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NAME:
CLASS: PRA U S
MOCK TEST 1 [SEPTEMBER 2015]
PAPER
CODE
COHORT
DURATION
CHEMISTRY 1
962/1
STPM 2016
1 hour 30 minutes
INVIGILATOR(s)
1.
DATE
DAY
DURATION
TIME
SUBJECT
TEACHER
2.
15 September 2015
Tuesday
1 hour 30 minutes
HR
1130 HR1300
INSTRUCTION TO CANDIDATES:
1. This paper consists of Section A, Section B and Section C.
2. Answer ALL questions in Section A and Section B.
Answer ANY TWO questions only in Section C.
3. For calculations, always show complete workings. Write your answer in correct significant
figures and correct unit.
4. Arrange and stapler your answers in numerical order.
SECTION A (15 marks)
Answer ALL the questions in Section A.
Blacken the corresponding answer on the objective answer sheet provided on page 4.
1. The mass spectrum of a gaseous element is shown below.
Relative intensity
10
11
20
21
22
m
e
102
6.66
4.16
103
1.67
104
6.66
104
4. The diagram below shows the electronic transitions between energy levels in the emission
spectrum of atomic hydrogen.
Which electronic transition will produce spectral lines in the visible region?
n=5
n=4
Energy
n=3
n=2
n=1
B
H
H2O
D
C
H2 O
H2O
Cl
Cu
H2O
2+
OH2
OH2
bond angle?
7. Copper(I) oxide is a reddish-brown solid. In which orbitals are the valence electrons of
copper(I) ion found?
A
3s
B
4s
C
3d
D
3d and 4s
8. Which factor is the most significant in explaining the non-ideal behavior of the gases present in
the reaction chamber in the Haber process?
A
Presence of catalyst.
B
High pressure of 150 atm.
C
High temperature of 450C.
D
Strong bonds between atoms in the nitrogen molecule.
2
10. Which statement explains why catalysts are often used in chemical reactions?
A
Catalysts increase the activation energies of reactions.
B
Catalysts increase the yield of reaction products.
C
Catalysts increase the enthalpy of reactions.
D
Catalysts increase the rate of reactions.
11. Gas X decomposes when heated under a constant pressure P and temperature T to form an
equilibrium mixture as shown below.
X(g)
2Y(g) + Z(g)
If the partial pressure of X is
1
4 P, what is the equilibrium constant, Kp,of the system at
temperature T?
A
1
4 P2
3
4 P2
4P 2
8P 2
12. Which is the correct observation when CaCO3 is heated at 800C in a closed vessel?
All the CaCO3 completely decomposed.
A
The number of moles of CaO and CO2 differs.
B
Only part of the CaCO3 decomposed even after prolonged heating.
C
The pressure in the vessel will increase until no more CaCO3 is left.
D
13. Solid silver chloride is soluble in aqueous ammonia via the following equilibrium:
AgCl(s) + 2NH3(aq)
[Ag(NH3)2]+(aq) + Cl(aq)
Which of the following would most likely cause the reappearance of silver chloride?
A
Adding more ammonia.
B
Adding excess of dilute hydrochloric acid.
C
Adding ammonium nitrate.
D
Warming the mixture.
14. Pure water is a weak electrolyte. This indicates that
A
Water is neutral.
B
Water is an amphoteric solvent.
C
Water undergoes partial dissociation.
D
The concentrations of H+ and OH ions in water are the same.
15. Which of the following solutions has the highest concentration of H+ ions?
A
C
1 mol dm3 H2SO4
1 mol dm3 H2CO3
3
1 mol dm H3PO4
3
C
C
C
C
C
D
D
D
D
D
6
7
8
9
10
C
C
C
C
C
D
D
D
11
B
12
13
D
D
14
15
15
2NO2(g)
H = positive
Brown
(a) 1.00 g of the above mixture occupies a volume of 380 cm 3 at 60C and 100 kPa. Calculate
the average relative molecular mass of the mixture.
[Gas constant, R = 8.31 J g1 C1]
[2 marks]
(b) Determine the mole fractions of N2O4 and NO2 in the mixture.
[3 marks]
[3 marks]
17. A buffer solution is a solution that can resist change in pH when a small amount of acid or base
is added.
(a) One of the buffer systems in the human blood is the carbonic acid/ bicarbonate ion
system. The equilibrium is given as shown below:
H2CO3(aq)
H+(aq) + HCO3(aq)
By using suitable equations, explain how the mixture acts as a buffer.
[3 marks]
(b) The normal pH of human blood is maintained between 7.35 and 7.45 by buffer systems.
State another buffer system in human blood.
[1 mark]
(c) Calculate the pH of a buffer solution formed by mixing 100 cm3 of 0.050 mol dm3 ethanoic
acid and 50 cm3 of 0.20 mol dm3 sodium ethanoate.
[Ka for ethanoic acid is 1.7
[3 marks]
Using a labelled energy diagram, show how the line marked L on the spectrum is formed.
