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A magnetic quadrupole
The magnetic state (or magnetic phase) of a material depends on temperature and other variables such as pressure and the applied magnetic eld. A material may exhibit more than one form of magnetism as these variables
change.
1
2
spoon always pointed south.
Alexander Neckam, by 1187, was the rst in Europe to
describe the compass and its use for navigation. In 1269,
Peter Peregrinus de Maricourt wrote the Epistola de magnete, the rst extant treatise describing the properties of
magnets. In 1282, the properties of magnets and the dry
compass were discussed by Al-Ashraf, a Yemeni physicist, astronomer, and geographer.[5]
SOURCES OF MAGNETISM
2 Sources of magnetism
See also: Magnetic moment
Magnetism, at its root, arises from two sources:
1. Electric current (see Electron magnetic moment).
2. Spin magnetic moments of elementary particles.
The magnetic moments of the nuclei of atoms are
typically thousands of times smaller than the electrons magnetic moments, so they are negligible in
the context of the magnetization of materials. Nuclear magnetic moments are very important in other
contexts, particularly in nuclear magnetic resonance
(NMR) and magnetic resonance imaging (MRI).
Michael Faraday, 1842
In 1600, William Gilbert published his De Magnete, Magneticisque Corporibus, et de Magno Magnete Tellure (On
the Magnet and Magnetic Bodies, and on the Great Magnet the Earth). In this work he describes many of his experiments with his model earth called the terrella. From
his experiments, he concluded that the Earth was itself
magnetic and that this was the reason compasses pointed
north (previously, some believed that it was the pole star
(Polaris) or a large magnetic island on the north pole that
attracted the compass).
An understanding of the relationship between electricity
and magnetism began in 1819 with work by Hans Christian rsted, a professor at the University of Copenhagen,
who discovered more or less by accident that an electric
current could inuence a compass needle. This landmark
experiment is known as rsteds Experiment. Several
other experiments followed, with Andr-Marie Ampre,
who in 1820 discovered that the magnetic eld circulating
in a closed-path was related to the current owing through
the perimeter of the path; Carl Friedrich Gauss; JeanBaptiste Biot and Flix Savart, both of whom in 1820
came up with the BiotSavart law giving an equation for
the magnetic eld from a current-carrying wire; Michael
Ordinarily, the enormous number of electrons in a material are arranged such that their magnetic moments (both
orbital and intrinsic) cancel out. This is due, to some extent, to electrons combining into pairs with opposite intrinsic magnetic moments as a result of the Pauli exclusion principle (see electron conguration), or combining
into lled subshells with zero net orbital motion. In both
cases, the electron arrangement is so as to exactly cancel the magnetic moments from each electron. Moreover,
even when the electron conguration is such that there are
unpaired electrons and/or non-lled subshells, it is often
the case that the various electrons in the solid will contribute magnetic moments that point in dierent, random
directions, so that the material will not be magnetic.
However, sometimeseither spontaneously, or owing to
an applied external magnetic eldeach of the electron
magnetic moments will be, on average, lined up. Then
the material can produce a net total magnetic eld, which
can potentially be quite strong.
The magnetic behavior of a material depends on its structure, particularly its electron conguration, for the reasons mentioned above, and also on the temperature. At
high temperatures, random thermal motion makes it more
dicult for the electrons to maintain alignment.
3.2
Paramagnetism
Materials
Uncompensated
orbital andspin
angular momentum
Permanent atomic
moments
Independen
t atomic
moments
Ideal paramagnetism
3.2 Paramagnetism
Electronic bands in
metals
Pauli spin
paramagnetism
Band
antiferromagnet
i sm
Cooperating atomic
moments
Ferromagnetism
Antiferromagnet
i sm
Ferrimagnetism
3.1
Diamagnetism
3.3 Ferromagnetism
Diamagnetism appears in all materials, and is the tendency of a material to oppose an applied magnetic eld,
and therefore, to be repelled by a magnetic eld. However, in a material with paramagnetic properties (that is,
with a tendency to enhance an external magnetic eld),
the paramagnetic behavior dominates.[8] Thus, despite its
universal occurrence, diamagnetic behavior is observed
only in a purely diamagnetic material. In a diamagnetic
material, there are no unpaired electrons, so the intrinsic electron magnetic moments cannot produce any bulk
eect. In these cases, the magnetization arises from
the electrons orbital motions, which can be understood
classically as follows:
When a material is put in a magnetic eld,
the electrons circling the nucleus will experience, in addition to their Coulomb attraction
to the nucleus, a Lorentz force from the magnetic eld. Depending on which direction the
electron is orbiting, this force may increase
the centripetal force on the electrons, pulling
them in towards the nucleus, or it may decrease
the force, pulling them away from the nucleus.
This eect systematically increases the orbital
magnetic moments that were aligned opposite
the eld, and decreases the ones aligned parallel to the eld (in accordance with Lenzs law).
This results in a small bulk magnetic moment,
with an opposite direction to the applied eld.
3 MATERIALS
Magnetic domains
3.4 Antiferromagnetism
3.5
Ferrimagnetism
Ferrimagnetic ordering
An electromagnet attracts paper clips when current is applied creating a magnetic eld. The electromagnet loses them when current and magnetic eld are removed.
