydrogen electrode as a
standard electrode which can be used to measure the potential of other
electrodes.
a) Show by drawing a labelled diagram: The components of standard
hydrogen potential.
b) Write the symbolic notation for the standard hydrogen half-cell.
2- What is the contribution of the following scientists in chemistry?
a) Avogadro
b) Wohler
c) Gay-Lussac
3- Which of the following reactions are complete and which are reversible?
Give reasons.
a) C2H5OH + CH3COOH = CH3COOC2H5 + H2O
b) AgNO3 (aq.) + BaCl2 (aq.) = 2AgCl(s) + Ba(NO3)2 (aq.)
c) 2Cu(NO3)2 (s) = 2CuO(s) + 4NO2 (g) + O2 (g)
d) CO(g) + H2O = CO2 + H2 (in a closed vessel)
QUESTION FOUR: (15 MARKS)
First:

1-

What is the proper alkyl halide for the preparation of: (ethanol), (2propanol)? Write the equations.
2- What is the result of the reaction of toluene with each of the
following?
a)Chlorine.
b)Mixture of conc. sulphuric and nitric acids.
()
-4 /...{ 266}
14
3-

Some primary cells are characterized by small size and various uses as
(earphones cameras watches).
Show the type of anode and cathode and the total reaction in the cell.

Second:
1- An alkyne has a molar mass 54gm. Deduce its molecular formula and
write its structural formula and the IUPAC name.
(H =1, C =12)
2- Calculate the concentration of hydrogen ions in a 0.1M solution of
hydrochloric acid at 25C given that the equilibrium constant: K a = 7.2
10-10
3- What is meant by qualitative analysis and quantitative analysis?
QUESTION FIVE: (15 MARKS)
First: Give a scientific reason for the following:
1- The nomenclature of the alcohol that contains 4 carbon atoms as
butanol only is considered to be inaccurate.
2- The amount of water vapour resulting from the elements of water
increases by increasing the pressure.
3- The law of mass action is not applied on strong electrolytic solutions.
4- Phenol is more acidic than ethyl alcohol.
Second:
1- What is the quantity of electricity in coulombs needed to separate 5.6
gm. of iron from a solution of iron III chloride given that (Fe = 55.86)?
Write the equation of the cathode.
2- Answer the following questions:

a) What does the ring inside

this figure indicate?

b) Aromatic benzene reacts by

2 types of reactions: (Addition
Substitution).
Show a chemical equation for each type with the conditions of
reaction.
c) A mixture of a solid substance contains sodium hydroxide and sodium
chloride. 0.1 gm. of the mixture was titrated using 10ml of 0.1M
hydrochloric acid solution. Calculate the percentage of sodium
hydroxide in the solution.
()