[2 marks]
(b) (i)
State two conditions when real gases behave almost like ideal gases.
[2 marks]
(ii) Explain why xenon exhibits the greatest deviation from ideal behavior compared with
other elements in Group 18.
[2 marks]
(c) Helium has a triple point temperature of 1.0 K and critical point temperature of 5.0 K.
Solid helium has the same density as liquid helium.
(i)
[3 marks]
(ii) State and explain the effect on the melting point of helium when the pressure is
increased.
[2 marks]
(iii) Helium-5 is an unstable isotope of helium. The rate constant, k, for its radioactive
disintegration is 9.12
[4 marks]
[1 mark]
(b) The Haber process for the manufacture of ammonia involves the following equilibrium.
N2(g) + 3H2(g)
2NH3(g)
H = 95 kJ mol1
State and explain how the equilibrium composition of ammonia would change (if any) with
the following alterations:
(i) Lowering the temperature,
[3 marks]
(ii) Decreasing the pressure,
[3 marks]
(iii) Addition of a suitable catalyst.
[3 marks]
(c) A mixture containing 1 mol of nitrogen and 3 mol of hydrogen were allowed to achieve
equilibrium at 180C, 2000 atm and in the presence of a catalyst. The equilibrium mixture
was found to contain 1.8 mol of ammonia.
(i) Determine the equilibrium constant Kc.
[2 marks]
(ii) What can be said of the magnitude of Kc?
[1 mark]
[2 marks]
20. (a) Mercury(II) chloride reacts with oxalate ion, C2O42 according to the equation:
2HgCl2(aq) + C2O42(aq)
Initial rate
[HgCl2]
[C2O42]
0.068
0.068
0.102
0.035
0.14
0.035
[6 marks]
[3 marks]
(b) Phenol, C6H5OH, is a weak organic acid. A solution containing 0.385 g of phenol in 2.00
dm3 solution has a pH of 6.29 at 25C.
Calculate:
(i) the molar concentration of the phenol solution,
[2 marks]
(ii) the acid dissociation constant of phenol at 25C.
[4 marks]
SECTION C
Question
Answers
Examiners
use only
SECTION C
Question
Answers
Examiners
use only
SECTION C
Question
Answers
Examiners
use only
10
2
(II)
6.9
Li
9.0
Be
Group (Kumpulan)
9
10
11
12
13
(III)
14
(IV)
15
(V)
16
(VI)
17
(VII)
27.0
Al
13
69.7
Ga
31
115
In
49
204
Tl
81
28.1
Si
14
72.6
Ge
32
119
Sn
50
207
Pb
82
31.0
P
15
74.9
As
33
122
Sb
51
209
Bi
83
32.1
S
16
79.0
Se
34
128
Te
52
[209]
Po
84
35.5
Cl
17
79.9
Br
35
127
I
53
[210]
At
85
18
(VIII)
4.0
He
2
20.2
Ne
10
40.0
Ar
18
83.8
Kr
36
131
Xe
54
[222]
Rn
86
10.8
B
12.0
C
14.0
N
16.0
O
19.0
F
163
Dy
66
[251]
Cf
98
165
Ho
67
[252]
Es
99
167
Er
68
[257]
Fm
100
169
Tm
69
[258]
Md
101
173
Yb
70
[259]
No
102
175
Lu
71
[262]
Lr
103
23.0
Na
11
39.1
K
19
85.5
Rb
37
133
Cs
55
[223]
Fr
87
24.3
Mg
12
40.1
Ca
20
87.6
Sr
38
137
Ba
56
[226]
Ra
88
a
X
b
45.0
Sc
21
88.9
Y
39
139
La
57
227
Ac
89
47.9
Ti
22
91.2
Zr
40
178
Hf
72
[261]
Rf
104
50.9
V
23
92.9
Nb
41
181
Ta
73
[262]
Db
105
52.0
Cr
24
95.9
Mo
42
184
W
74
[266]
Sg
106
54.9
Mn
25
[98]
Tc
43
186
Re
75
[264]
Bh
107
55.8
Fe
26
101
Ru
44
190
Os
76
[269]
Hs
108
58.9
Co
27
103
Rh
45
192
Ir
77
[268]
Mt
109
58.7
Ni
28
106
Pd
46
195
Pt
78
[281]
Ds
110
63.5
Cu
29
108
Ag
47
197
Au
79
[272]
Rg
111
65.4
Zn
30
112
Cd
48
201
Hg
80
[285]
Cn
112
140
Ce
58
232
Th
90
141
Pr
59
231
Pa
91
144
Nd
60
238
U
92
[145]
Pm
61
237
Np
93
150
Sm
62
[244]
Pu
94
152
Eu
63
[243]
Am
95
157
Gd
64
[247]
Cm
96
159
Tb
65
[247]
Bk
97
The proton numbers and approximate relative atomic masses shown in the table are for use in the examination unless stated otherwise in an individual question.