Like ferromagnetism, ferrimagnets retain their magnetization in the absence of a eld. However, like antiferromagnets, neighboring pairs of electron spins like to point 5 Magnetism, electricity, and spein opposite directions. These two properties are not concial relativity
tradictory, because in the optimal geometrical arrangement, there is more magnetic moment from the sublatMain article: Classical electromagnetism and special reltice of electrons that point in one direction, than from the
ativity
sublattice that points in the opposite direction.
As a consequence of Einsteins theory of special relaMost ferrites are ferrimagnetic. The rst discovered magnetic substance, magnetite, is a ferrite and was originally
believed to be a ferromagnet; Louis Nel disproved this,
however, after discovering ferrimagnetism.
3.6
Superparamagnetism
MAGNETIC FORCE
might be considered to be primarily magnetism, e.g. perturbations in the magnetic eld are necessarily accompanied by a nonzero electric eld, and propagate at the speed
of light.
B = 0 H,
where 0 is the vacuum permeability.
In a material,
B = 0 (H + M).
The quantity 0 M is called magnetic polarization.
If the eld H is small, the response of the magnetization When a charged particle moves through a magnetic eld
M in a diamagnet or paramagnet is approximately linear: B, it feels a Lorentz force F given by the cross product:[10]
M = H,
F = q(v B)
Magnetic dipoles
8.1
Magnetic monopoles
9 Quantum-mechanical origin of
magnetism
In principle all kinds of magnetism originate (similar
to superconductivity) from specic quantum-mechanical
phenomena (e.g. Mathematical formulation of quantum
mechanics, in particular the chapters on spin and on the
Pauli principle). A successful model was developed already in 1927, by Walter Heitler and Fritz London, who
derived quantum-mechanically, how hydrogen molecules
are formed from hydrogen atoms, i.e. from the atomic hydrogen orbitals uA and uB centered at the nuclei A and
B, see below. That this leads to magnetism is not at all
obvious, but will be explained in the following.
According to the Heitler-London theory, so-called twobody molecular -orbitals are formed, namely the resulting orbital is:
1
(r1 , r2 ) = (uA (r1 )uB (r2 ) + uB (r1 )uA (r2 ))
2
Here the last product means that a rst electron, r1 , is
in an atomic hydrogen-orbital centered at the second nucleus, whereas the second electron runs around the rst
nucleus. This exchange phenomenon is an expression
for the quantum-mechanical property that particles with
identical properties cannot be distinguished. It is specic
not only for the formation of chemical bonds, but as we
will see, also for magnetism, i.e. in this connection the
term exchange interaction arises, a term which is essential for the origin of magnetism, and which is stronger,
Nevertheless, some theoretical physics models predict the roughly by factors 100 and even by 1000, than the enerexistence of these magnetic monopoles. Paul Dirac ob- gies arising from the electrodynamic dipole-dipole interserved in 1931 that, because electricity and magnetism action.
show a certain symmetry, just as quantum theory predicts
As for the spin function (s1 , s2 ) , which is responsible
that individual positive or negative electric charges can be
for the magnetism, we have the already mentioned Paulis
observed without the opposing charge, isolated South or
principle, namely that a symmetric orbital (i.e. with the +
North magnetic poles should be observable. Using quansign as above) must be multiplied with an antisymmetric
tum theory Dirac showed that if magnetic monopoles exspin function (i.e. with a sign), and vice versa. Thus:
ist, then one could explain the quantization of electric
chargethat is, why the observed elementary particles
1
carry charges that are multiples of the charge of the elec(s1 , s2 ) = ((s1 )(s2 ) (s1 )(s2 ))
tron.
2
Certain grand unied theories predict the existence I.e., not only uA and uB must be substituted by and
of monopoles which, unlike elementary particles, are , respectively (the rst entity means spin up, the secsolitons (localized energy packets). The initial re- ond one spin down), but also the sign + by the sign,
13
11 Living things
Some organisms can detect magnetic elds, a phenomenon known as magnetoception. Magnetobiology
studies magnetic elds as a medical treatment; elds
naturally produced by an organism are known as
biomagnetism.
12 See also
Coercivity
Magnetic hysteresis
Magnetar
Magnetic bearing
Magnetic circuit
REFERENCES
Magnetic cooling
Magnetic eld viewing lm
Magnetic stirrer
Magnetic structure
Micromagnetism
Neodymium magnet
Plastic magnet
Rare-earth magnet
10
10.1
Units
SI
Spin wave
Spontaneous magnetization
Vibrating sample magnetometer
10.2
Other
Gravitomagnetism
13 References
[1] Fowler, Michael (1997). Historical Beginnings of Theories of Electricity and Magnetism. Retrieved 2008-0402.
[2] Vowles, Hugh P. (1932). Early Evolution of Power Engineering. Isis (University of Chicago Press) 17 (2): 412
420 [41920]. doi:10.1086/346662.
[3] Li Shu-hua, Origine de la Boussole 11. Aimant et Boussole, Isis, Vol. 45, No. 2. (Jul., 1954), p.175
[4] Li Shu-hua, Origine de la Boussole 11. Aimant et Boussole, Isis, Vol. 45, No. 2. (Jul., 1954), p.176
14
Further reading
15 External links
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16.1
16.2
Images
File:A_man_is_violently_rubbed_with_magnets._Coloured_lithograph_Wellcome_V0011767.jpg Source:
https://upload.
wikimedia.org/wikipedia/commons/b/b4/A_man_is_violently_rubbed_with_magnets._Coloured_lithograph_Wellcome_V0011767.jpg
16.3
Content license
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16.3
Content license