11
(Nombor proton dan anggaran jisim atom relatif yang ditunjukkan dalam jadual adalah untuk digunakan dalam peperiksaan kecuali yang sebaliknya dinyatakan dalam soalan
yang tertentu.)
12
RUBRIC
10
11
12
13
14
15
pV =nRT @ pV =
( Mm )
r
M r=
RT @ M r=
mRT
pV
M r=72.8
b
46 x +92 ( 1x )=72.8
x=0.417
13
RUBRIC
c
K p=
(PNO )
PN O
2
(0.417 100)
( 0.583 100)
29.8 kPa
1
7
The buffer solution consists of undissociated weak acid, H2CO3 and its conjugate
base, HCO3.
When [acid] increased,
The equilibrium position will shift to the left to form undissociated H 2CO3. The
added H+ is removed and pH remains constant.
H+(aq) + HCO3(aq)
H2CO3(aq)
Then, the unstable H2CO3 will decompose into CO2 and H2O. CO2 is
removed from the blood via exhalation.
H2CO3(aq)
CO2(g) + H2O(l)
H2O(l) + HCO3(aq)
NOTE: [H+] and [OH] remains constant, hence the pH of buffer solution
remains unchanged.
b
Either one:
Amino acid, H2NCHRCOOH
H2PO4 / HPO42 system
NOTE:
WCR
[CH3COOH] =
0.050 100
(100+50)
1
30
mol dm3
[CH3COONa] =
0.20 50
(100+50)
1
15
mol dm3
pH= p K a +log 10
[CH 3 COONa ]
[ CH 3 COOH ]
1
1
14
RUBRIC
( 151 )
( 301 )
n=5
n=4
Energy
L
n=3
n=2
n=1
1
8
b(i)
Low pressure
High temperature
1
1
b(ii)
Xe has the largest atomic size in Group 18 and the most number of electrons.
Intermolecular forces and volume of gas particles/ atoms cannot be ignored.
1
1
c(i)
Pressure/ atm
Liquid
Solid
Gas
1.0
5.0
NOTE:
15
Temperature/ K
1
1
RUBRIC
c(iii)
There is no change in volume during the phase change between solid and liquid
helium.
Thus, pressure will not affect the melting point of helium.
1
1
t 1 =
2
t 1 =
2
ln 2
k
ln 2
20
9.12 10
1
1
22
t 1 =7.60 10
1
9
1
9
(a)
b(i)
Lowering the temperature will force the equilibrium position to shift to the righthand side.
A catalyst does not alter the equilibrium position (and the equilibrium composition).
It just increases the rates of forward and reverse reaction (by the same factor) so
that equilibrium is achieved in a shorter time.
b(ii)
b(iii)
c(i)
N 2 ( g )+3 H 2 ( g ) 2 NH 3 ( g)
1
(1 0.9)
0.1
3
(3 2.7)
0.3
Initial/ mol
:
Change/ mol
:
Equilibrium/ mol :
0
1.8
1.8
K c =
[NH 3 ]
3
[N 2 ][H 2]
1
16
RUBRIC
(1.8)
( 0.1 )( 0.3)3
K c =
K c =1200 mol dm
1
c(ii)
Kc
N2
H2
to
At low temperature (180C), the yiels of ammonia is high. However, the rate of
reaction at such a low temperature would be very slow// It takes a long time
for the yield to be achieved. In order to increase the rate of reaction, a catalyst
(iron) is added.
High pressure (2000 atm) would ensure a high yield. However, if the pressure is
too high, the cost of production would also be high because the pipes and
storage tanks have to be thick enough to withstand the pressure.
The magnitude of
and
NH 3 .
c(iii)
2
0
a(i)
Experiment II 4.16
0.14
:
=
Experiment I 0.230 0.035
18.1=4
b=2.1 2
1
1.5=1.5
a=1
1
2
0
a(ii)
k =
0.230
( 0.068 ) (0.035)2
HgCl2 + 2C2O42
Hg + HgCl2
fast
slow
6 1
2.8 10 mol dm s
1
1
2HgCl
17
RUBRIC
fast
[C2O4 CO2] 2
M
1
CO2 + C2O42
fast
HgCl2 + C2O42
[HgCl2 C2O4]2
slow
fast
[C2O4 CO2] 2
Hg2Cl2
fast
CO2 + C2O42
0.385
6 ( 12.0 )+ 6 (1.0 )+ 16.0
b(i)
Number of moles of phenol
0.385
94.0
mol
0.004096 mol
1
Molar concentration of phenol =
0.004096
2.00
= 2.05
a(ii)
K a=
mol dm3
C6H5O(aq) + H+(aq)
1
1
C 6 H 5 O
+
H
18
RUBRIC
K a=
+
H
K a=
( 106.29 )
( 2.05 103 )
+
H
106.29
2.05 103
4
=2.50 10 @ 0.0250
19